Various embodiments of the present invention pertain to apparatus and methods for reducing the thermal or electrical interface resistance between two devices that are in contact and, more particularly, to improvements by using an interface including carbon nanoparticles that have been altered with either electron-donating molecules or electron-withdrawing molecules.
As the size of electronic devices scales down and power densities increase, the demand for innovative cooling solutions becomes more imperative. Thermal interface materials (TIMs) such as thermal greases and gels with highly conductive particle additives are commonly used in microprocessor cooling solutions where operating temperatures are near 100° C. However, recent reliability tests on polymeric TIMs using thermogravitic analysis revealed a dramatic increase in thermal interface resistance as operating temperatures and exposure times increased. Because of their high thermal conductivity, mechanical compliance, and stability over a wide temperature range, carbon nanotubes have been extensively studied as conductive elements. Several recent reports have shown that dense, vertically aligned CNT arrays are viable alternatives to current state-of-the-art TIMs. However, when contact sizes between a nanotube and an opposing surface become comparable to the mean free path of the dominant energy carriers, nanoscale constriction resistance becomes important. For CNT TIMs similar to those in this study, the resistive component at the CNT ‘free tip’ and opposing metal substrate has been shown to cause the largest constriction of heat flow in comparison to the bulk CNT and growth substrate resistances [9]. Reduction of this ‘free tip’ constrictive resistance using novel CNT TIM composite structures is shown in several embodiments of the inventions disclosed herein.
Recent thermal resistance values for CNT based TIMs have been measured to be between 1-20 mm2 K/W. The thermal resistance values include both bonded and non-bonded interfaces, and measurements were obtained using different characterization techniques (1D reference bar, thermoreflectance, photoacoustic, and 3-omega). Weak bonding at heterogeneous interfaces, differences in phonon dispersion and density of states, and wave constriction effects are factors that could hinder further reduction in thermal contact resistance. Adverse phonon constriction can be moderated by increasing the interfacial contact area. In an effort to increase the interfacial contact area, developments in bonded and semi-bonded CNT TIMs have rendered thermal interface resistances as low as 1.3 mm2 K/W and 2 mm2 K/W, respectively. CNTs exhibit ballistic conduction of electrons in the outermost tubes and ohmic current-voltage characteristics with certain metals. When this effect is coupled with a strong metallic-like bond at the CNT/metal substrate interface, phonon constriction could be circumvented by using electrons as a secondary energy carrier. A possible way to achieve electron transmission is through a strong CNT/metal substrate bond and sufficiently high electron DOS at the interface.
Silicon carbide (SiC), with a band gap near 3.3 eV, is attractive for high-temperature power electronic applications such as high-voltage switching for more efficient power distribution and electric vehicles, powerful microwave electronics for radar and cellular communications, and fuel efficient jet aircraft and automobile engines. At high temperatures, phonon scattering with charge carriers increases while the charge carrier mobility, which dictates electrical conductivity, is adversely affected. In order to maintain sufficient electrical conductivities for reliable operation in such applications, innovative heat dissipation methods that can withstand high temperature environments are necessary.
With regards to the performance of a Si/CNT interface with a commercial phase change material (PCM) applied to a CNT array, there is a decrease in thermal resistance of approximately 10 mm2 K/W between Si/PCM/Cu interfaces and Si/CNT/PCM/Cu interfaces, which achieved a low value of approximately 5 mm2 K/W at 350 kPa. Also, there can be a 50% reduction in thermal interface resistance by wicking paraffin wax into CNT arrays grown on both sides of Cu foil. It is possible that such improvement is the result of an increase in contact area and reduction in constriction resistance at the ‘free tip’ interface. However, PCMs and paraffin wax suffer similar disadvantages as polymeric TIMs at high temperatures. In contrast, thermal resistances near 10 mm2 K/W in a dry SiC/CNT/Ag interface can be achieved, with the possibility of a weak dependence of thermal interface resistance on temperatures up to 250° C., indicating that the TIM was suitable for high temperature applications.
What is needed are thermal interface materials and construction methods that have lowered thermal interface resistance and improved long term characteristics. Various embodiments of the present invention do this in novel and unobvious ways.
Various embodiments of the present invention pertain to altering the charge density of carbon nanotubes to add to the effectiveness of CNT thermal interface materials.
While heat conduction in carbon nanotubes is commonly dominated by phonon transport, some embodiments of the present invention pertain to methods for opening channels for electron transport to provide an alternative transport path that is particularly useful at interfaces, where the longer phonon wavelength and/or lower electron densities can dramatically impede transport.
In some embodiments, CNT TIMs are enhanced with Pd nanoparticles using a method for CNT synthesis and a process for bonding interfaces using Pd hexadecanethiolate. Structures enhanced with Pd nanoparticles exhibited improved thermal performance and thermal interface resistances that are comparable to previously reported values in the literature and that can outperform some state-of-the-art TIMs used in industry.
Various embodiments of the present invention pertain to thermal interface materials (TIMs) that have enhanced thermal stability across a wide temperature range. Structures made according to these various embodiments are suitable for a variety of applications, particularly high temperature electronics.
One embodiment of the present invention pertains to a method including providing a growth substrate and growing carbon nanotubes from the growth substrate. Still further embodiments include applying a solution containing a metal organic compound to the nanotube array and thermally decomposing the solution around the nanotubes and substrate.
Another embodiment of the present invention pertains to a method including growing carbon nanotubes from the growth substrate, each nanotube being anchored at one end to the growth substrate, and altering the density of states of energy carriers in the nanotubes.
Yet another embodiment of the present invention pertains to a method for fabricating a thermal interface, including providing a first growth substrate and a second substrate. Yet other embodiments include growing a first plurality of carbon nanotubes from a first surface of the first growth substrate, each nanotube of the first plurality being anchored at one end to the first surface. Still other embodiments include placing a second plurality of carbon nanotubes on a second surface of the second growth substrate. Still further embodiments include placing the first plurality of nanotubes in contact with the second plurality of nanotubes and applying a solution containing a metal organic compound to the contacting nanotubes, and thermally decomposing the solution.
Another embodiment of the present invention pertains to a method for fabricating a thermal interface. Other embodiments include providing a first growth substrate and a second growth substrate. Yet other embodiments include growing a first plurality of carbon nanotubes from a first surface of the first growth substrate, and growing a second plurality of carbon nanotubes from a second surface of the second growth substrate. Yet other embodiments further include placing the first plurality of nanotubes in contact with the second plurality of nanotubes with the first surface being opposite of the second surface and altering the density of states of an energy carrier in the contacting nanotubes.
It will be appreciated that the various apparatus and methods described in this summary section, as well as elsewhere in this application, can be expressed as a large number of different combinations and subcombinations. All such useful, novel, and inventive combinations and subcombinations are contemplated herein, it being recognized that the explicit expression of each of these combinations is excessive and unnecessary.
For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiments illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, such alterations and further modifications in the illustrated device, and such further applications of the principles of the invention as illustrated therein being contemplated as would normally occur to one skilled in the art to which the invention relates. At least one embodiment of the present invention will be described and shown, and this application may show and/or describe other embodiments of the present invention. It is understood that any reference to “the invention” is a reference to an embodiment of a family of inventions, with no single embodiment including an apparatus, process, or composition that must be included in all embodiments, unless otherwise stated.
The use of an N-series prefix for an element number (NXX.XX) refers to an element that is the same as the non-prefixed element (XX.XX), except as shown and described thereafter. As an example, an element 1020.1 would be the same as element 20.1, except for those different features of element 1020.1 shown and described. Further, common elements and common features of related elements are drawn in the same manner in different figures, and/or use the same symbology in different figures. As such, it is not necessary to describe the features of 1020.1 and 20.1 that are the same, since these common features are apparent to a person of ordinary skill in the related field of technology. Although various specific quantities (spatial dimensions, temperatures, pressures, times, force, resistance, current, voltage, concentrations, wavelengths, frequencies, heat transfer coefficients, dimensionless parameters, etc.) may be stated herein, such specific quantities are presented as examples only. Further, with discussion pertaining to a specific composition of matter, that description is by example only, and does not limit the applicability of other species of that composition, nor does it limit the applicability of other compositions unrelated to the cited composition.
This application incorporates by reference U.S. patent application Ser. No. 11/873,952, titled ELECTROTHERMAL INTERFACE MATERIAL ENHANCER to inventors Fisher and Cola.
Some embodiments of the present invention utilize CNT TIMs enhanced with palladium (Pd) nanoparticles to achieve low thermal interface resistances suitable for electronics in a wide temperature range. Several possible enhancements of CNTs with Pd nanoparticles are disclosed herein. One enhancement is an increase in contact area between the CNT ‘free tips’ and an opposing metal substrate that is formed from the Pd weld. This increase in contact area mitigates the phonon bottleneck at the CNT/metal substrate interface. Another concerns increasing electron density of states (DOS) near the Fermi level at the CNT/metal substrate interface that is a result of charge transfer between CNTs and Pd nanoparticles. In some embodiments, it is possible that electrons are used as a secondary energy carrier at the interface. One- and two-sided interfaces, comprised of CNT arrays grown on Si substrates, are bonded to opposing metal substrates using a new method that utilizes the behavior of Pd hexadecanethiolate upon thermolysis. Using a transient PA technique, bulk and component thermal interface resistances of the Pdbonded CNT interfaces were resolved.
In one embodiment, CNT TIMs enhanced with Pd nanoparticles were fabricated using a new process for bonding interfaces using Pd hexadecanethiolate. A transient photoacoustic technique was used to resolve bulk and component thermal interface resistances. Structures enhanced with Pd nanoparticles exhibited improved thermal performance and thermal interface resistances that are comparable to previously reported values in the literature and that outperform most state-of-the-art TIMs used in industry. It is possible that the majority of improved performance can be attributed to the Pd weld that reduced phonon reflection at the interface by increasing the contact area between the CNT ‘free-tips’ and an opposing metal substrate. In addition, some embodiments contemplate utilizing electrons as a secondary energy carrier at the interface because of an increase in electron density of states at the CNT/Ag interface. In some embodiments, it is possible that there is a dependence that electron transmission has on wave vector conservation and disorder. With thermal stability across a wide temperature range, these structures are suitable for a variety of applications, particularly high-temperature electronics.
Functionalizing CNTs with metal nanoparticles (Pt, Au, Pd, Ag, Au) has been an area of growing interest for a diverse set of applications. For example, a biosensor involving Au/Pd nanocubeaugmented SWCNTs showed significant increases in glucose sensing capabilities. The increased performance was attributed to a highly sensitive surface area, low resistance pathway at the nanocube-SWCNT interface, and selective enzyme adhesion, activity, and electron transfer at the enzyme, Au/Pd nanocube interfaces. Metal nanoparticles can adhere to CNTs through covalent or van der Waals interactions, which can lead to charge transfer. Single-walled CNTs interacting with Au and Pt nanoparticles can exhibit an increase in the ratio of metallic to semiconducting tubes. Charge density analysis showed a decrease in electron density in the valance band of Au and an increase in the outer orbitals of C, indicating direct charge transfer. There can also be changes in the Raman G-band peak intensity for pristine and silver nanoparticle-decorated metallic SWCNTs, indicating that the nanoparticles alter the electronic transitions of the tubes. With its high work function and strong adhesion to CNTs, Pd can be a metal that electronically couples well to CNTs. Additionally, efficient carrier injection from Pd monolayers to graphene can be accomplished because of the band structure that results from the hybridization between the d orbital of Pd and orbital of graphene.
Metal alkanethiolates can serve as sources of metal clusters upon thermolysis and yield either metal or metal sulfide nanoparticles. While some metal alkanethiolates are insoluble in most organic solvents, Pd alkanethiolates have been reported to be soluble in these solvents and also exhibit repeated self-assembly. The soluble nature of Pd alkanethiolates in such solvents makes them attractive for forming smooth, thin films on substrates. Some embodiments of the present invention use Pd hexadecanethiolate (
Pd hexadecanethiolate has been patterned using electron beam lithography and subsequent formation of Pd nanoparticles on thermolysis was demonstrated. Energy-dispersive spectral (EDS) values before and after thermolysis were 21:71:8 and 90:9.6:0.4 for (Pd:C:S), respectively. Most notably, electrical measurements yielded resistivity values of Pd nanoparticles that were similar to that of bulk Pd. Although what is shown and described is the use of a particular metal alkanethiolate, the present invention is not so limited, and pertains to the use of compounds including other metals, including iron, gold, and silver as examples. Further, other embodiments include the use of butane thiolates, including various metal butane thiolates, including palladium butane thiolate.
In one embodiment of the present invention, an apparatus is constructed as follows: an electron beam evaporative system was used to deposit a tri-layer metal catalyst stack consisting of 30 nm Ti, 10 nm Al, and 3 nm Fe on polished intrinsic Si substrates. For a two-sided interface, the tri-layer catalyst was deposited on both a Si substrate and 25 μm thick Cu foil purchased from Alfa Aesar (Puratronic®, 99.999% metals basis). Vertically oriented CNT arrays of moderately high density were then synthesized in a SEKI AX5200S microwave plasma chemical vapor deposition (MPCVD) system. The growth chamber was evacuated to 1 Torr and purged with N2 for 5 min. The samples were heated in N2 (30 sccm) to a growth temperature of 900° C. The N2 valve was then closed and 50 sccm of H2 was introduced to maintain a pressure of 10 Torr in the growth chamber. After the chamber pressure stabilized, a 200 W plasma was ignited and 10 sccm of CH4 was introduced to commence 10 minutes of CNT synthesis.
The samples were imaged using a Hitachi field-emission scanning electron microscope (FESEM).
For preparation of Pd hexadecanethiolate, an equimolar solution of Pd(OAc)2 (Sigma Aldrich) in toluene was added to hexadecanethiol and stirred vigorously. Following the reaction, the solution became viscous and the initial yellow color deepened to an orange-yellow color. The hexadecanethiolate was washed with methanol and acetonitrile to remove excess thiol and finally dissolved in toluene to obtain a 200 mM solution. Using a micropipette, approximately 16 μL of Pd hexadecanethiolate was added to the CNT array. The CNT array 40 was then heated for 5 minutes at 130° C. to evaporate the toluene. Finally, the sample was formed by sandwiching the structure under a pressure of 273 kPa and commencing thermolysis by baking at 250° C. for 2 hours in air. In yet other embodiments, the CNT array has applied to it solution including a metal acetate, thiol and toluene
Although a particular process for decomposing has been shown and described, the present invention is not limited to these parameters, which are by way of example only. Further examples include, for those embodiments using a hexadecane thiolate, a range of temperatures from about 230 C to about 300 C. In those embodiments using a butane thiolate, another non-limiting range of temperatures is from about 160 C to about 300 C. Further, although thermolysis has been shown and described as being performed at a pressure of 273 kPa, it is understood that in other embodiments any range of pressure can be used, include 0 kPa applied pressure. Further, although thermolysis was accomplished in air, it is also understood that other embodiments are not so limited, and contemplate atmospheres of nitrogen or high vacuum.
Various embodiments of the present invention contemplate thermal interfaces comprising a single layer of carbon nanotubes attached to a substrate and having free tips in contact with a second, opposing substrate. Yet other embodiments of the present invention contemplate two substrates, each having carbon nanotubes attached, in which the free tips of both sets of carbon nanotubes are in contact with each other.
a) shows a thermal interface comprising a substrate 30 (such as silicon) from which a forest of nanotubes 40 has been grown. The nanotubes 40 are attached at one end to substrate 30. The other end of the CNTs 40 is free, such that the length of the nanotubes substantially extends away from substrate 30. A second substrate 60 (such as silver, copper, gold, or any suitable heat-conducting substrate) is placed opposite of the growth substrate 30, such that the array of carbon nanotubes 40 is located between the two substrates. The metal nanoparticles 50 (such as palladium nanoparticles) are subsequently introduced into the assembly 20 preferably by any of the methods described herein. As is noted herein, the nanoparticles can both decrease the thermal resistance from the free tip of the CNT 40 to the opposing substrate 60 as a “weld,” but also the nanoparticles 40 can bond with more than one carbon nanotube 40, possibly through defect sites.
In some embodiments, substrate 30 can be utilized as part of a component with which it is desired to exchange heat. In some embodiments, assembly 20 can be a separate component that is applied to a thermal interface of a device such as an electronic component.
b) shows an assembly 120 in which carbon nanotubes have been grown both from a first substrate 130, and also from a second substrate 160. Each array of carbon nanotubes (array 140 grown from substrate 130; and array 170 grown from substrate 160) are attached at one end to their respective substrate, with the other, free tip end of the CNTs being located away from the substrate. As shown in
A transient photoacoustic (PA) technique was used to characterize thermal interface resistances.
R
bulk
=R
Si-CNT
+R
CNT
+R
CNT-Ag (1)
where RCNT is the resistance of the CNT array and RSi-CNT and RCNT-Ag are the contact resistances at the Si-CNT and CNT-Ag interfaces, respectively. Briefly, in a given PA measurement the sample surface is surrounded by a sealed acoustic cell that is pressurized with He gas at 34 kPa. The sample is then heated over a range of frequencies by a 350 mW, modulated laser source. The thermal response of the multilayer sample induces a transient temperature field in the gas that is related to cell pressure. A microphone housed in the chamber wall measures the phase shift of the temperature-induced pressure response in the acoustic chamber. Using the acoustic signal in conjunction with a thermal model developed that is based on a set of one-dimensional heat conduction equations, thermal interface resistances are determined using a least-squares fitting method.
The PA technique was used to resolve bulk thermal interface resistances of one- and two-sided TIMs with configurations of Si/CNT/Ag and Si/CNT/CNT/Cu. The latter samples had CNT arrays grown on both the Si and Cu substrates, and the resulting interface formed a two-sided, Velcro™-like structure (see
In order to ensure proper operation of the pressure-field microphone used in the PA setup, the maximum temperature tested was 250° C., and the chamber pressure was limited to 34 kPa. Bulk resistance measurements for the Si/CNT/Ag and i/CNT/CNT/Cu samples were taken in a temperature range of 27° C. to 250° C. while the component resistance measurement on the second Si/CNT/Ag sample was performed at 27° C.
Within the temperature range, the Si/CNT/Ag and Si/CNT/CNT/Cu structures decorated with Pd nanoparticles outperformed the structures without Pd nanoparticles where the average thermal resistance value for the Pd nanoparticle-enhanced structures was 11 mm2 K/W and 5 mm2 K/W, respectively. Averaging thermal resistances across the temperature range yielded reductions of thermal resistance across the interface of approximately 50% in both cases. In addition, all structures exhibited only small variations in performance across the temperature range, indicating thermal stability and applicability to high-temperature devices.
The summary results in Table 1 indicate that reductions in bulk thermal resistance between decorated and undecorated TIMs occurred at the Si-CNT and CNT-Ag interfaces, with the latter having the largest reduction. These results indicate that the dominant thermal resistance was at the CNT ‘free tip’ interface as opposed to the growth substrate interface where the CNTs are well adhered. This reduction at the CNT-Ag interface can be attributed to two mechanisms. First, upon thermolysis, a strong bond between at the CNT/Ag was created such that greater contact area was achieved. It is possible that the bond results in the majority of improvement to the reduced phonon reflection at the CNT/Ag interface. In addition, the increase in contact area may reduce phonon reflection at the boundary consisting of nano-sized contacts and provided enhanced pathways for heat conduction.
Thermal treatment of Pd hexadecanethiolate at 230 C in air can produce metallic Pd nanowires with a specific electrical resistivity near 0.300 μΩm. Thermal treatment of structures in this study could have produced a metallic-like bond between CNT free ends and Ag foil via Pd nanoparticles in which a higher electron DOS near the Fermi level at the CNT/Ag interface was established.
Two types of contacts can exist at a CNT/metal interface: side- and end-contacted. Although the general orientation of the, CNT arrays in
For larger diameter tubes, such as the CNTs in some embodiments of the present invention, wavevector conservation becomes a consideration. However, such conservation principles can be relaxed when disorder (defects and impurities) are present. Plasma-enhanced chemical vapor deposition (PECVD) grown CNTs in previous work have exhibited relatively high defects at the sidewalls due to plasma etching. Thus, the additional disorder from sidewall defects caused by PECVD synthesis and Pd impurities at the CNT/Ag interface could relax wave vector conservation constraints. In this case, additional scattering from defects and Pd impurities could increase the transmission probability across the CNT/Ag interface, mediated by the presence of the Pd nanoparticles. It is possible that similar effects are operative for the two sided TIM configuration (
Referring to
Yet other embodiments of the present invention pertain to an apparatus to be inserted between a processor chip or an integrated circuit (IC) device and a heat sink to allow the chips or IC devices to operate at lower temperatures. Yet other embodiments pertain to an apparatus to be inserted between an electrical device and a connecting electrical device to allow electricity to pass between the devices with minimal resistance.
An interface with a CNT array directly synthesized on one side of the interface has been measured to have a thermal resistance less than 8 mm2K/W, which is better than the resistance of the state of the art commercial thermal interface materials. An interface with a CNT array directly synthesized on both sides of the interface has been measured to have a thermal resistance of 4 mm2K/W, which is similar to the resistance of a soldered joint. Park et al. studied the effects of a CNT layer on electrical resistance between Cu substrates. For an apparent contact area of 0.31 mm2, they reported an 80% reduction in electrical resistance from a bare Cu/Cu interface to Cu/MWCNT/Cu interface.
When contact sizes between a nanotube and another material (e.g. CNT-Cu interface) are relatively small there is exists a major impediment to heat flow at the true heterogenous material interface in which ballistic phonon effects can substantially decrease conductance. These effects include impedance mismatch and wave constriction at nanoscale contacts. Some embodiments of the present invention use an approach in which this phonon “bottleneck” is circumvented by altering the charge density in the nanotubes via exposure to electron-donating and withdrawing molecular species. The process includes increasing the electronic contribution to thermal conductivity at a CNT-substrate interface by chemically opening electron channels for the transport of heat.
The thermal interface resistance of a CNT TIM with this process is measured using a photoacoustic technique. At moderate pressures, a 40% reduction in bulk thermal interface resistance from the minimum to maximum aniline concentrations was observed. The use of another electron-donating molecule, TTF, is expected to provide much improved performance because of the increased alteration of the charge density. These results indicate that the enhanced thermal conduction by electrons, with their smaller wavelengths, opens a new route for heat transfer and improves thermal conductance, particularly between the free CNT tips and opposing substrate.
The CNT arrays can be synthesized using any CNT synthesis technique that allows for dense, vertically oriented CNT arrays to be directly grown on both sides or one side of substrates while having strong mechanical adhesion between the CNTs and the surfaces (e.g. microwave plasma chemical vapor deposition (MPCVD) and a Ti underlayer on the substrates surfaces to promote adhesion). Addition of the molecular species (aniline, TTF, TONE) can be accomplished by dip coating the array in the chemical solution and drying in vacuum. TTF and TONE can to be mixed with toluene prior to dip coating the array and drying in vacuum.
In addition to the use of aniline (or phenylamine), the present invention contemplates the use of other aromatic amines, including as examples o-toluidine; 2, 4, 6-trimethylaniline; anisidine; or 3-trifluoromethylaniline. Further, although the use of TTF has been shown and described, it is understood that other embodiments of the present invention contemplate the use of other organosulfur compounds, including as examples tetracyanoquinodimethane; tetramethyltetrathiafuvalene; tetramethylselenafulvalenes; or dimethylanthracene. In addition, although the use of TONE has been shown and described, although it is recognized that other embodiments of the present invention contemplate the use of other organic compounds such as tricyanomethane; tetracyanoethylene; tetracyanoquinodimethanide; nitrobenzene; etra sodium; 1,3,6,8-Pyrenetetrasulfonic acid; or 9,10-dibromoanthracene.
Further, some embodiments of the present invention pertain to the use of electron-donating materials, some non-limiting examples of which include tetracyanoquinodimethane; tetramethyltetrathiafulvalene; tetramethylselenafulvalenes; or dimethylanthracene. The use of an electron-withdrawing material has been disclosed, and it is recognized that non-limiting list of examples includes tricyanomethane; tetracyanoethylene; tetracyanoquinodimethanide; nitrobenzene; etra sodium; 1,3,6,8-pyrenetetrasulfonic acid; or 9,10-dibromoanthracene.
While the inventions have been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiment has been shown and described and that all changes and modifications that come within the spirit of the invention are desired to be protected.
This application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 61/158,187, filed Mar. 6, 2009, entitled MOLECULAR DOPING OF CARBON NANOTUBE THERMAL INTERFACE MATERIALS, and U.S. Provisional Patent Application Ser. No. 61/234,270, filed Aug. 15, 2009, entitled PALLADIUM THIOLATE BONDING OF CARBON NANOTUBES, both of which are incorporated herein by reference.
Number | Date | Country | |
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61158187 | Mar 2009 | US | |
61234270 | Aug 2009 | US |