Claims
- 1. A method for improving the coating of substrates by a water based coating formulation of a water soluble, crosslinkable resin containing polyethylene oxide segments as water solubilizing units and being derived from diepoxides, said formulation containing an ionic fluorinated surfactant, which comprises adding an effective amount of a watersoluble or water-dispersible, resin-compatible product obtained by reacting
- (a) an R.sub.f containing anhydride of the formula I ##STR49## wherein Q is a tetraradical of a tricarboxylic or tetracarboxylic acid selected from the group consisting of trimellitic acid, 3,3',4,4'-benzophenonetetracarboxylic acid and 1,2,4,5-benzenetetracarboxylic acid,
- X is hydrogen or carboxy;
- R.sub.f is perfluoroalkyl of 6 to 18 carbon atoms;
- a is 1 or 2;
- A is hydrogen or group II; ##STR50## m is O; Q.sub.1 is the same as Q, and
- R.sub.3 is the residue of an R.sub.f substituted aliphatic alcohol or diol of the structure ##STR51## where R.sub.1 is a branched or straight chain alkylene of 1 to 12 carbon atoms, alkylenethioalkylene of 4 to 12 carbon atoms, alkyleneoxyalkylene of 4 to 12 carbon atoms or alkyleneiminoalkylene of 4 to 12 carbon atoms where the nitrogen atom contains as the third substituent hydrogen or alkyl of 1 to 6 carbon atoms; and
- R.sub.2 is straight or branched chain alkylene of 1 to 12 carbon atoms or an alkylenepolyoxyalkylene of the formula C.sub.n H.sub.2n COC.sub.k H.sub.2k).sub.r where n is 1 or 12, k is 2 to 6 and r is 1 to 40; with
- (b) a tertiary amine containing compound selected from the group consisting of N,N-dimethylaminoethanol; N-methyldiethanolamine; 3;l -dimethylamino-1-propanol; 1-dimethylamino-2-propanol; and N,N-bis(2-hydroxypropyl)aniline; in the ratio of one mole of the tertiary amine containing compound (b) used for each mole of anhydride group of R.sub.f containing compound (a); with the mol ratio of carboxy/R.sub.f groups in the product being 1 to 4; to said formulation.
- 2. A method according to claim 1 wherein the effective amount of the water soluble or water dispersible product is from 0.03 to 0.2% by weight of solids.
- 3. A method according to claim 1 wherein the ionic surfactant is amphoteric fluorinated surfactant.
- 4. A method according to claim 1 where in the R.sub.f containing anhydride of formula I
- Q is the tetraradical of 3,3',4,4'-benzophenonetetracarboxylic acid; X is carboxy; R.sub.f is perfluoroalkyl of 6 to 18 carbon atoms; a is 1 or 2; A is group II ##STR52## m is 0; Q.sub.1 is the same as Q and R.sup.3 is the residue of an R.sub.f substituted aliphatic alcohol or diol of the structure ##STR53## where R.sup.1 is a branched or straight chain alkylene of 1 to 4carbon atoms; and
- R.sup.2 is a branched or straight chain alkylene of 1 to 4 carbon atoms or alkylenepolyoxyalkylene of the formula C.sub.n H.sub.2n (OC.sub.k H.sub.2k).sub.r where n is 1 to 4, k is 2 to 4 and r is 1 to 20.
- 5. A method according to claim 4 wherein the R.sub.f containing anhydride of formula I R.sup.1 is ethylene; and R.sub.2 is methylene or methylenepolyoxyalkylene of the formula CH.sub.2 (OC.sub.k H.sub.2k).sub.r where k is 2 and r is 1 to 20.
- 6. A method according to claim 1 wherein the tertiary amine containing compound (b) is N,N-dimethylaminoethanol.
- 7. A method according to claim 1 wherein the R.sub.f containing anhydride has the structure ##STR54## where R.sub.f is perfluoroalkyl of 6 to 18 carbon atoms.
- 8. A method according to claim 7 wherein the tertiary amine containing compound (b) is N,N-dimethylaminoethanol.
- 9. A method according to claim 1 wherein the mol ratio of carboxy/R.sub.f groups in the product obtained by reacting (a) with (b) is 2 to 4.
Parent Case Info
The present application is a divisional of application Ser. No. 646,689, filed Jan. 5, 1976, now U.S. Pat. No. 4,058,537, issued Nov. 15, 1977.
US Referenced Citations (2)
Divisions (1)
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Number |
Date |
Country |
Parent |
646689 |
Jan 1976 |
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