This application claims priority to European Patent Application No. EP20207537 filed on Nov. 13, 2020 incorporated herein by reference in its entirety.
The present disclosure relates to a perovskite precursor composition, a method of preparing perovskite film, a perovskite film and a perovskite solar cell, in more detail, a perovskite precursor solution for preparing a humid air-stable perovskite layer and the method of deposition of a perovskite layer, and to solar cells obtained using such a perovskite layer.
Perovskite solar cells (PSCs) have experienced considerable recent development, with major improvements in power conversion efficiency (PCE). In particular, hybrid organic-inorganic perovskite light harvesters belong to an interesting class of materials which exhibit a suitable band gap, high absorption coefficients, long charge mobility and long diffusion length, combined with easy and low-cost processing methodologies. Organic-inorganic lead halide perovskite solar cells (PSCs) have been attracting increasing attention in the past few years due to the amazing rise in their power conversion efficiency (PCE) from 3.8% [Ref.1] to 25.2% [Ref.2] However, the stability of the PSC devices under working conditions still remains challenging. There were numerous approaches that have been applied to tackle this issue up to now:
(1) doping 2-D perovskites into 3-D perovskite. For example, by treatment of the perovskite with phenyl ethyl-ammonium iodide (PEAI), the PEAI can reach the 3D perovskite surface, reacting with excess PbI2, leading to in situ growth of PEA2PbI4 as a 2D perovskite interlayer. The thus formed 2D/3D hybrid structure at the interface can significantly improve the performance of the perovskite solar cell [Refs. 4, 5];
(2) tuning the composition of perovskite [Ref. 6] or applying methylammonium iodide free precursors [Ref. 7]. In addition, compositional substitution within the 3-D perovskite network can strengthen the hydrogen bonding within the 3D-perovskite structure, optimize the tilting of the octahedral structure of PbI6 [Ref. 8] and improve the overall stability [Ref. 9];
(3) adopting passivation techniques [Ref. 10]. Passivation by fumigation [Ref. 11] or through laser irradiation [Ref. 12] of the perovskite film can improve the uniformity of the film and repair the defects in the film for increased light harvesting. Passivation of the perovskite film with volatile organic Lewis bases such as pyridine [Ref. 21] or gaseous methylamine [Ref. 22] have been reported.
In addition to the above mentioned approaches, adding some additives in the perovskite precursor can improve the efficiency and stability for PSCs:
(a) For instance, incorporation of large cations into the perovskite structure. Guanidinium has been utilized as an effective large cation additive to stabilize the PSCs with high PCE, enhancing the stability owing to formation of additional hydrogen bonds [Ref. 13];
(b) Doping perovskite with imidazolium-based ionic liquids (ILs) containing fluorinated chains [Ref. 14] or allyl groups [Ref. 15] in the cation can improve the quality of the perovskite film, increase the hydrophobicity of the film surface protecting the hydrolysis when exposed to moisture and thus increase the stability;
(c) Doping perovskite with self-polymerizable imidazolium-based ionic liquids [Ref. 16] can effectively add a protection layer to the perovskite film, allowing the perovskite solar cells to be manufactured in air.
Ionic liquids (ILs) are non-volatile salts with high thermal stability and electrochemical stability due to their strong electrostatic forces between their molecular ions. ILs have been widely used as additives [Ref. 17].
With a view notably to providing improved stability for perovskite solar cells, in particular for long-term use and/or in the presence of air, the present disclosure has been achieved.
In a first aspect, the present disclosure thus relates to a perovskite precursor composition comprising:
wherein, in the formula (1):
R1 is C1-C4 alkyl; and
R2 is —(CH2)n— wherein n is 2 to 6; and in the formula (2):
R2a is —(CH2)a— wherein a is 1 to 6; and
R2b is —(CH2)b— wherein b is 1 to 6.
R1 may be C1-C3 alkyl. R1 may be methyl. n may be 2 to 4. n may be 2 or 3. a may be 2 to 4. a may be 3. b may be 2 to 4. b may be 3.
Here, in the above-mentioned perovskite precursor composition, the anionic counterion for the cationic imidazole derivative of the formula (1) or the formula (2) may be a halide anion which is one or more among Cl−, Br− and I−. The halide anion may be Cl−.
In a second aspect, the present disclosure relates to a perovskite precursor composition comprising:
wherein, in the formula (1):
R1 is C1-C6 alkyl; and
R2 is —(CH2)n— wherein n is 1; and
wherein anionic counterion for the cationic imidazole derivative of the formula (1) is chloride (Cl−).
R1 may be C1-C3 alkyl. R1 may be methyl.
In preferred specific examples, the salt of the cationic imidazole derivative is one of the following:
Salts of ionic liquid imidazolium species with many types of N-borne side chain are widely used notably as solvents in catalytic reactions, and in electrochemical applications. They are prepared and available not only with halide (such as chloride, bromide and iodide) anion counterions, but also with nitrate or acetate, dicyanamide, or fluorinated anions such as BF4−, PF6−, trifluoromethane sulfonate, bis(trifluoromethyl sulfonyl)imide etc. The most preferred imidazolium salts [C1CNmim]Cl, [C3CNmim]Cl and [(C3CN)2im]Cl used in the present disclosure are all commercially available, for example from the suppliers Sigma-Aldrich, Alfa Chemistry, ABClabtory Scientific. Methods of synthesis of [C1CNmim]Cl and [C3CNmim]Cl have further been described in Zhao et al., Inorg. Chem. 2004, 43, 6, 2197-2205, and for [(C3CN)2im]Cl in Zhao et al., Chem. Commun., 2004, 2500-2501. As a further example of interest in the present disclosure, [C4CNmim]Cl is commercially available from Chemieliva Pharmaceutical, and its synthesis is described in Zhao et al., Inorg. Chem. 2004, 43, 6, 2197-2205.
In the perovskite precursor composition of the present disclosure, in addition to a salt of a cationic imidazole derivative in which at least one of the two nitrogen atoms in the imidazole ring is linked to a carbon chain bearing a cyano (—C≡N) group, as perovskite precursors, one may use ABX3 materials wherein:
A are organic cations and/or Group 1 metal cations, and the Group 1 metal cations being Cs and/or Rb;
B being at least one metal selected from the group consisting of: Pb, Sn, Bi, Cu, Ag and their mixtures; and
X being halides such as Cl, Br, I and their mixtures.
The organic cations may be at least one selected from the group consisting of: methylammonium (MA), butylammonium (BA), formamidinium (FA) and guanidinium (GUA). B may be Pb.
In a third aspect, the disclosure relates to method of preparing a perovskite film comprising the steps of:
(A) preparation of the perovskite precursor composition of the first aspect or the second aspect;
(B) providing a substrate; and
(C) formation of a perovskite film on the surface of the substrate.
In a fourth aspect, the disclosure relates to a perovskite film prepared by the method of the third aspect.
In a fifth aspect, the disclosure relates to a perovskite solar cell comprising:
(a) a transparent conductive layer;
(c) a perovskite film comprising the perovskite precursor composition of the first aspect or the second aspect; and
(e) an electrode,
optionally further comprising one or more of: (b) an electron transport layer; (b′) an electron-blocking layer; (d) a hole transport layer; and (d′) a hole-blocking layer.
Features, advantages, and technical and industrial significance of exemplary embodiments of the disclosure will be described below with reference to the accompanying drawings, in which like signs denote like elements, and wherein:
In the present disclosure, functionalized ILs containing CN functional groups in the imidazolium cation were used as additives to add to a perovskite layer. Without wishing to be bound by any particular theory, it is believed that the pre-installed CN group in the cation of the ILs can function as a Lewis base for coordination to the Pb(II) center in the formation of the 3-D perovskite structure. It is further believed that the coordination of the CN group to the Pb(II) will compete with the I/Br anion in the formation of the 3-D perovskite film, slowing the nucleation process, resulting in formation of film with increased uniformity and less defects. The Cl anion can be encapsulated in the 3-D network for strengthening of the hydrogen bonding and optimizing the structure tilting for increased stability. Different ILs with different lengths of the alkyl chains have been studied.
Based on the results of SEM, XRD, UV and PL, the present inventors concluded that as regards the influence of IL on photovoltaic performance, the ILs studied with cyano (CN) groups, compared with the ILs without CN groups, probably on account of a role of the CN group for coordination to the Pb(II) center in the formation of the 3-D perovskite structure, result in better film quality. Further, the Cl anion that can be encapsulated inside the 3-D perovskite structure is believed to form much stronger hydrogen bonds with protons in the methylammonium(MA)/formamidinium(FA) cation, locking the protons in rigid positions and preventing the phase transformation for increased stability. As a result, PSCs modified with CN functionalized ILs show not only improved open circuit voltage and fill factor of PSCs, but also reduced the risk of exposure to the atmosphere, leading to significant enhancement of device stability.
<Organic-Inorganic Hybrid Perovskites>
The term “organic-inorganic hybrid perovskites”, hereinafter also referred to as “hybrid perovskites”, as used herein, refers to ABX3 materials with A being organic cation groups such as methylammonium (MA), butylammonium (BA), formamidinium (FA), or the alkali metals Cs or Rb, and their mixtures; B being a metal such as Pb, Sn, Bi, Cu, Ag and their mixtures; and X being halides such as Cl, Br, I and their mixtures. More generally, a perovskite can be represented by the formula A1wA2xA3(1-w-x)B1yB2(1-y)X1zX2(3-z), wherein A1, A2 and A3 are the same or different organic cation groups such as methylammonium (MA), butylammonium (BA), formamidinium (FA), or the alkali metal cations Cs+ or Rb+; w and x are both 0 or more and 1 or less; B1 and B2 are the same or different metals such as Pb, Sn, Bi, Cu or Ag; y is 0 or more and 1 or less; X1 and X2 are the same or different halides such as Cl, Br or I; and z is 0 or more and 1 or less. Preferred organic-inorganic hybrid perovskites in the present disclosure have lead (Pb) as the majority metal B in molar terms, and most preferably lead (Pb) is the sole metal B, so that the perovskite is of the form A1wA2xA3(1-w-x)PbX1zX2(3-z). More preferably X1 and X2 are Br and I.
Layered perovskites contain additional bulkier molecules such as phenethylamine (PEA) or phenethylammonium, hexylammonium (HA) and longer chain ammonium species, which confine different perovskite domains into different repeating units. Specific examples given here comprise inorganic metal-halide multi-layered perovskites. These examples are non-limiting.
In an appropriate perovskite (precursor) material for the present disclosure, a combination of caesium (Cs) metal cation and organic cations such as formamidinium (FA) and/or methylammonium (MA) may be used. A particularly preferred cation system is the triple cation system Cs-FA-MA. The anions used as perovskite (precursor) material for the present disclosure may appropriately contain a mixture of iodide (I) and bromide (Br) anions. A particularly preferred peroxide precursor system is (Cs0.08FA0.8MA0.12)Pb(I0.88Br0.12)3.
Perovskite Precursors
The choice of perovskite precursors may determine the material's optoelectronic properties, such as band-gap energy, charge-transport, and/or binding energy, which affect the performance of the final device.
Perovskite precursors used in the composition of the present disclosure are not particularly limited.
In one embodiment, the precursors are:
The at least one organic halide compound in the (A) precursor can be, for example, at least one selected from the group consisting of methylammonium (MA), formamidinium (FA), phenylethylammonium (PEA) and guanidinium (GUA). Particular examples of metal halide in the (B) precursors are PbCl2, PbBr2, PbI2. It may be noted that metal carboxylates, particularly lead (Pb) carboxylates such as Pb (CH3COO)2 may be used instead of metal halides.
Perovskite Coating Solution
Ionic liquids (ILs) have no vapor pressure and cannot evaporate. In this respect, ILs are not a traditional solvent that can be removed after spin-coating and aging at 100° C.—ILs will stay. Furthermore, ionic liquids may form eutectic liquids (mixtures of several ion pairs, such as cations MA; FA, imidazolium cation, anions: I−, Cl−) with components from the perovskite solution. The nucleation process from a eutectic liquid is slower than in pure DMSO or DMF.
In addition to ionic liquids (ILs) of the present disclosure, a solvent can appropriately be added to the mixture of perovskite precursor components and can be, for example, dimethylsulfoxide (DMSO), dimethylformamide (DMF), a combination of DMSO:DMF, gamma-butyrolactone (GBL), N-methyl-2-pyrrolidone (NMP), dimethylacetamide (DMAc) and acetonitrile (ACN).
A preferred solvent is, for example, DMSO or DMF or gamma butyrolactone.
An appropriate concentration of the perovskite precursors, in terms of Pb, is from 0.6 to 1.4 M (mole per litre). The amount of functionalized ILs as dopants in the perovskite precursor composition is appropriately between 0.5 and 1.0 mol % of functionalized IL dopants with respect to the amount of perovskite metal atom other than Cs or Rb, for example with respect to the amount of Pb in the most common case of a lead-based perovskite. An exemplary amount of functionalized IL dopants with respect to the amount of perovskite metal atom such as Pb is 0.75 mol %.
<Method of Preparing a Perovskite Film>
In a method of preparing a perovskite film according to the present disclosure, the method comprises the steps of:
(A) preparation of a perovskite precursor composition according to the disclosure;
(B) providing a substrate;
(C) formation of a perovskite film on the surface of the substrate.
The perovskite film can be formed, for example, by spin-coating, printing, slot-die coating and meniscus coating. The slot-die coating method is preferable for large-area deposition.
In the above-mentioned method of preparing a perovskite film according to the present disclosure, the substrates may appropriately be flexible or rigid conductive substrates.
In one aspect, the present disclosure further relates to a perovskite film or layer prepared by the above-mentioned method.
<Perovskite Solar Cell>
A perovskite solar cell, such as may be prepared using the perovskite film or layer of the present disclosure as set out above, may comprise the following layers:
(a) a transparent conducting layer;
(c) a perovskite layer;
(e) an electrode layer
Preferably, the perovskite solar cell can further comprise one or more of: (b) an electron transport layer; (b′) an electron-blocking layer; (d) a hole transport layer; and (d′) a hole-blocking layer.
The presence of at least one of these layers leads to a higher device efficiency.
The above-mentioned three layers can be disposed in the order of appearance above. Further, an electron transport layer can be situated between the transparent conducting layer and the perovskite layer, and a hole transport layer can be situated between the perovskite layer and an electrode layer.
In one embodiment, the perovskite solar cell may have a conventional n-i-p structure comprising a transparent conducting layer, an electron transport later, a perovskite layer, a hole transport layer and an electrode layer in this order.
In another embodiment, the perovskite solar cell may have an inverted p-i-n structure comprising a transparent conducting layer, a hole transport later, a perovskite layer, an electron transport layer and an electrode layer in this order.
In still another embodiment, the perovskite solar cell can further comprise mesoporous scaffold, in the perovskite layer.
Generally, in the so-called p-i-n or n-i-p structures, the electron (n) or hole (p) blocking layers are situated in the bottom and top of the perovskite layer (i), in a sandwich configuration, with the perovskite layer (i) being in the middle. A mesoporous TiO2 layer is usually an electron transport layer (in the n side), but it could also be a hole transport layer (p side).
<(a) Transparent Conductive Layer>
A transparent conductive layer is not particularly limited and can comprise or consist of, for example, a fluorine-doped tin oxide (FTO), indium tin oxide (ITO), doped zinc oxide, carbon nanotube networks or graphene, and preferably an FTO.
<(b) Electron Transport Layer (ETL)>
The electron transport layer is not particularly limited and can comprise or consist of, for example, TiO2, SnO2, Nb-doped SnO2, Sb-doped SnO2, C60 and C60 derivatives, bathocuproine (BCP), a combination of C60/BCP, and a combination of TiO2/SnO2 bilayer.
Among these materials, a combination of TiO2/SnO2 layer is preferred for n-i-p configuration, and a combination of C60/BCP is preferred for p-i-n configuration.
<(b′) Hole-Blocking Layer>
An optional hole blocking layer can be, for example, 2,9-dimethyl-4,7-diphenylphenanthroline (BCP), TiO2, ZnO.
When the electron transport layer (ETL) material is TiO2, TiO2 behaves as both electron transport and hole blocking, given that the layer is compact. However if the ETL material is mesoporous, the perovskite solution infiltrates and touches the FTO electrode (which will produce losses). In order to avoid the direct contact between perovskite and FTO when the ETL material is mesoporous, typically a compact layer of TiO2 may be advantageously incorporated between FTO and mesoporous-TiO2 (blocking layer).
<(d′) Electron-Blocking Layer>
An optional electron blocking layer can be, for example, AlGaN.
<(d) Hole Transport Layer>
The hole transport layer is not particularly limited, and can comprise of consist of, for example, spiro-OMeTAD (2,2′,7,7′-tetrakis-(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene), pyrene-based materials (such as PY-1, PY-2, PY-3), Truxene-core based materials, phenothiazine-based materials, acridine-, thiophene-, biphenyl-, bithiophene-, tetrathiophene-, difluorobenzene and phenyl-based materials, triazine-based materials, benzotrithiophen- and squaraine-based materials, fluorene- and spiro-fluorene-based materials and carbazole-based materials, phthalocyanines, carbon, metal complexes, CuNCS, NiOx, and preferably spiro-OMeTAD.
<(e) Electrode Layer>
The electrode layer is not particularly limited and can comprise or consist of, for example, Au, C, Ag, Cu or Al. Among these, Au is preferred in the laboratory scale since it is very efficient but expensive. For industrial applications, carbon and Cu are preferred.
<Method of Preparing a Solar Cell Device Comprising a Perovskite Film>
The present disclosure also relates to a method of preparing a solar cell device comprising a perovskite film. The method of the present disclosure comprises the following steps:
1) preparing a transparent conducting oxide layer;
2) optionally preparing and depositing an electron transport layer;
3) optionally preparing and depositing a hole-blocking layer;
4) preparing and depositing a perovskite layer;
5) optionally preparing and depositing an electron-blocking layer
6) optionally preparing and depositing a hole transport layer; and
7) preparing and depositing an electrode layer
<(1) Preparing a Conducting Oxide Layer>
A conductive oxide layer can for example be prepared on an FTO glass. In such a method, an etched FTO glass is cleaned and then its surface is treated, and can be later treated for example by spin-coating a TiO2 layer which acts as electron transport layer.
A person skilled in the art knows applying an appropriate preparation method for a given conducting oxide layer material.
<(2) Optionally Preparing and Depositing an Electron Transport Layer (ETL)>
An optional electron transport layer can for example be prepared with TiO2, for example by spin-coating followed by annealing.
When the ETL material is TiO2, TiO2 behaves as both electron transport and hole blocking material, given that the layer is compact. However if the ETL material is mesoporous, the perovskite solution may infiltrate and touch the FTO electrode (which will produce losses). In order to avoid the direct contact between perovskite and FTO when the ETL material is mesoporous, commonly a compact layer of TiO2 is incorporated between the FTO and mesoporous-TiO2 (blocking layer). Therefore optionally, a TiO2-blocking layer can be deposited before between the conductive layer and an electron transport layer.
<(3) Optionally Preparing and Depositing a Hole-Blocking Layer>
A person skilled in the art knows applying an appropriate preparation method for a hole-blocking material.
If the hole-blocking layer material is an organic material, like BCP, it can be prepared from solution (spin coating from organic solvent like chlorobenzene) or via thermal sublimation.
If the hole-blocking layer material is an inorganic material, like TiO2, it can be prepared by spin-coating a precursor solution and then thermal annealing. For example, a diluted titanium diisopropoxide bis(acetylacetonate) solution (Sigma-Aldrich) in ethanol can be applied by spray pyrolysis at 450 C.
A person skilled in the art knows applying an appropriate preparation method for a given electron transport layer material.
<(4) Preparing and Depositing a Perovskite Layer>
A perovskite solar layer can be deposited by the method as disclosed above, using a perovskite precursor solution as disclosed above. This step can be conducted in ambient air (the temperature was around 25° C. and humidity was about 30-50% RH).
A person skilled in the art knows applying an appropriate preparation method for a given perovskite layer material.
<(5) Optionally Preparing and Depositing an Electron-Blocking Layer>
A person skilled in the art knows applying an appropriate preparation method for an electron-blocking material.
If the electron-blocking layer material is an organic material it could be added from solution (spin coating), like for Spiro-OMeTAD, PEDOT:PSS, PolyTPD, PTAA.
If the electron-blocking layer material is NiOx, it can be prepared from spin-coating a precursor solution and then thermal annealing.
<(6) Optionally Preparing and Depositing a Hole Transport Layer (HTL)>
An optional hole transport layer can then be formed for example by spin-coating a solution comprising Spiro-OMeTAD. This step can be conducted in ambient air (the temperature was around 25° C. and humidity was about 30-50% RH).
A person skilled in the art knows applying an appropriate preparation method for a given hole transport layer material.
<(7) Preparing and Depositing an Electrode Layer>
An electrode layer can be prepared for example by evaporating gold (Au).
A person skilled in the art knows applying an appropriate preparation method for an electrode layer material.
In the method of preparing a solar cell according to the disclosure, the method may appropriately be carried out under a relative humidity of 10% or more and 60% or less, preferably 20% or more and 50% or less, more preferably 25% or more and 45% or less, and 3 most preferably 0% or more and 40% or less.
In the method of preparing a solar cell according to the disclosure, in some embodiments, at least one of the steps (1) and (3) may be carried out under an ambient temperature of 15° C. or more and 30° C. or less, preferably 15° C. or more and 25° C. or less and most preferably 20° C. or more and 25° C. or less. However, the temperature of the steps may vary. The perovskite-containing layer may be appropriately deposited in ambient temperature but then annealed at a temperature of around 100° C. The steps (1) and (3) can be or not, depending on the material, carried out at ambient temperature, but for example the common TiO2 electron transport material is deposited in ambient temperature and then annealed at high temperature 500° C. There are alternatives, such as SnO2 deposited at 150° C.
The present disclosure is detailed below with examples, but the scope of the present disclosure is not to be considered to be limited to the following examples.
Perovskite Precursor Solutions
The precursor solution: The precursor solution (without IL) was prepared by dissolving PbI2 (1.190 M, TCI), PbBr2 (0.155 M, TCI), CsI (0.105 M, TCI), FAI (1.040 M, Dyesol) and MABr (0.155 M, Dyesol) in a mixed solvent of DMF:DMSO=4:1 (volume ratio). The precursor solutions with ILs were prepared by mixing PbI2 (1.190 M, TCI), PbBr2 (0.155 M, TCI), CsI (0.105 M, TCI), FAI (1.040 M, Dyesol) and MABr (0.155 M, Dyesol) by adding the same molar amount of ILs (0.75 mol %), and then mixed in DMF:DMSO=4:1 (volume ratio).
Device Fabrication
<Preparing a Transparent Conductive Layer>
Fluorine-doped tin oxide (FTO) coated glass substrates (Nippon Sheet Glass, TEC8) were cleaned with detergent, deionized water, acetone and isopropanol in an ultrasonic bath for 10 min respectively. The FTO substrates were treated with an UV/Ozone cleaner for 15 min before being used.
<Preparing a TiO2-Blocking Layer>
TiO2 compact layers (cp-TiO2) were deposited onto the clean FTO substrates by spray pyrolysis using a titanium diisopropoxide bis-(acetylacetonate) solution (75% in 2-propanol, Sigma-Aldrich), which was diluted in 2-propanol (99.8%, Acros Organics) at 1:15 volume ratio on 450° C. and followed by in situ annealing for 30 min.
<Preparing and Depositing Mesoporous Scaffold Layer and Electron Transport Layer>
The mesoporous TiO2 (mp-TiO2) solution, was composed of 1 g TiO2 paste (30NR-D, Greatcell Solar) diluted in 10 ml anhydrous ethanol solution, then the meso-TiO2 layer was deposited onto the FTO/cp-TiO2 substrate by one-step spin-coating process at 4500 rpm for 20 s. After annealing at 125° C. for 30 min, the mp-TiO2 films were gradually heated to 500° C. in air, and then they were baked at the same temperature for 20 min to remove organic components.
SnO2 layers were prepared by spin-coating 0.1 M SnCl4 aqueous (99%, Acros Organics) solution by one-step process at 3000 rpm for 20 s, then the substrates were transferred onto a hotplate and heated between 150° C. and 190° C. for 1 h. Before using, the FTO/cp-TiO2/mp-TiO2/SnO2 substrates were treated with UV/Ozone for 30 min.
<Preparing and Depositing a Perovskite Layer>
The different kinds of perovskite precursors were spin-coated on the top of FTO/cp-TiO2/mp-TiO2/SnO2 substrates at 1000 r.p.m. for 10 s and continuously at 5000 rpm for 30 s. During the second step, 100 μL of chlorobenzene was dropped on the films at 15 s. Then, the films were annealed on the hotplate at 100° C. for 1 h. For all PSC devices, the perovskite absorber layer was thus prepared via a one-step spin-coating method. Once the perovskite films are fabricated, the films are further treated with PEAI. Specifically, after cooling to room temperature, a solution of Phenethylammonium iodide (PEAI) diluted in isopropanol (IPA) (14.9 mg/l mL) was spun on the substrate at 4000 rpm for 30 s.
<Preparing and Depositing a Hole Transport Layer>
The spiro-OMeTAD solution was prepared by dissolving in chlorobenzene with 4-tert-butylpyridine, Li[TFSI] in acetonitrile, and Co [t-BuPyPz]3 [TFSI]3 (FK209, Dyesol) in acetonitrile at a molar ratio of spiro-OMeTAD:FK209:Li[TFSI]:TBP of 1:0.03:0.5:3.3. After that, 40 μL spiro-OMeTAD solution was deposited by spin-coating at 4000 rpm for 20 s on the perovskite layer as the hole transport layer (may also be called hole-transporting material (HTM) layer).
<Preparing and Depositing an Electrode Layer>
Finally, the Au electrode was evaporated onto the hole-transporting material (HTM) layer with a thickness of 70 nm.
Study of Grain Morphology
All functionalized ILs were adopted as dopants with the same amount (0.75 mol %) in the triple-cation (Cs0.08FA0.8MA0.12)Pb(I0.88Br0.12)3 perovskite precursor, in order to investigate the effect of ILs according to changes in the number of the CN groups and length of the alkyl group. The perovskite solution with the different ILs was prepared using the methods as described in the experimental example section above. All samples were deposited on the FTO/cp-TiO2/mp-TiO2/SnO2, then the films were annealed on the hotplate at 100° C. for 1 h.
As shown in
It has been reported that addition of low concentration of IL containing [BF4]− could slightly enlarge grain size. It is here confirmed that ILs with Cl− had the same beneficial effect during the process of crystal growth. Furthermore, with the same amount of dopant concentration, it was revealed that grain size of perovskite films enlarge with the length of the alkyl unit and the number of the CN groups.
X-Ray Diffraction Data and Study of Crystallinity
In addition to the morphology, the X-ray diffraction (XRD) patterns (
It is known that slow nucleation/crystallization process will result in formation of large grain size and high crystallinity. Since the annealing step is identical for the all perovskite films, the grain size/crystallinity difference could derive from introduction of ILs. Notably, one may observe that the film without IL exhibited lowest crystallization degree. The films with doped ILs showed stronger diffraction, suggesting better crystallinity. As shown in the right-hand column through the zoom-in view of the (110) diffraction peak of perovskite, the intensity of (110) peak increased appreciably, indicating the crystallinity of perovskite films was improved.
Further, the crystallinity of the perovskite films was enhanced in accordance with decreased values of full width at half maximum (FWHM) for the (110) peaks. Consistent with previous reports, the “without IL” films not only have poor crystallinity, but also have the trend of phase transformation to yellow phase (δ-phase) for formamidinium (FA). However, the intensity of the main diffraction peaks increased slightly with different ILs doped and no peaks at ˜11.8°, suggesting enhanced crystallinity and excellent stability for perovskite films. Interestingly, the (001) peak of PbI2 disappeared gradually with increasing the length of the alkyl unit and the number of the CN group of ILs.
Photoluminescence Studies
Steady photoluminescence (PL) and time-resolved photoluminescence (TRPL) measurements were carried out to investigate the non-radiative carrier recombination of the perovskite film and charge separation or collection processes at interface. Compared with the perovskite film without IL, the emission intensities of those with ILs perovskite films were significantly increased (
TRPL analysis was used to further validate the crystalline quality of perovskite films. Biexponential fits were performed on TRPL curves to quantify the carrier dynamics. As shown in
X-Ray Photoelectron Spectroscopy (XPS) Studies
X-ray photoelectron spectroscopy (XPS) analysis was implemented to probe the surface composition and chemical state of all films. Perovskite films containing [C3CNmim]Cl and without IL were studied, putting the corresponding samples at room temperature for 3 days (RH≈50%) in the air and then verifying the degradation products.
As shown in
Thermal Stability
Furthermore, the thermal stability of films with [C3CNmim]Cl and without IL were investigated by placing the films on a hotplate at 150° C. for 30 minutes in air before XPS measurements were taken. It was shown that metallic Pb was detected in both samples. However, the ratio of metallic Pb in the perovskite without IL is higher than in the perovskite with [C3CNmim]Cl, indicating that the [C3CNmim]Cl effectively improves thermal stability. The formation of metallic Pb due to the presence of the in the perovskite film has not been routinely studied [Ref. 23]. The low concentration of metallic Pb should be due to the better film quality by applying IL as additive. The presence of metallic Pb indicates the presence of iodide deficiencies in the perovskite lattice of samples. In addition, the metallic Pb species in the film were likely to act as recombination centres. From the above, the introduction of IL ([C3CNmim]Cl) can improve the air stability and thermal stability simultaneously. The increased stability of the perovskite film with [C3CNmim]Cl could be due to the increased film quality as the CN group in the cation will compete with the I/Br anion in the formation of the 3-D perovskite network, resulting in a slow crystallization process and subsequently better quality. The incorporation of the Cl anion in the 3-D perovskite bulk will strengthen the hydrogen bonding, preventing phase transformation and increase the stability.
Perovskite Solar Cell Performance Comparison
The architecture of PSCs used was shown in
Performance comparison with all kinds of PSCs including that with ILs ([C1CNmim]Cl, [C3CNmim]Cl, [(C3CN)2im]Cl) and without IL ae shown in
Both the length of the alkyl unit and the number of CN groups of ionic liquids (ILs) are seen to influence the open circuit voltage (Voc) of the resulting films. It can be seen that the Voc of PSCs with IL were enhanced from PSC without IL (1.09 V) to 1.11 V (with [C1CNmim]Cl) to 1.15 V (with [C3CNmim]Cl) and 1.15 V (with [(C3CN)2im]Cl).
The short circuit current density (Jsc) of PSCs with ILs were similar [(23.00 mA cm−2 (with [C1CNmim]Cl) to 22.73 mA cm−2 (with [C3CNmim]Cl) and 22.21 mA cm−2 (with [(C3CN)2im]Cl)), lower than that without IL (23.30 mA cm−2).
The fill factor (FF) of the PSCs are sensitive to the quality of the perovskite layer as well as those of the electron transport materials (ETMs) and hole transport materials (HTMs). PSCs with ILs exhibited higher FF from 0.810 (with [C1CNmim]Cl) to 0.819 (with [C3CNmim]Cl) and 0.815 (with [(C3CN)2im]Cl).
From the above, the PSCs doped with [C3CNmim]Cl showed the best performance with a power conversion efficiency (PCE) of 21.34% among all devices doped with IL samples, compared with devices doped with [C1CNmim]Cl (20.71%) and [(C3CN)2im]Cl (20.84%). All are higher than that without IL (19.73%).
Thus, it can be seen that perovskite solar cells doped with ILs can reach a high integrated performance. The enhancement should be ascribed to the reduced photo-generated charge recombination at the perovskite interface as evidenced by PL measurements. In general, the hysteresis between forward and reverse scanning is a key aspect to evaluate the integrated performance of PSCs. Moreover, the J-V curves of a device based on with ILs perovskite at forward and reverse scanning exhibits small hysteresis. The hysteresis of PCEs are 3% PSCs doped with [C3CNmim]Cl and 5% for PSCs without IL respectively. These results indicated that doping with ILs as additives can provide high-performance PSCs with nearly-eliminated hysteresis.
For statistical results, twenty (20) devices were fabricated. Among the devices doped with [C1CNmim]Cl, [(C3CN)2im]Cl or without IL perovskite devices, PSC doped with [C3CNmim]Cl present substantially better performance. As can be seen from the histogram of the statistical efficiency distribution, the devices doped with C3CNmim]Cl showed excellent performance with a narrow PCE distribution. As for the device stability test, the steady-state photocurrent density of the PSCs was firstly measured at a fixed bias potential, where the maximum output power was detected in the J-V curve. The photocurrent output of the devices with and without IL show similar performance, with only a minimal decrease observed for device without IL after 150 s compared to that of the devices with IL (
In summary, it has thus been demonstrated that ILs containing CN group in the alkyl side of the imidazolium cation and halogen anions, preferably Cl anion, can serve as effective additives for perovskite precursor, and notably a triple cation (Cs, FA, MA) perovskite precursor, achieving the performance with better stability of the resulting PSC device. Both the length of the alkyl unit linking the imidazolium ring and the number of the CN groups influence the overall performance.
In The influence of ILs on the photovoltaic performance of PSCs could be attributed to completion effect of the CN to the I/Br anion in the formation of the 3-D perovskite film resulting better quality and encapsulation of the Cl anion due to the halide exchange Cl—I/Br which results in strengthening of the hydrogen bond for increased stability. These results indicate that doping PSCs with CN functionalized ILs not only improves the open circuit voltage and fill factor of PSCs, but also reduce the risk of exposure to the atmosphere, thus leading to significant enhancement of device stability. The PSC device demonstrated a high PCE 21.34%, higher than that without IL. Noteworthy, the unencapsulated device retained about 95% of their original efficiencies after a 1000 h aging study.
Number | Date | Country | Kind |
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20207537.0 | Nov 2020 | EP | regional |