Paint detackification using water-dispersible polymeric latexes

Abstract

Water-dispersible polymeric latexes are excellent paint detackifying agents for treating the circulating water in paint spray booths when latexes have an average particle size less than 10 microns.

Description

INTRODUCTION

This invention relates to a method for the treatment of wet spray booths by the use of small particle size water-dispersible polymeric latexes which diminishes the tackiness of coating material entrained in the circulating water which is sprayed for collecting surplus paint. The invention precludes the coating material from adhering fast to the interior surfaces of the circulating water systems.

Generally in automotive coating process, the yield of the paint applied to an automobile body ranges from 50 to 80%. The remaining 50 to 20% of the used paint constitutes an excess to be removed. The automobile body is spray painted. Over-sprayed paint is collected in a water spray. This water containing the over-sprayed paint is circulated for re-use.

In wet spray booths constructed as described above, the surplus paint which is collected in the washing water is tacky. It adheres to the water-film panel, the piping system, the spray nozzle, etc. of the spray booth, clogs the piping system and the nozzle, and seriously degrades the efficiency of water washing. Further, when the surplus paint so deposited clogs the waste gas discharge system and interferes with the flow air in the spray booth, the vapor of the solvent of the paint fills up the interior of the booth to produce a state dangerous to safety and hygiene. Also, the greater part of the surplus paint settles to the bottom of the booth and the circulation pit in the spray booth. This sediment of paint so formed hardens into a rubbery mass with elapse of time. The removal of this hardened mass and the cleaning of the bottoms take up much time and labor.

The paint collected in the washing water not merely undergoes adhesion or sedimentation within the system but also dissolves into components or disperses into fine particles. An increase in dissolved solids accelerates the progress of corrosion inside the system. The solvent in the paint increases the hydrocarbon content of the waste gas from the booth and also dissolves into the cleaning water and increases the COD (chemical oxygen demand) of the water being circulated. The solvent of the paint, depending on the kind thereof, acidifies the circulating water and consequently accelerates the corrosion of the system.

PRIOR ART

In U.S. Pat. No. 4,764,561 there is described a paint spray booth detackifying composition which includes mixtures of styrene-acrylate polymer and a melamine-formaldehyde polymer and the method of using same.

THE FIGURE

The figure shows a laboratory test apparatus used to evaluate the invention.

THE INVENTION

The invention comprises a method for the treatment of the circulating water which collects surplus paint in a paint spray booth which comprises treating this water with a paint detackifying agent comprising a water-dispersible polymeric latex having a dry average particle size less than 10 microns. These latexes are particularly effective in detackifying low solids enamels, e.g., 35% by weight solids or less. When these latexes are used to treat high solids enamels, base coat or clear coat enamels, they are advantageously used in combination with water-soluble or dispersible coagulants.

WATER-DISPERSIBLE POLYMERIC LATEXES

The water-dispersible polymeric latexes may be selected from a large number of polymeric emulsions of water-dispersible polymers.

Exemplary are the polyvinyl acetals which commercially have molecular weights ranging from as little as 10,000 to as high as about 50,000. Typical commercial polyvinyl acetals are the polyvinyl formals.

Polyvinyl acetate is another water-dispersible polymer which in latex form may be employed in the invention. In addition to its homopolymers, its copolymers formed from the following monomers may also be used: acrylic acid, acrylonitrile, chloroprene, diallyl phthalate, diethyl fumarate, ethylene, ethyl vinyl ether, isobutyl methacrylate, isopropenyl acetate, maleic anhydride, styrene, vinyl chloride, and N-vinylpyrrolidinone.

Another useful latex is polyvinyl chloride. Also useful are the various vinyl ether latexes such as the methyl and ethyl vinyl ether latexes. A list of typical vinyl ethers that may be polymerized to produce useful latexes are those set forth below in Table I.

TABLE I______________________________________ CH.sub.3 CH.sub.2 OCHCH.sub.2 (CH.sub.3).sub.3 COCHCH.sub.2 (CH.sub.3).sub.2 CHOCHCH.sub.2 ClCH.sub.2 CH.sub.2 OCHCH.sub.2 aryl vinyl ethers ##STR1## ##STR2## ##STR3## ##STR4##______________________________________

A group of preferred polymers are those of styrene and its copolymers, particularly the copolymers of styrene with butadiene and acrylate esters, e.g., methyl acrylate and ethyl acrylate.

Another preferred group of polymers are the acrylate esters and their copolymers. Typical acrylate esters are the methyl and ethyl acrylates.

For a more detailed description of latexes of the above type, reference may be had to Kirk-Othmer, Encyclopedia of Chemical Technology, Third Edition, Vol. 23, John Wiley & Sons, Inc., 1983, which is incorporated herein by reference.

Particle Size and Concentration of the Water-Dispersible Polymeric Latexes

A critical feature of the invention resides in the fact that the dry particle size of the water-dispersible polymeric latex must be small, e.g., 10 microns or less. In a preferred embodiment, the average particle size is 5 microns or less with a most preferred particle size range being 1 micron or less. The amount of the active polymers in the latex should be at least 200 ppm. Good results are achieved using latexes having polymer concentrations

200-400 ppm.

The Water-Soluble Coagulants These well-known compounds may be either inorganic, polymeric or blends of inorganic and polymeric flocculants. In certain instances, certain cationic surfactants such as fatty substituted amines or fatty substituted quaternary polymers function as coagulants. Typical of the coagulants that may be used are those described in Cocks, Canadian Patent 731,212, which is incorporated herein by reference.

Other useful coagulants are the quaternary ammonium salt polymers formed by reacting epichlorohydrin with diethyl amine. This technology is described in Panzer, et al, U.S. Pat No. Re 28,807, which is incorporated herein by reference. A preferred coagulant is the melamineformaldehyde resin described in U.S. Pat No. 4,764,561.

When the coagulants are used in conjunction with water-dispersible polymeric latex, the mixture may have a mole ratio ranging from 20:1 to 1:20. This ratio will depend on the particular combination of coagulant and latex used and the composition of the paint treated.

Dosage

The amount of water-dispersible polymeric latex product which contains the water-dispersible polymer used to produce paint detackification may vary between as little as 1 to as much as 5,000 ppm. A typical dosage is within the range of 40 to 600 ppm. Dosage is based upon the weight of the circulating water used to collect the surplus paint. When the water-dispersible polymeric latexes are combined with the water-soluble coagulants, a useful dosage of such products is also between 40-600 ppm.

Evaluation of the Invention

EXAMPLE 1

In this laboratory test using the test apparatus shown in the figure, desired amounts of detackifiers are added to the water manually or using a chemical pump to monitor the chemical demand. These detackifiers are allowed to mix in the tank through water recirculation for 5 minutes. The paint being tested is then sprayed into the chamber at a rate of 2 ml/min. through an air atomized spray gun located 12 inches above the center of the scrubbing section. The test paint is sprayed for 5 minutes, then the paint kill is tested for tackiness or stickiness. The testor wets his hand with the water solution in the test tank, then takes a sample of the floating paint sludge from the water tank, squeezes, and rubs tightly between his fingers. Any tackiness or stickiness present is a poor paint kill. A chart for degree of paint kill is provided below to assure consistent description. A minimum degree of kill of 6 is required to assure booth cleanliness.

At the conclusion of a good paint kill, paint is continuously sprayed, and the paint sludge conditions tested every few minutes. At any given time, if any trace of tackiness of sludge is present, paint spray should be discontinued and the program re-examined. The amount of paint sprayed should be recorded, and the chemical dosage and condition of sludge.

Additionally chemicals should be added and paint spray resumed. Repeat this process at least four times.

______________________________________Chart for Degree of Paint Kill______________________________________10 Perfect Complete kill, sludge is soupy9 Excellent Paint sludge is non-tacky, non-gritty8 Very Good Paint sludge is not tacky or gritty, but slightly plastic, may roll7 Good Not tacky, plastic consistency, sludge rolls and can easily reroll6 OK Minimum performance, very slightly tacky; rolls with water and reroll; can wash off without rubbing5 Borderline May stick slightly to glove but falls off with rubbing4 Unacceptable Slight tacky, sticks to glove with pressure, does not rub off, may roll3 Moderate failure Does not roll, sticks to glove, smears2 Severe failure Tacky, smears1 Very sticky Smears0 Like raw paint______________________________________

The invention was evaluated and the results obtained are as follows:

TABLE II______________________________________Latex No. Water-insoluble Polymeric Latex Tested______________________________________1 An acrylate-vinyl acetate-vinyl chloride polymer Particle size: 0.6.mu. Supplied by Union Carbide2 A vinyl acetate polymer Particle size: 0.5.mu. Supplied by National Starch3 A styrene-acrylate polymer Particle size: 0.5.mu. Supplied by Rohm & Haas4 A styrene-acrylate polymer Particle size: 0.06-0.09.mu. Supplied by Emulsion System M. W. 100,000-150,0005 A styrene-butadiene polymer Supplied by B. F. Goodrich6 A styrene-acrylate polymer Particle size: 0.5.mu. Supplied by Emulsion System M. W. 50,000-100,0007 A styrene-acrylate-acrylamide polymer Particle size: 0.5.mu. Supplied by Emulsion System8 A styrene-acrylate polymer Particle size: 0.5.mu. Supplied by Essential Chemicals9 (RWL-112) - polystyrene latex polymer Particle size: 0.3.mu. Supplied by Morton Thiokol______________________________________

Latexes were tested alone at pH 9-10 as a single detackifier. When high concentration latex (i.e., 5,000 ppm-10,000 ppm) was used or when a lower solids enamel paint (lower than 35% solids) and lacquer paint were used, the above latexes gave a good detackification property.

Latexes where also tested with a variety of coagulants. These compositions are shown in Table IV.

However, when a high-solid enamel or base coat/clear coat enamel paint was used, additional coagulants had to be used in conjunction with the latex to obtain an acceptable paint kill.

For more quantitative test results, the pilot recirculator test was then used.

Several coagulants were tested in combination with the latexes. Table III shows the coagulants used in the test.

TABLE III______________________________________Coagulant No.______________________________________1 Poly aluminum chloride + epi-DMA2 EDC/NH.sub.2 CH.sub.3 Cl quaternary3 TEA quat./Alum4 Aniline formaldehyde5 EPI/DMA-NH.sub.3 crosslinked6 EDC/NH.sub.3 /NaOH7 Ditallow dimethyl ammonium chloride8 Calcium chloride9 Melamine formaldehyde10 Clay/polyamine11 Poly aluminum chloride12 Rohm & Haas XE-492______________________________________

The results of the tests using the latexes with the coagulants are set forth below in Table IV.

TABLE IV______________________________________ Ratio of Latex:Latex No. Coagulant No. Coagulant Results______________________________________9 6 4.5:1 Kill 39 2 6.0:1 Kill 39 11 1.7:1 Kill 59 8 + 11 1.0:1 Kill 69 9 1.0:9 Kill 76 11 1.0:3 Kill 56 2 5.0:1 Kill 36 4 1.7:1 Kill 46 8 0.3:1 Kill 26 1 1.0:1 Kill 76 7 2.5:1 Kill 26 5 5.0:1 Kill 56 3 1.0:1 Kill 26 9 1.0:12 Kill 8-94 12 1.0:1 Kill 44 9 1.0:1 Kill 54 7 1.0:7 Kill 21 4 2.6:1 Kill 51 9 2.8:1 Kill 62 9 1.0:8 Kill 52 4 2.0:1 Kill 3______________________________________ Note: See the Chart for Degree of Paint Kill.

Claims

1. A method of treating circulating wash water from a paint spray booth, said wash water containing an over-sprayed portion of an enamel paint which, prior to spraying, has a solids content of 35% by weight or less in order to prevent said over-sprayed paint contained in said wash water from adhering to the interior surfaces of the circulating water system, which method comprises adding to said water a water-dispersible, polymeric latex detackifier selected from the group consisting of polyvinyl acetate, copolymers of vinyl acetate, polyvinyl chlorides, polystyrene and copolymers of styrene, said latex detackifier having an average particle size of less than 10 microns and being present in an amount to detackify said over-sprayed paint contained in said wash water.

2. The method of claim 1, wherein the water-dispersible polymeric latex is selected form the group consisting of polyvinyl acetate, copolymers of vinyl acetate, polystyrene and copolymers of styrene.

3. A method of treating circulating wash water from a paint spray booth, said wash water containing an over-sprayed portion of an enamel paint, which, prior to spraying, has a solids content greater than 35% by weight in order to prevent said over-sprayed paint contained in said wash water from adhering to the interior surfaces of the circulating water system, which method comprises adding to said water (a) a water-dispersible, polymeric styrene-acrylate latex having an average particle size of less than 10 microns and (b) a melamine-formaldehyde coagulant, said latex detackifier and coagulant being present in an amount to detackify said over-sprayed paint contained in said wash water.