Various embodiments of the present invention relate to frames useful in packaging assemblies for retaining a product in a box, and to the packaging assemblies incorporating those frames, for example, packaging assemblies used to protect a packaged product during shipment by retaining the product within a box.
Protective packaging structures may be used to help protect a product during transport, for example, from physical shock, dust, and other contaminants. For example, a product may be enclosed in a box with additional packing materials (e.g., crumpled paper, air-filled plastic cushions, molded foam) to restrain the product movement inside the box and to cushion the product.
One type of packaging assembly is known as “suspension packaging.” In typical suspension packaging, the packaged product is suspended between two sheets each attached to opposing frames sized to fit within a corresponding box. Another type of packaging assembly is known as retention packaging. In typical retention packaging, a product is retained between a sheet and a rigid backing frame to which the sheet is attached. Examples of retention and suspension packaging are described in more detail in U.S. Pat. Nos. 4,852,743; 4,923,065; 5,071,009; 5,287,968; 5,388,701; 5,678,695; 5,893,462; 6,010,006; 6,148,590; 6,148,591; 6,289,655; 6,302,274; and 6,311,844, each of which is incorporated herein in its entirety by reference.
While existing retention structures provide a level of protection for the packaged object, there is room for improvement, for example, by enhancing the protective qualities and/or reducing the cost of the structure.
A frame of the presently disclosed subject matter is useful in a packaging assembly for retaining a product within a box. The frame includes a panel and a sheet. The panel has a panel length from the left edge to the right edge of the panel. The panel length is greater than the box length. The panel has a panel width from the front edge to the rear edge of the panel. The panel width being greater than the box width. The panel defines a left slot configured to receive the left closure flap of the box and a right slot configured to receive the right closure flap of the box. The panel includes a left panel flap extending from the left slot to the left edge of the panel, a right panel flap extending from the right slot to the right edge of the panel,
a front panel flap extending from the left panel flap to the right panel flap; and a rear panel flap extending from the left panel flap to the right panel flap. The left panel flap is foldably connected to the front panel flap and to the rear panel flap. The right panel flap is foldably connected to the front panel flap and the rear panel flap. The panel defines a panel opening circumscribed by the left, right, front, and rear panel flaps. The sheet is attached to the front panel flap and the rear panel flap and extends over the panel opening.
A packaging assembly for retaining a product includes a box and the above-described frame. The frame is positionable in an installed position having the left closure flap of the box extending through the left slot of the panel and the right closure flap of the box extending through the right slot of the panel. The packaging assembly is positionable in a retained position having the frame in the installed position, as well as the left panel flap and the left closure flap folded inwardly to place the left panel flap on top of the left closure flap, the right panel flap and the right closure flap folded inwardly to place to the right panel flap on top of the right closure flap, the front panel flap folded inwardly on top of the left panel flap and the right panel flap, the rear panel flap folded inwardly on top of the left panel flap and the right panel flap, the front closure flap folded inwardly on top of the front panel flap, and optionally the rear closure flap folded inwardly on top of the rear panel flap. A product placed on the sheet is retainable between the sheet and one or more of the left, right, front, and rear closure flaps.
These and other objects, advantages, and features of the presently disclosed subject matter will be more readily understood and appreciated by reference to the detailed description and the drawings.
Various aspects of the subject matter disclosed herein are described with reference to the drawings. For purposes of simplicity, like numerals may be used to refer to like, similar, or corresponding elements of the various drawings. The drawings and detailed description are not intended to limit the claimed subject matter to the particular form disclosed. Rather, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the claimed subject matter.
The presently disclosed subject matter includes frames, for example frame 14 (
Frames of the various disclosed embodiments (e.g., frame 14 of
For example, in embodiments of the presently disclosed subject matter, frame 14 and frame 114 comprise a panel 16 having a panel length L1 measured from the outermost left edge 18 to the outermost right edge 20 of the panel. (
Frames 14 and 114 comprise panel 16. (
Panel 16 comprises a left panel flap 30 extending from the left slot 26 to the left edge 18 of the panel. The panel 16 comprises a right panel flap 32 extending from the right slot 28 to the right edge 20 of the panel. Front panel flap 34 extends from the left panel flap 30 to the right panel flap 32. Rear panel flap 36 extends from the left panel flap 30 to the right panel flap 32. (See, e.g.,
The left panel flap 30 is foldably connected to the front panel flap 34 and to the rear panel flap 36. The right panel flap 32 is foldably connected to the front panel flap 34 and to the rear panel flap 36. The left panel flap 30 may be delineated from the front panel flap 34 by a first fold line 46 that is aligned with left slot 26. The left panel flap 30 may also be delineated from the rear panel flap 36 by second fold line 48 aligned with left slot 26. Right panel flap 32 may be delineated from front panel flap 34 by third fold line 50 aligned with right slot 28. Right panel flap 32 may also be delineated from rear panel flap 36 by fourth fold line 52 aligned with right slot 28. (See, e.g.,
A “fold line” as used herein (and as depicted in the drawings as a broken line, for example as in
The left panel flap 30 may include a fifth fold line 54 and a sixth fold line 56, which extend generally perpendicularly from the left slot 26. The fifth and sixth fold lines delineate the left panel flap 30 into a left flap intermediate portion 58 between the fifth and sixth fold lines and a left front corner piece 60 and a left rear corner piece 62 on opposing ends of the left flap intermediate portion 58. (
The right panel flap 32 may include a seventh fold line 64 and an eighth fold line 66, which extend generally perpendicularly from the right slot 28. The seventh and eighth fold lines delineate the right panel flap 32 into a right flap intermediate portion 68 between the seventh and eighth fold lines and a right front corner piece 70 and a right rear corner piece 72 on opposing ends of the right flap intermediate portion 68. (
Panel 16 defines a panel opening 38 circumscribed by the left, right, front, and rear panel flaps 30, 32, 34, and 36. In the embodiments illustrated in
The panel 16 may comprise front door 74 foldably connected to the front panel flap 34 and extending into panel opening 38. The front door 74 may be foldably connected to the front panel flap 34 along a front door fold line 78 along a front panel flap edge 80 adjacent the panel opening 38. The panel 16 may also comprise rear door 76 foldably connected to the rear panel flap 36 and extending into panel opening 38. The rear door 76 may be foldably connected to the rear panel flap 36 along a rear door fold line 82 along a rear panel flap edge 84 adjacent the panel opening 38. (See, e.g.,
In the frame embodiment 114 of
Continuing with the frame 114 of
Continuing with
This configuration for the lengths L2, L3, L5, and L7 of the left and right panel flaps and the front and rear doors may permit, for example, the left panel flap 30 and the right panel flap 32 to be folded inwardly without being blocked while the front door 174 and the rear door 176 are in an upward orientation. (See, e.g.,
The front door 174 may comprise a left door-tab portion 94 at the left edge 96 of the front door distal to the front door fold line 178 and a right door-tab portion 98 at the right edge 100 of the front door distal to the front door fold line 178. The rear door 176 may comprise a left door-tab portion 102 at the left edge 104 of the rear door distal to the rear door fold line 182 and a right door-tab portion 106 at the right edge 108 of the rear door distal to the rear door fold line 182. A front tab spacing length L8 taken from the left edge 96 to the right edge 100 may be greater than the front door length L5. Similarly, a rear tab spacing length L9 taken from the left edge 102 to the right edge 108 may be greater than the rear door length L7. (
This configuration for the lengths L8 and L9 relative the front and rear door lengths L5 and L7 may permit the front door 174 and rear door 176, when lifted upwardly, to extend beyond the distance between the upwardly-oriented left and right closure flaps 252, 256 of the box 12, such that the front and rear doors may be held in an open or upward orientation, as illustrated in
The front door 174 defines a left front cutaway opening 226 at the left extent of the front door 174. The area of the left front cutaway opening 226 may be defined as the area within the panel opening 38 that is also within the border defined by the left extent of the front door 174, the front panel flap 34, and the left slot 26. The area of the left front cutaway opening 226 may be at least as large as the area of the left front corner piece 60.
The front door 174 defines a right front cutaway opening 228 at the right extent of the front door 174. The area of the right front cutaway opening 226 may be defined as the area within the panel opening 38 that is also within the border defined by the right extent of the front door 174, the front panel flap 34, and the right slot 28. The area of the right front cutaway opening 228 may be at least as large as the area of the right front corner piece 70.
The rear door 176 defines a left rear cutaway opening 230 at the left extent of the rear door 176. The area of the left rear cutaway opening 230 may be defined as the area within the panel opening 38 that is also within the border defined by the left extent of the rear door 176, the rear panel flap 36, and the left slot 26. The area of the left front cutaway opening 230 may be at least as large as the area of the left rear corner piece 62.
The rear door 176 defines a right rear cutaway opening 232 at the right extent of the rear door 176. The area of the right rear cutaway opening 232 may be defined as the area within the panel opening 38 that is within the border defined by the right extent of the rear door 176, the rear panel flap 36, and the right slot 28. The area of the right rear cutaway opening 232 may be at least as large as the area of the right rear corner piece 72.
At least one edge of these cutaway openings 226, 228, 230, 232 may have an arcuate configuration, which may be configured and sized to accommodate the closing of the left and right panel flaps while the front and rear doors are in an upward orientation, as shown in
The front and rear doors may be of generally equal size, for example, as illustrated in
Either or both of the front and rear doors may define one or more apertures, indents, or cutaway portions as finger holds, for example, finger holds 234 of
The panel may also comprise one or more of a front left panel tab 210, a front right panel tab 212, a left rear panel tab 214, and a right rear panel tab 216. (
Panel 16, and any of the panels and/or boxes of the various embodiments described herein, may comprise a substantially rigid, lightweight, foldable material, for example, panel 16, or any of the portions of panel 16 described herein, may be formed of one or more of any of the following materials: cellulosic-based materials (e.g., cardboard, corrugated cardboard, paperboard, chipboard), plastic, and compressed foam. For example, panel 16 may comprise corrugated cardboard, for example, any of single-wall B-flute, C-flute, and/or E-flute corrugated cardboard, B/C double-wall corrugated cardboard, and/or E/B double-wall corrugated cardboard; and for example having the minimum bursting strength (per Mullen Bursting Test) of any of non-test, 150, 175, 200, 250, 275, and 350 psi. The panel, and any of the panels and frames of the various embodiments described herein, may have an average thickness of, for example, at most, and/or at least, any of the following thicknesses: 0.03, 0.06, 0.12, 0.18, 0.25, 0.3, 0.4, and 0.5 inches.
In an embodiment, frame 14 comprises sheet 40 attached to the front panel flap 34 and the rear panel flap 36 of panel 16, and extending over (i.e., across) the panel opening 38. In the drawings, sheet 38 is shown completely covering panel opening 38; in alternative embodiments the sheet may extend over the panel opening and only partially cover the panel opening (not illustrated). The sheet 40 may be extended over the panel opening 38 such that the sheet does not cover either or both of the left and right slots 26, 28. Further, the sheet may extend over the panel opening such that it only partially covers the panel opening. (Not illustrated.) Also, one or more sheets, such as a total of any of one, two, three, or four may be used to extend over the panel opening and attach to the front and rear panel flaps.
Sheet 40 may be attached to panel 16, for example to the front panel flap 34 and the rear panel flap 36, by any of the ways described herein. In the drawings, sheet 40 is attached to panel 16 along attachment zones 42 comprising adhesive 44. As shown, an attachment zone 42 may extend continuously along the length of front panel flap 34 and rear panel flap 36. However, attachment zones 42 may alternatively extend discontinuously or periodically as shown in
In the drawings, sheet 40 is shown attached to the panel 16 by adhering with adhesive 44; however, the sheet may be attached to the panel, for example, by one or more of any of the following: adhering (e.g., with hot melt adhesive), gluing, heat welding, ultrasonic welding, stapling, tacking, fastening, clipping (see, e.g., U.S. Pat. No. 5,694,744 to Jones, which is incorporated herein in its entirety by reference), tab/slot engagement (see, e.g., U.S. Pat. No. 6,073,761 to Jones, which is incorporated herein in its entirety by reference), anchoring, retaining and/or securing (see, e.g., U.S. Patent Application Publication 2004/0108239 A1 to McDonald et al. published Jun. 10, 2004, which is incorporated herein in its entirety by reference, and which discloses a sleeve having pockets or pouches for receiving a flap as shown in
Useful types of adhesives for attaching sheets to panels are known to those of skill in the art, and as those of ordinary skill know depend on the composition of the materials to be adhered. For example, a polyurethane-based sheet may be adhered with a polyurethane-based adhesive, such as a water-borne aliphatic polyurethane dispersion.
Sheet 40, and any of the sheets of the various embodiments described herein, may comprise any of the materials, compositions, and polymers set forth herein with respect to sheets, and may have any thickness, properties, treatments, additives, and other characteristics (e.g., flexibility, elasticity, optics, strength, elastic recovery, transparency, load tear resistance, puncture resistance) as set forth herein with respect to sheets.
Sheet 40 may have a composition and thickness providing acceptable performance properties (e.g., flexibility, elasticity, optics, strength) for the given packaging application of expected use. The sheet may have a thickness of at most any of the following: 10 mils, 6 mils, 5 mils, 4 mils, 3 mils, 2 mils, 1.5 mils, and 1 mil. (A “mil” is equal to 0.001 inch.) The sheet may also have a thickness of at least any of the following: 0.5 mils, 1 mil, 1.5 mils, 2 mils, and 3 mils.
The sheet may have an elastic recovery in either or both of the transverse and longitudinal directions of at least any of the following values: 60%, 65%, 70%, 75%, 80%, and 85%, measured according to ASTM D5459 at 100% strain, 30 seconds relaxation time, and 60 second recovery time.
The sheet may have a maximum load tear resistance in either or both of the transverse and longitudinal directions of at least any of the following values: 400, 450, 500, 550, and 600 grams force, measured according to ASTM D1004.
The sheet may have a slow puncture maximum load of at least any of the following values: 4, 4.5, 5, 5.5, 6, 6.5, and 7 pounds force, measured according to ASTM F1306 using a crosshead speed of 5 inches per minute.
The sheet may have a Young's modulus sufficient to withstand the expected handling and use conditions, yet may provide a “soft” feel that may be desirable for a packaging application. The sheet may have a Young's modulus of at least any of the following values: 2,000; 2,500; 3,000; 3,500; and 4,000 pounds/square inch. The sheet may have a Young's modulus of no more than about any of the following values: 8,000; 10,000; 15,000; 20,000; 30,000; and 40,000 pounds/square inch. The Young's modulus is measured in accordance with ASTM D882, measured at a temperature of 73° F.
The sheet may be transparent so that the packaged article (e.g., product 28) may be visible through the sheet. “Transparent” as used herein means that the material transmits incident light with negligible scattering and little absorption, enabling objects to be seen clearly through the material under typical unaided viewing conditions (i.e., the expected use conditions of the material). The transparency (i.e., clarity) of the retention sheet may be at least any of the following values: 65%, 70%, 75%, 80%, 85%, and 90%, measured in accordance with ASTM D1746.
The sheet may have a heat-shrink attribute. For example, the sheet may have any of a free shrink in at least one direction (i.e., machine or transverse directions), in each of at least two directions (i.e., machine and transverse directions), measured at any of 160° F. and 180° F. of at least any of the following: 7%, 10%, 15%, 20%, 25%, 30%, 40%, 50%, 55%, 60%, and 65%. Alternatively, the sheet may be non-heat shrinkable (i.e., has a total free shrink of less than 5% measured at 160° F.). Unless otherwise indicated, each reference to free shrink in this application means a free shrink determined by measuring the percent dimensional change in a 10 cm×10 cm specimen when subjected to selected heat (i.e., at a certain temperature exposure) according to ASTM D 2732.
The sheet may comprise, for example, one or more fabrics, such as one or more of the following: wovens, knits, nonwovens, and openwork meshes (e.g., netting), spandex, including Lycra® brand spandex, and elastic fabrics.
The sheet may comprise one or more polymers, for example, one or more of any of the following polymers: thermoplastic polymers, polyolefins, polyethylene homopolymers (e.g., low density polyethylene), polyethylene copolymers (e.g., ethylene/alpha-olefin copolymers (“EAOs”), ethylene/unsaturated ester copolymers, and ethylene/(meth)acrylic acid), polypropylene homopolymers, polypropylene copolymers, polyvinyl chloride, various types of natural or synthetic rubber (e.g., styrene-butadiene rubber, polybutadiene, neoprene rubber, polyisoprene rubber, ethylene-propylene diene monomer (EPDM) rubber, polysiloxane, nitrile rubber, and butyl rubber), and polyurethane (i.e., any one or more of polyurethane, polyether polyurethane, polyester polyurethane, and polycarbonate polyurethane, any of which may be aliphatic and/or aromatic). The sheet may also comprise thermoplastic polyolefin elastomers (TPOs), which are two-component elastomer systems comprising an elastomer (such as EPDM) finely dispersed in a thermoplastic polyolefin (such as polypropylene or polyethylene). “Copolymer” as used in this application means a polymer derived from two or more types of monomers, and includes terpolymers, etc.
A sheet comprising polyolefin (e.g., polyethylene), polyvinyl chloride, and/or polyurethane may be useful for lightweight applications, for example, where a sheet thickness of from 2 to 4 mils may be desirable. A sheet comprising polyurethane may provide desirable elastomeric, puncture resistance, temperature resistance, and tackiness characteristics.
The sheet may comprise effective amounts of one or more of tackifiers, antiblocking agents, and slip agents—or may be essentially free of any of these components. Tackifiers, antiblocking agents, and slip agents, and their effective amounts, are known to those of ordinary skill in the art.
The sheet may be manufactured by thermoplastic film-forming processes known in the art (e.g., tubular or blown-film extrusion, coextrusion, extrusion coating, flat or cast film extrusion). A combination of these processes may also be employed.
At least one side of the sheet may be corona and/or plasma treated to change the surface energy of the sheet, for example, to increase the ability of the sheet to adhere to a panel or frame.
Films that may be useful as sheets are described in U.S. Pat. No. 6,913,147 issued Jul. 5, 2005 and entitled “Packaging Structure Having a Frame and Film,” which is incorporated herein in its entirety by reference.
A packaging assembly may comprise any of the various embodiments of frames of the disclosed subject matter herein and a box 12.
Box 12 (as illustrated in the drawings, e.g.,
Box 12 comprises a left wall 250 and a left closure flap 252 foldably connected to the top of the left wall 252. Right wall 254 opposes the left wall 252. A right closure flap 256 is foldably connected to the top of the right wall 254. A front wall 260 extends from the left wall 250 to the right wall 254. Front closure flap 262 is foldably connected to the top of the front wall 260. Rear wall 264 opposes the front wall 260 and extends from the left wall 250 to the right wall 254. Rear closure flap 266 is foldably connected to the top of the rear wall 264. Rear closure flap 266 may be optional, that is may not be present, for example in the case where standard tuck end (STE) or reverse tuck end (RTE) boxes (not illustrated) are used.
Box 12 has a given box length L10 from the left to the right, and a given box width W2 from the front to the rear of the box, as illustrated in
The box may be configured such that the front and rear walls of the box have a different height than the left and right walls of the box. For example, as illustrated with box 112 of
For the packaging assemblies of the disclosed subject matter, the frame 14, 114 is positionable (i.e., is configured relative the box to be positioned) in an installed position having the left closure flap 252 of the box extending through the left slot 26 of the panel and the right closure flap 256 of the box extending through the right slot 28 of the panel.
The packaging assembly, for example, any of packaging assembly 10 (
the left panel flap 30 and the left closure flap 252 are folded inwardly to place the left panel flap on top of the left closure flap (
the right panel flap 32 and the right closure flap 256 are folded inwardly to place to the right panel flap on top of the right closure flap (
the front panel flap is folded inwardly on top of the left panel flap and the right panel flap (
the rear panel flap is folded inwardly on top of the left panel flap and the right panel flap (
the front closure flap is folded inwardly on top of the front panel flap (
the optional rear closure flap (if present) is folded inwardly on top of the rear panel flap (
When a packaging assembly of any of the disclosed embodiments is in the retained position, a product 268 (for example, a book or an electronic device) that has been placed on the sheet 40 is retainable between the sheet 40 and one or more of the left, right, front, and rear closure flaps of the box. For example, in the retained position a product placed on the sheet 40 may be retainable between the sheet 40 and at least one of the front and rear doors.
Beyond this basic description above of the retained position, there are some variations and/or additional detail retained positions of the presently disclosed subject matter, as set forth below.
By way of example, a packaging assembly in the retained position may have the left panel flap 30 folded along the first fold line 46, the second fold line 48, and the left slot 26 to place the left panel flap 30 on top of an inwardly-folded left closure flap 252; and have the right panel flap 32 is folded along the third fold line 50, the fourth fold line 52, and the right slot 28 to place the right panel flap 32 on top of the inwardly-folded right closure flap 256, also as shown in
Further, a packaging assembly in the retained position may have the left panel flap 30 folded along the fifth fold line 54 and the right panel flap 32 folded along the seventh fold line 64 to place (a) the left front corner piece 60 between the left flap intermediate portion 58 and the front panel flap 34 and (b) the right front corner piece 70 between the right flap intermediate portion 68 and the front panel flap 34. (
A packaging assembly when placed in the retained position may have a first portion 270 of the sheet 40 between the front panel flap 34 and one or more of the left closure flap 252 and the right closure flap 256; and a second portion 272 of the sheet 40 between the rear panel flap 36 and one or more of the left closure flap 252 and the right closure flap 256. (See
A packaging assembly in the retained position may have a first portion 274 of the sheet 40 between the front panel flap 34 and the front closure flap 262; and a second portion 276 of the sheet 40 between the rear panel flap 36 and the rear closure flap 266. (
A packaging assembly 10 in the retained position may have the frame in the installed position such that the front and rear doors 74, 76 extend beneath the sheet 40. (See
A packaging assembly 210 in the retained position may have the front door 174 extending between (i) the front closure flap 262 and (ii) the left and right closure flaps 252, 256; and the rear door 176 extending between (iii) the rear closure flap 266 and (iv) the left and right closure flaps 252, 256. (See
After placement of any of the packaging assemblies of the presently disclosed subject matter in the retained position (e.g., such that the box has been closed), the box may be secured to maintain the packaging assembly in the retained position (and, e.g., the box in the closed configuration). For example, the box may be taped, stapled, or otherwise secured closed by methods known in the art.
By using types of machinery well known to those of skill in the field, panel 16 may be cut to the desired shapes and provided with slots, openings, fold lines or lines of detachability, using the known types of machinery, for example, to slit, crease, crimp, emboss, perforate, scored, or otherwise weaken the panel in desired regions. Adhesive 44 may be applied to the panel 16 in selected areas, for example, the attachment zones 42. The sheet 40 may be attached to the panel 16 to make the frame by laminating or adhering the sheet with adhesive 44 to the panel. The sheet material may be provided in roll form, unrolled, and then cut to the desired length and width either before or after attachment to the panel. The packaging assembly comprising the frame and box may be provided or shipped having both configured in a lay flat arrangement. Such configurations may facilitate the provision of multiple frames in a convenient stacked or bundled arrangement (not illustrated). Box 12 may also be provided in a lay-flat configuration, and for example, finally assemble completed after shipment to the location for packaging.
A product 268 may be packaged using any of the packaging assemblies disclosed herein. First the packaging assembly comprising a box and frame is provided. The frame may then be positioned in the installed position relative the box. A product 268 is placed on the sheet 40. The packaging assembly is positioned in the retained position, as described herein. As a result, the product 268 is retained between the sheet 40 and one or more of the left, right, front, and rear closure flaps.
Using the embodiment of
Using the embodiment of
Using the embodiment of
As part of the step of lifting the front and rear doors, the lifting step may lift the front and rear doors to extend beyond the distance between the left and right closure flaps, such that the front and rear doors are held in an upward orientation, as shown in
The folding of the left closure flap and the left panel flap may be conducted to occur simultaneously, and further the folding of the right closure flap and the right panel flap may also be conducted to occur simultaneously. The dimensions and/or configuration for the cutaway openings 226, 228, 230, 232 (e.g., having a arcuate configuration) and the lengths L2, L3, L5 and L7 of the left and right panel flaps and the front and rear doors (e.g., as shown in
Also, the folding of the front door, the front panel flap, and the front closure flap may be conducted to occur simultaneously; and the folding of the rear door, the rear panel flap, and the rear closure flap may be conducted to occur simultaneously.
Any numerical value ranges recited herein include all values from the lower value to the upper value in increments of one unit provided that there is a separation of at least 2 units between any lower value and any higher value. As an example, if it is stated that the amount of a component or a value of a process variable (e.g., temperature, pressure, time) may range from any of 1 to 90, 20 to 80, or 30 to 70, or be any of at least 1, 20, or 30 and/or at most 90, 80, or 70, then it is intended that values such as 15 to 85, 22 to 68, 43 to 51, and 30 to 32, as well as at least 15, at least 22, and at most 32, are expressly enumerated in this specification. For values that are less than one, one unit is considered to be 0.0001, 0.001, 0.01 or 0.1 as appropriate. These are only examples of what is specifically intended and all possible combinations of numerical values between the lowest value and the highest value enumerated are to be considered to be expressly stated in this application in a similar manner.
The above descriptions are those of preferred embodiments of the invention. Various alterations and changes can be made without departing from the spirit and broader aspects of the invention as defined in the claims, which are to be interpreted in accordance with the principles of patent law, including the doctrine of equivalents. Except in the claims and the specific examples, or where otherwise expressly indicated, all numerical quantities in this description indicating amounts of material, reaction conditions, use conditions, molecular weights, and/or number of carbon atoms, and the like, are to be understood as modified by the word “about” in describing the broadest scope of the invention. Any reference to an item in the disclosure or to an element in the claim in the singular using the articles “a,” “an,” “the,” or “said” is not to be construed as limiting the item or element to the singular unless expressly so stated. The definitions and disclosures set forth in the present Application control over any inconsistent definitions and disclosures that may exist in an incorporated reference. All references to ASTM tests are to the most recent, currently approved, and published version of the ASTM test identified, as of the priority filing date of this application. Each such published ASTM test method is incorporated herein in its entirety by this reference.
Filing Document | Filing Date | Country | Kind |
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PCT/US2015/049660 | 9/11/2015 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2016/040787 | 3/17/2016 | WO | A |
Number | Name | Date | Kind |
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5893462 | Ridgeway | Apr 1999 | A |
5894932 | Harding | Apr 1999 | A |
5967327 | Jones | Oct 1999 | A |
6302274 | Ridgeway | Oct 2001 | B1 |
7882956 | McDonald | Feb 2011 | B2 |
8016112 | Kasiwabara | Sep 2011 | B2 |
8499937 | McDonald et al. | Aug 2013 | B2 |
8714357 | Ridgeway | May 2014 | B2 |
20070095711 | Thompson | May 2007 | A1 |
20130233752 | Hammerschmidt | Sep 2013 | A1 |
Entry |
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Written Opinion of the International Searching Authority from the European Patent Office. dated Sep. 12, 2015. |
International Search Report from the European Patent Office. dated Sep. 12, 2015. |
Number | Date | Country | |
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20170247162 A1 | Aug 2017 | US |
Number | Date | Country | |
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62049048 | Sep 2014 | US |