Abrasive articles made from abrasive platelets are useful for abrading, finishing, or grinding a wide variety of materials and surfaces in the manufacturing of goods. In particular, finishing of welding beads (e.g., especially mild steel welds), flash, gates, and risers off castings by offhand abrading with a handheld right-angle grinder is an important application for coated abrasive discs. In view of the above, there continues to be a need for improving the cost, performance, and/or life of the abrasive articles as well as manufacturing thereof.
The present disclosure provides a method including receiving, at a shaped abrasive particle placement tool comprising cavities, shaped abrasive particles, determining whether a threshold number of cavities of the cavities includes a shaped abrasive particle of the shaped abrasive particles situated properly therein, in response to determining there is not a threshold number of cavities of the cavities with a shaped abrasive particle of the shaped abrasive particles situated properly therein, receiving, at the shaped abrasive particle placement tool, further shaped abrasive particles, and in response to determining that at least the threshold number of cavities of the cavities includes a shaped abrasive particle of the shaped abrasive particles situated properly therein, releasing the shaped abrasive particles from the shaped abrasive particle placement tool into at least one binding material on a substrate to adhere the first shaped abrasive particles and the second shaped abrasive particles to the substrate.
The method can further include one or more of: after receiving the shaped abrasive particles removing, from shaped abrasive particle placement tool, at least one of the received shaped abrasive particles improperly situated in a cavity of the cavities; before depositing the shaped abrasive particles into the at least one binding material, removing further shaped abrasive particles that are not in a respective cavity of the cavities off the shaped abrasive particle placement tool; vibrating the shaped abrasive particle placement tool to situate shaped abrasive particles of the shaped abrasive particles into a cavity of the cavities; wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
The present disclosure further provides another method including receiving, at a shaped abrasive particle placement tool comprising first cavities with a first specified characteristic and second cavities with a lesser corresponding characteristic, first shaped abrasive particles with a corresponding characteristic greater than the second characteristic and less than the first characteristic, after receiving the first abrasive particles, receiving, at the shaped abrasive particle placement tool, second shaped abrasive particles with a corresponding characteristic less than the second characteristic, and releasing the shaped abrasive particles from the shaped abrasive particle placement tool into at least one binding material on a substrate to adhere the first shaped abrasive particles and the second shaped abrasive particles to the substrate.
The method can further include one or more of: before receiving the second shaped abrasive particles and after receiving the first shaped abrasive particles, removing first shaped abrasive particles that are not in a respective first cavity of the first cavities of the shaped abrasive particle placement tool or removing first shaped abrasive particles that are not properly situated in a respective first cavity of the first cavities of the shaped abrasive particle placement tool and receiving further first shaped abrasive particles until a threshold number of the first cavities includes a first shaped abrasive particle situated therein; before depositing the shaped abrasive particle placement tool into the at least one binding material, sweeping or blowing second shaped abrasive particles off that are not in a respective second cavity of the second cavities off the shaped abrasive particle placement tool and receiving further second shaped abrasive particles until a threshold number of the second cavities includes a second shaped abrasive particle situated therein; wherein the characteristic includes a height, width, or depth; wherein the first shaped abrasive particles or the second shaped abrasive particles are not equilateral triangles; further comprising vibrating the shaped abrasive particle placement tool to situate a first shaped abrasive particle of the first shaped abrasive particles into a first cavity of the first cavities; and wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
The present disclosure further provides a shaped abrasive particle placement tool including a substrate including an abrasive article receiving surface and a back surface opposite the abrasive article receiving surface, cavities formed in the substrate including one or more sidewalls, the cavities including first cavities and second cavities, the first cavities including a first width and first length at the abrasive article receiving surface, and a first depth indicating a distance the first cavities extend from the abrasive article receiving surface towards the back surface, the second cavities including a second width and second length at the abrasive article receiving surface, and a second depth indicating a distance the second cavities extend from the abrasive article receiving surface towards the back surface, wherein one or more of (1) the first width is greater than the second width, (2) the first length is greater than the second length, or (3) the first depth is greater than the second depth, first shaped abrasive particles situated in the first cavities, the first shaped abrasive particles including (1) a width and length less than the first width and first length, respectively, and greater than the second width or second length, respectively, or (2) a height greater than a threshold greater than the second depth and less than the threshold greater than the first depth, and second shaped abrasive particles situated in the second cavities, the second shaped abrasive particles including (1) a width and length less than the second width and the second length, respectively, or (2) a height less than the threshold greater than the second depth.
The shaped abrasive particle placement tool can further include one or more of: wherein the first cavities are situated in a non-random orientation relative to one another; wherein the first width is greater than the second width or the first length is greater than the second length; wherein the first shaped abrasive particles include a width and length less than the first width and first length, respectively, and greater than the second width or second length, respectively; wherein the second shaped abrasive particles include a width and length less than the second width and the second length, respectively; wherein the first depth is greater than the second depth; wherein the first abrasive articles include a height greater than a threshold greater than the second depth and less than the threshold greater than the first depth; and the second abrasive articles include a height less than the threshold greater than the second depth; wherein at least one of the first and second shaped abrasive particles includes a non-equilateral triangle shape; wherein the first cavities include at least two at least partial triangular walls connected to each other and separated by two sidewalls; wherein the first cavities include four at least partially triangular walls forming a pyramid or truncated pyramid shape; wherein the first shaped abrasive particles and the second shaped abrasive particles include a respective different characteristic; wherein the characteristic is surface area of a major surface of the first shaped abrasive particles and the second shaped abrasive particles; wherein the first cavities and the second cavities include different respective depths and the first cavities and the second cavities are situated in an alternating pattern in the substrate; wherein at least one second cavity of the second cavities is situated between two nearest first cavities with respective major surfaces within 10 degrees of a parallel with each other; wherein the cavities include pods of cavities situated with major surfaces within 10 degrees of perpendicular to each nearest pod, each pod comprising a second cavity of the second cavities situated between two first cavities of the first cavities, and wherein the respective major surfaces of the first cavities and second cavity of the pod are within 10 degrees of parallel to each other; wherein the cavities further include third cavities, a width of the third cavities is less than the second width which is less than the first width; and wherein the cavities are situated with a second cavity of the second cavities between a first cavity of the first cavity and a third cavity of the third cavities; wherein the characteristic includes aspect ratio indicating a ratio of height a shaped abrasive particle extends from an axis perpendicular to the major surface of the substrate to a width of the element parallel to the major surface of the substrate; and wherein the first cavities and the second cavities are situated randomly relative to one another in the substrate.
The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present document.
Reference will now be made in detail to certain embodiments of the disclosed subject matter, examples of which are illustrated in part in the accompanying drawings. While the disclosed subject matter will be described in conjunction with the enumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.
Throughout this document, values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.
In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. The statement “at least one of A and B” has the same meaning as “A, B, or A and B.” In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that section.
In the methods described herein, the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.
The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range and includes the exact stated value or range.
The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more, or 100%.
As used herein “shaped abrasive particle” means an abrasive particle having a predetermined or non-random shape. One process to make a shaped abrasive particle, such as a shaped ceramic abrasive particle, includes shaping the precursor ceramic abrasive particle in a mold having a predetermined shape to make ceramic shaped abrasive particles. Ceramic shaped abrasive particles, formed in a mold, are one species in the genus of shaped ceramic abrasive particles. Other processes to make other species of shaped ceramic abrasive particles include extruding the precursor ceramic abrasive particle through an orifice having a predetermined shape, printing the precursor ceramic abrasive particle though an opening in a printing screen having a predetermined shape, or embossing the precursor ceramic abrasive particle into a predetermined shape or pattern. In other examples, the shaped ceramic abrasive particles can be cut from a sheet into individual particles. Examples of suitable cutting methods include mechanical cutting, laser cutting, or water jet cutting. Non-limiting examples of shaped ceramic abrasive particles include shaped abrasive particles, such as triangular plates, or elongated ceramic rods/filaments. Shaped ceramic abrasive particles are generally homogenous or substantially uniform and maintain their sintered shape without the use of a binder such as an organic or inorganic binder that bonds smaller abrasive particles into an agglomerated structure and excludes abrasive particles obtained by a crushing or comminution process that produces abrasive particles of random size and shape. In many embodiments, the shaped ceramic abrasive particles comprise a homogeneous structure of sintered alpha alumina or consist essentially of sintered alpha alumina.
In the embodiment shown in
The shaped abrasive particle 100 includes a height 112, a width 114, and a length 116. Different shaped abrasive particles can have different height, length, and/or width. The height 112 is the distance from the side 106A that will contact the surface of an abrasive article substrate to an opposite edge 110B. The width 114 is the distance from the triangular top major surface 104 to the triangular bottom major surface 102. The length 116 is the distance between edges 110A, 110C of the side 106A that will contact the surface of an abrasive article substrate. Some embodiments herein regard shaped abrasive articles that include shaped abrasive particles of different length, width, shape, or other characteristic.
Shaped abrasive particles of different characteristics or shapes can be attached to a substrate of a shaped abrasive article. The shaped abrasive article can include an elliptical, rectangular (or other polygonal), or irregular footprint. The shaped abrasive particles can be attached using a binding agent that adheres the shaped abrasive particle to the substrate. The shaped abrasive particles can be selectively deposited on a binding agent-coated substrate in a deliberate manner, such that the shaped abrasive particles form a pattern or are otherwise placed in a deliberate location and orientation on the substrate. The pattern can include shaped abrasive particles of different sizes or shapes situated relative to one another in regular repetition. The pattern can include a wide array of intentional designs. The pattern can help provide a specified grinding characteristic when the shaped abrasive particles are situated in contact with an object and moved so the abrasive particles remove a portion of a surface of the object. The grinding characteristic can include a pressure, a pattern, a depth, a smoothness, or the like.
Some patterns can include the shaped abrasive particles aligned either substantially parallel or substantially perpendicular to each other. As used herein, parallel shaped abrasive particles means that major surfaces of the shaped abrasive particles face about the same direction (lines perpendicular to major surfaces of respective shaped abrasive particles are about parallel). As used herein perpendicular shaped abrasive particles means that major surfaces of the shaped abrasive particles face respective directions that are about 90 degrees from one another (lines perpendicular to major surfaces of respective shaped abrasive particles are about perpendicular). With reference to the shaped abrasive particle 100, the top major surface 104 and the bottom major surface 102 are examples of major surfaces.
Some other patterns include the shaped abrasive particles aligned parallel to one another, perpendicular to one another, or some angle therebetween. For example, a first shaped abrasive particle can be aligned about 5 degrees, 10 degrees, 20 degrees, 30 degrees, 45 degrees, 60 degrees, 75 degrees, 85 degrees, or some angle therebetween, from a most proximate (nearest) shaped abrasive particle.
Yet other patterns include shaped abrasive particles of different hardness situated in specified or random locations on the substrate. For example, a harder shaped abrasive particle can be situated to contact a surface of the object first and a softer shaped abrasive particle can be situated to contact the surface of the object second. In another example, a shaped abrasive particle with a hardness configured to break upon contact with the object can be situated at a specified or random location on the substrate. These shaped abrasive particles are sometimes called grinding aids. A grinding aid can have a Moh's hardness less than aluminum oxide, while a shaped abrasive particle can have a Moh's hardness greater than aluminum oxide. The shaped abrasive particles can include diamond, cubic boron nitride (CBN), aluminum oxide, a combination thereof, or the like.
Various abrasive articles with various patterns of shaped abrasive particles and techniques of how to make and use the articles are discussed with reference to the remaining FIGS.
Some of the shaped abrasive particles 502 and shaped abrasive particles 504 can be selectively situated relative to one another in pods 510A, 510B, 510C, and 510D. The pods 510A-510D can be selectively situated relative to one another. In such a manner, the shaped abrasive article can include a micro pattern (a pattern where individual shaped abrasive particles are situated relative to other shaped abrasive particles) and a macro pattern (a pattern defined by pods of multiple shaped abrasive particles situated relative to other pods). The micro pattern of the article 500 includes four shaped abrasive particles including alternating shaped abrasive particles 502 and shaped abrasive particles 504 in repetition. In the pod 510, shaped abrasive particles 502 and 504 alternate with a shaped abrasive particle 502 parallel to and situated between two shaped abrasive particles 504. The macro pattern of the article 500 includes most proximate pods situated perpendicular to each other. Parallel and perpendicular regarding pods include the direction the top major surface 104 and bottom major surface 102 of the shaped abrasive particles 502, 504 of the pod 510 are facing relative to the direction the top major surface 104 and bottom major surface 102 of the shaped abrasive particles 502, 504 of another pod.
The abrasive particles 502, 504 can include ceramic, diamond, a combination thereof, or other material. The abrasive particles 502, 504 can be fired or otherwise processed to have a specified hardness. The specified hardness can be within a specified tolerance. A shaped abrasive particle that is harder can remove material from an object that is softer. If a shaped abrasive particle is softer than the object, it can break and change the pressure or other grinding characteristic of the article 500. In some embodiments, some of the abrasive particles 502, 504 can include grinding aid that transfers to the article being ground. The grinding aid can be melted by heat of the grinding.
The abrasive particles 502, 504 as illustrated include different heights 112D and 112E, respectively. The differing heights can allow the taller shaped abrasive particles 504 to contact the object before the shaped abrasive particles 502. The shaped abrasive particles 504 can grind the object until they become about the same height or shorter than the shaped abrasive particles 502. The shaped abrasive particles 502 can include a different grinding characteristic than the shaped abrasive particles 504. For example, the shaped abrasive particles 502 can be softer, include a differently shaped grinding point, or the like.
The binding agent 508 can include an epoxy, resin, or a combination thereof. The binding agent 508 can include a resinous adhesive. In some examples, the binding agent 508 can include abrasive particles distributed therein. The resinous adhesive can include one or more resins chosen from a phenolic resin, an epoxy resin, a urea-formaldehyde resin, an acrylate resin, an aminoplast resin, a melamine resin, an acrylated epoxy resin, a urethane resin, a polyester resin, a dying oil, and mixtures thereof.
The substrate 506 can be flexible or rigid. Examples of suitable materials for forming a flexible backing include a polymeric film, a metal foil, a woven fabric, a knitted fabric, paper, vulcanized fiber, a staple fiber, a continuous fiber, a nonwoven, a foam, a screen, a laminate, and combinations thereof. The substrate 506 can be shaped to allow the abrasive article to be in the form of sheets, discs, belts, pads, or rolls. In some embodiments, the substrate 506 can be sufficiently flexible to allow coated abrasive article to be formed into a loop to make an abrasive belt that can be run on suitable grinding equipment. In other embodiments, the substrate 506 can be cut to be circular, rectangular, or other shape.
Making the abrasive articles 500, 600, 700, and 800 can include unique challenges not realized in forming an abrasive article with shaped abrasive particles of substantially uniform shape and size. For example, a shaped abrasive particle of smaller width can fit into a cavity for a shaped abrasive particle of larger width, but not vice versa. Thus, if the shaped abrasive particles with smaller width are provided before the shaped abrasive particles with larger width, the shaped abrasive particles with larger width may have fewer cavities available. This situation can be avoided by carefully choosing which shaped abrasive particles are provided and in which order the shaped abrasive particles are provided.
Optionally, filling assist member 1021 is provided after shaped abrasive particle feeder 1018 to move shaped abrasive particles 992 around on the surface of production tool 1000 and to help orientate or slide shaped abrasive particles 992 into the cavities 1020. Filling assist member 1021 can be, for example, a doctor blade, a felt wiper, a brush having a plurality of bristles, a vibration system, a blower or air knife, a vacuum box, or combinations thereof. Filling assist member 1021 moves, translates, sucks, or agitates shaped abrasive particles 992 on dispensing surface 1012 (top or upper surface of production tool 1000 in
After leaving the shaped abrasive particle filling and excess removal section of apparatus 990 generally illustrated at 1021, shaped abrasive particles 992 in production tool 1000 travel towards resin coated hacking 1014. Shaped abrasive particle transfer roll 1022 is provided and production tooling 1000 can wrap at least a portion of the roll's circumference. In some embodiments, production tool 1000 wraps between 30 to 180 degrees, or between 90 to 180 degrees of the outer circumference of shaped abrasive particle transfer roll 1022. In some embodiments, the speed of the dispensing surface 1012 and the speed of the resin layer of resin coated hacking 1014 are speed matched to each other within ±10 percent, ±5 percent, or ±1 percent, for example.
Various methods can be employed to transfer shaped abrasive particles 992 from cavities 1020 of production tool 1000 to resin coated backing 1014. One method includes a pressure assist method where each cavity 1020 in production tooling 1000 has two open ends or the back surface or the entire production tooling 1000 is suitably porous and shaped abrasive particle transfer roll 1022 has a plurality of apertures and an internal pressurized source of air. With pressure assist, production tooling 1000 does not need to be inverted but it still may be inverted. Shaped abrasive particle transfer roll 1022 can also have movable internal dividers such that the pressurized air can be supplied to a specific arc segment or circumference of the roll to blow shaped abrasive particles 992 out of the cavities and onto resin coated backing 1014 at a specific location. In some embodiments, shaped abrasive particle transfer roll 1022 may also be provided with an internal source of vacuum without a corresponding pressurized region or in combination with the pressurized region typically prior to the pressurized region as shaped abrasive particle transfer roll 1022 rotates. The vacuum source or region can have movable dividers to direct it to a specific region or arc segment of shaped abrasive particle transfer roll 1022. The vacuum can suck shaped abrasive particles 992 firmly into cavities 1020 as the production tooling 1000 wraps shaped abrasive particle transfer roll 1022 before subjecting shaped abrasive particles 992 to the pressurized region of shaped abrasive particle transfer roll 1022. This vacuum region be used, for example, with shaped abrasive particle removal member to remove excess shaped abrasive particles 992 from dispensing surface 1012 or may be used to simply ensure shaped abrasive particles 992 do not leave cavities 1020 before reaching a specific position along the outer circumference of the shaped abrasive particle transfer roll 1022.
After separating from shaped abrasive particle transfer roll 1022, production tooling 1000 travels along first web path 999 back towards the shaped abrasive particle filling and excess removal section of the apparatus with the assistance of idler rolls 1016 as necessary. An optional production tool cleaner can be provided to remove stuck shaped abrasive particles still residing in cavities 1020 and/or to remove binding agent 508 transferred to dispensing surface 1012. Choice of the production tool cleaner can depend on the configuration of the production tooling and could be either alone or in combination, an additional air blast, solvent or water spray, solvent or water bath, an ultrasonic horn, or an idler roll the production tooling wraps to use push assist to force shaped abrasive particles 992 out of the cavities 1020. Thereafter endless production tooling 1020 or belt advances to a shaped abrasive particle filling and excess removal section to be filled with new shaped abrasive particles 992.
Various idler rolls 1016 can be used to guide the shaped abrasive particle coated substrate 1014 having a predetermined, reproducible, non-random pattern of shaped abrasive particles 992 on the first major surface that were applied by shaped abrasive particle transfer roll 1022 and held onto the first major surface by the make coat resin along second web path 1032 into an oven for curing the make coat resin. Optionally, a second shaped abrasive particle coater can be provided to place additional abrasive particles, such as another type of abrasive particle or diluents, onto the make coat resin prior to entry in an oven. The second abrasive particle coater can be a drop coater, spray coater, or an electrostatic coater as known to those of skill in the art. Thereafter a cured backing with shaped abrasive particles 992 can enter an optional festoon along second web path 1032 prior to further processing such as the addition of a size coat, curing of the size coat, and other processing steps known to those of skill in the art of making coated abrasive articles.
Although maker 990 is shown as including production tool 1000 as a belt, it is possible in some alternative embodiments for maker 990 to include production tool 1000 on vacuum pull roll 1022. For example, vacuum pull roll 1022 may include a plurality of cavities 1020 to which shaped abrasive particles 992 are directly fed. Shaped abrasive particles 992 can be selectively held in place with a vacuum, which can be disengaged to release shaped abrasive particles 992 on substrate 506. Further details on maker 990 and suitable alternative may be found at US 2016/0315081, to 3M Company, St. Paul MN, the contents of which are hereby incorporated by reference.
The particle organizers 1104A, 1104B separate the shaped abrasive particles 504, 502 and guide them to a cavity (see
The particle remover 1106A, 1106B removes shaped abrasive particles 504, 502 that have not made into a cavity, are not properly situated in a cavity, or are situated in an improper cavity. A shaped abrasive particle 504, 502 can be symmetrical or non-symmetrical. For example, a symmetrical shaped abrasive particle can include an equilateral triangle. Non-symmetrical shaped abrasive particles include other shapes.
The particle organizers 1104A, 1104B can help guide the shape abrasive particles 504, 502 to the proper cavities in the holding device 1112. The particle removers 1106A, 1106B can help remove shaped abrasive particles 504, 502 that extend too far beyond the surface 1138 (extend beyond the surface 1138 by over a threshold distance). The cleaner 1108A, 1108B can remove shaped abrasive particles 504, 502 or debris left on or in the holding device 1112. The cleaner 1108A, 1108B can project a fluid at the surface 1138 (see
The larger shaped abrasive particles 504 cannot fit properly in the cavities for the smaller shaped abrasive particles, and the smaller shaped abrasive particles can fall into a cavity for a larger shaped abrasive particle and block a larger shaped abrasive particle from falling into a proper cavity. To help ensure that the shaped abrasive particles do not fall through the cavities or a smaller shaped abrasive particle is not situated in a cavity configured for a larger shaped abrasive particle, larger shaped abrasive particles 504 can be provided first. Then a next largest shaped abrasive particle can be provided, such as through another shaped abrasive particle feeder, and so on. In this manner, the cavities 1222 of the holding device 1112 can be filled properly.
Referring to
As previously discussed, shaped abrasive particles can vary in other characteristics beyond shape and size. For example, shaped abrasive particles can include different hardness, such as by including different materials or by being fired or otherwise formed for a different amount of time or using a different method. In another example, some shaped abrasive particles can be configured to break on contact, while others can be configured to grind on contact. To situate these different shaped abrasive particles in pre-determined locations, the different shaped abrasive particles can include corresponding different respective size characteristics as well. Then the shaped abrasive particles can be processed, such as by the system 1100 of
In some embodiments, however, manufacturing tooling to situate the different shaped abrasive particles in specific locations on a substrate can be cost prohibitive, time prohibitive, or unnecessary. In some embodiments, a random distribution of different shaped abrasive particles will be sufficient to achieve a specific grinding profile. In such embodiments, the different shaped abrasive particles can have substantially the same size and shape. These different shaped abrasive particles can be loaded together in an abrasive particle feeder. The provisioning of the different shaped abrasive particles to the holding device 1112 can randomize the locations of the corresponding different shaped abrasive particles. The ratio of different particles to each other in the final abrasive article can be controlled, at least in part, by the distribution of different shaped abrasive particles provided to the abrasive particles feeder.
The protrusion 1970 can be situated at respective voids in the surface of the holding device 1974. A void is a location on the surface that is not part of a cavity. The protrusion 1970 can include a conical, cylindrical, parabolic, hemispherical, semi elliptical, or other shape. The protrusion 1970 can promote movement of the shaped abrasive particles 504 to respective cavities. For example, if a shaped abrasive particle 504 lands in a flat void, the shaped abrasive particle 504 can tend to stay in the void. With the protrusion 1970 in the void, the shaped abrasive particle 504 can contact the protrusion 1970 and be directed towards a cavity.
The cavities 1222 extend from the surface 2080 in a direction opposite which the protrusions 1970 extend from the surface 2080. The distance the cavities 1222 extend away from the surface 2080 is sometimes called a depth.
The shaped abrasive particles 504, after contacting a protrusion 1970 can move towards the cavity 1222. The protrusion 1970 can include a sloped surface that helps guide the shaped abrasive particle 504 in a specified direction. For example, the protrusion can be conical (as shown in
In some embodiments, the holding device 2792 can be passed under the abrasive particle feeder 1102. The holding device 2792 can then be processed by one or more of the guider 1104, the remover 1106, and the cleaner 1108. The holding device 2792 can then be analyzed, such as by human eye, a camera, or other vision system to determine about how many of the cavities 3010 have abrasive particles 504 situated therein. If there are sufficient abrasive particles 504, the holding device 2792 can be passed for further processing. If there are insufficient abrasive particles 504, the holding device 2792 can be passed back under the abrasive particle feeder 1102 another time. The holding device 2792 can then be processed by one or more of the guider 1104, the remover 1106, and the cleaner 1108 and re-analyzed. This process can repeat until a sufficient number of the cavities 3010 include a shaped abrasive particle 504 therein.
The method 3100 can further include guiding, by one or more protrusions between proximate cavities of the cavities, a shaped abrasive particle of the shaped abrasive particles to a cavity of the cavities. The method 3100 can further include, wherein the respective protrusions comprise a conical shape, a cylindrical shape, a rectilinear shape, a polygonal shape, or an irregular shape. The method 3100 can further include depositing a fluid, solid, or a combination thereof on the abrasive particle receiving surface before receiving the shaped abrasive particles. The method 3100 can further include, wherein the cavities include a hydrophilic surface. The method 3100 can further include, wherein the abrasive particle receiving surface is hydrophilic.
The method 3200 can further include, after receiving the shaped abrasive particles removing, from shaped abrasive particle placement tool, at least one of the received shaped abrasive particles improperly situated in a cavity of the cavities. The method 3200 can further include, before depositing the shaped abrasive particles into the at least one binding material, removing further shaped abrasive particles that are not in a respective cavity of the cavities off the shaped abrasive particle placement tool. The method 3200 can further include vibrating the shaped abrasive particle placement tool to situate shaped abrasive particles of the shaped abrasive particles into a cavity of the cavities. The method 3200 can further include, wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
The method 3300 can further include before receiving the second shaped abrasive particles and after receiving the first shaped abrasive particles, removing first shaped abrasive particles that are not in a respective first cavity of the first cavities off the shaped abrasive particle placement tool and receiving further first shaped abrasive particles until a threshold number of the first cavities includes a first shaped abrasive particle situated therein. The method 3300 can further include before depositing the shaped abrasive particle placement tool into the at least one binding material, sweeping or blowing second shaped abrasive particles off that are not in a respective second cavity of the second cavities off the shaped abrasive particle placement tool and receiving further second shaped abrasive particles until a threshold number of the second cavities includes a second shaped abrasive particle situated therein. The method 3300 can further include, wherein the characteristic includes a height, width, or depth.
The method 3300 can further include, wherein the first shaped abrasive particles or the second shaped abrasive particles are not equilateral triangles. The method 3300 can further include vibrating the shaped abrasive particle placement tool to situate a first shaped abrasive particle of the first shaped abrasive particles into a first cavity of the first cavities. The method 3300 can further include, wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
The terms and expressions that have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the embodiments of the present disclosure. Thus, although the present disclosure has been specifically disclosed by specific embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those of ordinary skill in the art, and that such modifications and variations are within the scope of embodiments of the present disclosure.
The following exemplary embodiments are provided, the numbering of which is not to be construed as designating levels of importance:
Example 1 includes an abrasive article comprising a substrate, shaped particles disposed on the substrate, wherein the shaped particles include first shaped abrasive particles and second shaped particles, and wherein a characteristic of the first shaped abrasive particles is different from a corresponding characteristic of the second shaped particles, and at least one binding agent securing the shaped particles to the substrate.
In Example 2, Example 1 further includes, wherein the second shaped particles are grinding aids.
In Example 3, at least one of Examples 1-2 further includes, wherein the second shaped particles are second shaped abrasive particles.
In Example 4, at least one of Examples 1-3 further includes, wherein the characteristic includes one or more of a height, width, length, shape, or hardness.
In Example 5, at least one of Examples 1-4 further includes, wherein a majority of the shaped particles are situated in a specified pattern on the substrate.
In Example 6, at least one of Examples 1-5 further includes, wherein each of the first shaped abrasive particles includes at least two triangular major faces connected to each other and separated by three sidewalls, and on a respective basis, one sidewall of at least 90 percent of the first shaped abrasive particles is disposed facing, proximate, and secured to the substrate by the at least one binding agent.
In Example 7, at least one of Examples 1-6 further includes, wherein a shape of the first shaped abrasive particles includes a tetrahedron or a trapezoid.
In Example 8, at least one of Examples 1-7 further includes, wherein the characteristic is surface area of a major surface of the first shaped abrasive particles and the second shaped particles.
In Example 9, at least one of Examples 1-8 further includes, wherein the characteristic is hardness of the first shaped abrasive particles and the second shaped particles.
In Example 10, at least one of Examples 1-9 further includes, wherein the characteristic is a height of the first shaped abrasive particles and the second shaped particles.
In Example 11, at least one of Examples 1-10 further includes, wherein the characteristic is a width of the first shaped abrasive particles and the second shaped particles.
In Example 12, at least one of Examples 1-11 further includes, wherein the characteristic is height and the first shaped abrasive particles and second shaped particles are situated in a non-random sequence on the substrate.
In Example 13, Example 12 further includes, wherein at least one second shaped particle is situated between two nearest first shaped abrasive particles with respective major surfaces within 10 degrees of a parallel with each other.
In Example 14, at least one of Examples 12-13 further includes, wherein the abrasive material includes pods of shaped particles situated with major surfaces within 10 degrees of perpendicular to each nearest pod, each pod comprising a second shaped particle of the second shaped particles situated between two first shaped abrasive particles of the first shaped abrasive particles, and wherein the respective major surfaces of the first shaped abrasive particles and second shaped particles of the pod are within 10 degrees of parallel to each other.
In Example 15, at least one of Examples 12-14 further includes, wherein the abrasive material includes pods of shaped particles situated with major surfaces within 10 degrees of perpendicular to each nearest pod, each pod comprising a second shaped particle of the second shaped particles or first shaped abrasive particles of the first shaped abrasive particles, and wherein the respective major surfaces of the shaped particles of the pod are within 10 degrees of parallel to each other.
In Example 16, at least one of Examples 1-15 further includes, wherein the characteristic includes surface area of a surface facing and secured to the substrate, the shaped abrasive particles further include third shaped abrasive particles, the surface area of the surface of the third shaped abrasive particles greater than the surface area of the surface of the second shaped abrasive particles, which is greater than the surface area of the surface of the first shaped abrasive particles, and the shaped abrasive particles are situated with a second shaped abrasive particle of the second shaped abrasive particles between a first shaped abrasive particle of the first shaped abrasive particles and a third shaped abrasive particle of the third shaped abrasive particles.
In Example 17, at least one of Examples 1-16 further includes, wherein the characteristic includes hardness and the second shaped particles include a grinding aid.
In Example 18, at least one of Examples 1-17 further includes, wherein the characteristic includes hardness and the first shaped abrasive particles include a Moh's hardness lesser than a Moh's hardness of aluminum oxide.
In Example 19, at least one of Examples 1-18 further includes, wherein the characteristic includes hardness and the first shaped abrasive particles and second shaped particles are situated with harder elements configured to contact a surface to be ground before softer elements.
In Example 20, at least one of Examples 1-19 further includes, wherein the characteristic includes aspect ratio indicating a ratio of height an element extends from an axis perpendicular to the major surface of the substrate to a width of the element parallel to the major surface of the substrate.
In Example 21, at least one of Examples 1-20 further includes, wherein the first shaped abrasive particles and the second shaped abrasive particles are situated randomly relative to one another on the substrate.
In Example 22, at least one of Examples 15-21 further includes, wherein the characteristic is hardness and a ratio of the number of first shaped abrasive particles to the number of second shaped abrasive particles is configured to provide a specified pressure profile when in contact with an object to be grinded.
Example 23 includes an abrasive article comprising a substrate, shaped abrasive particles organized on a major surface of the substrate to contact an object in a sequence such that a first particle of the shaped abrasive particles in the sequence removes a specified width and depth of material and a second particle of the shaped abrasive particles in the sequence removes at least one of (1) a larger width of the material than the first particle and (2) a larger depth of the material than the first particle, and at least one binding agent securing the shaped abrasive particles to the substrate.
In Example 24, Example 23 further includes, wherein each of the first shaped abrasive particles and second shaped abrasive particles includes a polygonal, elliptical, or irregular shaped major surface.
In Example 25, at least one of Examples 23-24 further includes, wherein the first particle includes a narrower width than the second particle.
In Example 26, at least one of Examples 23-25 further includes, wherein the first particle includes a smaller height than the second particle.
In Example 27, at least one of Examples 23-26 further includes, wherein the major surface of the substrate defines an x-y plane including an x-axis and a y-axis, wherein the shaped abrasive particles include major faces extending from the major substrate in a z-direction perpendicular to the x-y plane, wherein the faces of different, proximate abrasive particles of the abrasive particles are oriented at different angles relative to the x-axis.
In Example 28, at least one of Examples 23-27 further includes, wherein the first particle is harder than the second particle.
In Example 29, at least one of Examples 23-28 further includes, wherein the abrasive material includes pods of shaped abrasive particles situated with major surfaces within 10 degrees of perpendicular to each nearest pod, each pod comprising shaped abrasive particles of substantially a same orientation, size, and shape, and wherein the respective major surfaces of the shaped abrasive particles of the pod are within 10 degrees of parallel to each other.
In Example 30, at least one of Examples 23-29 further includes third particles adhered to the substrate, the third particles including a grinding aid.
In Example 31, at least one of Examples 23-30 further includes, wherein the sequence of particles includes particles with different hardness and are situated with harder elements configured to contact a surface to be ground before softer elements contact the surface to be ground.
In Example 32, at least one of Examples 23-31 further includes, wherein the sequence of particles includes particles with different aspect ratio of a ratio of height an element extends from an axis perpendicular to the major surface of the substrate to a width of the element parallel to the major surface of the substrate.
Example 33 includes a shaped abrasive particle placement tool comprising a substrate including an abrasive article receiving surface defining an x-y plane including an x-axis and a y-axis and a back surface opposite the abrasive article receiving surface, cavities formed in the substrate, the cavities including one or more sidewalls, the cavities including a width and length at the abrasive article receiving surface, and a depth defined by a distance the first cavities extend from the abrasive article receiving surface towards the back surface, wherein the one or more sidewalls of proximate cavities of the cavities are situated such that corresponding sidewalls of the proximate cavities are oriented at different angles relative to the x-axis, and shaped abrasive particles situated in the cavities.
In Example 34, Example 33 further includes, wherein the cavities include at least two at least partial triangular walls connected to each other and separated by two sidewalls.
In Example 35, at least one of Examples 33-34 further includes, wherein the first cavities include four at least partially triangular walls forming a pyramid or truncated pyramid shape.
In Example 36, at least one of Examples 33-35 further includes, wherein the proximate cavities include a first cavity and a second cavity and the angle of the sidewalls of the first cavity relative to the x-axis is at least ten degrees greater than the angle of the sidewalls of the second cavity relative to the x-axis.
Example 37 includes a shaped abrasive particle placement tool comprising a substrate including an abrasive particle receiving surface defining an x-y plane including an x-axis and a y-axis and a back surface opposite the abrasive particle receiving surface, cavities formed in the substrate, the cavities including one or more sidewalls, the cavities including a width and length at the abrasive article receiving surface, and a depth defined by a distance the first cavities extend from the abrasive article receiving surface towards the back surface in a direction parallel to a z-axis perpendicular to the x-y plane, and respective protrusions between two or more proximate cavities, the respective protrusions extending from the abrasive article receiving surface in a direction parallel to the z-axis and away from the back surface, and shaped abrasive particles situated in the cavities.
In Example 38, Example 37 includes wherein the respective protrusions comprise a hemispherical shape.
In Example 39, at least one of Examples 37-38 further includes, wherein the respective protrusions comprise a conical shape.
In Example 40, at least one of Examples 37-39 further includes, wherein the respective protrusions comprise a cylindrical shape.
In Example 41, at least one of Examples 37-40 further includes, wherein the respective protrusions comprise a rectilinear shape.
In Example 42, at least one of Examples 37-41 further includes, wherein the respective protrusions comprise a polygonal shape.
In Example 43, at least one of Examples 37-42 further includes, wherein the respective protrusions comprise irregular shapes.
In Example 44, at least one of Examples 37-43 further includes, wherein the shaped abrasive particles, include a fluid, solid, or a combination thereof thereon.
In Example 45, at least one of Examples 43-44 further includes, wherein the cavities include a hydrophilic surface.
In Example 46, at least one of Examples 43-45 further includes, wherein the abrasive particle receiving surface is hydrophilic.
Example 47 includes a shaped abrasive particle placement tool comprising a substrate including an abrasive article receiving surface defining an x-y plane including an x-axis and a y-axis and a back surface opposite the abrasive article receiving surface, cavities formed in the substrate, the cavities including one or more sidewalls, the cavities including a width and length at the abrasive article receiving surface, and a depth defined by a distance the cavities extend from the abrasive article receiving surface towards the back surface in a direction parallel to a z-axis perpendicular to the x-y plane, and shaped abrasive particles situated in the cavities, wherein the shaped abrasive particles, include a fluid, solid, or a combination thereof thereon.
In Example 48, Example 47 further includes, wherein the cavities include a hydrophilic surface.
In Example 49, at least one of Examples 47-48 further includes respective protrusions between proximate cavities, the respective protrusions extending from the abrasive article receiving surface in a direction parallel to the z-axis and away from the back surface.
In Example 50, Example 49 further includes, wherein the respective protrusions comprise a hemispherical shape.
In Example 51, at least one of Examples 49-50 further includes, wherein the respective protrusions comprise a conical shape.
In Example 52, at least one of Examples 49-51 further includes, wherein the respective protrusions comprise a cylindrical shape.
In Example 53, at least one of Examples 49-52 further includes, wherein the respective protrusions comprise a rectilinear shape.
In Example 54, at least one of Examples 49-53 further includes, wherein the respective protrusions comprise a polygonal shape.
In Example 55, at least one of Examples 49-54 further includes, wherein the respective protrusions comprise irregular shapes.
In Example 56, at least one of Examples 47-55 further includes, wherein the abrasive particle receiving surface is hydrophilic.
Example 57 includes a method of making an abrasive article, the method comprising receiving shaped abrasive particles at an abrasive particle receiving surface of a substrate, the abrasive particle receiving surface defining an x-y plane including an x-axis and a y-axis and a back surface opposite the abrasive article receiving surface, cavities formed in the substrate, the cavities including one or more sidewalls, the cavities including a width and length at the abrasive article receiving surface, and a depth defined by a distance the cavities extend from the abrasive article receiving surface towards the back surface in a direction parallel to a z-axis perpendicular to the x-y plane, and releasing the shaped abrasive particles from the cavities of the substrate onto a binding agent on a surface of a substrate of the abrasive article.
In Example 58, Example 57 further includes guiding, by one or more protrusions between proximate cavities of the cavities, a shaped abrasive particle of the shaped abrasive particles to a cavity of the cavities.
In Example 59, Example 58 further includes, wherein the respective protrusions comprise a conical shape.
In Example 60, at least one of Examples 58-59 further includes, wherein the respective protrusions comprise a cylindrical shape.
In Example 61, at least one of Examples 58-60 further includes, wherein the respective protrusions comprise a rectilinear shape.
In Example 62, at least one of Examples 58-61 further includes, wherein the respective protrusions comprise a polygonal shape.
In Example 63, at least one of Examples 58-62 further includes, wherein the respective protrusions comprise irregular shapes.
In Example 64, at least one of Examples 57-63 further includes depositing a fluid, solid, or a combination thereof on the abrasive particle receiving surface before receiving the shaped abrasive particles.
In Example 65, Example 64 further includes, wherein the cavities include a hydrophilic surface.
In Example 66, at least one of Examples 64-65 further includes, wherein the abrasive particle receiving surface is hydrophilic.
Example 67 includes a method comprising receiving, at a shaped abrasive particle placement tool comprising cavities, shaped abrasive particles, determining whether a threshold number of cavities of the cavities includes a shaped abrasive particle of the shaped abrasive particles situated properly therein, in response to determining there is not a threshold number of cavities of the cavities with a shaped abrasive particle of the shaped abrasive particles situated properly therein, receiving, at the shaped abrasive particle placement tool, further shaped abrasive particles, and in response to determining that at least the threshold number of cavities of the cavities includes a shaped abrasive particle of the shaped abrasive particles situated properly therein, releasing the shaped abrasive particles from the shaped abrasive particle placement tool into at least one binding material on a substrate to adhere the first shaped abrasive particles and the second shaped abrasive particles to the substrate.
In Example 68, Example 67 further includes after receiving the shaped abrasive particles removing, from shaped abrasive particle placement tool, at least one of the received shaped abrasive particles improperly situated in a cavity of the cavities.
In Example 69, at least one of Examples 67-68 further includes before depositing the shaped abrasive particles into the at least one binding material, removing further shaped abrasive particles that are not in a respective cavity of the cavities off the shaped abrasive particle placement tool.
In Example 70, at least one of Examples 67-69 further includes vibrating the shaped abrasive particle placement tool to situate shaped abrasive particles of the shaped abrasive particles into a cavity of the cavities.
In Example 71, at least one of Examples 67-70 further includes, wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
Example 72 includes a method comprising receiving, at a shaped abrasive particle placement tool comprising first cavities with a first specified characteristic and second cavities with a lesser corresponding characteristic, first shaped abrasive particles with a corresponding characteristic greater than the second characteristic and less than the first characteristic, after receiving the first abrasive particles, receiving, at the shaped abrasive particle placement tool, second shaped abrasive particles with a corresponding characteristic less than the second characteristic, and releasing the shaped abrasive particles from the shaped abrasive particle placement tool into at least one binding material on a substrate to adhere the first shaped abrasive particles and the second shaped abrasive particles to the substrate.
In Example 73, Example 72 further includes before receiving the second shaped abrasive particles and after receiving the first shaped abrasive particles, removing first shaped abrasive particles that are not in a respective first cavity of the first cavities off the shaped abrasive particle placement tool and receiving further first shaped abrasive particles until a threshold number of the first cavities includes a first shaped abrasive particle situated therein.
In Example 74, at least one of Examples 72-73 further includes before depositing the shaped abrasive particle placement tool into the at least one binding material, sweeping or blowing second shaped abrasive particles off that are not in a respective second cavity of the second cavities off the shaped abrasive particle placement tool and receiving further second shaped abrasive particles until a threshold number of the second cavities includes a second shaped abrasive particle situated therein.
In Example 75, at least one of Examples 72-74 further includes, wherein the characteristic includes a height, width, or depth.
In Example 76, at least one of Examples 72-75 further includes, wherein the first shaped abrasive particles or the second shaped abrasive particles include major surfaces that are not equilateral triangles.
In Example 77, at least one of Examples 72-76 further includes vibrating the shaped abrasive particle placement tool to situate a first shaped abrasive particle of the first shaped abrasive particles into a first cavity of the first cavities.
In Example 78, at least one of Examples 72-76 further includes, wherein releasing the shaped abrasive particles from the shaped abrasive particle placement tool includes vibrating the shaped abrasive particle placement tool.
Example 79 includes a shaped abrasive particle placement tool comprising a substrate including an abrasive article receiving surface and a back surface opposite the abrasive article receiving surface, cavities formed in the substrate including one or more sidewalls, the cavities including first cavities and second cavities, the first cavities including a first width and first length at the abrasive article receiving surface, and a first depth indicating a distance the first cavities extend from the abrasive article receiving surface towards the back surface, the second cavities including a second width and second length at the abrasive article receiving surface, and a second depth indicating a distance the second cavities extend from the abrasive article receiving surface towards the back surface, wherein one or more of (1) the first width is greater than the second width, (2) the first length is greater than the second length, or (3) the first depth is greater than the second depth, first shaped abrasive particles situated in the first cavities, the first shaped abrasive particles including (1) a width and length less than the first width and first length, respectively, and greater than the second width or second length, respectively, or (2) a height greater than a threshold greater than the second depth and less than the threshold greater than the first depth, and second shaped abrasive particles situated in the second cavities, the second shaped abrasive particles including (1) a width and length less than the second width and the second length, respectively, or (2) a height less than the threshold greater than the second depth.
In Example 80, Example 79 further includes, wherein the first cavities are situated in a non-random orientation relative to one another.
In Example 81, at least one of Examples 79-80 further includes, wherein the first width is greater than the second width or the first length is greater than the second length, the first shaped abrasive particles include a width and length less than the first width and first length, respectively, and greater than the second width or second length, respectively, and the second shaped abrasive particles include a width and length less than the second width and the second length, respectively.
In Example 82, at least one of Examples 79-81 further includes, wherein the first depth is greater than the second depth, the first abrasive articles include a height greater than a threshold greater than the second depth and less than the threshold greater than the first depth, and the second abrasive articles include a height less than the threshold greater than the second depth.
In Example 83, at least one of Examples 79-82 further includes, wherein at least one of the first and second shaped abrasive particles includes a major surface that is a non-equilateral triangle shape.
In Example 84, at least one of Examples 79-83 further includes, wherein the first cavities include at least two at least partial triangular walls connected to each other and separated by two sidewalls.
In Example 85, at least one of Examples 79-84 further includes, wherein the first cavities include four at least partially triangular walls forming a pyramid or truncated pyramid shape.
In Example 86, at least one of Examples 79-85 further includes, wherein the first shaped abrasive particles and the second shaped abrasive particles include a respective different characteristic.
In Example 87, Examples 86 further includes, wherein the characteristic is surface area of a major surface of the first shaped abrasive particles and the second shaped abrasive particles.
In Example 88, at least one of Examples 79-87 further includes, wherein the first cavities and the second cavities include different respective depths and the first cavities and the second cavities are situated in an alternating pattern in the substrate.
In Example 89, Example 88 further includes, wherein at least one second cavity of the second cavities is situated between two nearest first cavities with respective major surfaces within 10 degrees of a parallel with each other.
In Example 90, Example 89 further includes, wherein the cavities include pods of cavities situated with major surfaces within 10 degrees of perpendicular to each nearest pod, each pod comprising a second cavity of the second cavities situated between two first cavities of the first cavities, and wherein the respective major surfaces of the first cavities and second cavity of the pod are within 10 degrees of parallel to each other.
In Example 91, at least one of Examples 86-90 further includes, wherein the cavities further include third cavities, a width of the third cavities is less than the second width which is less than the first width, and the cavities are situated with a second cavity of the second cavities between a first cavity of the first cavity and a third cavity of the third cavities.
In Example 92, at least one of Examples 86-91 further includes, wherein the characteristic includes aspect ratio indicating a ratio of height a shaped abrasive particle extends from an axis perpendicular to the major surface of the substrate to a width of the element parallel to the major surface of the substrate.
In Example 93, at least one of Examples 79-92 further includes, wherein the first cavities and the second cavities are situated randomly relative to one another in the substrate.
This application is a national stage filing under 35 U.S.C. 371 of PCT/IB2019/060627, filed Dec. 10, 2019, which claims the benefit of U.S. Provisional Application No. 62/781,057, filed Dec. 18, 2018, the disclosures of which are incorporated by reference in their entireties herein.
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PCT/IB2019/060627 | 12/10/2019 | WO |
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WO2020/128720 | 6/25/2020 | WO | A |
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