The present invention relates to fuel cells as well as fuel cell stacks and the cooling thereof.
Fuel Cells are believed to be one of the most important energy technologies in the future energy system ranging from application areas such as transportation to stationary power generation. The central component in a fuel cell is the electrolyte enabling effective proton transport capability while being non-electrically conductive. The electrolyte also effectively separates the anode, which contains the fuel, and the cathode, containing the oxidant. In the case of the PEM (Polymer Electrolyte Membrane) fuel cell, the electrolyte is typically made of Nafion™ manufactured by Dupont®. Hydrogen is typically fed to the anode and air to the cathode compartment. This reaction produces water on the cathode side. A catalyst is placed both on the cathode and anode side and on top of these, a Gas Diffusion Layer (GDL) is placed, which acts to remove produced water, assist diffusion of oxygen to the reaction sites and conduct electrons from the reaction sites. At last, electrically conductive bipolar plates transport fuel and oxidant to the reaction sites.
Typically fuel cells are cooled pumping either a liquid or gas through what is termed the cooling plates placed in between the anode and cathode bipolar plates. Typically, if the heat generated by the stack is going to be utilized for heating purposes, the fuel cell will be liquid cooled. On the other hand, if the fuel cell is used for APU (Auxiliary Power Unit) or other mobile power applications, the heat is rejected to the surroundings. This invention primarily relates to the first case, where the fuel cell waste heat can be used for heating purposes such as in Combined Heat and Power plants (CHP's).
It is therefore the object of the invention to provide a fuel cell for heating purposes and electricity production, which is simple in construction.
This purpose is achieved with a hydrogen fuel cell, for example a PEM fuel cell, with channels through the fuel cell for transport of a cooling fluid through the fuel cell wherein the channels are configured for convection driven motion of the cooling fluid through the channels. Even though the convection effect could be combined with driving force by a fluid pump, it is preferred that the fuel cell is arranged for cooling by cooling fluid that is only convention driven through the channels.
The advantage of the invention is that no pump is required to circulate the cooling water, nor valves, temperature transmitters etc. which simplifies the system and reduces costs in comparison with prior art systems. In fact, the fuel cell temperature is automatically controlled as well as the temperature difference between inlet and outlet of fuel the cell coolant. Moreover, the fuel cell is significantly compacter due to exclusion of external pumps, pipes etc.
In a practical embodiment, this can be achieved, if the channels are arranged in an inclining orientation for convection driven motion of the cooling fluid through the channels. For example, the channels may be arranged vertically.
In a certain embodiment, there is provided a cooling fluid circuit from one end of a channel to the opposite end of a channel, implying a re-circulation of the fluid through the channels. Such a circuit may, optionally, be in thermal contact with a central heating liquid in a low temperature part of the fluid circuit for transfer of thermal energy to the central heating liquid and in thermal contact with a hot tap water supply in a high temperature part of the fluid circuit for transport of thermal energy to the tap water. Alternatively, the cooling fluid circuit is in thermal contact with a central heating liquid in a low temperature part of the fluid circuit for transfer of thermal energy to the central heating liquid, in thermal contact with a hot tap water supply in a medium temperature part of the fluid circuit for transport of thermal energy to the tap water, and in thermal contact with ventilation air in a high temperature part of the fluid circuit for transfer of thermal energy to the ventilation air.
Instead of a direct thermal contact between the cooling fluid circuit and optional central heating, tap water supply and/or air ventilation, there may be provided an intermediate liquid reservoir. For this and other reasons, according to another embodiment, the cooling fluid circuit is in thermal contact with separate liquid reservoir, for example a water tank, at least partly surrounding the fuel cell. Such a water tank may, optionally, have a cold water inlet and a hot water outlet. An additional advantage is that—due to the heat capacity of the reservoir—the fuel cell is always operating within the optimum temperature range, and does not need any startup phase where the fuel cell is heated first.
Optionally, the cooling fluid may be water, though in many instances, it is of advantage, if the cooling fluid has at least on of the following properties,
The invention has the following advantages over existing technology:
1. The system is inherently simplified as no pump is required to circulate the cooling water, nor valves, temperature transmitters etc.
2. The Control system is simplified as the fuel cell temperature is automatically controlled as well as the temperature difference between inlet and outlet of fuel cell.
3. The fuel cell is always operating within the optimum temperature range, and does not need any startup phase where the fuel cell is heated.
4. As the fuel cell stack is placed inside the hot water reservoir all heat emission is transferred to the hot water reservoir if heating and saturation of reactant gases is neglected resulting in a cooling efficiency close to 100%.
5. The system will be significantly compacter due to exclusion of external pumps, pipes etc.
6. The total system price is expected to be much lower than that of existing technology for the above reasons.
The invention will be explained in more detail with reference to the drawing, where
The following contemplates a method of cooling a fuel cell stack while simultaneously being able to reuse the waste heat produced by the stack by means of natural convection in the coolant reservoir.
The description of the preferred construction of the fuel cell is for illustrative purposes only and should not be limiting for the invention, application or uses.
Number | Date | Country | Kind |
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PA 2005 01275 | Sep 2005 | DK | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/DK2006/000490 | 9/5/2006 | WO | 00 | 6/25/2008 |