Claims
- 1. In a process for producing hydrogen peroxide by alternately hydrogenating an alkylanthraquinone and/or a tetrahydroalkylanthraquione and oxygenating the resulting alkylanthrahydroquinone and/or tetrahydroalkylanthrahydroquinone to regenerate the alkylanthraquinone and/or tetrahydroalkylanthraquinone and to produce hydrogen peroxide, the improvement comprising conducting the hydrogenation in the presence of a catalyst consisting essentially of an amorphous silica support having deposited thereon about 0.05-5 percent by weight based on the weight of silica of at least one oxide, hydroxide or carbonate of at least one metal selected from the group consisting of zirconium, thoriium, hafnium, cerium, and titanium and about 0.1-10 percent by weight based on the weight of silica of palladium metal; the metal oxide, hydroxide or carbonate being deposited before or simultaneously with the palladium metal in the form of its oxide, hydroxide or carbonate.
- 2. The process of claim 1 wherein the silica is essentially iron-free.
- 3. The process of claim 1 wherein the amorphous silica support is silica gel particles having an average particle size distribution in the range of about 10-300 microns and a surface area of about 20-600 m.sup.2 /g.
- 4. The process of claim 1 wherein the amorphous silica support is silica gel particles having a surface area in the range of about 100-350 m.sup.2 /g and about 0.1-2 percent by weight of the silica of an oxide, hydroxide or carbonate of zirconium, thorium or titanium is deposited thereon.
- 5. The process of claims 2, 3 or 5 wherein the metal oxide, hydroxide or carbonate is zirconium oxide.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a division of copending application Ser. No. 015,208, filed Feb. 26, 1979, which is a continuation-in-part of application Ser. No. 948,036, filed Oct. 2, 1978, now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
2914382 |
Holmes et al. |
Nov 1959 |
|
3030186 |
Kreuz et al. |
Apr 1962 |
|
3271327 |
McEvoy et al. |
Sep 1966 |
|
Divisions (1)
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Number |
Date |
Country |
Parent |
15208 |
Feb 1979 |
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Continuation in Parts (1)
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Number |
Date |
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Parent |
948036 |
Oct 1978 |
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