The present invention relates to a packaging material, in particular to a laminated packaging material, and to a method for manufacturing the laminated packaging material.
Furthermore, the invention relates to packaging containers being made of the laminated packaging material.
Carton based packaging containers for liquid food products are well known. For instance, Tetra Brik® packaging containers are used in many parts of the world for milk, juice and other beverages. There are several reasons why carton based packages have gained popularity. The environmental benefits of the packages, e.g. that the packages are to a large extent produced by renewable material, and the efficient logistics of brick shaped packages are some reasons why consumers today choose carton based packages instead of plastic bottles. Other reasons why carton based packages are popular are that the packaging machines producing the packaging containers are robust and cost efficient compared to other alternatives, and that the total cost for running a carton based packaging machine is very competitive.
Packaging containers for pourable food products need to have some barrier properties in order for the filled and unopened packaging containers to be able to be stored properly. The required shelf-life and the type of barrier needed depend on the type of food product, the type of packaging material, the type of packaging container, the type of opening device of the packaging container etc., and also on aseptic aspects and intended storage conditions. Generally, in all cases some degree of oxygen barrier is needed.
The packaging material is produced by laminating a plurality of polymer layers to a core material layer of carton or paperboard. The polymer layers protect the core material layer, which typically is made of carton or paperboard, from the liquid content of the resulting packaging container as well as from the humid outside environment. As packaging material manufacturing processes are improved in terms of speed and quality, and as polymer layers are improved and developed to be laminated in yet thinner layers, it is possible to reduce the total amount of polymer material for the laminated layers of the packaging material. The inside polymer layer is however also used to seal the packaging material when individual packaging containers are formed and filled. The general desire of reducing the polymer layer thickness of the inside of the packaging material is therefore in conflict with the requirement of having a sufficiently thick polymer layer in order to ensure proper sealings of the packaging material.
Thus, there is a need for an improved packaging material ensuring robust sealings, while still allowing the total polymer layer material to be reduced.
It is an object of the invention to at least partly overcome one or more of the above-identified limitations of the prior art.
To solve these objects, a packaging material for liquid food products is provided. The packaging material comprises a core layer, an outermost layer arranged to face the exterior of a packaging container made of the packaging material, and an innermost layer arranged to face the interior of the packaging container, said outermost layer and said innermost layer being laminated to the core layer. The laminated packaging material further comprises a locally applied heat sealable material portion arranged on the innermost layer.
The heat sealable material portion may be arranged at sealing areas corresponding to the position of transversal seals of the resulting packaging container.
The heat sealable material portion may be adhered to the innermost layer by means of a heat application process.
The heat application process may be an injection moulding process, a sintering process, a welding process, a spraying process, an ink-jet type of polymer printing process, or a 3D printing process.
The heat sealable material portion may have a cross-section having a width which increases towards the innermost layer, i.e. towards its base at the substrate surface.
The heat sealable material portion may have a cross-section having the shape of a triangle, or a truncated triangle. Alternatively, the heat sealable material portion may have a cross-section having the shape of the top of a circle or a half-circle.
The heat sealable material portion may have a cross-section having an asymmetric shape.
The heat sealable material portion may be arranged to have a varying cross-section along the extension of the transversal sealing areas.
The heat sealable material portion may have a cross-section providing a higher amount of polymer material at predetermined positions along the extension of the transversal sealing areas. In particular, such a cross-section may have a wider base, i.e. an increased width towards the innermost layer and/or a steeper inclination towards the apex or top of the cross-section.
The heat sealable portion may be applied only at some parts along the extension, or along the entire extension, of the transversal sealing areas.
The heat sealable material portion may have an enclosed cavity, i.e. be hollow inside.
The thickness of the heat sealable material portion may be 2-50 μm, preferably 3-30 μm, such as 3-20 μm, or 5-20 μm, and most preferred 5-15 μm.
The heat sealable material portion may be made of a thermoplastic material, such as a thermoplastic polymer.
The thermoplastic polymer may be selected from the group consisting of polyolefins and polyesters.
The thermoplastic polymer may be selected from the group consisting of polyethylene, polypropylene, polyethylene terephthalate (PET), polyethylene furanoate (PEF), polylactic acid polymer or copolymer (PLA), Polyhydroxyalkanoates (PHA) and blends or copolymers of two or more thereof.
The thermoplastic polymer of the locally applied heat sealable material portion may be selected from the group consisting of low density polyethylene LDPE, high density polyethylene HDPE, linear low density polyethylene LLDPE or single site catalysed linear low density polyethylene m-LLDPE, very low density polyethylene (VLDPE), ultra low density polyethylene (ULDPE) and blends and copolymers of two or more thereof.
The thermoplastic polymer may be a biodegradable polymer selected from the group consisting of polylactic acid polymer or copolymer (PLA), polyhydroxyalkanoates (PHA), cellulose or cellulose derivatives and blends or copolymers of two or more thereof. Examples of PHA are i.a. poly-3-hydroxybutyrate (PHB), polyhydroxyvalerate (PHV) and polyhydroxyhexanoate (PHH).
The heat sealable material portion may be arranged along the entire extension of the transversal sealing areas, or partly along the extension of the transversal sealing areas.
The heat sealable material portion may be arranged to have a varying cross-section along the extension of the transversal sealing areas.
The packaging material may further comprise a barrier layer arranged between the core layer and the innermost layer.
The barrier layer may be an aluminium foil or a metallised aluminium layer. The barrier may alternatively be a non-aluminium foil (“non-foil”) barrier, such as for example a vapour deposited coating of an inorganic oxide, metal oxide or a diamond-like carbon (DLC), such as a dispersion coated layer of polyvinyl alcohol (PVOH), ethylene vinyl alcohol (EVOH), starch or starch derivative, cellulose or cellulose derivative (such as micro-/nano-fibrillar cellulose), or such as a polymer barrier, such as a polyamide or ethylene vinyl alcohol (EVOH).
The core layer may be a cellulose based material, such as paper or paperboard.
According to a second aspect, a method for producing a packaging container using a laminated packaging material is provided. The method comprises the steps of: laminating an innermost layer and an outermost layer to a core layer or providing a laminated packaging material having an innermost layer and an outermost layer laminated to a core layer, heat applying a heat sealable material portion locally to said innermost layer, forming a packaging container open in one end from said packaging material, filling the packaging container through the open end and heat sealing the package container by means of the heat sealable material portion to form a closed packaging container.
Heat applying may be performed using an injection moulding process, a sintering process, a welding process, a spraying process, an ink-jet type of polymer printing process, a compression moulding process or a 3D printing process. The preferred heat application processes are injection moulding, such as high-pressure micro-injection moulding, ink-jet type of polymer printing and 3D printing, because these processes allow for shaping of the final geometry of the locally applied heat sealable material portion in a better way. High-pressure micro-injection moulding is the most preferred process, since it enables higher speeds of heat application and may involve very small amounts of polymer, and are thus suitable for high-speed packaging processes in filling and packaging machines.
The innermost layer may be a heat sealable polymer, preferably a thermoplastic polymer selected from polyolefins, such as polyethylenes, and from polyesters.
The innermost layer may be a heat sealable thermoplastic polymer selected from the group consisting of polyethylene, polypropylene, polyethylene therephthalate (PET), polyethylene furanoate (PEF), polylactic acid polymer or copolymer (PLA), Polyhydroxyalkanoates (PHA) and blends or copolymers of two or more thereof.
The innermost layer may be a heat sealable thermoplastic polymer selected from the group consisting of polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polyethylene furanoate (PEF) and any blend or copolymer of one or more thereof. The innermost layer may be thermoplastic polymer selected from the group consisting of polyethylene (PE) or polyethylene terephthalate (PET), and the material of the heat sealable material portion may be polyethylene (PE).
The thermoplastic polymer of the innermost layer and of the locally applied heat sealable material portion may be of the same type or of a different type of polymer.
The innermost layer may comprise a thermoplastic polymer selected from the group consisting of low, medium and high density polyethylene (LDPE, MDPE, HDPE), linear low density polyethylene and single-site or metallocene catalysed linear low density polyethylene (LLDPE, m-LLDPE) and polypropylene (PP) and blends and copolymers of two or more thereof.
The material of the heat sealable material portion may comprise a thermoplastic polymer selected from the group consisting of high/medium density polyethylene (HDPE, MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE, m-LLDPE), and blends and copolymers of two or more thereof.
The thermoplastic polymer of the innermost layer may be selected from the group consisting of low density polyethylene LDPE, high density polyethylene HDPE, linear low density polyethylene LLDPE or single site catalysed linear low density polyethylene m-LLDPE, and blends and copolymers of two or more thereof. The seal initiation temperature, i.e. the softening temperature, such as Vicat point or glass temperature (Tg) of the thermoplastic polymer of the of the locally applied heat sealable material portion may be equal to, or lower than a corresponding seal initiation temperature of the thermoplastic polymer of the innermost layer. The seal initiation temperature of the thermoplastic polymer of the of the locally applied heat sealable material portion may be 4 K, such as 5 K, such as 10 K lower than the respective or corresponding temperature of the innermost layer.
The melt temperature (Tm) of the thermoplastic polymer of the of the locally applied heat sealable material portion may be equal to, or lower than a corresponding melt temperature of the thermoplastic polymer of the innermost layer. The melt temperature of the thermoplastic polymer of the of the locally applied heat sealable material portion may be 4 K, such as 5 K, such as 10 K lower than the melt temperature of the innermost layer. The heat sealable material portion may be applied such that the cross-section has a width which increases towards the innermost layer. In an embodiment, the locally applied heat sealable material portion has a triangular cross-section or a cross-section having the shape of a truncated triangle. The cross-section configuration of a triangle or truncated triangle of the locally applied heat sealable material portion provides an optimal heat sealing operation in terms of operation efficiency, amount of material used and strength of the resulting heat seal joint.
The heat sealable material portion may have a cross-section having the shape of a triangle, or a truncated triangle. Alternatively, the heat sealable material portion may have a cross-section having the shape of the top of a circle or a half-circle.
The heat sealable material portion may have a cross-section having an asymmetric shape.
The heat sealable material portion may be arranged to have a varying cross-section along the extension of the transversal sealing areas.
The heat sealable material portion may have a cross-section providing a higher amount of polymer material at predetermined positions along the extension of the transversal sealing areas. In particular, such a cross-section may have a wider base, i.e. an increased width towards the innermost layer and/or a steeper inclination towards the apex or top of the cross-section.
The heat sealable portion may be applied only at some parts along the extension, or along the entire extension, of the transversal sealing areas.
The heat sealable material portion may have an enclosed cavity, i.e. have a hollow structure.
According to a third aspect, a packaging container made of a packaging material comprising a core layer and a thereto laminated outermost layer and an innermost layer is provided. A heat sealable material portion is locally arranged on the innermost layer.
Still other objectives, features, aspects and advantages of the invention will appear from the following detailed description as well as from the drawings.
Embodiments of the invention will now be described, by way of example, with reference to the accompanying schematic drawings, in which
Starting in
After unwinding the packaging material 100 from a reel 110 its longitudinal side edges 101a-b are brought together to form a longitudinal seal LS, thereby also forming a continuous tube 140 of the packaging material 100. More particularly, the longitudinal side edges 101a-b are attached to each other continuously in an overlapping manner. The tube 140 is filled with a desired product, preferably a liquid food product, from a filling pipe 150.
A series of packages 160 are formed from the tube 140 by making transversal sealings TS at an end of the tube 140, and cutting off the sealed portions, each sealed portion representing an individual package 160, as they are formed. In order to shape the packages 160 different forming tools can be used during the transversal sealing operation, or a separate forming process can be performed after the transversal sealing has been performed.
Alternatively, a blanks fed packaging machine is used. The blanks, in the form of pre-cut pieces of packaging material with two ends welded together such that a folded and sealed tubular sleeve is formed, are fed to the filling machine. The blanks are erected into an open sleeve, and then folded and sealed such that a closed top or bottom is formed. It is thereafter filled with product and sealed and folded at the open end such that a filled package container is obtained.
The laminated packaging materials 200, 200′ shown in
It should be noted that the dimensions of the heat sealable material portions 204, 204′ are exaggerated for illustrative purposes. The width of the heat sealable material portions 204, 204′ should be selected to provide a sufficient sealing in the longitudinal direction of the package 160, while the length of the heat sealable material portions 204, 204′ should be selected to extend along the entire sealing of the package 160. The thickness of the heat sealable material portions 204, 204′ should be selected such that a sufficient bonding is obtained, and may be from 5 to 50 μm, such as from 5 to 30 μm, such as from 5 to 20 μm.
The inventors have thus surprisingly found that it is sufficient and resource-saving, i.e. saving total raw material thermoplastic polymer amounts, to reduce the overall thickness of the innermost layer 203, 303′ but to instead provide the laminated packaging material 200, 200′ with the locally applied heat sealable material portion 204, 204′ at certain areas of the innermost layer 203, 203′ of the packaging material, as for example shown in
Since the heat sealable material portions 204, 204′ are applied non-homogenously on the laminated packaging material 200, 200′, they may preferably be provided to the packaging material 200, 200′ after the packaging material 110, 300 has been produced. The process of forming the laminated packaging material 100, 200, 200′ without the heat sealable material portions 204, 204′ is performed through a well-known manufacturing process also called converting, involving lamination operations. The bulk layer 201, 201′, innermost layer 203, 203′ and outermost layer 202, 202′ and optionally the barrier layer 205′, such as an aluminium foil or a metallised film, or other layers providing an oxygen barrier, as well as additional lamination layers are laminated together during the converting process. The thickness of the innermost layer 203, 203′ may be in the range of 1 to 50 μm, 2-50 μm, preferably 2-40 μm, 2-30 μm, 3-30 μm, 3-20 μm, 5-20 μm, 3-15 μm, 5-15 μm.
An exemplary formation of the heat sealable material portions 204, 204′, 404 using injection moulding is shown in
In
In a second stage of this example, illustrated in
In a third stage of this example, shown in
The heat sealable material portion 404 shown in
In addition a larger interface area between the heat sealable material portion 404 and the innermost layer 403 is achieved using a geometry of the heat sealable material portion 404 having a width which increases towards the innermost layer 403. By providing a triangular cross-section, or a cross-section having the shape of a truncated triangle, perpendicular to a transversal direction TD of the heat sealable material portion 404, more thermal energy is applied at the interface, thereby improving bonding of the heat sealable material portion 404 to the innermost layer 403. This is illustrated in
In
In a second stage, illustrated in
In a third stage shown in
It should be noted that the heat sealable material portions 404, 504 of
To facilitate a successful bonding between the innermost layer 203, 403, 503 and the heat sealable material portion 204, 404, 504, the interface between the innermost layer 203, 403, 503 and the heat sealable material portion 204, 404, 504 should have a desired temperature for as long as possible. The triangular shape of the cross-section, or a cross-section having the shape of a truncated triangle, prevents the heat sealable material portion 204, 404, 504 to flow outside the transversal seal areas TSA since the joining of heat sealable material portion 204, 404, 504 to form a seal generates an increased pressure. The cross-section also yields a larger surface area in the interface between the two surfaces than a rectangular shape of the cross-section if the same volume of the material forming the sealing element 204, 404, 504 is used.
The provided packaging material 100, 300 which has been produced in a converting process is unwound from its roll 110 and placed 620 in a heat sealable material portion forming station 40, 50 for forming the heat sealable material portions 204, 404, 504. The station 40, 50 is placed inside a filling machine or just before entry to the filling machine. The station 40, 50 may be an injection moulding station as shown in
Optionally, the laminated packaging material 100, 300 is placed 630 in contact with at least one mould 414, 416, 514. The mould 414, 416, 514 may have various shapes, forming heat sealable material portions 204, 204′, 404, 504 of different geometries. The moulds 414, 416, 514 may for instance have a cross-section perpendicular to the extension of the sealing elements 204, 204′, 404, 504 which is triangular, rectangular, hemispherical, or having the shape of a truncated triangle. Preferably, said cross-section has a width which increases towards the innermost layer, as shown in
Subsequently, the heat sealable material portions 204, 204′, 404, 504 are formed 640 by applying a heat sealable material 410, 510 onto the innermost layer 203, 203′, 403, 503 of the laminated packaging material 110, 300. Optionally, the heat sealable material 410, 510 is applied by injecting the material into a cavity 412, 512 of the mould 414, 416, 514 as shown in
Injection moulding is a well-established technique not the least for some of the suggested materials: PE, PP and PET. When manufacturing only small devices from these materials on a forward-moving packaging laminate material in a filling and packaging machine, using high-pressure micro-injection moulding, a first mould half having a first cavity is arranged on a first side of a fibre based packaging laminate, and a second mould half having a second cavity is arranged on an opposing side of the fibre based packaging laminate. Usually, the first mould cavity partly overlaps the second mould cavity in one or more overlapping areas. A small amount of a polymer melt is then injected into at least the first cavity. Due to pressure being built up in the first cavity, the melt will penetrate through the fibre-based packaging laminate in an overlapping area and also fill the second cavity for generation of an opening device extending through the packaging laminate.
The small amount of plastic employed by this technology vouches for that even if only a surface layer has started to solidify, this will be enough to retain the shape of the device until it has fully solidified, which in turn implies that the mould will be opened basically as soon as the injection is finalized. An outermost skin layer of the plastic melt will solidify as soon as it contacts the walls of a mould cavity, or the outermost layer of the packaging material. For non-complex designs this vouches for that the mould may be opened as soon as it is filled.
By the connection of the two parts, one on each side of the packaging material, i.e by the moulded so-called “bridge”, opening devices may be created that can apply forces on both sides of the material during opening, in an interactive way to promote easy opening while still using very little polymer material for the moulded parts of the opening device. Moreover, the high-pressure micro-injection moulding technology ensures a very time-efficient moulding process in high-speed filling machines, in the same operations as packages are formed, filled and sealed.
The heat sealable material 410, 510 is applied along what is to become transversal seals TS on the package formed from the finished laminated packaging material 200, 200′, 400, 500.
After the application of the heat sealable material 410, 510, the material 410, 510 is in direct contact with the innermost layer 203, 403, 503 of the laminated packaging material 100. A large surface area at the interface between the innermost layer 203, 403, 503 and the heat sealable material 410, 510 is advantageous for forming a seal between the heat sealable material portion 410, 510 and the surface of the innermost layer 203, 403, 503.
Finally, the heat sealable material portion 204, 204′, 404, 504 is bonded to the innermost layer when said heat sealable material 410, 510 solidify. The packaging material 200, 200′, 300, 400, 500 may subsequently proceed to a filling station and be formed into a package container 160, for example a package container 160 as shown in
The method 600 for producing a laminated packaging material 200, 200′, 300, 400, 500 comprising a locally distributed heat sealable material portion 204, 204′, 304, 404, 504 is performed after the converting process. Either, the method 600 is performed inside a filling machine or directly before the packaging material 100 enters the filling machine, after it has been unwound from the reel 110. Hence, feeding of the laminated packaging material 200, 200′, 300, 400, 500 should be sufficiently slow to allow for the attached heat sealable material portion 204, 204′, 304, 404, 504 to solidify. The speed of the packaging material may for instance be in the range of 0.5 m/s. Even though the speed is lower compared to when a packaging material is running through a converting station, a slower speed allows for the use of several different application methods for applying the heat sealable material 410, 510 on to the innermost layer 203, 203′, 303, 403, 503.
Application of the heat sealable material portion 204, 204′, 304, 404, 504 during the laminating/manufacturing process of converting will not be equally satisfactory, since the laminated packaging material 200, 200′, 300, 400, 500 comprising locally distributed heat sealable material portions 204, 204′, 304, 404, 504 will no longer be homogenously flat. Hence, the laminated packaging material 200, 200′, 300, 400, 500 cannot be reeled as a material reel 110 without damages and problems. The added heat sealable material portion 204, 204′, 304, 404, 504 will “build-up” while reeling and might provide uneven reels 110.
Furthermore, as mentioned above, normally the running speeds in converting are much higher than in the filing machine, which makes the application of a heat sealable material portion 204, 204′, 304, 404, 504 difficult. A local application of the extra heat sealable material portion 204, 204′, 304, 404, 504 during converting is thus much less preferred.
In
In
The later-to-be-formed cutting area 5c of the tube extends between the upper end seal 5a and the lower end seal 5b.
Thus, the transversal sealing area 140 comprises a lower sealing area 142, which is to form the lower seal of the package below as positioned in the tube at filling, an upper sealing area 144, which is to form the upper seal of the package above as positioned in the tube at filling, and a cutting area 146 arranged between the lower and upper sealing areas 142, 144.
Packages are cut off from a tube of the packaging material along a center line of the transversal cutting area 146, i.e. along a transversal linear cut 148. When the packages are cut off from the tube, they will thus have a narrow fin of packaging material extending below and above the upper and lower transversal seals 5a and 5b, respectively.
The additional heat sealable material is applied locally along the extensions of the lower and upper end seals, 5a and 5b.
Generally, a larger amount of heat sealable material may be arranged along the extensions of the end seal areas 5a,b at a lateral position corresponding to the position of the longitudinal seal of the tube 150a, 150b, where the longitudinal edges of the web-shaped packaging material are to overlap each other. When the bars of the transversal sealing jaws press the walls of the tube to each other to form a flat transversal seal, there will be higher pressure on the area of the longitudinal seal LS due to the double layers of material at the overlap seam 86. To ensure some heat sealable material to stay within the overlap, an extra amount is applied to this area. The extra amount is visible on the locally applied portion as a higher, or, as viewed from above as in this figure, a broader portion at the positions just beside the overlap seam.
A larger amount of heat sealable material may also be arranged along the extensions of the end seal areas 5a,b at a lateral position corresponding to the position where the tube will be folded during sealing, i.e. at a position corresponding to the lateral edge of the tube. The additional amount of thermoplastic polymer material has proven to improve seal strength of the tube at such positions 150c, 150d, thus also improving the integrity and appearance of the final package.
Similar larger amounts of heat sealable material may also be applied at other positions along the extensions of the end seal areas 5a, 5b to ensure a proper and durable transversal seal in the packages formed in the tube-filling and sealing operation.
From the description above follows that, although various embodiments of the invention have been described and shown, the invention is not restricted thereto, but may also be embodied in other ways within the scope of the subject-matter defined in the following claims.
Number | Date | Country | Kind |
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19186675.5 | Jul 2019 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2020/070171 | 7/16/2020 | WO |