Permanent magnet alloy for elevated temperature applications

Information

  • Patent Grant
  • 4902360
  • Patent Number
    4,902,360
  • Date Filed
    Friday, October 28, 1988
    36 years ago
  • Date Issued
    Tuesday, February 20, 1990
    34 years ago
Abstract
A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B, wherein, R is a combination of rare earth elements consisting essentially of, in atomic percent, neodymium 3 to 11 and balance holmium. The alloy may include optional additions of the rare earth elements gadolinium up to 10%, terbium up to 15%, dysprosium up to 16%, erbium up to 18% and thulium up to 12%.
Description

BACKGROUND OF THE INVENTION
It is known to use permanent magnet alloys, and particularly permanent magnet alloys embodying one or more rare earth elements with a transistion element iron and boron, for applications requiring permanent magnet properties at elevated temperatures. Specifically in this regard, permanent magnets used in electric motors may encounter motor operating temperatures in excess of 150.degree. C. The permanent magnet alloy R.sub.2 FE.sub.14 B has a temperature dependence of magnetization of -0.08% to -0.12% per .degree.C. over the temperature range of -50.degree. C. to 150.degree. C. Accordingly, this permanent magnet alloy is limited with respect to high-temperature applications, and particularly use in electric motors operating at temperatures in excess of 150.degree. C. For practical applications, it is necessary that permanent magnet alloys at the maximum operating temperature exhibit a magnetization of 8000 Gauss.
OBJECTS OF THE INVENTION
It is accordingly an object of the present invention to provide a permanent magnet alloy of a combination of rare earth elements, the transition element iron and boron with the alloy having improved magnetization at elevated temperatures.
A more specific object of the invention is to provide a permanent magnet alloy of a composition wherein the alloy is characterized by a low temperature coefficient of magnetization, e.g., .alpha. less than -0.01% over .degree.C. over a temperature range of over .alpha.-50.degree. C. to 250.degree. C., with a magnetization greater than 7500 Gauss at room temperature, e.g., 23 .+-.2.degree. C.
SUMMARY OF THE INVENTION
The alloy composition is a combination of rare earth elements (R), in atomic percent, in combination with the base composition R.sub.2 Fe.sub.14 B. R is neodymium 3 to 11% and balance holmium. The following are preferred limits for Nd and Ho and also preferred additional and optional rare earth elements.
______________________________________Nd 4-10 5-11 7-11 7-11 7-11Ho 83-96 76-94 78-90 75-95 82-92Tm 0-13 -- -- -- --Er -- 0-18 -- -- --Tb -- -- 0-12 -- --Dy -- -- -- 0-15 --Gd -- -- -- -- 0-10Nd 1-10 6-10 3-11 9-11 8-12Ho 80-90 76-96 76-92 75-88 72-88Tb 0-10 -- -- 0-12 --Gd 0-4 -- -- -- 0-8Dy -- 0-8 -- 0-15 0-15Er -- 0-14 0-18 -- --Tm -- -- 0-12 -- --______________________________________
The permanent magnet alloy of the invention including optional additional rare earth elements satisfies the above-stated properties with respect to a low temperature coefficient of magnetization in combination with magnetization at room temperature sufficient to enable the permanent magnets made from the alloy to retain sufficient magnetization for use at elevated temperatures.
This is achieved by combining the light rare earth element neodymium (Nd) with the heavy rare earth element holmium (Ho) with the transition element iron and boron. The heavy rare earth element provides the desired low temperature coefficient of magnetization (.alpha.) and neodymium provides the required high magnetization (M.sub.s). In this manner, as the operating temperature of the permanent magnet made from alloy is increased the base magnetization being at a relatively high level in combination with the temperature dependence or the temperature coefficient of magnetization, being low, permanent magnet properties are retained, specifically magnetization, at relatively high operating temperatures.
The permanent magnet alloy of the invention consists essentially of R.sub.2 FE.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 3 to 11 and balance Ho.
The alloy may optionally contain the additional rare earth elements gadolinium (Gd) up to 10%; terbium (Tb) up to 15%; dysprosium (Dy) up to 16%; erbium (Er) up to 18%, and thulium (Tm) up to 12%. Ho is preferably within the range of 72 to 92%.
The temperature coefficient of magnetization or the temperature dependence of magnetization in alloys of neodymium and iron result from the thermal effects on the ordered magnetic moment of the Nd sublattice and the iron sublattice. The magnetic moment of the Nd sublattice decreases much more rapidly than that of the iron sublattice. This results in a strong temperature dependence of the combined magnetic moment of Nd and iron. Consequently, as is well recognized, this alloy is not suitable to provide a constant flux in the presence of temperature variations. Although with heavy rare earth elements, such as Gd, Tb, Dy, Ho, Er, Tm, and Yb, the rare earth sublattice likewise exhibits a decrease in magnetic moment with increased temperature. It has been found, however, in accordance with the resent invention, that these moments oppose the larger moment of iron sublattices to result in enhancing the net moment of the alloy in the presence of temperature increases. It has further been found with respect to these aloys in accordance with the invention, that although this net improvement in magnetic moment is observed and achieved, the magnetization of these alloys is less than required for high temperature application. It is further been found in accordance with the invention that the magnetic moment may be increased by substituting part of the heavy rare earth element content with heavy rare earth-iron-boron alloys with neodymium alone or with one or more additional heavy rare earth elements. In this manner, the required combination of high magnetization and low temperature coefficient of magnetization is achieved. It is this combination of properties that is necessary for the production of useful permanent magnets for applicatios requiring the retention of magnetization at increased temperatures during application.





DESCRIPTION OF THE PREFERRED EMBODIMENTS AND SPECIFIC EXAMPLES
The temperature dependence of magnetization (.alpha.) of the heavy rare earth-iron-boron alloys are shown in Table I.
TABLE I______________________________________Magnetization M.sub.s and Temperature Coefficientof Heavy Rare Earth R.sub.2 Fe.sub.14 B Alloys* M.sub.s (-50-200.degree. C.)Alloy Bohr magneton/formula unit % per .degree.C.______________________________________Ho.sub.2 Fe.sub.14 B 15.69 +0.016Tb.sub.2 Fe.sub.14 B 13.27 -0.007Dy.sub.2 Fe.sub.14 B 13.70 +0.007Gd.sub.2 Fe.sub.14 B 16.56 -0.053Er.sub.2 FE.sub.14 B 17.54 -0.042Tm.sub.2 Fe.sub.14 B 21.80 -0.078______________________________________ *.alpha. = (MT2 - MT1)/M.sub.T1 .times. (T.sub.2 - T.sub.1) in percent, M.sub.T1 and M.sub.T2 are the magnetizations at temperatures T.sub.1 and T.sub.2 respectively.
As may be seen from the data presented Table I, the alpha values for the alloys are in the desired range; however, magnetization (M.sub.s) is lower than required. This is the case with respect to the alloys containing the heavy rare earth elements Ho, Tb and Dy. For the alloys of Table I having the heavy rare earth elements Gd, Er and Tm, the M.sub.s values are at acceptable levels but .alpha. is not within the required range.
In accordance with the invention and to demonstrate the effect of Nd with respect to increasing M.sub.s, Nd was added to the heavy rare earth element containing alloys of Table I. The results from the standpoint of the combination of M.sub.s and alpha by the addition of Nd is shown by the data presented in Tables II through Tables VII.
TABLE II______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Tb.sub.x).sub.2 Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Tb.sub.2 Fe.sub.14 BCOMPO-SITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.21 14496 -.099 .96796 4 31.83 14322 -.098 .96794 6 31.44 14148 -.097 .96692 8 31.05 13974 -.097 .96690 10 30.67 13800 -.096 .96588 12 30.28 13626 -.095 .96586 14 29.89 13452 -.094 .96484 16 29.51 13278 -.093 .96482 18 29.12 13104 -.092 .96380 20 28.73 12930 -.091 .96378 22 28.35 12756 -.091 .96276 24 27.96 12582 -.090 .96174 26 27.57 12408 -.089 .96172 28 27.19 12234 -.088 .96070 30 26.80 12060 -.087 .95968 32 26.41 11886 -.085 .95866 34 26.03 11713 -.084 .95764 36 25.64 11539 -.083 .95662 38 25.25 11365 -.082 .95560 40 24.87 11191 -.081 .95458 42 24.48 11017 -.080 .95356 44 24.09 10843 -.078 .95254 46 23.71 10669 -.077 .95052 48 23.32 10495 -.075 .94950 50 22.94 10321 -.074 .94748 52 22.55 10147 -.073 .94546 54 22.16 9973 -.071 .94344 56 21.78 9799 -.069 .94142 58 21.39 9625 -.068 .93940 60 21.00 9451 -.066 .93638 62 20.62 9277 -.064 .93336 64 20.23 9103 -.062 .92934 66 19.84 8929 -.060 .92632 68 19.46 8755 -.058 .92130 70 19.07 8581 -.056 .91628 72 18.68 8407 -.054 .91026 74 18.30 8233 -.051 .90324 76 17.91 8059 -.049 .89522 78 17.52 7885 -.046 .88520 80 17.14 7711 -.044 .87318 82 16.75 7537 -.041 .85816 84 16.36 7363 -.038 .83914 86 15.98 7189 -.035 .81612 88 15.59 7015 -.032 .78510 90 15.20 6841 - .028 .7448 92 14.82 6667 -.024 .6896 94 14.43 6493 -.020 .6114 96 14.04 6319 -.016 .5012 98 13.66 6145 -.012 .3510 100 13.27 5972 -.007 .167______________________________________
TABLE III______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Gd.sub.x).sub.2 Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Gd.sub.2 Fe.sub.14 BCOMPO-SITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.28 14526 -.099 .96796 4 31.96 14381 -.099 .96694 6 31.64 14237 -.098 .96692 8 31.32 14093 -.098 .96590 10 31.00 13498 -.097 .96588 12 30.68 13626 -.097 .96586 14 30.35 13452 -.096 .96484 16 30.03 13515 -.096 .96482 18 29.71 13371 -.095 .96380 20 29.39 13227 -.094 .96378 22 29.07 13082 -.094 .96276 24 28.75 12938 -.093 .96174 26 28.43 12794 -.093 .96172 28 28.11 12649 -.092 .96070 30 27.79 12505 -.091 .95968 32 27.47 12361 -.091 .95866 34 27.15 12216 -.090 .95864 36 26.83 12072 -.089 .95762 38 26.51 11928 -.089 .95660 40 26.19 11784 -.088 .95558 42 25.86 11639 -.087 .95456 44 25.54 11495 -.087 .95354 46 25.22 11351 -.086 .95252 48 24.90 11206 -.085 .95150 50 24.58 11062 -.084 .94948 52 24.26 10918 -.083 .94846 54 23.94 10773 -.083 .94744 56 23.62 10629 -.082 .94542 58 23.30 10485 -.081 .94440 60 22.98 10340 -.080 .94238 62 22.66 10196 -.079 .94036 64 22.34 10052 -.078 .93834 66 22.02 9907 -.077 .93632 68 21.70 9763 -.076 .93430 70 21.37 9619 -.075 .93128 72 21.05 9474 -.074 .92826 74 20.73 9330 -.072 .92624 76 20.41 9186 -.071 .92222 78 20.09 9041 -.070 .91920 80 19.77 8897 -.069 .91518 82 19.45 8753 -.068 .91116 84 19.13 8608 -.066 .90714 86 18.81 8464 -.065 .90212 88 18.49 8320 -.063 .89610 90 18.17 8175 -.063 .8908 92 17.85 8031 -.060 .8836 94 17.53 7887 -.059 .8754 96 17.21 7742 -.057 .8672 98 16.88 7598 -.055 .8570 100 16.56 7454 -.053 .846______________________________________
TABLE IV______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Dy.sub.x).sub.2 Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Dy.sub.2 Fe.sub.14 BCOMPO-SITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.21 14496 -.099 .96696 4 31.83 14322 -.098 .96694 6 31.44 14148 -.097 .96592 8 31.05 13974 -.096 .96490 10 30.67 13800 -.095 .96388 12 30.28 13626 -.094 .96286 14 29.89 13452 -.093 .96184 16 29.51 13278 -.092 .96082 18 29.12 13104 -.091 .95880 20 28.73 12930 -.090 .95778 22 28.35 12756 -.089 .95676 24 27.96 12582 -.087 .95474 26 27.57 12408 -.086 .95372 28 27.19 12234 -.085 .95170 30 26.80 12060 -.084 .94968 32 26.41 11886 -.082 .94766 34 26.03 11713 -.081 .94564 36 25.64 11539 -.080 .94262 38 25.25 11365 -.078 .94060 40 24.87 11191 -.077 .93758 42 24.48 11017 -.075 .93456 44 24.09 10843 -.073 .93054 46 23.71 10669 -.072 .92652 48 23.32 10495 -.070 .92250 50 22.94 10321 -.068 .91748 52 22.55 10147 -.066 .91246 54 22.16 9973 -.064 .90644 56 21.78 9799 -.062 .89942 58 21.39 9625 -.060 .89240 60 21.00 9421 -.058 .88338 62 20.62 9277 -.056 .87336 64 20.23 9103 -.054 .86134 66 19.84 8929 -.051 .84732 68 19.46 8755 -.049 .83130 70 19.07 8581 -.046 .81228 72 18.68 8407 -.043 .78926 74 18.30 8233 -.040 .76124 76 17.91 8059 -.037 .72822 78 17.52 7885 -.034 .68620 80 17.14 7711 -.031 .63418 82 16.75 7537 -.027 .57016 84 16.36 7363 -.023 .49114 86 15.98 7189 -.020 .39512 88 15.59 7015 -.015 .28310 90 15.20 6841 -.011 .1648 92 14.82 6667 -.006 .0606 94 14.43 6493 -.001 .0034 96 14.04 6319 -.004 .0212 98 13.66 6145 -.009 .1100 100 13.27 5972 -.015 .243______________________________________
TABLE V______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Tm.sub.x).sub.2 Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Tm.sub.2 Fe.sub.14 BCOMPO-SITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.38 14573 -.099 .96596 4 32.17 14476 -.099 .96394 6 31.95 14378 -.099 .96192 8 31.74 14281 -.098 .95890 10 31.52 14184 -.098 .95588 12 31.30 14087 -.098 .95286 14 31.09 13990 -.097 .94984 16 30.87 13892 -.097 .94682 18 30.66 13795 -.097 .94380 20 30.44 13698 -.096 .94078 22 30.22 13601 -.096 .93676 24 30.01 13504 -.096 .93274 26 29.79 13407 -.095 .92872 28 29.58 13309 -.095 .92470 30 29.36 13212 -.095 .91968 32 29.14 13115 -.094 .91466 34 28.93 13018 -.094 .91064 36 28.71 12921 -.094 .90462 38 28.50 12823 -.093 .89960 40 28.28 12726 -.093 .89358 42 28.06 12629 -.093 .88756 44 27.85 12535 -.092 .88154 46 27.63 12435 -.092 .87552 48 27.42 12337 -.091 .86850 50 27.20 12240 -.091 .86148 52 26.98 12143 -.091 .85446 54 26.77 12046 -.090 .84744 56 26.55 11949 -.090 .83942 58 26.34 11851 -.089 .83140 60 26.12 11754 -.089 .82238 62 25.90 11657 -.088 .81336 64 25.69 11650 -.088 .80434 66 25.47 11463 -.088 .79532 68 25.26 11366 -.087 .78530 70 25.04 11268 -.087 .77528 72 24.82 11171 -.086 .76526 74 24.61 11074 -.086 .75424 76 24.39 10977 -.085 .74322 78 24.18 10880 -.085 .73220 80 23.96 10782 -.084 .72018 82 23.74 10685 -.084 .70816 84 23.53 10588 -.083 .69514 86 23.31 10491 -.082 .68312 88 23.10 10394 -.082 .67010 90 22.88 10296 -.081 .6568 92 22.66 10199 -.081 .6436 94 22.45 10102 -.080 .6294 96 22.23 10005 -.080 .6142 98 22.02 9908 -.079 .6000 100 21.80 9810 -.078 .585______________________________________
TABLE VI______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Er.sub.x) Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Er.sub.2 Fe.sub.14 BCOMPO-SITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.30 14534 -.099 .96596 4 32.00 14399 -.098 .96394 6 31.70 14263 -.098 .96192 8 31.39 14128 -.097 .95890 10 31.09 13992 -.096 .95688 12 30.79 13857 -.096 .95386 14 30.49 13721 -.095 .95084 16 30.19 13585 -.094 .94782 18 29.89 13450 -.094 .94380 20 29.59 13314 -.093 .94078 22 29.29 13179 -.092 .93676 24 28.98 13043 -.091 .93274 26 28.68 12908 -.091 .92772 28 28.38 12772 -.090 .92370 30 28.08 12636 -.089 .91868 32 27.78 12501 -.088 .91266 34 27.48 12365 -.087 .90664 36 27.18 12230 -.087 .90062 38 26.88 12094 -.086 .89360 40 26.57 11958 -.085 .88658 42 26.27 11823 -.084 .87956 44 25.97 11867 -.083 .87154 46 25.67 11552 -.082 .86252 48 25.37 11416 -.081 .85350 50 25.07 11281 -.080 .84348 52 24.77 11145 -.079 .83246 54 24.47 11009 -.078 .82144 56 24.16 10874 -.077 .80942 58 23.86 10738 -.076 .79640 60 23.56 10603 -.075 .78238 62 23.26 10467 -.073 .76736 64 22.96 10332 -.072 .75134 66 22.66 10196 -.071 .73532 68 22.36 10060 -.070 .71730 70 22.06 9925 -.068 .69828 72 21.75 9789 -.067 .67826 74 21.45 9654 -.066 .65624 76 21.15 9518 -.064 .63422 78 20.85 9383 -.063 .61020 80 20.55 9247 -.061 .58518 82 20.25 9111 -.059 .55916 84 19.95 8976 -.058 .53114 86 19.64 8840 -.056 .50212 88 19.34 8705 -.054 .47310 90 19.04 8569 -.053 .4428 92 18.74 8434 -.051 .4106 94 18.44 8298 -.049 .3784 96 18.14 8162 -.047 .3452 98 17.84 8027 -.045 .3120 100 17.54 7891 -.042 .280______________________________________
TABLE VII______________________________________Magnetization and Temperature Coefficient of(Nd.sub.1-x Ho.sub.x).sub.2 Fe.sub.14 B Alloys Where x = 0to 100%W % Nd.sub.2 Fe.sub.14 B+ X % Ho.sub.2 FE.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X MB/FU GAUSS -50-200 R SQUARE______________________________________100 0 32.60 14670 -.099 .96798 2 32.26 14518 -.098 .96696 4 31.92 14366 -.097 .96594 6 31.59 14213 -.096 .96392 8 31.25 14061 -.095 .96290 10 30.91 13909 -.094 .96088 12 30.57 13757 -.093 .95986 14 30.23 13604 -.092 .95784 16 29.89 13452 -.091 .95582 18 29.56 13300 -.089 .95380 20 29.22 13148 -.088 .95178 22 28.88 12996 -.087 .94876 24 28.54 12843 -.085 .94674 26 28.20 12691 -.084 .94372 28 27.86 12539 -.083 .94070 30 27.53 12387 -.081 .93668 32 27.19 12235 -.080 .93366 34 26.85 12082 -.078 .92964 36 26.51 11930 -.077 .92462 38 26.17 11778 -.075 .92060 40 25.83 11626 -.073 .91458 42 25.50 11473 -.072 .90956 44 25.16 11321 -.070 .90254 46 24.82 11169 -.068 .89552 48 24.48 11017 -.066 .88750 50 24.14 10865 -.064 .87848 52 23.81 10712 -.062 .86846 54 23.47 10560 -.060 .85744 56 23.13 10408 -.058 .84442 58 22.79 10256 -.056 .83040 60 22.45 10103 -.054 .81438 62 22.11 9951 -.051 .79536 64 21.78 9799 -.049 .77334 66 21.44 9647 -.047 .74832 68 21.10 9495 -.044 .72030 70 20.76 9342 -.041 .68628 72 20.42 9190 -.038 .64826 74 20.08 9038 -.036 .60324 76 19.75 8886 -.033 .55122 78 19.41 8734 -.029 .49120 80 19.07 8581 -.026 .42418 82 18.73 8429 -.023 .34916 84 18.39 8277 -.019 .26914 86 18.05 8125 -.016 .18712 88 17.72 7972 -.012 .11110 90 17.38 7820 -.008 .0498 92 17.04 7668 -.003 .0106 94 16.70 7516 .001 .0014 96 16.36 7364 .006 .0242 98 16.03 7211 .011 .0750 100 15.69 7059 .016 .146______________________________________
In Tables II through Tables VII it may be seen that complete replacement of the heavy rare earth element with Nd is not desirable as the resulting values are not within the required range. In addition, the values ar not improved by the addition of Nd except for the relatively narrow ranges of Nd in combination with Ho in accordance with the composition limits of the invention.
It was additionally determined from an analysis of the magnitization curve as a function of temperature that a combination of two or more heavy rare earth elements with neodynium-iron-boron may provide optimum properties in accordance with the invention.
TABLE VIII______________________________________Magnetization and Temperature Coefficientof (NdDyHo).sub.2 Fe.sub.14 B AlloysW % Dy.sub.2 F.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y % Ho.sub.2 FE.sub.14COMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 14.04 6319 .004 .02186 4 10 14.28 6428 .004 .02176 4 20 14.53 6537 .004 .02266 4 30 14.77 6646 .004 .02256 4 40 15.01 6755 .005 .02246 4 50 15.25 6863 .005 .02336 4 60 15.49 6972 .005 .02326 4 70 15.74 7081 .005 .02316 4 80 15.98 7190 .005 .024 6 4 90 16.22 7298 .006 .02494 6 0 14.43 6493 -.001 .00384 6 10 14.67 6602 -.001 .00274 6 20 14.91 6711 -.001 .00164 6 30 15.15 6820 -.001 .00054 6 40 15.40 6928 -.000 .00044 6 50 15.64 7037 - .000 .00034 6 60 15.88 7146 .000 .00024 6 70 16.12 7255 .000 .00014 6 80 16.36 7364 .001 .000 4 6 90 16.61 7472 .001 .00192 8 0 14.82 6667 -.006 .06082 8 10 15.06 6776 -.006 .05072 8 20 15.30 6885 -.006 .04162 8 30 15.54 6994 -.005 .03452 8 40 15.78 7102 -.005 .02842 8 50 16.02 7211 -.005 .02332 8 60 16.27 7320 -.004 .01922 8 70 16.51 7429 -.004 .01512 8 80 16.75 7538 -.004 .013 2 8 90 16.99 7646 -.003 .01090 10 0 15.20 6841 -.011 .16480 10 10 15.44 6950 -.011 .14370 10 20 15.69 7069 -.010 .12560 10 30 15.93 7168 -.010 .10950 10 40 16.17 7275 -.009 .09540 10 50 16.41 7385 -.009 .08330 10 60 16.65 7494 -.009 .07320 10 70 17.14 7603 -.008 .06410 10 80 17/14 7711 -.008 .056 0 10 90 17.38 7820 -.008 .04988 12 0 15.59 7014 -.015 .28378 12 10 15.83 7124 -.015 .25468 12 20 16.07 7233 -.014 .22858 12 30 16.31 7342 -.014 .20548 12 30 16.56 7450 -.014 .18438 12 50 16.80 7559 -.013 .16628 12 60 17.04 7668 -.013 .14918 12 70 17.28 7777 -.012 .134 8 12 80 17.52 7885 -.012 .12186 14 0 15.98 7189 -.020 .39576 14 10 16.22 7298 -.019 .36366 14 20 16.46 7407 -.019 .33356 14 30 16.70 7516 -.018 .30546 14 40 16.94 7624 -.018 .28036 14 50 17.18 7733 -.017 .25626 14 60 17.43 7842 -.017 .23516 14 70 17.67 7951 -.016 .215 6 14 80 17.91 8059 -.016 .19784 16 0 16.36 7363 -.023 .49174 16 10 16.60 7472 -.023 .45964 16 20 16.85 7581 -.022 .42854 16 30 17.09 7690 -.022 .39944 16 40 17.33 7798 -.021 .37134 16 50 17.57 7907 -.021 .34524 16 60 17.81 8016 -.020 .32114 16 70 18.05 8125 -.020 .298 4 16 80 18.30 8233 -.019 .27782 18 0 16.75 7537 -.027 .57072 18 10 16.99 7646 -.027 .53962 18 20 17.23 7755 -.026 .50952 18 30 17.47 7864 -.025 .48042 18 40 17.72 7972 -.025 .45332 18 50 17.96 8081 -.024 .42622 18 60 18.20 8190 -.024 .40112 18 70 18.44 8299 -.023 .376 2 18 80 18.68 8407 -.023 .35480 20 0 17.14 7711 -.031 .63470 20 10 17.38 7820 -.030 .60660 20 20 17.62 7929 -.029 .57850 20 30 17.86 8146 -.029 .55040 20 40 18.10 8146 -.028 .52330 20 50 18.34 8255 -.028 .49720 20 60 18.59 8364 -.027 .47210 20 70 18.83 8473 -.027 .447 0 20 80 19.07 8581 -.026 .424______________________________________
As shown from Table VIII, by adding Nd to a combination of Ho and Dy in an iron-boron alloy both the alpha and M.sub.s are achieved in combination only when Nd is within the range of 8 to 11%, Ho in the range of 75 to 92%, and Dy in the range of 0 to 15%.
TABLE IX______________________________________Magnetization and Temperature Coefficientof (NdDyTm) AlloysW % Dy.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Tm.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 14.04 6319 .004 .02186 4 10 14.90 6703 -.010 .08976 4 20 15.75 7087 -.022 .25966 4 30 16.60 7471 -.033 .37756 4 40 17.46 7855 -.042 .45446 4 50 18.31 8239 -.050 .50536 4 60 19.16 8623 -.058 .54226 4 70 20.01 9007 -.065 .56916 4 80 20.87 9391 -.071 .590 6 4 90 21.72 9774 -.076 .60694 6 0 14.43 6493 -.001 .00384 6 10 15.28 6877 -.014 .17674 6 20 16.14 7261 -.026 .33564 6 30 16.99 7645 -.036 .43454 6 40 17.84 8029 -.045 .49744 6 50 18.70 8413 -.053 .54034 6 60 19.55 8797 -.060 .57024 6 70 20.40 9181 -.067 .59314 6 80 21.25 9565 -.073 .610 4 6 90 22.11 9948 -.078 .62492 8 0 14.82 6667 -.006 .06082 8 10 15.67 7051 -.019 .27072 8 20 16.52 7435 -.030 .40562 8 30 17.38 7819 -.039 .48652 8 40 18.23 8203 -.048 .53642 8 50 19.08 8587 -.055 .57132 8 60 19.94 8971 -.062 .59622 8 70 20.79 9355 -.069 .61512 8 80 21.64 9739 -.074 .629 2 8 90 22.49 10122 -.080 .64090 10 0 15.20 6841 -.011 .16480 10 10 16.06 7225 -.023 .36070 10 20 16.91 7609 -.033 .46960 10 30 17.76 7993 -.042 .53250 10 40 18.62 8377 -.050 .57240 10 50 19.47 8761 -.058 .60030 10 60 20.32 9145 -.065 .62020 10 70 21.17 9529 -.071 .63510 10 80 22.03 9913 -.076 .647 0 10 90 22.88 10296 -.081 .65688 12 0 15.59 7015 -.015 .28378 12 10 16.44 7399 -.027 .44268 12 20 17.30 7783 -.036 .52558 12 30 18.15 8167 -.045 .57348 12 40 19.00 8551 -.053 .60538 12 50 19.86 8935 -.060 .62628 12 60 20.71 9319 -.067 .64218 12 70 21.56 9703 -.073 .654 8 12 80 22.41 10086 -.078 .66386 14 0 15.98 7189 -.020 .39576 14 10 16.83 7573 -.030 .51366 14 20 17.68 7957 -.040 .57456 14 30 18.54 8341 -.048 .61046 14 40 19.39 8725 -.056 .63436 14 50 20.24 9109 -.062 .65026 14 60 21.09 9493 -.069 .66216 14 70 21.95 9877 -.074 .672 6 14 80 22.80 10260 -.080 .67984 16 0 16.36 7363 -.023 .49174 16 10 17.22 7747 -.034 .57464 16 20 18.07 8131 -.043 .61754 16 30 18.92 8515 -.051 .64344 16 40 19.78 8899 -.058 .66034 16 50 20.63 9283 -.065 .67224 16 60 21.48 9667 -.071 .68114 16 70 22.33 10051 -.076 .688 4 16 80 23.19 10434 -.081 .69382 18 0 16.75 7537 -.027 .57072 18 10 17.60 7921 -.037 .62562 18 20 18.46 8305 -.045 .65452 18 20 18.46 8689 -.053 .67242 18 40 20.16 9073 -.060 .68432 18 50 21.01 9457 -.067 .69222 18 60 21.87 9841 -.072 .69812 18 70 22.72 10224 -.078 .703 2 18 80 23.57 10608 -.083 .70780 20 0 17.14 7711 -.031 .63470 20 10 17.99 8095 -.040 .66860 20 20 18.84 8479 -.048 .68750 20 30 19.70 8863 -.056 .69840 20 40 20.55 9247 -.062 .70530 20 50 21.40 9631 -.069 .71020 20 60 22.25 10015 -.074 .71410 20 70 23.11 10398 -.079 .717 0 20 80 23.96 10782 -.084 .720______________________________________
As may be seen from the data presented in Table IX where the Nd is alloyed with Dy and Tm within the cited ranges none of the alloys meet the desired combination of properties.
TABLE X______________________________________Magnetization and Temperature Coefficientof (NdDyTb).sub.2 Fe.sub.14 B AlloysW % Dy.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Tb.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 14.04 6319 .004 .02186 4 10 14.04 6319 -.002 .00476 4 20 14.04 6319 -.000 .00066 4 30 14.04 6319 -.003 .01356 4 40 14.04 6319 -.005 .04446 4 50 14.04 6319 -.007 .09736 4 60 14.04 6319 -.009 .16826 4 70 14.04 6319 -.011 .25416 4 80 14.04 6319 -.013 .349 6 4 90 14.04 6319 -.015 .44594 6 0 14.43 6493 -.001 .00384 6 10 14.43 6493 -.004 .02074 6 20 14.43 6493 -.006 .05364 6 30 14.43 6493 -.008 .10254 6 40 14.43 6493 -.010 .16744 6 50 14.43 6493 -.012 .24434 6 60 14.43 6493 -.014 .32824 6 70 14.43 6493 -.016 .41614 6 80 14.43 6493 -.018 .501 4 6 90 14.43 6493 -.020 .58192 88 0 14.82 6667 -.006 .06082 8 10 14.82 6667 -.008 .10672 8 20 14.82 6667 -.010 .16562 8 30 14.82 6667 -.012 .23552 8 40 14.82 6667 -.014 .31142 8 50 14.82 6667 -.016 .39032 8 60 14.82 6667 -.018 .46922 8 70 14.82 6667 -.020 .54512 8 80 14.82 6667 -.022 .614 2 8 90 14.82 6667 -.024 .67790 10 0 15.20 6841 -.011 .16480 10 10 15.20 6841 -.013 .22770 10 20 15.20 6841 -.015 .29660 10 30 15.20 6841 -.017 .36850 10 40 15.20 6841 -.019 .44140 10 50 15.20 6841 -.021 .51230 10 60 15.20 6841 -.022 .57920 10 70 15.20 6841 -.024 .64010 10 80 15.20 6841 -.026 .696 0 10 90 15.20 6841 -.028 .74488 12 0 15.59 7015 -.015 .28378 12 10 15.59 7015 -.017 .34968 12 20 15.59 7015 -.019 .41658 12 30 15.59 7015 -.021 .48348 12 40 15.59 7015 -.023 .54638 12 50 15.59 7015 -.025 .60628 12 60 15.59 7015 -.026 .66118 12 70 15.59 7015 -.028 .710 8 12 80 15.59 7015 -.030 .75486 14 0 15.98 7189 -.020 .39576 14 10 15.98 7189 -.021 .45766 14 20 15.98 7189 -.023 .51756 14 30 15.98 7189 -.025 .57546 14 40 15.98 7189 -.027 .62836 14 50 15.98 7189 -.028 .67726 14 60 15.98 7189 -.030 .72216 14 70 15.98 7189 -.032 .762 6 14 80 15.98 7189 -.034 .79784 16 0 16.36 7363 -.023 .49174 16 10 16.36 7363 -.025 .54664 16 20 16.36 7363 -.027 .59854 16 30 16.36 7363 -.029 .64744 16 40 16.36 7363 -.030 .69134 16 50 16.36 7363 -.032 .73224 16 60 16.36 7363 -.034 .76814 16 70 16.36 7363 -.036 .800 4 16 80 16.36 7363 .037 .82982 18 0 16.75 7537 -.027 .57072 18 10 16.75 7537 -.029 .61862 18 20 16.75 7537 -.031 .66252 18 20 16.75 7537 -.032 .70342 18 40 16.75 7537 -.034 .74032 18 50 16.75 7537 -.036 .77322 18 60 16.75 7537 -.037 .80312 18 70 16.75 7537 -.039 .830 2 18 80 16.75 7537 -.041 .85480 20 0 17.14 7711 -.031 .63470 20 10 17.14 7711 -.032 .67560 20 20 17.14 7711 -.034 .71250 20 30 17.14 7711 -.036 .74640 20 40 17.14 7711 -.037 .77730 20 50 17.14 7711 -.039 .80520 20 60 17.14 7711 -.041 .83110 20 70 17.14 7711 -.042 .853 0 20 80 17.14 7711 -.044 .873______________________________________
This is also the case with respect to Table X wherein Nd is alloyed with Tb and Dy.
TABLE XI______________________________________Magnetization and Temperature Coefficientof (NdDyGd).sub.2 Fe.sub.14 B AlloysW % Dy.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Gd.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 14.04 6319 .004 .02186 4 10 14.37 6468 -.004 .02676 4 20 14.70 6616 -.012 .17766 4 30 15.03 6764 -.019 .36556 4 40 15.36 6912 -.025 .52346 4 50 15.69 7061 -.032 .63936 4 60 16.02 7209 -.038 .72126 4 70 16.35 7357 -.043 .77916 4 80 16.68 7505 -.049 .821 6 4 90 17.01 7654 -.054 .85294 6 0 14.43 6493 -.001 .00384 6 10 14.76 6642 -.009 .11374 6 20 15.09 6790 -.016 .29964 6 30 15.42 6938 -.023 .47054 6 40 15.75 7086 -.029 .60044 6 50 16.08 7235 -.035 .69334 6 60 16.41 7383 -.041 .75924 6 70 16.74 7531 -.046 .80614 6 80 17.07 7679 -.052 .841 4 6 90 17.39 7827 -.057 .86792 8 0 14.82 6667 -.006 .06082 8 10 15.15 6816 -.014 .23172 8 20 15.48 6964 -.020 .41262 8 30 15.80 7112 -.027 .55752 8 40 14.82 7260 -.033 .66242 8 50 16.13 7409 -.039 .73632 8 60 16.46 7557 -.044 .78922 8 70 16.79 7705 -.049 .82812 8 80 17.12 7853 -.054 .857 2 8 90 17.45 8001 -.059 .87990 10 0 17.78 6841 -.011 .16480 10 10 15.20 6990 -.018 .34970 10 20 15.53 7138 -.024 .50860 10 30 15.86 7286 -.031 .62650 10 40 16.19 7434 -.036 .71040 10 50 16.52 7583 -.042 .77130 10 60 16.85 7731 -.047 .81420 10 70 17.18 7879 -.052 .84710 10 80 17.51 8027 -.057 .871 0 10 90 17.84 8175 -.062 .89088 12 0 18.17 7015 -.015 .28378 12 10 15.59 7164 -.022 .45468 12 20 15.92 7312 -.028 .58658 12 30 16.25 7460 -.034 .68148 12 40 16.58 7608 -.040 .74938 12 50 16.91 7756 -.045 .79928 12 60 17.24 7905 -.050 .83518 12 70 17.57 8053 -.055 .862 8 12 80 17.90 8201 -.060 .88386 14 0 18.22 7189 -.020 .39576 14 10 15.98 7338 -.026 .54166 14 20 16.31 7486 -.032 .64956 14 30 16.64 7634 -.037 .72646 14 40 16.96 7782 -.043 .78136 14 50 17.29 7930 -.048 .82226 14 60 17.95 8079 -.053 .85216 14 70 18.28 8227 -.058 .875 6 14 80 18.61 8375 -.062 .89384 16 0 16.36 7363 -.023 .49174 16 10 16.69 7511 -.029 .61264 16 20 17.02 7660 -.035 .69954 16 30 17.35 7808 -.041 .76144 16 40 17.68 7956 -.046 .80734 16 50 18.01 8104 -.051 .84124 16 60 18.34 8253 -.056 .86614 16 70 18.67 8401 -.060 .886 4 16 80 19.00 8549 -.064 .90182 18 0 16.75 7537 -.027 .57072 18 10 17.08 7685 -.033 .66862 18 20 17.41 7834 -.038 .73952 18 20 17.74 7982 -.044 .79042 18 40 18.07 8130 -.049 .82832 18 50 18.40 8278 -.054 .85622 18 60 18.73 8427 -.058 .87812 18 70 19.06 8575 -.062 .895 2 18 80 19.38 8723 -.067 .90980 20 0 17.14 7711 -.031 .63470 20 10 17.47 7859 -.036 .71460 20 20 17.79 8008 -.042 .77250 20 30 18.12 8156 -.047 .81440 20 40 18.45 8304 -.051 .84630 20 50 18.78 8452 -.056 .87020 20 60 19.11 8601 -.060 .88910 20 70 19.44 8749 -.065 .903 0 20 80 19.77 8897 -.069 .915______________________________________
The Table XI the alloy compositions embodying Dy and Gd with neodynium do not provide alloys that meet the desired combination of properties.
TABLE XII______________________________________Magnetization and Temperature Coefficientof (NdHoTm).sub.2 Fe.sub.14 B AlloysW % Ho.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Tm.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 16.36 7364 .006 .02486 4 10 16.97 7639 -.007 .02976 4 20 17.59 7914 -.018 .15066 4 30 18.20 8189 -.029 .27456 4 40 18.81 8464 -.038 .37146 4 50 19.42 8739 -.047 .44536 4 60 20.03 9014 -.055 .50026 4 70 20.64 9289 -.062 .54216 4 80 21.25 9565 -.069 .575 6 4 90 21.87 9840 -.076 .60194 6 0 16.70 7516 -.001 .00184 6 10 17.31 7791 -.011 .07474 6 20 17.92 8066 -.022 .21164 6 30 18.54 8341 -.032 .32954 6 40 19.15 8616 -.041 .41744 6 50 19.76 8891 -.050 .48234 6 60 20.37 9167 -.057 .53124 6 70 20.98 9442 -.065 .56814 6 80 21.59 9717 -.071 .597 4 6 90 22.20 9992 -.078 .62192 8 0 17.04 7668 -.003 .01082 8 10 17.65 7943 -.015 .13372 8 20 18.26 8218 -.025 .27462 8 30 18.87 8493 -.035 .38252 8 40 19.49 8769 -.044 .46042 8 50 20.10 9044 -.052 .51832 8 60 20.71 9319 -.060 .56022 8 70 21.32 9594 -.067 .59312 8 80 21.93 9869 -.073 .618 2 8 90 22.54 10144 -.080 .63990 10 0 17.38 7820 -.008 .04980 10 10 17.99 8095 -.019 .20170 10 20 18.60 8370 -.029 .33560 10 30 19.21 8646 -.038 .43250 10 40 19.82 8921 -.047 .50140 10 50 20.44 9196 -.055 .55030 10 60 21.05 9471 -.062 .58720 10 70 21.66 9746 -.069 .61610 10 80 22.27 10021 -.075 .638 0 10 90 22.88 10296 -.081 .65688 12 0 17.72 7972 -.012 .11178 12 10 18.33 8248 -.022 .27268 12 20 18.94 8523 -.032 .39458 12 30 19.55 8798 -.041 .47848 12 40 20.16 9073 -.049 .53838 12 50 20.77 9348 -.057 .58028 12 60 21.38 9623 -.064 .61218 12 70 22.00 9898 -.071 .637 8 12 80 22.61 10173 -.077 .65786 14 0 18.05 8125 -.016 .18776 14 10 18.67 8400 -.026 .34266 14 20 19.28 8675 -.035 .44956 14 30 18.89 8950 -.044 .52146 14 40 20.50 9225 -.052 .57236 14 50 21.11 9500 -.059 .60826 14 60 21.72 9775 -.066 .63616 14 70 22.33 10051 -.073 .657 6 14 80 22.95 10326 -.079 .67484 16 0 18.39 8277 -.019 .26974 16 10 19.00 8552 -.029 .40864 16 20 19.62 8827 -.038 .49954 16 30 20.23 9102 -.047 .56044 16 40 20.84 9377 -.054 .60334 16 50 21.45 9653 -.062 .63424 16 60 22.06 9928 - .069 .65814 16 70 22.67 10203 -.075 .676 4 16 80 23.28 10478 -.081 .69082 18 0 18.73 8429 -.023 .34972 18 10 19.34 8704 -.032 .46962 18 20 19.95 8979 -.041 .54552 18 20 20.57 9254 -.049 .59642 18 40 21.18 9530 -.057 .63232 18 50 21.79 9805 -.064 .65822 18 60 22.40 10080 -.071 .67812 18 70 23.01 10355 -.077 .693 2 18 80 23.62 10630 -.082 .70680 20 0 19.07 8581 -.026 .42470 20 10 19.68 8856 -.035 .52360 20 20 20.29 9132 -.044 .58650 20 30 20.90 9407 -.052 .62840 20 40 21.52 9682 -.059 .65830 20 50 22.13 9957 -.066 .68020 20 60 22.74 10232 -.072 .69610 20 70 23.35 10507 -.078 .709 0 20 80 23.96 10782 -.084 .720______________________________________
As can be seen from the data presented in Table XII with neodynium within the range of 4 to 10%, Tm can be varied from 0 to 13% in combination with Nd and Ho within the range of 83 to 96% to achieve the desired combination of properties.
TABLE XIII______________________________________Magnetization and Temperature Coefficientof (NdHoEr).sub.2 Fe.sub.14 B AlloysW % Ho.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Er.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 16.36 7364 .006 .02486 4 10 16.55 7447 -.001 .00076 4 20 16.73 7530 -.007 .02466 4 30 16.92 7613 -.012 .07056 4 40 17.10 8305 -.018 .12246 4 50 17.29 7780 -.024 .17336 4 60 17.47 7863 -.029 .22026 4 70 17.66 7946 -.034 .26116 4 80 17.84 8029 -.039 .297 6 4 90 18.03 8112 -.044 .32894 6 0 16.70 7516 .001 .00184 6 10 16.89 7599 -.005 .01774 6 20 17.07 7682 -.011 .06464 6 30 17.26 7765 -.016 .12054 6 40 17.44 7849 -.022 .17644 6 50 17.63 7932 -.027 .22634 6 60 17.81 8015 -.032 .26924 6 70 18.00 8098 -.037 .30714 6 80 18.18 8181 -.042 .340 4 6 90 18.37 8265 -.047 .36892 8 0 17.04 7668 -.003 .01082 8 10 17.22 7751 -.009 .05772 8 20 17.41 7834 -.015 .11862 8 30 17.59 7918 -.020 .17852 8 40 17.78 8001 -.026 .23242 8 50 17.96 8084 -.031 .27932 8 60 18.15 8167 -.036 .31822 8 70 18.33 8250 -.041 .35212 8 80 18.52 8334 -.045 .381 2 8 90 18.70 8417 -.050 .40690 10 0 17.38 7820 -.008 .04980 10 10 17.56 7903 -.013 .11570 10 20 17.75 7987 -.019 .18160 10 30 17.93 8070 -.024 .24050 10 40 18.12 8153 -.029 .28940 10 50 18.30 8236 -.034 .33130 10 60 18.49 8319 -.039 .36620 10 70 18.67 8403 -.044 .39610 10 80 18.86 8486 -.048 .421 0 10 90 19.04 8569 -.053 .44288 12 0 17.72 7972 -.012 .11178 12 10 17.90 8056 -.017 .18468 12 20 18.09 8139 -.022 .24858 12 30 18.27 8222 -.027 .30248 12 40 18.46 8305 -.032 .34538 12 50 18.64 8388 -.037 .38228 12 60 18.83 8472 -.042 .41218 12 70 19.01 8555 -.046 .437 8 12 80 19.20 8638 -.051 .45886 14 0 18.05 8125 -.016 .18776 14 10 18.24 8208 -.021 .25866 14 20 18.42 8291 -.026 .31556 14 30 18.61 8374 -.031 .36246 14 40 18.79 8457 -.036 .39936 14 50 18.98 8541 -.040 .42926 14 60 19.16 8624 -.045 .45416 14 70 19.35 8707 -.049 .475 6 14 80 19.53 8790 -.054 .49384 16 0 18.39 8277 -.019 .26974 16 10 18.58 8360 -.024 .33164 16 20 18.76 8443 -.029 .38054 16 30 18.95 8527 -.034 .41844 16 40 19.13 8610 -.039 .44934 16 50 19.32 8693 -.043 .47424 16 60 19.50 8776 -.048 .49414 16 70 19.69 8859 -.052 .511 4 16 80 19.87 8943 -.056 .52682 18 0 18.73 8429 -.023 .34972 18 10 18.92 8512 -.028 .40162 18 20 19.10 8596 -.032 .44052 18 20 19.29 8679 -.037 .47142 18 40 19.47 8762 -.042 .49532 18 50 19.66 8845 -.046 .51522 18 60 19.84 8928 -.050 .53112 18 70 20.03 9012 -.055 .545 2 18 80 20.21 9095 -.059 .55780 20 0 19.07 8581 -.026 .42470 20 10 19.25 8665 -.031 .46460 20 20 19.44 8748 -.036 .49550 20 30 19.62 8831 -.040 .51940 20 40 19.81 8914 -.045 .53830 20 50 19.99 8997 -.049 .55320 20 60 20.18 9081 -.053 .56510 20 70 20.36 9164 -.057 .576 0 20 80 20.55 9247 -.061 .585______________________________________
As may be seen from the data presented in this Table, if Nd varies from 5 to 11%, Er from 0 and Ho from 76 to 94%, the alloys meet the desired combination of properties.
TABLE XIV______________________________________Magnetization and Temperature Coefficientof (NdHoTb).sub.2 Fe.sub.14 B AlloysW % Ho.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Tb.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 16.36 7364 .006 .02486 4 10 16.12 7255 .004 .01176 4 20 15.88 7146 .002 .00266 4 30 15.64 7037 -.001 .00056 4 40 15.40 6929 -.003 .01046 4 50 15.16 6820 -.005 .03736 4 60 14.91 6711 -.007 .08726 4 70 14.67 6602 -.010 .16716 4 80 14.43 6493 -.012 .278 6 4 90 14.19 6385 -.015 .41494 6 0 16.70 7516 .001 .00184 6 10 16.46 7407 -.001 .00174 6 20 16.22 7298 -.003 .01064 6 30 15.98 7190 -.005 .03154 6 40 15.73 7081 -.008 .06944 6 50 15.49 6972 - .010 .12834 6 60 15.25 6863 -.012 .20924 6 70 15.01 6754 -.014 .31414 6 80 14.77 6646 -.017 .435 4 6 90 14.53 6537 -.019 .56192 8 0 17.04 7668 -.003 .01082 8 10 16.80 7559 -.005 .02772 8 20 16.56 7450 -.008 .05762 8 30 16.31 7342 -.010 .10252 8 40 16.07 7233 -.012 .16442 8 50 15.83 7124 -.014 .24432 8 60 15.59 7015 -.017 .34122 8 70 15.35 6907 -.019 .44912 8 80 15.11 6798 -.021 .561 2 8 90 14.86 6689 -.024 .66890 10 0 17.38 7820 -.008 .04980 10 10 17.14 7711 -.010 .08470 10 20 16.89 7603 -.012 .13360 10 30 16.65 7494 -.014 .19650 10 40 16.41 7385 -.016 .27340 10 50 16.17 7276 -.018 .36330 10 60 15.93 7168 -.021 .46020 10 70 15.69 7059 -.023 .56010 10 80 15.44 6950 -.026 .657 0 10 90 15.20 6841 -.028 .74488 12 0 17.72 7972 -.012 .11178 12 10 17.47 8056 -.014 .16268 12 20 17.23 7755 -.016 .22458 12 30 16.99 7646 -.018 .29748 12 40 16.75 7537 -.020 .38038 12 50 16.51 7429 -.022 .46828 12 60 16.27 7320 -.025 .55918 12 70 16.02 7211 -.027 .647 8 12 80 15.78 7102 -.030 .72886 14 0 18.05 8125 -.016 .18776 14 10 17.81 8016 -.018 .24866 14 20 17.57 7907 -.020 .31756 14 30 17.33 7798 -.022 .39446 14 40 17.09 7690 -.024 .47536 14 50 16.85 7581 -.026 .55826 14 60 16.60 7472 -.029 .63816 14 70 16.36 7363 -.031 .713 6 14 80 16.12 7255 -.033 .78084 16 0 18.39 8277 -.019 .26974 16 10 18.15 8168 -.021 .33464 16 20 17.91 8059 -.023 .40654 16 30 17.67 7951 -.026 .48044 16 40 17.43 7842 -.028 .55634 16 50 17.18 7733 -.030 .63024 16 60 16.94 7624 -.032 .70014 16 70 16.70 7516 -.035 .764 4 16 80 16.46 7407 -.037 .82082 18 0 18.73 8429 -.023 .34972 18 10 18.49 8320 -.025 .41662 18 20 18.25 8212 -.027 .48552 18 20 18.01 8103 -.029 .55542 18 40 17.76 7994 -.031 .62332 18 50 17.52 7885 -.033 .68922 18 60 17.28 7777 -.036 .74912 18 70 17.04 7668 -.038 .803 2 18 80 16.80 7559 -.040 .85080 20 0 19.07 8581 -.026 .42470 20 10 18.83 8473 -.028 .48860 20 20 18.59 8364 -.030 .55350 20 30 18.34 8255 -.032 .61740 20 40 18.10 8146 -.035 .67930 20 50 17.86 8037 -.037 .73620 20 60 17.62 7929 -.039 .78710 20 70 17.38 7820 -.041 .833 0 20 80 17.14 7711 -.044 .873______________________________________
Table XIV shows that with Nd within the range of 7 to 11% the properties are obtained if Ho is maintained within the range of 78 to 90% and Tb varies 9 to 12%.
TABLE XV______________________________________Magnetization and Temperature Coefficientof (NdHoDy).sub.2 Fe.sub.14 B AlloysW % Ho.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Dy.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 16.36 7364 .006 .02486 4 10 16.12 7255 .005 .02476 4 20 15.88 7146 .005 .02466 4 30 15.64 7037 -.005 .02356 4 40 15.40 6929 -.005 .02346 4 50 15.16 6820 -.005 .02336 4 60 14.91 6711 -.005 .02226 4 70 14.67 6602 -.004 .02216 4 80 14.43 6493 -.004 .021 6 4 90 14.19 6385 -.004 .02194 6 0 16.70 7516 .001 .00184 6 10 16.46 7407 -.001 .00174 6 20 16.22 7298 -.001 .00064 6 30 15.98 7190 -.000 .00054 6 40 15.73 7081 -.000 .00044 6 50 15.49 6972 -.000 .00034 6 60 15.25 6863 -.000 .00024 6 70 15.01 6754 -.001 .00114 6 80 14.77 6646 -.001 .001 4 6 90 14.53 6537 -.001 .00392 8 0 17.04 7668 -.003 .01082 8 10 16.80 7559 -.004 .01272 8 20 16.56 7450 -.004 .01862 8 30 16.31 7342 -.004 .02252 8 40 16.07 7233 -.005 .02742 8 50 15.83 7124 -.005 .03332 8 60 15.59 7015 -.005 .03922 8 70 15.35 6907 -.006 .04812 8 80 15.11 6798 -.006 .058 2 8 90 14.86 6689 -.006 .04990 10 0 17.38 7820 -.008 .05680 10 10 17.14 7711 -.008 .06470 10 20 16.89 7603 -.008 .07360 10 30 16.65 7494 -.009 .08350 10 40 16.41 7385 -.009 .09540 10 50 16.17 7276 -.009 .10930 10 60 15.93 7168 -.010 .12520 10 70 15.69 7059 -.010 .14310 10 80 15.44 6950 -.011 .164 0 10 90 15.20 6841 -.011 .11188 12 0 17.72 7972 -.012 .12378 12 10 17.47 7864 -.012 .13768 12 20 17.23 7755 -.012 .15258 12 30 16.99 7646 -.013 .16948 12 40 16.75 7537 -.013 .18838 12 50 16.51 7429 -.014 .21028 12 60 16.27 7320 -.014 .23318 12 70 16.02 7211 -.015 .260 8 12 80 15.78 7102 -.015 .18786 14 0 18.05 8125 -.016 .20476 14 10 17.81 8016 -.016 .22366 14 20 17.57 7907 -.016 .24356 14 30 17.33 7798 -.017 .26646 14 40 17.09 7690 -.017 .47536 14 50 16.85 7581 -.018 .29026 14 60 16.60 7472 -.018 .31616 14 70 16.36 7363 -.019 .344 6 14 80 16.12 7255 -.019 .37584 16 0 18.39 8277 -.019 .26974 16 10 18.15 8168 -.020 .28964 16 20 17.91 8059 -.020 .31254 16 30 17.67 7951 -.021 .33544 16 40 17.43 7842 -.021 .36034 16 50 17.18 7733 -.022 .38724 16 60 16.94 7624 -.022 .41614 16 70 16.70 7516 -.023 .446 4 16 80 16.46 7407 -.023 .47882 18 0 18.73 8429 -.023 .34972 18 10 18.49 8320 -.023 .37262 18 20 18.25 8212 -.024 .39652 18 20 18.01 8103 -.024 .42142 18 40 17.76 7994 -.025 .44732 18 50 17.52 7885 -.025 .47522 18 60 17.28 7777 -.026 .50412 18 70 17.04 7668 -.026 .533 2 18 80 16.80 7559 -.027 .56480 20 0 19.07 8581 -.026 .42470 20 10 18.83 8473 -.027 .44760 20 20 18.59 8364 -.027 .47250 20 30 18.34 8255 -.028 .497B0 20 40 18.10 8146 -.028 .52330 20 50 17.86 8037 -.029 .55020 20 60 17.62 7929 -.029 .57810 20 70 17.38 7820 -.030 .606 0 20 80 17.14 7711 -.031 .634______________________________________
In Table XV the desired combination of properties are achieved with alloys containing the addition of 7 to 11%, Ho 75 to 90%, and Dy within the range of 0 to 15%.
TABLE XVI______________________________________Magnetization and Temperature Coefficientof (NdHoGd).sub.2 Fe.sub.14 B AlloysW % Ho.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Gd.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y MB/FU GAUSS -50-200 R SQUARE______________________________________96 4 0 16.36 7364 .006 .02486 4 10 16.45 7403 -.002 .00276 4 20 16.54 7443 -.009 .06466 4 30 16.63 7482 -.015 .19656 4 40 16.71 7521 -.022 .35646 4 50 16.80 7561 -.029 .50736 4 60 16.89 7600 -.035 .63026 4 70 16.98 7640 -.041 .72316 4 80 17.07 7679 -.047 .793 6 4 90 17.15 7719 -.053 .84394 6 0 16.70 7516 .001 .00184 6 10 16.79 7555 -.006 .03074 6 20 16.88 7595 -.013 .13764 6 30 16.96 7634 -.019 .28854 6 40 17.05 7674 -.026 .44244 6 50 17.14 7713 -.032 .57634 6 60 17.23 7753 -.038 .68124 6 70 17.32 7792 -.045 .76014 6 80 17.40 7832 -.050 .819 4 6 90 17.49 7871 -.056 .86192 8 0 17.04 7668 -.003 .01082 8 10 17.13 7707 -.010 .08772 8 20 17.22 7747 -.017 .22262 8 30 17.30 7786 -.023 .37652 8 40 17.39 7826 -.030 .51842 8 50 17.48 7865 -.036 .63432 8 60 17.57 7905 -.042 .72422 8 70 17.65 7944 -.048 .79112 8 80 17.74 7984 -.053 .840 2 8 90 17.83 8023 -.059 .87790 10 0 17.38 7820 -.008 .04980 10 10 17.47 7860 -.014 .16370 10 20 17.55 7899 -.021 .31060 10 30 17.64 7939 -.027 .45750 10 40 17.73 7978 -.033 .58340 10 50 17.82 8018 -.039 .68330 10 60 17.90 8057 -.045 .75920 10 70 17.99 8096 -.051 .81610 10 80 18.08 8136 -.056 .858 0 10 90 18.17 8175 -.062 .89088 12 0 17.72 7972 -.012 .11178 12 10 17.80 8012 -.018 .24768 12 20 17.89 8051 -.024 .39458 12 30 17.98 8091 -.030 .52848 12 40 18.07 8130 -.036 .63838 12 50 18.16 8170 -.042 .72428 12 60 18.24 8209 -.048 .78818 12 70 18.33 8249 -.053 .837 8 12 80 18.42 8288 -.059 .87386 14 0 18.05 8125 -.016 .18776 14 10 18.14 8164 -.022 .33166 14 20 18.23 8204 -.028 .47056 14 30 18.32 8243 -.034 .58946 14 40 18.41 8283 -.040 .68436 14 50 18.49 8322 -.045 .75826 14 60 18.58 8361 -.051 .81316 14 70 18.67 8401 -.056 .855 6 14 80 18.76 8440 -.062 .88684 16 0 18.39 8277 -.019 .26974 16 10 18.48 8316 -.025 .41064 16 20 18.57 8356 -.031 .53754 16 30 18.66 8395 -.037 .64144 16 40 18.74 8435 -.043 .72334 16 50 18.83 8474 -.048 .78624 16 60 18.92 8514 -.054 .83414 16 70 19.01 8553 -.059 .870 4 16 80 19.09 8593 -.064 .89782 18 0 18.73 8429 -.023 .34972 18 10 18.82 8469 -.029 .48162 18 20 18.91 8508 -.034 .59452 18 30 18.99 8547 -.040 .68542 18 40 19.08 8587 -.045 .75632 18 50 19.17 8626 -.051 .81022 18 60 19.26 8666 -.056 .85112 18 70 19.35 8705 -.061 .883 2 18 80 19.43 8745 -.066 .90780 20 0 19.07 8581 -.026 .42470 20 10 19.16 8621 -.032 .54460 20 20 19.25 8660 -.037 .64450 20 30 19.33 8700 -.043 .72340 20 40 19.42 8739 -.048 .78430 20 50 19.51 8779 -.054 .83020 20 60 19.60 8818 -.059 .86610 20 70 19.68 8858 -.064 .894 0 20 80 19.77 8897 -.069 .915______________________________________
Table XVI shows that the desired combination of properties may be achieved with 7 to 11% Nd, 82 to 90 % Ho, and 0 to 10% Gd.
It was further determined experimentally that the desired range of rare earth elements may be increased while achieving the desired combination of properties if three heavy rare earth elements are used in combination with Nd.
TABLE XVII______________________________________Magnetization and Temperature Coefficientof (NdTbGdHo).sub.2 Fe.sub.14 B AlloysW % Tb.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Ho.sub.2 Fe.sub.14 B Z % HoFe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHAW X Y Z MB/FU GAUSS -50-200 R SQUARE______________________________________38 2 0 60 15.11 6798 .002 .00728 2 0 70 15.35 6907 .005 .02218 2 0 80 15.59 7016 .007 .0408 2 0 90 15.83 7124 .009 .05934 2 4 60 15.24 6857 .000 .00024 2 4 70 15.48 6966 .002 .00614 2 4 80 15.72 7075 .005 .0194 2 4 90 15.96 7184 .007 .03530 2 8 60 15.37 6917 -.002 .00420 2 8 70 15.61 7025 .000 .00010 2 8 80 15.85 7134 .002 .0050 2 8 90 16.10 7243 .005 .01626 2 12 60 15.50 6976 -.004 .01816 2 12 70 15.74 7085 -.002 .0036 2 12 80 15.99 7193 .000 .00022 2 16 60 15.63 7035 -.006 .03912 2 16 70 15.88 7144 -.004 .0142 2 16 80 16.12 7253 -.002 .00318 2 20 60 15.77 7095 -.008 .0688 2 20 70 16.01 7203 -.006 .03336 4 0 60 15.49 6972 -.002 .00526 4 0 70 15.74 7081 .000 .00016 4 0 80 15.98 7190 .002 .0056 4 0 90 16.22 7298 .004 .01632 4 4 60 15.63 7031 -.004 .01922 4 4 70 15.87 7140 -.002 .00412 4 4 80 16.11 7249 .000 .0002 4 4 90 16.35 7358 .002 .00428 4 8 60 15.76 7091 -.006 .04218 4 8 70 16.00 7199 -.004 .0168 4 8 80 16.24 7308 -.002 .00324 4 12 60 15.89 7150 -.008 .07114 4 12 70 16.13 7259 -.006 .0354 4 12 80 16.37 7367 -.004 .01320 4 16 60 16.02 7209 -.010 .01416 4 20 60 16.15 7268 -.012 .1416 4 20 70 16.39 7377 -.010 .08834 6 0 60 15.88 7146 -.006 .04424 6 0 70 16.12 7255 -.004 .01714 6 0 80 16.36 7364 -.002 .0034 6 0 90 16.61 7472 .000 .00030 6 4 60 16.01 7205 -.008 .07420 6 4 70 16.25 7314 -.006 .03610 6 4 80 16.50 7423 -.004 .0140 6 4 90 16.74 7532 -.002 .00326 6 8 60 16.14 7265 -.010 .10916 6 8 70 16.39 7373 -.008 .0626 6 8 80 16.63 7482 -.006 .03122 6 12 60 16.28 7324 -.012 .14612 6 12 70 16.52 7433 -.010 .0922 6 12 80 16.76 7541 -.008 .05218 6 16 60 16.41 7383 -.014 .1858 6 16 70 16.65 7492 -.012 .12514 6 20 60 16.54 7442 -.016 .2234 6 20 70 16.78 7551 -.014 .15932 8 0 60 16.27 7320 -.010 .11322 8 0 70 16.51 7429 -.008 .06512 8 0 80 16.75 7538 -.006 .0322 8 0 90 16.99 7646 -.004 .01228 8 4 60 16.40 7379 -.012 .15118 8 4 70 16.64 7488 -.010 .0958 8 4 80 16.88 7597 -.008 .05524 8 8 60 16.53 7439 -.014 .19014 8 8 70 16.77 7547 -.012 .1294 8 8 80 17.01 7656 -.010 .08120 8 12 60 16.66 7498 -.016 .23010 8 12 70 16.90 7607 -.014 .1640 8 12 80 17.15 7715 -.011 .11116 8 16 60 16.79 7557 -.018 .2686 8 16 70 17.04 7666 -.015 .20012 8 20 60 16.93 7616 -.019 .3062 8 20 70 17.17 7725 -.017 .23530 10 0 60 16.65 7494 -.014 .19620 10 0 70 16.89 7603 -.012 .13310 10 0 80 17.14 7711 -.010 .08426 10 4 60 16.78 7553 -.016 .23616 10 4 70 17.03 7662 -.014 .1696 10 4 80 17.27 7771 -.012 .11422 10 8 60 16.92 7613 -.018 .27512 10 8 70 17.16 7721 -.015 .2052 10 8 80 17.40 7830 -.013 .14618 10 12 60 17.05 7672 -.019 .3138 10 12 70 17.29 7781 -.017 .24114 10 16 60 17.18 7731 -.021 .3484 10 16 70 17.42 7840 -.019 .27610 10 20 60 17.31 7790 -.023 .3820 10 20 70 17.55 7899 -.021 .31028 12 0 60 17.04 7668 -.018 .28218 12 0 70 17.28 7777 -.015 .2118 12 0 80 17.52 7885 -.013 .15124 12 4 60 17.17 7727 -.019 .32014 12 4 70 17.41 7836 -.017 .2474 12 4 80 17.65 7945 -.015 .18420 12 8 60 17.30 7786 -.021 .35510 12 8 70 17.55 7895 -.019 .2820 12 8 80 17.79 8004 -.017 .21716 12 12 60 17.44 7846 -.023 .3896 12 12 70 17.68 7955 -.021 .31712 12 16 60 17.57 7905 -.024 .4212 12 16 70 17.81 8014 -.022 .3498 12 20 60 17.70 7964 -.026 .450______________________________________
It was further determined experimentally that the desired range of rare earth elements may be increased while achieving the desired combination of properties if three heavy rare earth elements are used in combination with Nd.
In Table XVII Nd is combined with Tb, Gd and Ho. Specifically, the data show that if Nd varies from 1 to 10%, Tb 0 to 10%, and Gd 0 to 4% with Ho within the range of 80 to 90% the desired combination of properties is achieved.
TABLE XIX______________________________________Magnetization and Temperature Coefficientof (NdErDyHo).sub.2 Fe.sub.14 B AlloysW % Er.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Dy.sub.2 Fe.sub.14 B Z %HoFe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHA RW X Y Z MB/FU GAUSS -50-200 SQUARE______________________________________38 2 0 60 16.73 7528 -.013 .06528 2 0 70 16.54 7444 -.007 .02318 2 0 80 16.36 7361 -.001 .0018 2 0 90 16.17 7278 .005 .01834 2 4 60 16.56 7451 -.011 .04924 2 4 70 16.37 7368 -.005 .01114 2 4 80 16.19 7284 .001 .0014 2 4 90 16.00 7201 .008 .04130 2 8 60 16.39 7374 -.009 .03320 2 8 70 16.20 7291 -.002 .00310 2 8 80 16.02 7208 .004 .0100 2 8 90 15.83 7124 .010 .07726 2 12 60 16.22 7297 -.006 .02016 2 12 70 16.03 7214 -.000 .0006 2 12 80 15.85 7131 .006 .02822 2 16 60 16.05 7220 -.004 .00812 2 16 70 15.86 7137 .002 .0042 2 16 80 15.68 7054 .009 .05918 2 20 60 15.87 7144 -.002 .0018 2 20 70 15.69 7060 .005 .01736 4 0 60 17.03 7663 -.016 .10126 4 0 70 16.84 7580 -.010 .05016 4 0 80 16.66 7497 -.004 .0106 4 0 90 16.47 7414 .002 .00232 4 4 60 16.86 7586 -.014 .08322 4 4 70 16.67 7503 -.008 .03312 4 4 80 16.49 7420 -.002 .0022 4 4 90 16.30 7337 .004 .01428 4 8 60 16.69 7510 -.012 .06418 4 8 70 16.50 7426 -.006 .0198 4 8 80 16.32 7343 .000 .00024 4 12 60 16.52 7433 -.009 .04614 4 12 70 16.33 7350 -.003 .0074 4 12 80 16.15 7266 .003 .00620 4 16 60 16.35 7356 -.007 .02910 4 16 70 16.16 7273 -.001 .0010 4 16 80 15.98 7190 .005 .02416 4 20 60 16.18 7279 -.005 .0156 4 20 70 15.99 7196 .001 .00234 6 0 60 17.33 7799 -.019 .14324 6 0 70 17.15 7715 -.013 .08614 6 0 80 16.96 7632 -.007 .0334 6 0 90 16.78 7549 -.001 .00230 6 4 60 17.16 7722 -.017 .12420 6 4 70 16.97 7639 -.011 .06610 6 4 80 16.79 7556 -.005 .0180 6 4 90 16.61 7472 .001 .00126 6 8 60 16.99 7645 -.015 .10416 6 8 70 16.80 7562 -.009 .0476 6 8 80 16.62 7479 -.003 .0062 6 12 60 16.82 7568 -.012 .08412 6 12 70 16.63 7485 -.007 .0292 6 12 80 16.45 7402 -.001 .00018 6 16 60 16.65 7492 -.010 .0638 6 16 70 16.46 7408 -.004 .01414 6 20 60 16.48 7415 -.008 .0434 6 20 70 16.29 7332 -.002 .00332 8 0 60 17.63 7934 -.021 .19022 8 0 70 17.45 7851 -.016 .13012 8 0 80 17.26 7768 -.010 .0692 8 0 90 17.08 7685 -.005 .01728 8 4 60 17.46 7857 -.019 .17118 8 4 70 17.28 7774 -.014 .1098 8 4 80 17.09 7691 -.008 .04824 8 8 60 17.29 7781 -.017 .15214 8 8 70 17.11 7697 -.012 .0884 8 8 80 16.92 7614 -.006 .02920 8 12 60 17.12 7704 -.015 .13110 8 12 70 16.93 7621 -.010 .0650 8 12 80 16.75 7538 -.004 .01316 8 16 60 16.95 7627 -.013 .1086 8 16 70 16.76 7544 -.007 .04412 8 20 60 16.78 7550 -.011 .0852 8 20 70 16.59 7467 -.005 .02430 10 0 60 17.93 8070 -.024 .24020 10 0 70 17.75 7987 -.019 .18110 10 0 80 17.56 7903 -.013 .1150 10 0 90 17.38 7820 -.008 .04926 10 4 60 17.76 7993 -.022 .22316 10 4 70 17.58 7910 -.017 .1606 10 4 80 17.39 7827 -.011 .09222 10 8 60 17.59 7916 -.020 .20512 10 8 70 17.41 7833 -.015 .1382 10 8 80 17.22 7750 -.009 .06818 10 12 60 17.42 7839 -.018 .1848 10 12 70 17.24 7756 -.013 .11414 10 16 60 17.25 7763 -.016 .1634 10 16 70 17.07 7679 -.010 .08910 10 20 60 17.08 7686 -.014 .1390 10 20 70 16.89 7603 -.008 .06428 12 0 60 18.23 8205 -.026 .29218 12 0 70 18.05 8122 -.021 .2368 12 0 80 17.86 8039 -.016 .17024 12 4 60 18.06 8129 -.025 .27714 12 4 70 17.88 8045 -.019 .2174 12 4 80 17.69 7962 -.014 .14620 12 8 60 17.89 8052 -.023 .26110 12 8 70 17.71 7969 -.017 .1960 12 8 80 17.52 7885 -.012 .12116 12 12 60 17.72 7975 -.021 .2436 12 12 70 17.54 7892 -.015 .17312 12 16 60 17.55 7898 -.019 .2232 12 16 70 17.37 7815 -.013 .1488 12 20 60 17.38 7821 -.017 .201______________________________________
TABLE XXI______________________________________Magnetization and Temperature Coefficientof (NdErTmHo).sub.2 Fe.sub.14 B AlloysW % Er.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Tm.sub.2 Fe.sub.14 B Z %HoFe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHA RW X Y Z MB/FU GAUSS -50-200 SQUARE______________________________________38 2 0 60 16.73 7528 -.013 .06528 2 0 70 16.54 7444 -.007 .02318 2 0 80 16.36 7361 -.001 .0018 2 0 90 16.17 7278 .005 .01834 2 4 60 16.90 7604 -.015 .08824 2 4 70 16.71 7521 -.010 .04114 2 4 80 16.53 7438 -.004 .0074 2 4 90 16.34 7355 .003 .00430 2 8 60 17.07 7681 -.018 .11320 2 8 70 16.88 7598 -.012 .06210 2 8 80 16.70 7515 -.006 .0190 2 8 90 16.51 7431 .000 .00026 2 12 60 17.24 7758 -.020 .13816 2 12 70 17.05 7675 -.014 .0866 2 12 80 16.37 7591 -.008 .03722 2 16 60 17.41 7835 -.022 .16512 2 16 70 17.23 7751 -.016 .1122 2 16 80 17.04 7668 -.011 .05918 2 20 60 17.58 7911 -.024 .1918 2 20 70 17.40 7828 -.019 .13936 4 0 60 17.03 7663 -.016 .10126 4 0 70 16.84 7580 -.010 .05016 4 0 80 16.66 7497 -.004 .0106 4 0 90 16.47 7414 .002 .00232 4 4 60 17.20 7740 -.018 .12722 4 4 70 17.01 7657 -.012 .07312 4 4 80 16.83 7573 -.007 .0262 4 4 90 16.65 7490 -.001 .00028 4 8 60 17.37 7817 -.020 .15418 4 8 70 17.19 7733 -.015 .0998 4 8 80 17.00 7650 -.009 .04624 4 12 60 17.54 7893 -.022 .18114 4 12 70 17.36 7810 -.017 .1274 4 12 80 17.17 7727 -.011 .07020 4 16 60 17.71 7970 -.025 .20910 4 16 70 17.53 7887 -.019 .1550 4 16 80 17.34 7804 -.014 .09716 4 20 60 17.88 8047 -.027 .2366 4 20 70 17.70 7964 -.021 .18434 6 0 60 17.33 7799 -.019 .14324 6 0 70 17.15 7715 -.013 .08614 6 0 80 16.96 7632 -.007 .0334 6 0 90 16.78 7549 -.001 .00230 6 4 60 17.50 7875 -.021 .17120 6 4 70 17.32 7792 -.015 .11410 6 4 80 17.13 7709 -.010 .0560 6 4 90 16.95 7626 -.004 .01126 6 8 60 17.67 7952 -.023 .20016 6 8 70 17.49 7869 -.018 .1436 6 8 80 17.30 7786 -.012 .08322 6 12 60 17.84 8029 -.025 .22812 6 12 70 17.66 7946 -.020 .1732 6 12 80 17.47 7863 -.014 .11318 6 16 60 18.01 8106 -.027 .2558 6 16 70 17.83 8023 -.022 .20314 6 20 60 18.18 8183 -.029 .2824 6 20 70 18.00 8099 -.024 .23332 8 0 60 17.63 7934 -.021 .19022 8 0 70 17.45 7851 -.016 .13012 8 0 80 17.26 7768 -.010 .0692 8 0 90 17.08 7685 -.005 .01728 8 4 60 17.80 8011 -.023 .21918 8 4 70 17.62 7928 -.018 .1618 8 4 80 17.43 7845 -.013 .09824 8 8 60 17.97 8088 -.026 .24814 8 8 70 17.79 8005 -.020 .1934 8 8 80 17.60 7921 -.015 .13020 8 12 60 18.14 8165 -.028 .27610 8 12 70 17.96 8081 -.022 .2240 8 12 80 17.77 7998 -.017 .16316 8 16 60 18.31 8241 -.029 .3036 8 16 70 18.13 8158 -.024 .25412 8 20 60 18.48 8318 -.031 .3292 8 20 70 18.30 8235 -.026 .28430 10 0 60 17.93 8070 -.024 .24020 10 0 70 17.75 7987 -.019 .18110 10 0 80 17.56 7903 -.013 .1150 10 0 90 17.38 7820 -.008 .04926 10 4 60 18.10 8147 -.026 .26916 10 4 70 17.92 8063 - .021 .2146 10 4 80 17.73 7980 -.015 .14922 10 8 60 18.27 8223 -.028 .29812 10 8 70 18.09 8140 -.023 .2462 10 8 80 17.90 8057 -.018 .18418 10 12 60 18.44 8300 -.030 .3258 10 12 70 18.26 8217 -.025 .27714 10 16 60 18.62 8377 -.032 .3514 10 16 70 18.43 8294 -.027 .30710 10 20 60 18.79 8454 -.034 .3760 10 20 70 18.60 8370 -.029 .33528 12 0 60 18.23 8205 -.026 .29218 12 0 70 18.05 8122 -.021 .2368 12 0 80 17.86 8039 -.016 .17024 12 4 60 18.40 8282 -.028 .32114 12 4 79 18.22 8199 -.023 .2694 12 4 80 18.04 8116 -.018 .20720 12 8 60 18.58 8359 -.030 .34810 12 8 70 18.39 8276 -.025 .3010 12 8 80 18.21 8193 -.020 .24316 12 12 60 18.75 8436 -.032 .3746 12 12 70 18.56 8353 -.027 .33112 12 16 60 18.92 8513 -.034 .3992 12 16 70 18.73 8429 -.029 .3598 12 20 60 19.09 8589 -.036 .422______________________________________
Table XXI shows combinations of Nd with Er, Tm and Ho. The data shows that the desired combination of properties may be achieved if Nd varies from 3 to 11%, Tm from 0 to 12%, Er from 0 to 18%, and Ho from 76 to 92%.
TABLE XXIII______________________________________Magnetization and Temperature Coefficientof (NdTbDyHo).sub.2 Fe.sub.14 B AlloysW % Tb.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Dy.sub.2 Fe.sub.14 B Z %Ho.sub.2 Fe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHA RW X Y Z MB/FU GAUSS -50-200 SQUARE______________________________________38 2 0 60 15.11 6798 .002 .00728 2 0 70 15.35 6907 .005 .02218 2 0 80 15.59 7016 .007 .0408 2 0 90 15.83 7124 .009 .05934 2 4 60 15.11 6798 .003 .01224 2 4 70 15.35 6907 .005 .02914 2 4 80 15.59 7016 .008 .0484 2 4 90 15.83 7124 .010 .06830 2 8 60 15.11 6798 .004 .01820 2 8 70 15.35 6907 .006 .03610 2 8 80 15.59 7016 .008 .0570 2 8 90 15.83 7124 .010 .07726 2 12 60 15.11 6798 .005 .02516 2 12 70 15.35 6907 .007 .0456 2 12 80 15.59 7016 .009 .06522 2 16 60 15.11 6798 .006 .03312 2 16 70 15.35 6907 .008 .0532 2 16 80 15.59 7016 .010 .07518 2 20 60 15.11 6798 .006 .0418 2 20 70 15.35 6907 .009 .06336 4 0 60 15.49 6972 -.002 .00526 4 0 70 15.74 7081 .000 .00016 4 0 80 15.98 7190 .002 .0056 4 0 90 16.22 7298 .004 .01632 4 4 60 15.49 6972 -.001 .00222 4 4 70 15.74 7081 .001 .00112 4 4 80 15.98 7190 .003 .0092 4 4 90 16.22 7298 .005 .02128 4 8 60 15.49 6972 -.000 .00018 4 8 70 15.74 7081 .002 .0038 4 8 80 15.98 7190 .004 .01324 4 12 60 15.49 6972 .000 .00014 4 12 70 15.74 7081 .003 .0064 4 12 80 15.98 7190 .005 .01820 4 16 60 15.49 6972 .001 .00110 4 16 70 15.74 7081 .003 .0100 4 16 80 15.98 7190 .005 .02416 4 20 60 15.49 6972 .002 .0046 4 20 70 15.74 7081 .004 .01534 6 0 60 15.88 7146 -.006 .04424 6 0 70 16.12 7255 -.004 .01714 6 0 80 16.36 7364 -.002 .0034 6 0 90 16.61 7472 .000 .00030 6 4 60 15.88 7146 -.005 .03420 6 4 70 16.12 7255 -.003 .01110 6 4 80 16.36 7364 -.001 .0010 6 4 90 16.61 7472 .001 .00126 6 8 60 15.88 7146 -.005 .02516 6 8 70 16.12 7255 -.003 .0066 6 8 80 16.36 7364 -.000 .00022 6 12 60 15.88 7146 -.004 .01712 6 12 70 16.12 7255 -.002 .0032 6 12 80 16.36 7364 .000 .00018 6 16 60 15.88 7146 -.003 .0118 6 16 70 16.12 7255 -.001 .00114 6 20 60 15.88 7146 -.002 .0064 6 20 70 16.12 7255 -.000 .00032 8 0 60 16.27 7320 -.000 .11322 8 0 70 16.51 7429 -.008 .06512 8 0 80 16.75 7538 -.006 .0322 8 0 90 16.99 7646 -.004 .01228 8 4 60 16.27 7320 -.009 .09718 8 4 70 16.51 7429 -.007 .0538 8 4 80 16.75 7358 -.005 .02524 8 8 60 16.27 7320 -.009 .08214 8 8 70 16.51 7429 -.007 .0434 8 8 80 16.75 7538 -.004 .01820 8 12 60 16.27 7320 -.008 .06810 8 12 70 16.51 7429 -.006 .0330 8 12 80 16.75 7538 -.004 .01316 8 16 60 16.27 7320 -.007 .0566 8 16 70 16.51 7429 -.005 .02512 8 20 60 16.27 7320 -.007 .0442 8 20 70 16.51 7429 -.004 .01830 10 0 60 16.65 7494 -.014 .19620 10 0 70 16.89 7603 -.012 .13310 10 0 80 17.14 7711 -.010 .0840 10 0 90 17.38 7820 -.008 .04926 10 4 60 16.65 7494 -.013 .17716 10 4 70 16.89 7603 -.011 .1176 10 4 80 17.14 7711 -.009 .07222 10 8 60 16.65 7494 -.013 .15812 10 8 70 16.89 7603 -.010 .1022 10 8 80 17.14 7711 - .008 .06118 10 12 60 16.65 7494 -.012 .1408 10 12 70 16.89 7603 -.010 .08814 10 16 60 16.65 7494 -.011 .1234 10 16 70 16.89 7603 -.009 .07510 10 20 60 16.65 7494 -.010 .1080 10 20 70 16.89 7603 -.008 .06428 12 0 60 17.04 7668 -.018 .28218 12 0 70 17.28 7777 -.015 .2118 12 0 80 17.52 7885 -.013 .15124 12 4 60 17.04 7668 -.017 .26114 12 4 70 17.28 7777 -.015 .1924 12 4 80 17.52 7885 -.013 .13520 12 8 60 17.04 7668 -.016 .24110 12 8 70 17.28 7777 -.014 .1750 12 8 80 17.52 7885 -.012 .12116 12 12 60 17.04 7668 -.015 .2216 12 12 70 17.28 7777 -.013 .15812 12 16 60 17.04 7668 -.015 .2022 12 16 70 17.28 7777 -.013 .1428 12 20 60 17.04 7668 -.014 .184______________________________________
Table XXIII shows alloys wherein the Nd is combined with Tb, Dy and Ho. The desired combination of properties is achieved if Nd varies from 9 to 11, Dy varies from 0 to 15, Tb from 0 to 12 and Ho is within the range from 75 to 88%.
TABLE XXV______________________________________Magnetization and Temperature Coefficientof (NdGdDyHo).sub.2 Fe.sub.14 B AlloysW % Gd.sub.2 Fe.sub.14 B+ X % Nd.sub.2 Fe.sub.14 B+ Y %Dy.sub.2 Fe.sub.14 B+ Z %HoFe.sub.14 BCOMPOSITION M(25C) M(25C) ALPHA RW X Y Z MB/FU GAUSS -50-200 SQUARE______________________________________38 2 0 60 16.36 7361 -.017 .23028 2 0 70 16.27 7322 -.010 .08518 2 0 80 16.18 7282 -.003 .0068 2 0 90 16.10 7243 .005 .01634 2 4 60 16.23 7302 -.014 .17424 2 4 70 16.14 7263 -.007 .04614 2 4 80 16.05 7223 .000 .0004 2 4 90 15.96 7184 .007 .04230 2 8 60 16.10 7243 -.012 .12120 2 8 70 16.01 7203 -.004 .01810 2 8 80 15.92 7164 .003 .0070 2 8 90 15.83 7124 .010 .07726 2 12 60 15.96 7183 -.009 .07416 2 12 70 15.88 7144 -.002 .0026 2 12 80 15.79 7105 .006 .02722 2 16 60 15.83 7124 -.006 .03612 2 16 70 15.74 7085 .001 .0012 2 16 80 15.66 7045 .009 .06018 2 20 60 15.70 7065 -.003 .0118 2 20 70 15.61 7025 .004 .01536 4 0 60 16.68 7506 -.019 .29226 4 0 70 16.59 7466 -.013 .13716 4 0 80 16.50 7427 -.006 .0296 4 0 90 16.42 7387 .001 .00132 4 4 60 16.55 7446 -.017 .23622 4 4 70 16.46 7407 -.010 .09012 4 4 80 16.37 7367 -.003 .0082 4 4 90 16.28 7328 .004 .01328 4 8 60 16.42 7387 -.014 .18018 4 8 70 16.33 7348 -.007 .0508 4 8 80 16.24 7308 -.000 .00024 4 12 60 16.28 7328 -.012 .12714 4 12 70 16.20 7288 -.005 .0214 4 12 80 16.11 7249 .002 .00520 4 16 60 16.15 7268 -.009 .07910 4 16 70 16.06 7229 -.002 .0040 4 16 80 15.98 7190 .005 .02416 4 20 60 16.02 7209 -.006 .0406 4 20 70 15.93 7170 .001 .00134 6 0 60 17.00 7650 -.022 .35124 6 0 70 16.91 7611 -.015 .19414 6 0 80 16.82 7571 -.009 .0654 6 0 90 16.74 7532 -.002 .00330 6 4 60 16.87 7591 -.020 .29720 6 4 70 16.78 7551 -.013 .14310 6 4 80 16.69 7512 -.006 .0320 6 4 90 16.61 7472 .001 .00126 6 8 60 16.74 7531 -.017 .24116 6 8 70 16.65 7492 -.010 .0956 6 8 80 16.56 7452 -.003 .01022 6 12 60 16.60 7472 -.015 .18612 6 12 70 16.52 7433 -.008 .0552 6 12 80 16.43 7393 -.001 .00018 6 16 60 16.47 7413 -.012 .1328 6 16 70 16.39 7373 -.005 .02414 6 20 60 16.34 7354 -.009 .0844 6 20 70 16.25 7314 -.002 .00532 8 0 60 17.32 7794 -.024 .40622 8 0 70 17.23 7755 -.018 .25312 8 0 80 17.15 7715 -.011 .1112 8 0 90 17.06 7676 -.005 .01928 8 4 60 17.19 7735 -.022 .35518 8 4 70 17.10 7696 -.016 .2008 8 4 80 17.01 7656 -.009 .06924 8 8 60 17.06 7676 -.020 .30214 8 8 70 16.97 7636 -.013 .1484 8 8 80 16.88 7597 -.066 .03620 8 12 60 16.93 7616 -.017 .24710 8 12 70 16.84 7577 -.011 .1000 8 12 80 16.75 7538 -.004 .01316 8 16 60 16.79 7557 -.015 .1916 8 16 70 16.71 7518 -.008 .05912 8 20 60 16.66 7498 -.012 .1382 8 20 70 16.57 7458 -.005 .02730 10 0 60 17.64 7939 -.027 .45720 10 0 70 17.55 7899 -.021 .31010 10 0 80 17.47 7860 -.014 .1630 10 0 90 17.38 7820 -.008 .04926 10 4 60 17.51 7879 -.025 .41016 10 4 70 17.42 7840 -.018 .2586 10 4 80 17.33 7800 -.012 .11622 10 8 60 17.38 7820 -.022 .36012 10 8 70 17.29 7781 -.016 .2052 10 8 80 17.20 7741 -.009 .07418 10 12 60 17.25 7761 -.020 .3078 10 12 70 17.16 7721 -.013 .15314 10 16 60 17.11 7701 -.017 .2524 10 16 70 17.03 7662 -.011 .10510 10 20 60 16.98 7642 -.015 .1970 10 20 70 16.89 7603 -.008 .06428 12 0 60 17.96 8083 -.029 .50318 12 0 70 17.87 8043 -.023 .3658 12 0 80 17.79 8004 -.017 .21724 12 4 60 17.83 8024 -.277 .46014 12 4 70 17.74 7984 -.021 .3154 12 4 80 17.65 7945 -.014 .16820 12 8 60 17.70 7964 -.025 .41410 12 8 70 17.61 7925 -.018 .2630 12 8 80 17.52 7885 -.012 .12116 12 12 60 17.57 7905 -.022 .3646 12 12 70 17.48 7866 -.016 .21012 12 16 60 17.44 7846 -.020 .3122 12 16 70 17.35 7806 -0.14 .1598 12 20 60 17.30 7786 -.018 .257______________________________________
Table XXV shows alloy compositions of Nd with Gd, Dy and Ho if Nd varies from 8 to 12%, Dy from 0 to 15%, Gd from 0 to 8%, and Ho is within the range from 72 to 88%, the alloys exhibit the desired combination of properties.
Claims
  • 1. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B, wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 3 to 11 and balance Ho, said alloy exhibiting in combination .alpha. less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 2. The alloy of claim 1 wherein R includes up to 10% Gd.
  • 3. The alloy of claim 1 wherein R includes up to 15% Tb.
  • 4. The alloy of claim 1 wherein R includes up to 10% Dy.
  • 5. The alloy of claim 1 wherein R includes up to 18% Er.
  • 6. The alloy of claim 1 wherein R includes up to 12% Tm.
  • 7. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B, wherein R is a combination of rare earth elements consisitng essentially of, in atomic percent, Nd 3 to 11, at least one optional heavy rare earth element selected from the group consisting of Gd up to 10, Tb up to 15, Dy up to 16, Er up to 18 and Tm up to 12 and balance Ho, said alloy exhibiting in combination .alpha. less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 8. The alloy of claim 1, or claim 2, or claim 3, or claim 4, or claim 5, or claim 6 or claim 7 wherein Ho is 75 to 92%.
  • 9. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B, wherein R is a combination of rare elements consisting essentially of, in atomic percent, Nd 4 to 10, Tm 0 to 13 and Ho 83 to 96, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 10. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 5 to 11, Er 0 to 18, Ho 76 to 94, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250 .degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 11. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 7 to 11, Tb 9 to 12 and Ho 78 to 90, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 12. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, atomic percent Nd 7 to 11, Dy 0 to 15 and Ho 75 to 90, said alloy exhibiting in combinatio alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 13. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of a rare earth elements consisting essentially of, in atomic percent, Nd 7 to 11, Gd 0 to 10, and Ho 82 to 92, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 14. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 7 to 11, Gd 0 to 10, and Ho 82 to 92, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 15. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 6 to 10, Dy 0 to 8, Er 0 to 14, Ho 76 to 96, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 16. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 3 to 11, Tm 0 to 12, Er 0 to 18, and Ho 76 to 92, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 17. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 9 to 11, Dy 9 to 15, Tb 0 to 12, and Ho 75 to 88, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
  • 18. A permanent magnet alloy consisting essentially of R.sub.2 Fe.sub.14 B wherein R is a combination of rare earth elements consisting essentially of, in atomic percent, Nd 8 to 12, Dy 0 to 15, Gd 0 to 8, and Ho 72 to 88, said alloy exhibiting in combination alpha less than -0.01% per .degree.C. over the temperature range of -50.degree. C. to 250.degree. C. and M.sub.s greater than 7500 Gauss at room temperature.
Parent Case Info

This application is a continuation of application Ser. No. 010,738 , filed February 4, 1987, abandoned.

US Referenced Citations (1)
Number Name Date Kind
4533408 Koon Aug 1985
Foreign Referenced Citations (4)
Number Date Country
0101552 Feb 1984 EPX
0106948 May 1984 EPX
0108474 May 1984 EPX
0126179 Nov 1984 EPX
Continuations (1)
Number Date Country
Parent 10738 Feb 1987