Patent Grant
10768135
This invention relates to a method and an apparatus for detecting concentration of an oxidizing gas, and more particularly to a method and an apparatus for detecting concentration of the trace oxidizing gas.
The concentration of oxidizing gases in the air, such as the concentration of nitrogen dioxide or ozone, is one of several indicators for assessing the degree of air pollution. The main sources of oxidizing gases in the air are vehicle exhaust and factory exhaust. Recent researches show that excessive concentrations of oxidizing gases in the air can cause adverse effects on the respiratory system of the human body, such as irritation of the respiratory tract and reduction of pulmonary function, and even worsen the conditions of chronic lung diseases such as asthma, chronic bronchitis and emphysema. Therefore, with the increasing emphasis on air pollution prevention and control, the requirement for real-time monitoring of the concentration of oxidizing gases in the air also increases accordingly.
Although the conventional oxidizing gas detecting apparatus has the advantages of high sensitivity and high accuracy, it has the disadvantages of bulky size, complex structure expensive price, and is not suitable for real-time monitoring of environmental gases. The commonly used real-time monitoring apparatus for environmental gases is a metal oxide semiconductor detector. The metal oxide semiconductor detector has the advantages of small size, low cost, and good weathering resistance, but it also has the disadvantage that the detecting result is easily interfered by the reducing gas. In addition, the commonly used metal oxide semiconductor detector needs a high temperature such as 200 degrees Celsius and above to perform the concentration detection for trace gases, resulting the interference of the reducing gas being more obvious. Therefore, in order to satisfy the increasing demand of real-time monitoring of the concentration of oxidizing gas, it is necessary to develop the oxidizing gas detecting apparatus which has the ability to detect concentration of the trace gases and the detection result is not easily affected by the concentration of the reducing gas.
This invention relates to a method and an apparatus for detecting concentration of an oxidizing gas, to satisfy the requirement of real-time monitoring of the concentration of trace oxidizing gas, and to solve the problem that the detection result is easily interfered by the reducing gas.
The method for detecting the concentration of the oxidizing gas according to this invention comprises: providing a gas detecting module with the gas detecting module comprising a metal oxide and a plurality of nanoconductors, wherein the plurality of nanoconductors are distributed in the metal oxide; performing an electroreduction reaction and a photoreduction reaction simultaneously to the metal oxide; stopping the electroreduction reaction and the photoreduction reaction to the metal oxide; applying a first pulse-width modulation signal for reading an reduction-state resistance of the reduced metal oxide; providing the oxidizing gas to the reduced metal oxide; performing a redox reaction by photo-catalyzing the oxidizing gas and the reduced metal oxide; applying a second pulse-width modulation signal for reading an oxidation-state resistance of the oxidized metal oxide; and calculating the concentration of the oxidizing gas according to a ratio of the oxidation-state resistance to the reduction-state resistance.
The apparatus for detecting the concentration of the oxidizing gas according to this invention comprises a gas detecting module comprising a metal oxide and a plurality of nanoconductors, wherein the plurality of nanoconductors are distributed in the metal oxide, and the metal oxide is configured to perform a redox reaction with the oxidizing gas; a light module comprising a photoreducing light and at least one photocatalytic light, wherein the photoreducing light is configured to irradiate and drive the metal oxide to be photoreduced, and said at least one photocatalytic light is configured to catalyze a reaction of the oxidizing gas with the reduced metal oxide so that the oxidizing gas is reduced; and a control module electrically connected to the gas detecting module and the light module, wherein the control module is configured to drive the metal oxide to be electroreduced and photoreduced in a constant voltage mode, and to detect a reduction-state resistance of the reduced metal oxide and an oxidation-state resistance of the oxidized metal oxide in a pulse-width modulation mode, wherein the reduction-state resistance and the oxidation-state resistance are configured to calculate a concentration of the oxidizing gas.
According to the method for detecting concentration of an oxidizing gas and apparatus thereof, by firstly performing an electroreduction reaction and a photoreduction reaction simultaneously to the metal oxide; then stopping the electroreduction reaction and the photoreduction reaction to the metal oxide; then applying a first pulse-width modulation signal for reading an reduction-state resistance of the reduced metal oxide; then providing the oxidizing gas to the reduced metal oxide; then performing a redox reaction by photo-catalyzing the oxidizing gas and the reduced metal oxide; then applying a second pulse-width modulation signal for reading an oxidation-state resistance of the oxidized metal oxide, the sensitivity of the method for detecting concentration of an oxidizing gas is improved. Moreover, through performing a redox reaction by photo-catalyzing the oxidizing gas and the reduced metal oxide, the detection result of the concentration of the oxidizing gas is not easily interfered by the reducing gas. In this way, the method for detecting concentration of an oxidizing gas and apparatus thereof as set forth above can satisfy the requirement of real-time monitoring of the concentration of trace oxidizing gas, and can solve the problem that the detection result is easily interfered by the reducing gas.
The above description of the summary of this invention and the description of the following embodiments are provided to illustrate and explain the spirit and principles of this invention, and to provide further explanation of the scope of this invention.
The detailed features and advantages of the invention will be described in detail in the following description, which is intended to enable any person having ordinary skill in the art to understand the technical aspects of the present invention and to practice it. In accordance with the teachings, claims and the drawings of the invention, any person having ordinary skill in the art is able to readily understand the objectives and advantages of the invention. The following embodiments illustrate the invention in further detail, but the scope of the invention is not limited by any point of view.
First, the apparatus for detecting concentration of an oxidizing gas according to an embodiment of the present invention will be described here, please refer to
The apparatus 1 for detecting concentration of the oxidizing gas comprises a gas detecting module 110, a light module 120, a control module 130 and a casing 140. The gas detecting module 110, the light module 120, and the control module 130 are disposed inside the casing 140. The gas detecting module 110 electrically connects to the light module 120 via the control module 130.
The gas detecting module 110 comprises a substrate 111, a metal oxide 112, a plurality of nanoconductors 113, a first electrode 114, a second electrode 115, and a nano-metal catalyst layer 116. The substrate 111 is adapted to carry the metal oxide 112, the substrate's material is such as ceramic, high-molecular material, or glass.
The metal oxide 112 is disposed on the substrate 111. The metal oxide 112 and the oxidizing gas perform a redox reaction when the metal oxide 112 contacts with the oxidizing gas. For example, when the metal oxide 112 contacts with the nitrogen dioxide, the metal oxide 112 and the nitrogen dioxide can perform the redox reaction as shown in chemical equation (1)
HyMO3-x+yNO2↔MO3-x+yH++yNO2− Equation (1)
During the redox reaction performing by the metal oxide 112 and the oxidizing gas. the proportion of reduced metal oxide in the entire metal oxide can increase by applying a voltage to the metal oxide 112 or light having a wavelength matched to the metal oxide energy gap.
The nanoconductors 113 is such as the nanocarbon material with sp2 hybrid orbital or the conductive high-molecular material. The nanocarbon material comprises carbon nanotube, graphene, and nano-fullerene/nano-onion. The conductive high-molecular material comprises polyacetylene, polythiophene (PT), polypyrrole (PPY), polyaniline (PANI), poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS), and 3-hexylthiophene (P3HT).
The first electrode 114 and the second electrode 115 are disposed on the substrate 111. The first electrode 114 and the second electrode 115 are respectively connected to two opposite sides of the metal oxide 112. The first electrode 114 and the second electrode 115 are configured to apply voltages to the metal oxide 112 for increasing the proportion of reduced metal oxide 112 (HyMOx) in the entire metal oxide 112. The first electrode 114 and the second electrode 115 are also configured to apply voltages to the metal oxide 112 for reading the resistance value of the metal oxide 112. The voltage applied by the first electrode 114 and the second electrode 115 is such as 5 to 10 volts when the metal oxide 112 is reduced.
In the apparatus 1 for detecting concentration of the oxidizing gas of this embodiment, the metal oxide 112 only electrically connects directly to the first electrode 114 and the second electrode 115. As set forth above, compared to the conventional apparatus for detecting a concentration of the oxidizing gas adopting two different sets of electrodes separately to apply voltages to the metal oxide to perform the electroreduction reaction and to read the resistance value of the metal oxide, the apparatus 1 for detecting concentration of the oxidizing gas of this embodiment has the advantages of simple structure, low manufacturing cost and easy miniaturization by using a set of electrodes for both electroreduction and resistance reading.
The nano-metal catalyst layer 116 is disposed on a surface far from the substrate 111 of the metal oxide 112. The nano-metal catalyst layer 116 is configured to catalyze the oxidizing gas and the metal oxide 112 to perform the redox reaction. The nano-metal catalyst layer 116 is such as the mixture of gold and silver, gold, silver or palladium. The gas detecting module 110 comprises the nano-metal catalyst layer 116, however, this is not a limitation of the present invention. In other embodiments, the gas detecting module 110 does not comprise the nano-metal catalyst layer 116.
The light module 120 comprises a photoreducing light 121 and two photocatalytic lights 122, 123. The photoreducing light 121 is configured to irradiate and drive the metal oxide 112 to be photoreduced. Two photocatalytic lights 122, 123 are configured to catalyze the oxidizing gas and the reduced metal oxide to perform the redox reaction so that the oxidizing gas will be reduced. The photoreducing light 121 is the light with a wavelength of 254 to 430 nanometers, for example, a ultraviolet light with a wavelength of 254 nanometers, a ultraviolet light with a wavelength of 365 nanometers, or a blue light. The wavelengths of the photocatalytic lights 122, 123 range from 550 to 950 nanometers, and two photocatalytic lights have different wavelengths, for example, one is a near-infrared light with a wavelength of 850 nanometers while another one is a visible light with a wavelength of 950 nanometers. In the apparatus 1 for detecting concentration of the oxidizing gas of this embodiment, the number of the photocatalytic lights are two, however, this number is not the limitation. In the apparatuses for detecting concentration of the oxidizing gas of other embodiments, the photocatalytic light is a composite light source that can emit the composite light with different wavelengths or a monochromatic light.
The control module 130 is, for example but not limited to, a data processing apparatus such as a computer, and the control module 130 comprises a pulse-width modulator 131 electrically connecting to the gas detecting module 110, a first voltage regulator 132, a second voltage regulator 133, and a controller 134 electrically connecting to the gas detecting module 110 and the light module 120. The control module 130 is configured to drive the metal oxide 112 to be electroreduced and photoreduced in a constant voltage mode, and to detect a reduction-state resistance of the reduced metal oxide and 112 an oxidation-state resistance of the oxidized metal oxide 112 in a pulse-width modulation mode. In detail, the gas detecting module 110 electrically connects to a power source P through the controller 134 in the constant voltage mode, and the controller 134 instructs the first voltage regulator 132 and the second voltage regulator 133 to maintain the voltages of the first electrode 114 and the second electrode 115 to perform the electroreduction of the metal oxide 112, meanwhile, the controller 134 instructs the photoreducing light 121 of the light module 120 to irradiate to perform the photoreduction of the metal oxide 112. The gas detecting module 110 electrically connects to the power source P through the controller 134 and the pulse-width modulator 131 in the pulse-width modulation mode. The controller 134 instructs the pulse-width modulator 131 to convert the voltage signal outputted by the power source P to the pulse-width modulation signals with a specified pulse width, so the reduction-state resistance of the reduced metal oxide 112 and the oxidation-state resistance of the oxidized metal oxide 112 can be read for multiple times. The ratio of the reduction-state resistance and the oxidation-state resistance is configured to calculate the concentration of the oxidizing gas.
The method for detecting concentration of an oxidizing gas will be described hereinafter. Please refer to
First, the execution of the step S101 is to provide the gas detecting module comprising the metal oxide and the nanoconductors. In this embodiment, the apparatus 1 for detecting concentration of an oxidizing gas will be provided in step S101, and said apparatus 1 for detecting concentration of an oxidizing gas comprises the required gas detecting module 110.
Next, the execution of the step S102 is to perform the electroreduction reaction and the photoreduction reaction simultaneously to the metal oxide 112 of the gas detecting module 110. In this embodiment, the control module 130 of the apparatus 1 for detecting concentration of an oxidizing gas simultaneously activates the first electrode 114 and the second electrode 115 of the gas detecting module 110, and the photoreducing light 121 of the light module 120. Meanwhile, the controller 134 of the control module 130 instructs the first voltage regulator 132 and the second voltage regulator 133 to maintain the voltages of the first electrode 114 and the second electrode 115 in a constant value ranging from 5 to 10 volts (such as the voltages keeps at 10V), so that the gas detecting module 110 is in a constant-voltage state. Maintaining the voltages of the first electrode 114 and the second electrode 115 at 5 volts to 10 volts helps to enhance the efficiency of reducing the metal oxide 112.
As shown in
Next, the execution of the step S103 is to stop performing the electroreduction reaction and the photoreduction reaction to the metal oxide 112. In this embodiment, the control module 130 turns off the first electrode 114, the second electrode 115, and the photoreducing light 121. In detail, the reaction rate of the electroreduction is usually slower than that of the photoreduction, therefore in this embodiment, the photoreduction reaction to the metal oxide 112 will be stopped first, then the electroreduction reaction to the metal oxide 112 will be stopped after 0.1 seconds to 5 minutes.
Next, the execution of the step S104 is to read the reduction-state resistance Rair of the reduced metal oxide 112 by applying the first pulse-width modulation signal W1. As shown in
Next, the execution of the step S105 is to provide the oxidizing gas to the reduced metal oxide 112. In this embodiment, the oxidizing gas is introduced from the opening of the side wall of the casing 140 so that the oxidizing gas diffuses inside the casing 140 and contacts with the metal oxide 112. The oxidizing gas is, for example but not limited to, nitrogen dioxide or ozone.
Next, the execution of the step S106 is to photo-catalyze the oxidizing gas and the reduced metal oxide 112 for performing the redox reaction. As shown in
Next, the execution of the step S107 is to apply a second pulse-width modulation signal W2 for reading an oxidation-state resistance Rs of the oxidized metal oxide 112. As shown in
Next, the execution of the step S108 is to calculate the concentration of the oxidizing gas according to the oxidation-state resistance Rs and the reduction-state resistance Rair. In this embodiment, the ratio of the oxidation-state resistance Rs and the reduction-state resistance Rair can be outputted to a computer (not depicted) and the ratio is compared with a database stored in the computer to obtain the concentration of the oxidizing gas.
Instead of using a heating method to react a metal oxide 112 with an oxidizing gas, the method for detecting concentration of an oxidizing gas in this embodiment reduces and oxidizes the metal oxide 112 by photoreduction and photocatalytic method, therefore, step S106 can be performed at a room temperature so that the detection result of the concentration of the oxidizing gas is not easily interfered by the reducing gas.
In the step S102, performing the photoreduction reaction by the photoreducing light 121 with a wavelength of 254 nanometers to 430 nanometers can efficiently reduce the metal oxide 112. Please refer to
As shown in
In the step S106, the metal oxide 112 can be efficiently oxidized by performing the photocatalysis with the two-color composite light. Please refer to
As shown in
In the step S106, performing the photocatalysis with the light having a wavelength of 550 nanometers to 950 nanometers can efficiently oxidize the metal oxide 112. Please refer to
As shown in
The method for detecting concentration of an oxidizing gas and the apparatus for detecting concentration of an oxidizing gas of the present invention have a high sensibility to apply for the detection of the oxidizing gas with low concentration. Please refer to
The method for detecting concentration of an oxidizing gas according to the present invention adopts photocatalysis to oxidize the metal oxide, so the detection result of the concentration of the oxidizing gas is not easily interfered by the reducing gas. Please refer to
The apparatus for detecting concentration of an oxidizing gas comprises a nano-metal catalyst layer configured to catalyze the oxidizing gas and the metal oxide to perform the redox reaction, further improving the efficiency of the redox reaction. Please refer to
As shown in
The nano-metal catalyst layer of the apparatus for detecting concentration of an oxidizing gas according to an embodiment of the present invention is a mixture of gold/silver, with better catalytic effect than gold, silver or palladium. Please refer to
As shown in
As set forth above, according to the method for detecting concentration of an oxidizing gas and the apparatus thereof, by firstly performing an electroreduction reaction and a photoreduction reaction simultaneously to the metal oxide; then stopping the electroreduction reaction and the photoreduction reaction to the metal oxide; then applying a first pulse-width modulation signal for reading an reduction-state resistance of the reduced metal oxide; then providing the oxidizing gas to the reduced metal oxide; then performing a redox reaction by photo-catalyzing the oxidizing gas and the reduced metal oxide; then applying a second pulse-width modulation signal for reading an oxidation-state resistance of the oxidized metal oxide, the sensitivity of the method for detecting concentration of an oxidizing gas is improved. Moreover, through performing a redox reaction by photo-catalyzing the oxidizing gas and the reduced metal oxide, the detection result of the concentration of the oxidizing gas is not easily interfered by the reducing gas. In this way, the method for detecting concentration of an oxidizing gas and apparatus thereof as set forth above can satisfy the requirement of real-time monitoring of the concentration of trace oxidizing gas, and can solve the problem that the detection result is easily interfered by the reducing gas.
Although the aforementioned embodiments of this invention have been described above, this invention is not limited thereto. The amendment and the retouch, which do not depart from the spirit and scope of this invention, should fall within the scope of protection of this invention. For the scope of protection defined by this invention, please refer to the attached claims.
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| Number | Date | Country | |
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| 20190195823 A1 | Jun 2019 | US |
