This invention relates to a packaging for two or more fluids. More specifically the invention relates to a compartmented pouch package system in which two or more reactive fluids may be stored separately from each other but which also provides for a combination of these fluids within the pouch and subsequent dispensing of the combined fluids.
For a long time hand-held spray guns have been used to dispense paints and liquid coatings onto substrates. A reservoir of the paint or liquid coating is mounted on the spray gun and is operatively connected by a feed-line to the nozzle of the gun. An appropriate actuator in the gun controls the release of the liquid from the reservoir and the emission of a stream or pulse of gas which drives the released liquid from the nozzle.
For coatings and paints of the one component (1K) type it is common for the reservoir to be provided in the form of a rigid cup, walled chamber or cylindrical body which either retains the component directly or encloses a flexible bag or pouch which holds the liquids therein. Examples of such reservoirs are given in U.S. Pat. No. 6,796,514, U.S. Pat. No. 6,945,429, U.S. Pat. No. 5,582,350 and U.S. Pat. No. 6,942,126.
FR 2 645 437 A discloses a flexible bag for pharmaceutical products which can be separated into two or more compartments using a removable clamp.
U.S. Pat. No. 4,731,053 relates to a container device that is useful for separately storing two ingredients, and subsequently mixing the two ingredients within the container device. Storage of medicaments and dehydrated food are mentioned as suitable applications. The container device comprises a flexible bag and releasable partitioning means in the form of a frame with constituent arms which divides the flexible bag at the ends opposite to the pivot about which the constituent arms can be moved.
For coatings and paints that are of the multi-component type, the first, second and any further reactive components are individually dosed into such rigid cups or cylindrical bodies and, optionally, mixed therein prior to or after the attachment of the reservoir to the spray gun. The act of dosing the components exposes the user to any solvents used in those components. The user is also provided with difficult and time-consuming task of controlling the ratio by volume of each component of the coating dosed into the reservoir: Errors in component ratio are common. And the mixing of the components within the reservoir is often made more difficult by the cumbersome nature of the cups or bodies.
The inventors have recognized a need in the art to replace cups, cylindrical bodies and walled chambers as the means of retaining two component coatings immediately prior to dispensing. More particularly, they have recognized the need to provide a packaging which is suitable for stably storing two or more liquids separately in a precise dosage ratio, which is easy to use and manipulate and which allows for the two or more liquids to be easily mixed and dispensed via a conventional spray gun without exposing the user to either of the liquids, and more particularly any solvents used therein.
In accordance with a first aspect of the present invention there is provided a packaging for fluids, said packaging comprising: a) a flexible pouch preferably made from water and/or solvent impermeable material and having a total capacity, said pouch being provided with at least one port through which fluids may be introduced and dispensed, each said port being provided with a closing valve; and b) a frame for retaining said pouch which may define open and closed positions resulting from movement of two pairs of constituent arms about pivots provided at each end of a frame axial member, and a linear cavity is provided within the axial member, and a hinge member is provided parallel to the axial member and mounted at the top arms and wherein, in the closed position the frame is adapted to divide the total capacity of the pouch into first and second portions between which portions no communication of introduced fluids is possible, and further wherein, in the open position, the frame does not so divide the pouch allowing communication between fluids in each portion.
The pouch should preferably be provided with two ports which are adapted to allow the first and second portions of the pouch formed by the closure of the frame to be independently filled with fluids. The use of closing valves on the or on each port means that the act of filling the portions of the pouch can be performed within a closed system. The so-introduced fluids can be retained in each portion, separately, until the fluids are required to be mixed and dispensed from the packaging. This obviously enables the packaging to store two fluids that would otherwise be reactive to each other.
At the time of mixing, the arms of the frame are rotated from their closed position to their open position alleviating the pressure on the boundary between the two portions. At some point in the rotation of the arms, fluid communication between the two portions becomes possible. The mixing of the two fluids in each portion may be facilitated by shaking the packaging or by allowing the fluid retained in one portion to flow under gravity into fluid retained in the second portion.
The packaging of this invention provides for storing and then mixing of different fluids in precisely controlled volume ratios based either on the capacity of each of the first and second portions or on the volume of fluids introduced into each said portion. Suitably, the volume retained in the first and second portions of the pouch formed by the closure of the frame are in the ratio from 1:1 to 10:1. Preferably that volume ratio is in the range from 1:1 to 3:1, more preferably the first and second portions of the pouch retain equal volumes of fluid and most preferably the first and second portions have equal volumetric capacity.
The port of one of the first and second portions may be opened to allow the mixed liquids therein to be dispensed from the packaging. In practice the act of filling each portion or compartment therein can contaminate a given port. It may therefore be advantageous to provide a further port in one of the portions which is used exclusively for the dispensing of the mixed liquids. Such a further port may be sealed with closure means until dispensing is to occur and will typically be larger than the ports used to fill the first and second portions.
The packaging is particularly suitable for inclusion within a spraying device such as a conventional spray gun: The port used for dispensing the mixed fluids is attached directly to the spraying device, preferably in a manner which provides a closed system.
In accordance with a second aspect of the invention there is therefore provided a spraying device comprising: i) a spray nozzle; ii) a compressible fluid packaging comprising: a) a flexible pouch having a total capacity, said pouch being provided with at least one port through which fluids may be introduced and dispensed, each said port being provided with a closing valve; and b) a frame for retaining said pouch which may define open and closed positions resulting from movement of its constituent arms about a pivot and wherein, in the closed position the frame is adapted to divide the total capacity of the pouch into first and second portions between which portions no communication of the introduced fluids is possible, and further wherein, in the open position, the frame does not so divide the pouch allowing communication between fluids in each portion; and iii) a feed line extending between the spray nozzle and an open end surrounded by a first connection member to connect the open end of the feed line to a corresponding second connection member surrounding the at least one port of the compressible fluid packaging, wherein said first connection member is provided with a member acting on the closing valve of the packaging to cause its being opened when the first and second connection members are mutually connected.
As the packaging can separately store two or more fluids which are reactive towards each other, the packaging and the spraying device have particular utility in the context of two component (2K) and multi-component coating compositions. In accordance with a third aspect of the invention there is provided a process of finishing or refinishing an automobile or large transportation vehicle, comprising the steps of: Providing a multi-component coating composition in the packaging as defined hereinbefore, wherein said frame is in the closed position such that the first and second portions of the flexible pouch each contain one reactive component of the coating; moving said frame to an open position and mixing the reactive components of said coating composition; and, dispensing said coating composition through the port of the packaging into a spraying device and thereby onto the surface of an automobile or large transportation vehicle. Large transportation vehicles include trains, buses, trucks, and airplanes as well as parts of thereof.
The invention will be described with reference to the appended drawings in which:
a is an expanded view of the encircled region provided in
b is an expanded view of the same region of
a is an expanded view of the encircled region provided in
As used herein a “multi-component coating composition” means a coating composition having at least two components stored separately. Typically, one container contains a crosslinkable component and optionally contains solvent and/or other adjuvants; a further container typically contains the crosslinking component and optionally solvent and/or other adjuvants. The containers containing the two reactive components are typically sealed to increase the shelf life of the components of the coating composition. The two or more components are mixed just prior to use to form a pot mix, which has a limited pot life, typically ranging from a few minutes (15 minutes to 45 minutes) to a few hours (4 hours to 8 hours). The pot mix is applied as a layer of a desired thickness on a substrate surface, such as an auto body. After application, the layer dries and cures at ambient or elevated temperatures to form a coating on the substrate surface having desired coating properties, such as, high gloss, mar-resistance and resistance to environmental etching.
The flexible pouch (10) should be made of a water and/or solvent tolerant and impermeable material, preferably a laminate comprising at least one layer of polyethylene, high density polyethylene (HDPE) or polypropylene. Thin metallic foils, in particular aluminium foil, may also be employed either as the pouch material or as a barrier layer within a laminar pouch material. The exact material used for the pouch and the number of layers thereof will depend on the specific contents of the pouch and whether a printable outer layer is required.
The frame (20) is shown in detail in
The bases of the arms (22, 23) are joined by a beam (29) which also extends across the width of the frame (20). Each arm (22, 23) is also provided with a resilient latch (22b, 23b) which may be reversibly deviated from its standard position by the application of a small force.
The bases of the arms (24, 25) are joined by a beam (30) which also extends across the width of the frame (20). In the centre of this beam is disposed a connection member (31) which will be described in more detail herein below. Each arm (24, 25) is also provided with an aperture (24a, 25a) the apertures being sized to receive the latches (22b, 23b).
When the arms (22, 23) are rotated downwards to the closed position shown in
In a first non-limiting method of forming the packaging of this invention, the frame (20) is disposed in an open position—such as is shown in
In a second non-limiting method of forming the packaging, the frame (20) may be initially dismantled into two or more parts. The large diameter port (16) of an empty pouch (10) is first brought into contact with the connection member (31) and the associated arms (24, 25) and beam (30) of the first part of the frame. The second, remaining parts of the frame are then assembled about the pouch into, for example, the frame position shown in
In either exemplary method, when the hinge member (27) becomes fully engaged with the linear cavity (28) the folded pouch is divided into first (11) and second (12) portions. In this configuration, the port (15) is disposed in the first portion (11) and the port (14) is disposed within the second portion (12) of the pouch (10).
A particular advantage of the use of the frame (20) as opposed to a free-standing clip or clamp is that the pouch will automatically be folded at the right location when this methodology is employed. Furthermore, the lever effect of the arms (22, 23, 24, 25) serves to generate a large closing force on the pouch which ensures the components remain separated even during long term storage, transport and handling of the packaging.
In the embodiment of
The frame (20) is typically fabricated from steel, aluminum or plastic. In any event, the material from which it is fabricated must be suitably robust for exerting a constraining force sufficient to maintain a fluid impermeable boundary between the first (11) and second (12) portions when in a closed position. The support provided by the frame (20) to the pouch (10) ensures that the packaging is maintained in a compact form at all times which greatly facilitates its handling.
In use, the packaging of
The mixed fluids may then be dispensed through port (16) by opening the valve thereof.
In a preferred mode of operation, the first (11) and second (12) pouches are each filled to a volume that is less than or equal to a half of their total capacity. The second portion is vertically disposed above the first portion to mix the fluids retained therein. Once the fluids have been joined, the combined volume allows for the frame (20) to be re-closed, so that the pouch (10) again becomes folded symmetrically into a filled and empty portion respectively. This has the benefit that no mixture is present in the emptied compartment: All of the mixture is present in that portion (11) which has an outflow via port (16).
Referring to
In a preferred embodiment of the invention the movement of the arms of the frame (20) from the closed position to the open position about the pivot acts to stretch the flexible material of the pouch in the region of said pivot. This may be achieved by adapting the frame (20) such that the total beam (29)—hinge member (27)—beam (30) distance in the open position of the frame is larger than that distance when the frame is in the closed position: By also making that distance in open position slightly less than the length of the pouch in filled condition, a force will be exerted on the material inside the pouch that will open the pouch in the middle. This pulling or stretching action facilitates the movement of fluids between each portion.
A further embodiment of the pouch (10) has been shown in plan view in
Each compartment (12a, 12b) is provided with a port (14a, 14b) which allows fluids to be introduced separately there into when the pouch is mounted into a frame and that frame is in its closed position. The undivided portion (11) of the pouch is also provided with a separate port (15) for this purpose.
In the use of this pouch (10) the frame (not shown) will be moved from its closed position to its open position, alleviating the pressure on the boundary between the two portions (11, 12(a, b)). At some point in the rotation of the frame the hydrostatic pressure in the portions will force open the boundary allowing the fluids retained in each portion to mix. To ensure adequate mixing of two fluids retained in the second portion (12a, 12b) and the one fluid retained in the first portion (11), it is preferred to position the packaging vertically and for the fluids in the second portion to flow under gravity into the lower, first portion.
It will of course be recognized that different positions of the seam (53) to that shown will allow precise control of the volumetric capacity of each compartment (12a, 12b). Furthermore, more than one such seam may be included, thereby allowing the division of a portion of the pouch into three or more compartments.
The pouch of
Further embodiments of the pouches (10) are shown in
In a further embodiment of the pouch that is not shown, the pouch is not symmetrical. One half of the pouch is wider than the other such that when the pouch is folded about its midpoint, the two portions thus formed have different volumetric capacities. Through appropriate manufacturing techniques, pouches which can be divided into first and second portions of specific ratios by volumetric capacity can be produced.
The packaging described above is particularly suitable for inclusion within a spraying device. A suitable hand-operable spraying device (90) is illustrated in
The spraying device (90) comprises an internal feed line (not shown) which extends between the spray nozzle (91) and the open end of a first connector member (94). The central connector member (190) of the packaging is operatively attached to that first connector member (94): That first connector member is necessarily provided with means to act on the connector member (94) to open and, optionally, close the valve thereof (not shown).
In a preferred aspect of the invention the connection between the members (94, 190) is provided in accordance with the teaching of WO2007128739 (Akzo Nobel Coatings International B.V.): The disclosure of this document is herein incorporated by reference.
In a first preferred embodiment from that disclosure the connector member (94) has a closing valve comprising a closing member dimensioned to be tightly pressed onto an inner ledge along the inner diameter of the pouch connector member (190). The first connection member (94) is provided with a protrusion or finger to press the closing member away from the ledge or shoulder surrounding the port of said pouch.
In a second preferred embodiment from that disclosure, the connector member (94) has a closing valve comprising a nipple and a cap, the nipple having a top end provided with at least one opening and a protrusion which is in register with an opening in the top end of the cap, the opening being dimensioned to fit tightly over the protrusion and the cap being slide-able over the nipple between a closed position, when the protrusion closes off the opening in the cap's top end, and an open position, when the protrusion is pulled out of the opening.
In a third preferred embodiment from that disclosure, the connector member (94) has a closing valve that includes a plug with a central bore leading from an outlet opening to an outer end provided with a narrowing inner diameter and a cap comprising a closed end and an open end defined by a profiled edge apt to form a snap joint in cooperation with the narrowing inner diameter of the plug's outer end, the cap being attached to the plug by flexible spokes. Herein it advantageous to provide the first connection member (94) with a hollow protrusion with a head dimensioned to fit tightly into the plug's cap and radial openings below the head.
In each of these embodiments the first (94) and second (190) connection members cooperate to form either a screw connection or a bayonet catch.
Although the packaging of this invention has been described for use with a spray gun for coatings, it may equally be used with other devices suitable for dispensing or spraying fluids.
After a required volume of the fluids retained within the pouches has been dispensed, the frame and pouch may be disconnected from the spray device. Packaging which still retains a useable volume of fluid may be stored for later use within the pot-life of the mixture. Emptied pouches may be removed from the frames of the packaging after use and discarded or, alternatively, the complete packaging may be discarded as a whole.
The frames and the pouches can obviously be prepared in a number of different sizes suitable for different applications of the packaging. These sizes can be standardized such that the packaging components can be manufactured in bulk, thereby achieving economy of manufacture. Particular mention with regard to bulk manufacture of pouches may be made of pouches having a total volumetric capacity of 2 litres, 1 litre, 750 ml, 500 ml, 400 ml, 300 ml, 200 ml and 100 ml.
Although the present invention is not intended to be limited by the fluids present in each portion and/or each compartment of the package, it will be recognized that the invention is very suitable for storing liquids and particularly suitable for storing liquids that are reactive towards one another. The mixing of such fluids thus initiates a reaction within the pouch: The reaction mixture is then dispensed from the packaging at an appropriate time after the initiation of the reaction, that time being dependent on the chemistries involved and/or the tolerance of the pouch to the thermodynamic conditions generated by the reaction.
In a highly preferred use, the packaging retains a two component (2K-) coating composition wherein the first and second portions of the flexible pouch each contain one reactive component of the 2K-coating: The two components of the coating composition are mixed within the packaging and dispensed and the composition appropriately cured. An advantageous use of the packaging in this manner would be in the 2K polyurethane technology which is widely used in the automotive refinish market. A first liquid component (A) comprising at least one hydroxyl functional polymer and a second liquid component (B) comprising a crosslinker capable of crosslinking with said hydroxyl functional polymer (A) to form a film, may each be retained in a separate portion of the packaging: These two components are mixed within the packaging and then preferably dispensed from that packaging using a spraying device of the aforementioned form. The composition is then cured in the appropriate manner.
As is known in this art, the hydroxyl functional polymer (A) will typically be selected from the group consisting of hydroxyl-containing polymers derived from ethylenically unsaturated monomers such as vinyl and acrylic monomers, hydroxyl functional polymers derived from epoxy polymers, hydroxyl-containing alkyd polymers, polyurethane polyol polymers, polyether polyol polymers or polyester polyol polymers. The crosslinker (B) capable of crosslinking with the hydroxyl functional polymer to form a film may for example include aminoplasts and polyisocyanates, with multifunctional polyisocyanates being the most preferred. Examples of suitable candidates for components (A) and (B) may be found throughout the prior art, for example in U.S. Pat. Nos. 4,913,972 and 6,316,119.
A pouch constructed from a laminate of polyethylene, aluminium foil and polyethylene terephthalate (PET) was provided in the form illustrated in
The empty pouch was mounted within an open frame as shown in
Using a plunger pump, 200 ml of Sikkens Autoclear PC Standard (hydroxyl acrylic resins available from Akzo Nobel N.V.) was metered through the provided port into the first portion of the pouch formed by the closure of the frame. 100 ml of Sikkens Autoclear PC Hardener (polyisocyanate resins available from Akzo Nobel N.V.) was similarly metered into the second portion of the pouch formed by the frame closure.
After a storage period of 5 days, the frame was opened in a manner which disposed the second portion containing the hardener component vertically above the first portion containing the hydroxyl functional polymer component. The two components were joined under the action of gravity. After joining the two components, the packaging was shaken for 5 seconds to mix the components. Directly after mixing the packaging was attached to a standard air assisted spray gun (DeVilbiss GTi gravity feed spray gun) and the coating applied on a panel that had been previously coated with Sikkens Autobase Plus. After the recommended flash-off time of 3 minutes the clearcoat was dried for 30 minutes at 60° C.
The drying time, clearcoat hardness and clearcoat appearance showed no difference from a conventionally mixed and applied clearcoat of the same type.
Number | Date | Country | Kind |
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09151247.5 | Jan 2009 | EP | regional |
61/147191 | Jan 2009 | US | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP10/50656 | 1/21/2010 | WO | 00 | 7/15/2011 |