The present invention relates to a recycling technique for a packaging container.
In recent years, the recycling techniques capable of reducing the amount of waste have attracted attention. Patent Literature 1 discloses a recycling technique for a packaging container containing plastic and metal. In this technique, the packaging container is heated to melt the metal and burn the plastic. This makes it possible to recover the metal contained in the packaging container.
Patent Literature 1: Japanese Patent Application Laid-Open No. Hei 05-507669
However, in the recycling technique described above, an environmental load is given due to CO2 generated by burning of the plastic, and the like. The inventors of the present application have conceived that, in the packaging container containing plastic and metal as described above, separating and recovering not only metal but also plastic to be reusable can further reduce the environmental load.
An object of the present invention relates to a technique for improving recyclability of a packaging container having gas barrier property. Solution to Problem
A laminated sheet according to an embodiment of the present invention is used for manufacturing a packaging container.
The laminated sheet comprises a pair of plastic sheets, a barrier sheet, a barrier region, an easily peelable region, and a fixing region. The barrier sheet has flexibility and is disposed between the pair of plastic sheets.
In the barrier region, the pair of plastic sheets and the barrier sheet overlap with each other.
The easily peelable region is provided in the barrier region.
The fixing region is located in a circumference of the easily peelable region. In the fixing region, the pair of plastic sheets are fixed to each other directly and/or via the barrier sheet.
A peel strength between the pair of plastic sheets and the barrier sheet in the easily peelable region is smaller than a direct peel strength between the pair of plastic sheets and/or a peel strength between the pair of plastic sheets via the barrier sheet in the fixing region.
According to the present invention, it is possible to improve recyclability of a packaging container having gas barrier property.
Hereinafter, embodiments of the present invention will be described with reference to the drawings. Note that, in this specification and drawings, substantially the same components will be denoted by the same reference symbols, and a repetitive description thereof will be omitted. Further, expressions on the vertical and horizontal directions used in this specification represent directions along the plane of each drawing.
[Configuration of Packaging Container 10]
A packaging container 10 according to this embodiment has a planar shape of a rectangle having four sides respectively located in the vertical and horizontal directions as shown in
As shown in
Each of the plastic sheets 21a and 21b is formed as a base material having flexibility. As a resin material forming the plastic sheets 21a and 21b, polyethylene or polypropylene is preferably used. In addition to them, for example, other polyolefin-based resins, acrylic resins, vinyl chloride-based resins, polycarbonate-based resins, polystyrene-based resins, ethylene-vinyl alcohol copolymer-based resins, polyimide-based resins, and the like can be used.
From the viewpoint of recyclability, each of the plastic sheets 21a and 21b is preferably formed as a single-layer sheet formed of a single kind of resin material. Note that each of the plastic sheets 21a and 21b may be formed of a multilayer sheet containing a plurality of kinds of sheets formed of polyethylene, ethylene-vinyl alcohol copolymers, PET, polyamide, and the like on the basis of the requests for strength, bonding property, appearance, and the like other than the recyclability. Also in such a configuration, it is possible to enhance recyclability by forming a multilayer sheet by combining only sheets formed of resin materials having a common system (e.g., polyolefin-based, or polyester-based).
The barrier sheet 22 is a sheet member having gas barrier property capable of blocking water vapor, oxygen, and the like. The barrier sheet 22 is of a non-polymer type, which is formed of a material other than a polymer material (non-polymer material), and has flexibility by which it is flexibly deformable together with the plastic sheets 21a and 21b. As the barrier sheet 22, for example, a metal sheet formed of a metal material, a stone film, or the like can be used. As the metal material for forming the barrier sheet 22, aluminum or an alloy thereof is preferably used, and in addition thereto, for example, copper, titanium, or the like can be used. In the barrier sheet 22, it is preferable that the oxygen permeability is smaller than 1 cc/m2dayatm and the water vapor permeability is smaller than 1 g/m2 day as a reference of the gas barrier property.
The thickness of each of the sheet portions 11a and 11b is preferably 25 μm or more and 1200 μm or less. The thickness of each of the plastic sheets 21a and 21b in the sheet portions 11a and 11b is preferably 10 μm or more and 500 μm or less, more preferably 10 μm or more and 200 μm or less, and most preferably 20 μm or more and 100 μm or less. The thickness of the barrier sheet 22 in each of the sheet portions 11a and 11b is preferably 5 μm or more and 200 μm or less, more preferably 6 μm or more and 100 μm or less, and most preferably 6 μm or more and 60 μm or less.
The packaging container 10 includes a barrier region B and an extending region E. As shown in
In the sheet portions 11a and 11b, a fixing region G is provided, in which the plastic sheets 21a and 21b are fixed to each other over the entire circumference of the barrier sheet 22. Thus, the barrier sheet 22 is sealed between the plastic sheets 21a and 21b inside of the fixing region G over the sheet portions 11a and 11b. In the packaging container 10, it is preferable that the peel strength between the plastic sheets 21a and 21b in the fixing region G is 2 N/15 mm or more. In this respect, in the fixing region G having the configuration shown in
Note that the peel strength according to this embodiment is measured by a T-peel strength test based on JIS K 6854-3. In the measurement of the peel strength, a test piece having a width of 15 mm is used, and the test speed is 100 mm/min. In this embodiment, an average value excluding the peak value in a plurality of measured values obtained by this measurement is defined as a peel strength. This method of measuring a peel strength is applied not only to the peel strength of the fixing region G, but also to the peel strength of an easily peelable region Bp, which will be described later.
Further, the packaging container 10 includes a sealing region S in which the sheet portions 11a and 11b are sealed. The sealing region S extends continuously along the outer edge portion of the extending region E, and seals the sheet portions 11a and 11b along three sides of the outer shape of the packaging container 10. As a result, a storage portion
V, which is a space closed over the entire circumference, is formed between the sheet portions 11a and 11b.
G, and the sealing region S coincide with each other. However, in the packaging container 10, at least one of the extended region E, the fixing region G, or the sealing region S may not coincide. For example, in the packaging container 10, as shown in
In the packaging container 10, an object to be packaged is stored in the storage portion V between the sheet portions 11a and 11b. The object that can be stored in the storage portion V of the packaging container 10 may be any of solid, liquid, and gas. Specifically, examples of such an object include a liquid soap, a shampoo, a detergent, a cosmetic, a bathwater additive, a food product, and a beverage. In the packaging container 10, since the storage portion V is isolated from an external environment by the barrier sheets 22 disposed in the barrier region B, it is possible to prevent the inflow and outflow of a water vapor and oxygen between the storage portion V and the external environment, and further it is possible to block electromagnetic waves such as ultraviolet rays and infrared rays from the external environment. As a result, in the packaging container 10, the quality of the object in the storage portion V can be maintained for a long period of time.
The barrier region B includes the easily peelable region Bp having a low peel strength, the peel strength being necessary for peeling off the plastic sheets 21a and 21b and the barrier sheet 22 from each other in each of the sheet portions 11a and 11b. In other words, in the packaging container 10, the peel strength between the plastic sheets 21a and 21b and the barrier sheet 22 in the easily peelable region Bp is smaller than the peel strength between the plastic sheets 21a and 21b in the fixing region G. More specifically, in the packaging container 10, the peel strength between the plastic sheets 21a and 21b and the barrier sheet 22 in the easily peelable region Bp is preferably less than 2 N/15 mm, and more preferably 1 N/15 mm or less.
In the configuration shown in
Further, the packaging container 10 according to this embodiment is not limited to the configurations shown in
Note that the pseudo-bonding of the plastic sheets 21a and 21b and the barrier sheet 22 in the easily peelable region Bp of the packaging container 10 only needs to have a configuration in which the plastic sheets 21a and 21b and the barrier sheet 22 can be easily peeled off from each other, and is not limited to the above configuration. For example, in the easily peelable region Bp of the packaging container 10, use of an adhesive having a weak adhesion force also makes it possible to bond the plastic sheets 21a and 21b and the barrier sheet 22 over the entire surfaces thereof. Further, the pseudo-bonding of the plastic sheets 21a and 21b and the barrier sheet 22 in the easily peelable region Bp of the packaging container 10 is not limited to a technique using an adhesive, and other different-material bonding techniques may be used. Examples of the different-material bonding techniques available for the pseudo-bonding include various welding methods such as electric resistance welding, high-frequency induction heating, ultrasonic welding, and hot plate welding, and laser joining methods. Also in such cases, the plastic sheets 21a and 21b and the barrier sheet 22 can be fixed by pattern bonding in a similar pattern as that described above. Further, use of such a condition that the peel strength has a weak adhesion force so as to remain within the above range also makes it possible to bond the plastic sheets 21a and 21b and the barrier sheet 22 over the entire surfaces thereof.
[Recycling Method for Packaging Container 10]
As described above, in the packaging container 10, high gas barrier property is obtained by using the barrier sheet 22. In contrast, in a general packaging container, the plastic sheet and the barrier sheet are firmly fixed by an adhesive or a laminate such as a coextrusion over the entire regions of the plastic sheet and the barrier sheet, and thus it has been difficult to separately reuse the plastic sheet and the barrier sheet.
In contrast, in the packaging container 10 according to this embodiment, providing the easily peelable region Bp makes it possible to easily separate and recover the plastic sheets 21a and 21b and the barrier sheet 22, so that high recyclability is obtained. In other words, in the packaging container 10 according to this embodiment, both high gas barrier property and high recyclability can be achieved. Hereinafter, a recycling method for the packaging container 10 according to this embodiment will be described. Note that, in the packaging container 10 to be recycled, it is generally assumed that at least a part of the sealing region S is peeled off when the packaging container 10 is opened. However, in the following, description will be given on the assumption that all of the sealing region S of the packaging container 10 remains without being peeled off, for convenience of description.
In the recycling method for the packaging container 10 according to this embodiment, at least a part of the easily peelable region Bp is first cut away from the packaging container 10 to be recycled.
When the packaging container 10 is cut along the cutting line L, as shown in
As described above, in the easily peelable region Bp, the peel strength between the plastic sheets 21a and 21b and the barrier sheet 22 is low in each of the sheet portions 11a and 11b. Thus, in the first portion 10a, as shown in
Note that the method of separating the plastic sheets 21a and 21b and the barrier sheet 22 in the recycling method for the packaging container 10 according to this embodiment is not limited to the configuration in which the first portion 10a and the second portion 10b are completely separated from each other as described above. For example, the easily peelable region Bp of the packaging container 10 may be linearly cut along both lateral edge portions thereof, and the barrier sheet 22 may be taken out from the plastic sheets 21a and 21b in a subsequent step.
Further, as an object to be recycled in this embodiment, a used packaging container 10 is mainly assumed, but it may be an unused packaging container 10. The unused packaging container 10 is opened in advance to take out an object stored in the storage portion V, and thus it can be recycled in the similar manner as that above.
[Manufacturing Method for Packaging Container 10]
A laminated sheet 20 shown in
The laminated structure of the laminated sheet 20 can be formed, for example, under a reduced-pressure atmosphere at a pressure lower than an atmospheric pressure. As a result, in the laminated sheet 20, the plastic sheets 21a and 21b and the barrier sheet 22 can satisfactorily come into close contact with each other without interposing air bubbles or the like in the easily peelable region Bp. The laminated structure of the laminated sheet 20 can be formed by, for example, supplying each of the plastic sheets 21a and 21b and barrier sheet 22 as a continuous sheet. Further, only the barrier sheet 22 may be supplied as a sheet, or each of the plastic sheets 21a and 21b and the barrier sheet 22 may be supplied as a sheet.
Further, in order to improve the adhesiveness between the plastic sheets 21a and 21b and the barrier sheet 22 in the laminated sheet 20, a mechanical pressing force in the thickness direction may be applied to the laminated structure including the plastic sheet 21a and 21b and the barrier sheet 22. For example, the laminated structure of the laminated sheet 20 is sandwiched between rotating rolls to expel gas, whereby high adhesiveness between the plastic sheets 21a and 21b and the barrier sheet 22 can be obtained. Further, taper processing or the like is performed on a pressing surface, which applies a pressing force to the laminated structure, whereby the plastic sheets 21a and 21b and the barrier sheet 22 can be bonded to each other in a pseudo manner at the same time as the gas is expelled. Furthermore, when a pressing force is applied to the laminated structure, the laminated structure may be heated. In this configuration, since the followingness of the plastic sheets 21a and 21b softened by heating with respect to the barrier sheet 22 is improved, it is possible to allow gas to escape favorably.
The fixing region G in which the plastic sheets 21a and 21b are directly fixed to each other is formed in the extending region E of the laminated sheet 20. The fixing region G is provided in the extending region E so as to surround the entire circumference of the easily peelable region Bp, and seals the plastic sheets 21a and 21b. As a result, the barrier sheet 22 is hermetically sealed between the plastic sheets 21a and 21b, and its movement between the plastic sheets 21a and 21b is restricted. Thus, in the laminated sheet 20, a stable laminated structure is favorably maintained.
In the manufacturing process of the laminated sheet 20, the fixing region G is formed in a state in which the barrier sheet 22 is sandwiched between the plastic sheets 21a and 21b. At that time, for example, the plastic sheets 21a and 21b and the barrier sheet 22 are not directly fixed to each other, so that the easily peelable region Bp having a low peel strength can be obtained. The fixing region G of the laminated sheet 20 can be formed by, for example, performing thermal fusion on the plastic sheets 21a and 21b by heat sealing. Thus, the fixing region G can be easily formed in a short time. Note that the method of forming the fixing region G is not limited to heat sealing, and may be ultrasonic welding, for example, or may be a method using a fixing material such as an adhesive. In the laminated sheet 20, it is preferable that the peel strength between the plastic sheets 21a and 21b in the fixing region G is 2 N/15 mm or more.
Note that in the laminated sheet 20 shown in
Further, as described above, in order to obtain the configuration in which the plastic sheets 21a and 21b and the barrier sheet 22 are bonded to each other in a pseudo manner in the easily peelable region Bp of the packaging container 10, it is preferable that the plastic sheets 21a and 21b and the barrier sheet 22 are bonded to each other in a pseudo manner at the stage of the laminated sheet 20. For example, in the laminated sheet 20, as shown in
Furthermore, as shown in
R2 for reducing the peel strength between the plastic sheets 21a and 21b and the barrier sheet 22 if necessary. The easily peelable layer R2 can be provided between each of the plastic sheets 21a and 21b and the barrier sheet 22. The easily peelable layer R2 can be formed by, for example, being applied to at least one of the plastic sheet 21a, 21b or the barrier sheet 22. For example, a silicone-based release agent, a fluorine-based release agent, a wax, a surfactant, or the like can be used as the easily peelable layer R2.
Further, in addition to the above, for example, a material having high bonding property with respect to the plastic sheets 21a and 21b and low bonding property with respect to the barrier sheet 22 can be used as the easily peelable layer R2. In the laminated sheet 20 using such an easily peelable layer R2, the easily peelable layer R2 and the barrier sheet 22 can be easily peeled off from each other.
Hereinafter, a manufacturing example of the packaging container 10 using the laminated sheet 20 shown in
The laminated sheet 20 shown in
Each sealing region S in the packaging container 10 can be formed by, for example, performing thermal fusion on the sheet portions 11a and 11b by heat sealing. Thus, the sealing region S can be easily formed in a short time. Note that the method of forming the sealing region S is not limited to heat sealing. For example, a sealing member such as an adhesive may be used to form the sealing regions S along the two right and left sides of the sheet portions 11a and 11b. Further, in addition to the direct sealing method, various methods for sealing the storage portion V can be used for forming the sealing region S along the upper side of the sheet portions 11a and 11b. For example, a method using a discharge mechanism including a spout, a pump, a film valve, or the like can be used.
Note that in the manufacture of the packaging container 10, as shown in
[Other Configuration Examples of Packaging Container 10]
In the packaging container 10 according to this embodiment, as shown in
Further, in the packaging container 10 according to this embodiment, as shown in
For example, as shown in
Further, as shown in
For example, as shown in
[Other Embodiments]
Hereinabove, each embodiment of the present invention has been described, but the present invention is not limited to the embodiment described above and can be variously modified as a matter of course without departing from the gist of the present invention.
For example, the sheet portions 11a and 11b of the packaging container 10 of the present invention may not have a configuration in which the continuous laminated sheet 20 is folded back at the folding line F. In other words, as shown in
Further, the pair of plastic sheets 21a and 21b used for the laminated sheet 20 need not necessarily be the same and may be different from each other. For example, the plastic sheets 21a and 21b may be formed of different kinds or systems of resin materials from each other or may have different thicknesses from each other.
Furthermore, the planar shape of the packaging container 10 of the present invention does not have to be a rectangular shape, and a shape generally used as a packaging body can be optionally applied in accordance with the shape, properties, and the like of an object to be stored in the storage portion V. As an example, the planar shape of the packaging container 10 may be one of or a combination of two or more of the rectangular, polygonal, round, elliptical, and trapezoidal shapes. In the packaging container 10, it is preferable that the sealing regions S are provided at least at two positions along the contour even in any planar shape. Further, the planar shape of the laminated sheet 20 used for manufacturing the packaging container 10 does not need to be a rectangular shape and can be optionally determined in accordance with the planar shape required for the packaging container 10. As an example, the planar shape of the laminated sheet 20 may be one of or a combination of two or more of the rectangular, polygonal, round, elliptical, and trapezoidal shapes. In the laminated sheet 20, it is preferable that the fixing regions G are provided at least at two positions along the contour even in any planar shape.
In addition, the packaging container 10 of the present invention can also have a configuration in which a plurality of storage portions V whose circumference is airtightly sealed by the sealing region S are arranged side by side in the in-plane direction. Further, the configuration of the packaging container 10 of the present invention can be applied to containers of various shapes, and is not limited to the planar, pillow-type container described above. For example, it can also be applied to a container having a three-dimensional shape, such as a standing pouch provided with a collapsible gusset at the bottom.
10 packaging container
11
a, 11b sheet portion
20 laminated sheet
21
a, 21b plastic sheet
22 barrier sheet
B barrier region
Bp easily peelable region
E extending region
G fixing region
S sealing region
V storage portion
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/JP2019/050713 | 12/24/2019 | WO |