Patent Grant
12122729
The present application relates to the technical field of materials, and more particularly relates to perovskite type compounds.
Energetic compound is a type of explosives with high energy density. The black powder, which is the first known energetic material discovered by ancient Chinese in the ninth century, is prepared by mixing sulfur, potassium nitrate, and charcoal powder, and has poor effect and unstable performance. In modern times, nitroglycerin, which had initially been discovered as a medicinal product, was found to be a high explosive later in manufacturing. Although nitroglycerin demonstrates much better performance in comparison to black powder, it is very dangerous for production and transportation due to its high sensibility. Through unremitting manufacturing and research, Alfred Bernhard Nobel found that diatomite can adsorb nitroglycerin, which, at the expense of certain explosive performance, can effectively improve the safety of products. Thus, nitroglycerin was successfully applied to industrial application. Nowadays, explosives with higher performance than nitroglycerin have been discovered and put into use one after another. The well-known trinitrotoluene (TNT) and the organic energetic materials such as cyclotrimethylene trinitramine (RDX) and cyclotetramethylene tetranitramine (HMX), which have a high detonation performance in comparison to TNT, are widely used in weapons and ammunition around the world. In recent years, the industrialization process of hexanitrohexaazaisowurtzitane (CL-20), an organic explosive with high performance, high cost and complicated procedures, has been explored by Chinese scientists, which has promoted the prospect of upgrading the military ammunition in China. In recent years, some metal-organic frameworks containing energetic organic ligands (e.g. Angew. Chem. Int. Ed. 2013, 52, 14031; Chem. Eur. J. 2013, 19, 1706) have attracted growing attention. With rich ligand adjustability and high detonation performance indicated by theoretical calculations, such energetic metal-organic frameworks are regarded as an important direction for the development of next-generation explosives.
In the course of modern explosive development, different explosives have demonstrated improved properties in different aspects, but are also inevitably accompanied by some defects of their own. For example, explosive potassium perchlorate was once used as the pro-oxidant for flash bombs, but it was eventually abandoned due to its high impact sensitivity which makes it prone to explosion in transit (see “High Energy Materials: Propellants, Explosives and Pyrotechnics”, p. 347, edited by Jai Prakash Agrawal, Wiley-VCH Press, 2010). Among existing organic energetic materials as well as metal-organic framework energetic materials which are still in the stage of fundamental research, it is not rare to find those that have excellent detonation performance, but most of them are difficult to apply due to disadvantages of complicated synthetic processes, numerous steps, high cost, and poor stability, as well as high impact and friction sensitivities. Therefore, how to design and synthesize insensitive high-energetic materials with the advantages of low cost, high energy density and low sensitivity (high safety) is an everlasting pursuit in the field of energetic materials.
A first objective of the present application is to provide a sort of novel energetic materials.
A second objective of the present application is to provide a sort of novel energetic materials with high safety.
A third objective of the present application is to provide a sort of novel energetic materials with high detonation performance.
A fourth objective of the present application is to provide a sort of novel energetic materials with a high energy density.
In the field of energetic materials, the present application takes perovskite type compounds as energetic material for the first time, and makes a breakthrough and finds that the perovskite type compound is particularly suitable to be used as the energetic material.
The said perovskite type compound has an energetic group, such as a ClO4− energetic group. This type of energetic material may be used as, but not limited to an explosive. For example, this material further may be used as a propellant, rocket fuel or a gas generant of safety air bags.
The perovskite type compound is a solid compound having same type of crystal structure as calcium titanate (CaTiO3). They have the same chemical general formula ABX3, where A and B are cations of different sizes, and X is an anion. An ideal structure is a high-symmetric cubic structure, and the structural features may be described as follows: each B-site cation is connected with six adjacent X anions, and each X anion is connected with two adjacent B-site cations, thereby forming a three-dimensional anionic framework consisting of cubic cage units. Cavities of these cubic cage units are filled with the A-site cations. A is at least one cation, B is at least one cation, and X is at least one anion. When perovskite includes more than one A cations, different A cations may be distributed at A sites in an ordered or disordered manner. When the perovskite includes more than one B cations, different B cations may be distributed at B sites in an ordered or disordered manner. When the perovskite includes more than one X anions, different X anions may be distributed at X sites in an ordered or disordered manner.
At present, perovskite type compounds are generally studied and applied as ferroelectric materials, photoelectric materials, electromagnetic materials, etc.
As a finding of the present application, a three-dimensional structure is formed in perovskite type compound in which cation A is larger than cation B, and X is the energetic anionic group. In addition to endowing the compound with the effects of energetic materials, such a structure can also enable the compound to overcome some defects in existing energetic materials. For example, as the inventor speculates, the structural characteristics of perovskite type compound provide the compound with high stability, so as to overcome the unsafety of explosives having poor stability in the prior art; in addition, the structural characteristics of the compound, such as rich energetic groups, as well as alternately arranged oxidizing energetic anions and reducing organic cations in the space, endow the compound with excellent performance on instantaneously releasing energy at detonation. Low sensitivity in storage and instantaneous burst at detonation, these two seemingly contradictory characteristics are integrated due to the three-dimensional spatial structural characteristics of perovskite type compounds, which enables the compound to be particularly suitable for being used as energetic materials such as insensitive high-energetic explosives.
An energetic ligand refers to an explosive ligand. However, not all compounds containing explosive ligands are explosive; whether or not a compound is explosive depends on its entire molecular structure rather than on a single ligand (see The Study of Explosives, p. 3, Zhang Huazhu, et al., Beijing: Ordnance Industry Press, 2004). Common explosive ligands include ClO3−, ClO4−, NO3−, ONC−, N(NO2)2−, diazenyl, azide ions, and nitro ligands.
X of the present application is at least one anionic energetic ligand. In some embodiments, X is an oxidizing anionic energetic ligand. In some embodiments, X is a monovalent anionic energetic ligand. In some embodiments, X is a monovalent halogen-containing energetic ligand.
In some embodiments, the anionic energetic ligand (X) may be one, two or more of: ClO4−, BrO4−, IO4−, ONC−, NO3− and N(NO2)2−.
In some embodiments, the anionic energetic ligand (X) may be one, two or more of: ClO4−, BrO4− and IO4−.
A of the present application is at least one organic cation. In some embodiments, A is a reducing organic cation.
In some embodiments, A is at least one nitrogen-containing organic cation.
In some embodiments, A is at least one nitrogen-containing heterocycle organic cation.
In some embodiments, A is at least one nitrogen-containing six-membered heterocycle organic cation.
In some embodiments, A is one, two or more of organic cations formed by protonizing the following organic matters and derivatives of the organic cations: 1,4-diazabicyclo[2.2.2]octane, pyrazine, piperazine, 3-aminopyrrolidine, imidazoline, amino-triazole, amino-tetrazole, ethanediamine, cyanoguanidine, phenylenediamine, 1,5-diaminopentane, cyclohexanediamine and the like.
In some embodiments, A is selected from one, two or more of the following organic cation parents and derivatives thereof:
1,4-diazabicyclo[2.2.2]octane-1,4-diium,
pyrazine-1,4-diium,
piperazine-1,4-diium,
1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium,
1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium,
imidazolidine-1,3-diium,
3-ammonio-1H-1,2,4-triazol-1-ium,
5-ammonio-2H-tetrazol-2-ium,
cyclohexane-1,2-diaminium,
2-ammoniopyrrolidin-1-ium,
ethane-1,2-diaminium.
In some embodiments, A is selected from one, two or more of the following organic cation parents and derivatives thereof:
1,4-diazabicyclo[2.2.2]octane-1,4-diium,
pyrazine-1,4-diium,
piperazine-1,4-diium,
1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium,
1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium.
The derivatives of the organic cations of A are that hydrogen atoms bonded to the organic cation parents be substitute with substituent ligand(s) simultaneously or differently. Common substituent ligands include methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, nitryl and the like. In some embodiments, the substituent ligand is selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, and nitryl. In some embodiments, the substituent is methyl.
In some embodiments, A is selected from a group consisting of
1,4-diazabicyclo[2.2.2]octane-1,4-diium,
pyrazine-1,4-diium,
piperazine-1,4-diium,
1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium,
1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, and the derivatives thereof;
wherein in said derivatives, at least one of the shown hydrogen atoms bonded to the organic cation parents is substituted with substituents selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, nitryl and the like. In some embodiments, the substituent ligand is selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, and nitryl.
In some embodiments, A is selected from a group consisting of
In some embodiments, A is selected from a group consisting of 1,4-diazabicyclo[2.2.2]octane-1,4-diium, pyrazine-1,4-diium, piperazine-1,4-diium, 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, and the derivatives thereof; wherein in the derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of the organic cation parents is substituted with substituents which is methyl.
In some embodiments, A is selected from a group consisting of 1,4-diazabicyclo[2.2.2]octane-1,4-diium, piperazine-1,4-diium, and the derivatives thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with at least one substituent, wherein each of the substituent is selected from a group consisting of hydroxyl and methyl.
In some embodiments, A is selected from a group consisting of 1,4-diazabicyclo[2.2.2]octane-1,4-diium, piperazine-1,4-diium, and the derivatives thereof, wherein in said derivatives, one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, A is selected from a group consisting of 1,4-diazabicyclo[2.2.2]octane-1,4-diium, piperazine-1,4-diium, 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, and the derivatives of 1,4-diazabicyclo[2.2.2]octane-1,4-diium, piperazine-1,4-diium; wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of the organic cation parents is substituted with substituents which is methyl.
The B is at least one monovalent cation.
In some embodiments, B is selected from one, two or more of the following cations: an alkali metal ion, NH4+.
In some embodiments, the alkali metal ion is selected from one, two or more of Na+, K+, Rb+ and Cs+.
In some embodiments, A is selected from one, two or more of a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and derivatives thereof. In some embodiments, A is selected from one or two of organic cations such as the 1,4-diazabicyclo[2.2.2]octane-1,4-diium and the 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium.
In some embodiments, B is selected from one, two or more of Na+, K+ and NH4+. In some embodiments, B is selected from Na+ and NH4+. In some embodiments, B is selected from NH4+.
In some embodiments, X is selected from one, two or more of ClO4−, NO3− and IO4−. In some embodiments, X is selected from one or two of ClO4− and NO3−, or selected from one or two of ClO4− and IO4−. In some embodiments, X is selected from ClO4−.
In some embodiments, A is selected from one, two or more of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a pyrazine-1,4-diiumpyrazine-1,4-diium, a piperazine-1.4-diiumpiperazine-1.4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium; B is selected from one, two or more of Na+, K+, Rb+ and NH4+; and X is selected from one, two or more of ClO4−, NO3− and IO4−; in some embodiments, X is selected from one or two of ClO4− and IO4−, or selected from one or two of ClO4− and NO3−.
In some embodiments, A is selected from one, two or more of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium; B is selected from one, two or more of Na+, K+, Rb+ and NH4+; and X is selected from one or two of ClO4− and NO3−, or one or two of ClO4− and IO4−; in some embodiments, X is selected from ClO4−.
In some embodiments, A is selected from one or two of organic cations such as 1,4-diazabicyclo[2.2.2]octane-1,4-diium and 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium; B is selected from one, two or more of Na+, K+, Rb+ and NH4+; and X is selected from one or two of ClO4− and NO3−, or one or two of ClO4− and IO4−; in some embodiments, X is selected from ClO4−.
In some embodiments, A is selected from one or two of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium and a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium; B is selected from one, two or more of Na+, K+ and NH4+; and X is selected from one or two of ClO4− and NO3−, or one or two of ClO4− and IO4−; in some embodiments, X is selected from ClO4−.
In some embodiments, A is an organic cation such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium; B is selected from one or two of Na+ and NH4+; and X is selected from one or two of ClO4− and NO3−, or one or two of ClO4− and IO4−; in some embodiments, X is selected from ClO4−.
In some embodiments, A and X are selected from the above-mentioned any possible selections, and B is selected from NH4+.
In some embodiments, A is selected from one, two or more of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a pyrazine-1,4-diium, a piperazine-1.4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and derivatives thereof, X is selected from one, two or more of ClO4−, BrO4− and IO4−; and B is selected from NH4+.
When B is NH4+, and after the compound completely explodes, no metallic salt solid substances remain, and gas generated per mole may be up to 15.25 moles. With this nature, the compound is more favorably used as an explosive, rocket fuel, a propellant, and a gas generants of safety air bags, etc., and is particularly suitable for application fields with high requirements for the gas yield. For example, the compound is used as the rocket fuel.
In some embodiments, A and X are selected from the above-mentioned any possible selections, and B is Na+.
In some embodiments, A is selected from one, two or more of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a pyrazine-1,4-diium, a piperazine-1.4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and derivatives thereof; X is selected from one, two or more of ClO4−, BrO4− and IO4−; and B is selected from Na+.
In some embodiments, A is 1,4-diazabicyclo[2.2.2]octane-1,4-diium, X is ClO4−, and B is Na+.
When B is Na+, particular advantages are as follows: theoretically, in comparison with such a situation that B is K+, the density is reduced. It is generally considered that the reduced density ρ may reduce the performance of the energetic material (a Kamlet-Jacob equation of deducing a detonation velocity D and a detonation pressure P of the energetic material: D=1.01Φ1/2 (1+1.30ρ), P=1.558Φρ2, where Φ=31.68N(MQ)1/2; N is a gas mole number generated by unit mass of the material; M is an average mole mass of a gas product; and Q is a heat output per unit mass of the material. Therefore, the density is in positive correlation with the influence of the detonation velocity and the detonation pressure, and is particularly in square index relation with the influence of the detonation pressure). However, the present application finds that (see Embodiment 1) when the compound is used as the energetic material, it has been simply and clearly foreseen that lightweight sodium ions may reduce the density of the material, according to which, speculation can be made that negative effects may be generated on the detonation velocity and the detonation pressure of the material, but all experiments and theoretical calculation have proven that the use of the sodium ions achieves a better effect on multiple performances instead. For example, through comparison of DAP-1 (see Embodiment 1, B of the perovskite type compound is Na+) and DAP-2 (see Embodiment 2, B of the perovskite type compound is K+), the heat output per unit mass is increased, and the gas mole number per unit mass is increased, so that theoretical forecasted values of the detonation velocity and the detonation pressure of DAP-1 are both higher than those of DAP-2. In addition, sodium perchlorate serving as a raw material of DAP-1 is easier to dissolve in a polar solvent than potassium perchlorate serving as a raw material of DAP-2, so that the amount of a solvent for synthesizing DAP-1 is much less than the amount of a solvent for synthesizing DAP-2. Therefore, in experiment and manufacturing, DAP-1 is more convenient to synthesize. DAP-1 is possibly more suitable to be applied to the fields of high explosives and propellants than DAP-2.
In some embodiments, A and X are selected from the above-mentioned any possible selections, and X is NO3−.
In some embodiments, A is selected from one, two or more of organic cations such as a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, a pyrazine-1,4-diium, a piperazine-1.4-diium, a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium and derivatives thereof; B is selected from one, two or more of Na+, K+, Rb+ and NH4+; and X is NO3−.
When X is NO3−, the compound does not contain a halogen element, so that no hydrogen halide gas is produced after the explosion of the compound, thereby reducing characteristic signals and relieving environmental pollution. This nature enables the compound to be particularly suitable for application fields with requirements for low characteristic signals. For example, the compound is used as a low characteristic signal propellant or rocket fuel.
ABX3 may be obtained by the reaction among the A component, the B component and the X component which are added into a liquid reaction system in any order. In some embodiments, the liquid reaction system is a polar solvent capable of dissolving the A component, the B component and the X component, or is obtained by using a known synthesis method. There is no limitation on reaction temperature, which may be adjusted within an extremely large range, such as 0 to 100° C.
In some embodiments, the present application provides a preparation method of the compound, including:
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, pyrazine or a derivative thereof, piperazine or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1-oxide or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide or a derivative thereof, organic salt containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, organic salt containing a pyrazine-1,4-diium or a derivative thereof, organic salt containing a piperazine-1,4-diium or a derivative thereof, organic salt containing a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and organic salt containing a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, pyrazine or a derivative thereof, piperazine or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1-oxide or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide or a derivative thereof, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, salt or solution containing a pyrazine-1,4-diium or a derivative thereof, salt or solution containing a piperazine-1,4-diium or a derivative thereof, salt or solution containing a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and salt or solution containing a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the organic cation parents is substituted with substituents selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, nitryl and the like. In some embodiments, the substituent ligand is selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, and nitryl.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, pyrazine or a derivative thereof, piperazine or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1-oxide or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide or a derivative thereof, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, salt or solution containing a pyrazine-1,4-diium or a derivative thereof, salt or solution containing a piperazine-1,4-diium or a derivative thereof, salt or solution containing a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and salt or solution containing a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with substituents selected from a group consisting of methyl, ethyl, isopropyl, tertiary butyl, hydroxy, oxo, carboxyl, halogen, sulfydryl, peroxyl, diazenyl, nitryl and the like.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, pyrazine or a derivative thereof, piperazine or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1-oxide or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide or a derivative thereof, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, salt or solution containing a pyrazine-1,4-diium or a derivative thereof, salt or solution containing a piperazine-1,4-diium or a derivative thereof, salt or solution containing a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and salt or solution containing a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, piperazine or a derivative thereof, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and salt or solution containing a piperazine-1,4-diium or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, piperazine or a derivative thereof, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, and salt or solution containing a piperazine-1,4-diium or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl, hydroxyl or oxo ligand.
In some embodiments, the said A component is at least one of 1,4-diazabicyclo[2.2.2]octane or a derivative thereof, piperazine or a derivative thereof, 1,4-diazabicyclo[2.2.2]octane 1-oxide, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide, salt or solution containing a 1,4-diazabicyclo[2.2.2]octane-1,4-diium or a derivative thereof, salt or solution containing a piperazine-1,4-diium or a derivative thereof, salt or solution containing a 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, and salt or solution containing a 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, the said A component is at least one of: 1,4-diazabicyclo[2.2.2]octane, pyrazine, piperazine, 1,4-diazabicyclo[2.2.2]octane 1-oxide, 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide, or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, the said A component is at least one of salt or solution containing: a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, pyrazine-1,4-diium, piperazine-1,4-diium, 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl, wherein said salt or solution containing chloride or iodide.
In some embodiments, the said A component is at least one of, chloride or iodide of, a 1,4-diazabicyclo[2.2.2]octane-1,4-diium, pyrazine-1,4-diium, piperazine-1,4-diium, 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium, or a derivative thereof, wherein in said derivatives, at least one of the hydrogen atoms bonded to the nitrogen atom of organic cation parents is substituted with methyl.
In some embodiments, a cation of the B component is selected from one, two or more of alkali metal ions and NH4+. The B component is at least one of ammonium salt, sodium salt, potassium salt, rubidium salt, cesium salt, ammonium alkali, sodium alkali, potassium alkali, rubidium alkali and cesium alkali.
In some embodiments, said X component is at least one of a halogen-containing energetic acids and halogen-containing energetic salts.
In some embodiments, said polar solvent is one, two or more of water, ethanol and methanol.
In some embodiments, the organic salt containing the 1,4-diazabicyclo[2.2.2]octane-1,4-diium is hydrochloride of 1,4-diazabicyclo[2.2.2]octane.
In some embodiments, the said organic salt containing the 1,4-diazabicyclo[2.2.2]octane-1,4-diium derivative is at least one of hydrochloride of 2-hydroxy-1,4-diazabicyclo[2.2.2]octane, hydrochloride of 2-carbonyl-1,4-diazabicyclo[2.2.2]octane and hydrochloride of 2-methyl-1,4-diazabicyclo[2.2.2]octane.
In some embodiments, the said organic salt containing the pyrazine-1,4-diium is hydrochloride of pyrazine.
In some embodiments, the said organic salt containing the pyrazine-1,4-diium derivative is at least one of hydrochloride of 2-hydroxy-pyrazine and hydrochloride of 2-methyl-pyrazine.
In some embodiments, the said organic salt containing the piperazine-1,4-diium is hydrochloride of piperazine.
In some embodiments, the said organic salt containing the piperazine-1,4-diium derivative is at least one of hydrochloride of 2-hydroxy-piperazine and hydrochloride of 2-methyl-piperazine.
In some embodiments, the said organic salt containing the 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium is hydrochloride of 1,4-diazabicyclo[2.2.2]octane 1-oxide.
In some embodiments, the said organic salt containing the 1-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium derivative is at least one of hydrochloride of 2-hydroxy-1,4-diazabicyclo[2.2.2]octane 1-oxide and hydrochloride of 2-carbonyl-1,4-diazabicyclo[2.2.2]octane 1-oxide.
In some embodiments, the said organic salt containing the 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium is hydrochloride of 1,4-diazabicyclo[2.2.2]octane 1,4-dioxide.
In some embodiments, the said organic salt containing the 1,4-dihydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium derivative is at least one of 2-hydroxy-1,4-diazabicyclo[2.2.2]octane 1,4-dioxide and hydrochloride of 2-carbonyl-1,4-diazabicyclo[2.2.2]octane 1,4-dioxide.
In some embodiments, the said ammonium salt is at least one of ammonium perchlorate, ammonium tetrafluoroborate, ammonium periodate, ammonium perrhenate, ammonium carbonate, ammonium nitrate, ammonium phosphate, ammonium chloride and ammonium fluoride.
In some embodiments, the said sodium salt is at least one of sodium perchlorate, sodium tetrafluoroborate, sodium periodate, sodium perrhenate, sodium carbonate, sodium nitrate, sodium phosphate, sodium chloride and sodium fluoride.
In some embodiments, the said potassium salt is at least one of potassium perchlorate, potassium tetrafluoroborate, potassium periodate, potassium perrhenate, potassium carbonate, potassium nitrate, potassium phosphate, potassium chloride and potassium fluoride.
In some embodiments, the said rubidium salt is at least one of rubidium perchlorate, rubidium tetrafluoroborate, rubidium periodate, rubidium perrhenate, rubidium carbonate, rubidium nitrate, rubidium phosphate, rubidium chloride and rubidium fluoride.
In some embodiments, the said cesium salt is at least one of cesium perchlorate, cesium tetrafluoroborate, cesium periodate, cesium perrhenate, cesium carbonate, cesium nitrate, cesium phosphate, cesium chloride and cesium fluoride.
In some embodiments, the said ammonium alkali is ammonia water.
In some embodiments, the said sodium alkali is sodium hydroxide.
In some embodiments, the said potassium alkali is potassium hydroxide.
In some embodiments, the said rubidium alkali is rubidium hydroxide.
In some embodiments, the said cesium alkali is cesium hydroxide.
In some embodiments, said X component is a perchlorate radical containing substance. For example, said X component is a perchloric acid.
In some embodiments, the said polar solvent is at least one of water, ethanol and methanol.
In some embodiments, when the perovskite type compound ABX3 contains a perchlorate radical, characteristic peaks of an infrared absorption spectrum of the perchlorate radical are ranged from 1070 to 1100 cm−1 and 617 to 637 cm−1.
When the perovskite type compound ABX3 contains a nitrate radical, characteristic peaks of an infrared absorption spectrum of the nitrate radical are ranged from 1375 to 1390 cm−1 and 845 to 860 cm−1.
When in a cubic system, the 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 12.1±0.70°, 21.1±1.00° and 24.4±1.20°. Further, the 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 12.1±0.70°, 21.1±1.00°, 24.4±1.20°, 27.4±1.30° and 36.57±0.88°.
Or, in a monoclinic system, an 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 12.6±0.5°, 21.7±0.5°, 22.4±0.5°, 22.7±0.5°, 25.4±0.5° and 26.8±0.5°. Further, the 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 12.6±0.5°, 21.7±0.5°, 22.4±0.5°, 22.7±0.5°, 25.4±0.5°, 26.8±0.5°, 27.2±0.5°, 37.7±0.5° and 38.4±0.5°.
Or, in a hexagonal system, an 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 17.7±0.5°, 20.4±0.5°, 23.9±0.5°, 24.8±0.5°, 29.7±0.5° and 30.5±0.5°. Further, the 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern is about: 10.3±0.5°, 17.7±0.5°, 20.4±0.5°, 23.9±0.5°, 24.8±0.5°, 27.0±0.5°, 29.7±0.5°, 30.5±0.5° and 32.2±0.5° and 37.0±0.5°.
The present application has the outstanding beneficial effects that:
The inventor designs a series of perovskite type compounds having energetic groups, and makes relevant experiments and researches on the prospect of these compounds serving as novel high-performance explosives in the energetic field. In the present application, such perovskite type energetic compounds (ABX3, corresponding to an abbreviation DAP in the following embodiments and endowed with respective numbers) having the energetic ligands are provided. Experiments and calculations indicate that their energy densities and explosive performance may be comparable with those of high-performance active-duty military explosives RDX and HMX. Furthermore, the compounds have excellent safety performance, with non-volatile and non-hygroscopic characteristics, and are prepared from cheap and readily-available raw materials through a simple synthesis process. These compounds are novel energetic compounds having practical values in the energetic fields.
The ABX3 may be synthesized by a synthesis method of the present application. A synthesis method (Z. M. Jin, Y. J. Pan, X. F. Li, M. L. Hu, L. Shen, Journal of Molecular Structure, 2003, 660, 67) of a perovskite type compound (C6H14N2)[K(ClO4)3], which is disclosed by Z. M. Jin et al, may be also employed for reference.
X in ABX3 is at least one anionic energetic ligand. The energetic ligand is an explosive ligand. Common explosive ligands include, but not limited to, ClO3−, ClO4−, IO4−, NO3−, ONC−, diazenyl, azide ion, nitryl, and the like.
In ABX3, for example, X may include one or more ions. For example, 2, 3, 4, 5, 6, 7, 8, 9, 10 . . . types of X ions may exist at the same time. The same is true for A and B. When perovskite includes more than one type of A cations, different A cations may be distributed at A sites in an ordered or disordered manner. When the perovskite includes more than one type of B cation, different B cations may be distributed at B sites in an ordered or disordered manner. When the perovskite includes more than one type of X anion, different X anions may be distributed at X sites in an ordered or disordered manner.
Based on this nature, the above-mentioned “X is at least one . . . ligand/ion”, “A is at least one . . . ligand/ion”, “B is at least one . . . ligand/ion”, “X is selected from . . . ”, “A is selected from . . . ”, “B is selected from . . . ”, etc. should be understood for example that for X, an ABX3 three-dimensional framework includes many X sites, each of which consists of one type of ions. In the three-dimensional framework, the multiple X sites may consist of the same type of ions, and also may consist of different types of ions. When the X sites consist of different ions, at least some sites (or most sites) are . . . ligands/ions. At this moment, such a situation that a few of sites in the whole ABX3 three-dimensional framework are not the . . . ligands/ions or some other foreign ions is not excluded as long as the number of these sites may not affect the overall performance to a large extent. The few of sites may, for example, have the mole number less than 50 percent, for example, not more than 40 percent, 30 percent, 25 percent, 20 percent, 15 percent, 10 percent, 9 percent, 8 percent, 7 percent, 6 percent, 5 percent, 4 percent, 3 percent, 2 percent or 1 percent . . . . For A and B, it is the same.
The present application performs various identification and characterization methods including powder X-ray diffraction identification, single-crystal structure characterization test, infrared spectral characterization, thermal stability characterization, differential scanning calorimetry (DSC), sensitivity characterization, and detonation heat/detonation pressure/detonation velocity calculation.
There into, powder X-ray diffraction data under a room temperature condition are collected on a Bruker D8 Advance diffractometer by adopting a Cu-Kα ray. A scanning mode is as follows: θ: 2θ linkage, stepping scanning, a 2θ step length being 0.02°. Single crystal X-ray diffraction data are collected on an Oxford Gemini S Ultra CCD diffractometer through a graphite monochromator in a co scanning manner by using a Mo-Kα X-ray. An SADABS program is adopted for absorption correction. A direct method is used for analysis, and then all non-hydrogen coordinates are calculated by using a differential Fourier function method and a least square method, and finally the structure is refined by using a full-matrix least-square technique. Organic hydrogen atoms are generated geometrically. The calculation work is completed on a PC by using Olex2 and SHELX program packages. Infrared spectral data are acquired on an IR Tensor 27 instrument. A dried sample and KBr are pressed into a transparent thin-sheet test sample. Thermogravimetric analysis is collected on a TA Q50 instrument in a nitrogen atmosphere at a scanning speed of 5° C./min. A DSC curve is collected on a TA DSC Q2000 instrument in the nitrogen atmosphere at the scanning speed of 5° C./min.
The sensitivity characterization is to test impact, friction and thermal sensitivities according to the National Military Standards GJB772A-97 of the People's Republic of China. The impact sensitivity is tested by a 601.1 explosive probability method. The friction sensitivity is tested by a 602.1 explosive probability method. The thermal sensitivity is tested by a 606.1-burst point 5 s delay method. The electrostatic sensitivity is tested by the third section of the industrial initiating explosive material test method WJ/T 9038.3-2004: electrostatic-spark sensitivity test.
At a room temperature, characteristic peaks of a perchlorate radical ligand in an infrared absorption spectrum are ranged from 1070 to 1100 cm−1 (corresponding to asymmetric stretching vibration) and 617 to 637 cm−1 (corresponding to asymmetric bending vibration). Characteristic peaks of a nitrate radical ligand in the infrared absorption spectrum are ranged from 1375 to 1390 cm−1 (corresponding to asymmetric stretching vibration) and 845 to 860 cm−1 (corresponding to asymmetric bending vibration).
In one embodiment, an adopted compound serving as an energetic material is (C6H14N2)[Na(ClO4)3] (which is recorded as DAP-1), and is crystallized in the cubic space group Pa-3 at 223 K, with a cell length of 14.1537(1)Å. An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.3±0.5°, 21.5±0.5°, 24.9±0.5°, 27.9±0.5°, 35.6±0.5° and 37.2±0.5°. Athermal stability analysis result shows that an explosion temperature of the compound may be up to 360° C. A differential scanning calorimetry result shows that heat released at 360° C. is 4398 J/g. A safety characterization result shows that DAP-1 is insensitive in impact sensitivity, friction sensitivity and electrostatic-spark sensitivity tests under the National Military Standards. Under the standard of Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-1 is about 17 J, and the friction sensitivity is about 36 N. The burst point of DAP-1 is 340° C. (5 s delay method). Detonation heat, detonation velocity and detonation pressure values obtained according to a Density Functional Theory (DFT) are respectively 1.53 kcal/g, 8.85 km/s and 37.31 GPa.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2)[K(ClO4)3] (which is recorded as DAP-2), and is crystallized in the cubic space group Pa-3 at 223 K, with a cell length of 14.2910(1)Å. An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.15±0.5°, 21.27±0.5°, 24.63±0.5°, 27.64±0.5°, 35.20±0.5° and 36.89±0.5°. Athermal stability analysis result shows that the explosion temperature of the compound may be 362° C. A differential scanning calorimetry result shows that heat released at 377° C. is 4076 J/g. A safety characterization result shows that under the standard of Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-2 is about 16 J, and the friction sensitivity is about 42 N. Detonation heat, detonation velocity and detonation pressure values obtained theoretically by the DFT are respectively 1.46 kcal/g, 8.64 km/s and 35.73 GPa.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2)[Rb(ClO4)3] (which is recorded as DAP-3), and is crystallized in the cubic space group Pa-3 at 223 K, with a cell length of 14.453(2)Å. An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.0±0.5°, 21.0±0.5°, 24.3±0.5°, 27.3±0.5°, 34.7±0.5° and 36.4±0.5°. A thermal stability analysis result shows that the explosion temperature of the compound may be up to 343° C. A differential scanning calorimetry result shows that heat released at 369° C. is 3797 J/g. A safety characterization result shows that under the standard of the Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-3 is about 22 J, and the friction sensitivity is about 28 N. Detonation heat, detonation velocity and detonation pressure values obtained theoretically by the DFT are respectively 1.33 kcal/g, 8.43 km/s and 35.14 GPa.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2)[NH4(ClO4)3] (which is recorded as DAP-4), and is crystallized in the cubic space group Pa-3 at 223 K, with a cell length of 14.4264(1)Å. An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) diffraction of the compound at the room temperature is about: 12.0±0.5°, 21.0±0.5°, 24.4±0.5°, 27.3±0.5°, 34.8±0.5° and 36.5±0.5°. A thermal stability analysis result shows that the explosion temperature of the compound may be up to 370° C. A differential scanning calorimetry result shows that heat released at 364° C. is 5177 J/g. A safety characterization result shows that under the standard of Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-4 is about 23 J, and the friction sensitivity is about 36 N.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2O2)[K(ClO4)3] (which is recorded as DAP-O22), and is crystallized in the cubic space group Fm-3c at 298 K, with a cell length of 14.745(3)Å. An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 11.9±0.5°, 20.8±0.5°, 24.1±0.5°, 27.0±0.5°, 34.4±0.5° and 36.1±0.5°. A thermal stability analysis result shows that a detonation temperature of the compound may be 354° C. A differential scanning calorimetry result shows that heat released at 358° C. is 5424 J/g. A safety characterization result shows that under the standard of the Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-O22 is about 11 J, and the friction sensitivity is about 14 N.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2O)[K(ClO4)3] (which is recorded as DAP-O12). An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.1±0.5°, 21.1±0.5°, 24.4±0.5°, 27.3±0.5°, 34.8±0.5° and 36.5±0.5°.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2O2)[NH4(ClO4)3] (which is recorded as DAP-O24). An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 11.9±0.5°, 20.8±0.5°, 24.0±0.5°, 27.0±0.5°, 34.4±0.5° and 36.0±0.5°. A differential scanning calorimetry result shows that heat released at 357° C. is 4632 J/g. A safety characterization result shows that under the standard of the Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-O24 is about 4 J, and the friction sensitivity is about 32 N.
In another embodiment, an adopted compound serving as the energetic material is (C4H12N2)[Na(ClO4)3] (which is recorded as PAP-1). An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.6±0.5°, 21.7±0.5°, 22.4±0.5°, 22.7±0.5°, 25.4±0.5°, 26.8±0.5°, 27.2±0.5°, 37.7±0.5° and 38.4±0.5°. A differential scanning calorimetry result shows that heat released at 375° C. is 4685 J/g.
In another embodiment, an adopted compound serving as the energetic material is (C4H12N2)[NH4(ClO4)3] (which is recorded as PAP-4). A differential scanning calorimetry result shows that heat released at 356° C. is 3780 J/g.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2)[K(NO3)3] (which is recorded as DAN-2). An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 12.6±0.5°, 17.9±0.5°, 22.0±0.5°, 25.5±0.5°, 28.6±0.5°, 31.3±0.5°, 36.4±0.5°, 38.7±0.5°, 40.9±0.5° and 43.0±0.5°. A differential scanning calorimetry result shows that heat released at 177° C. is 1222 J/g. A safety characterization result shows that under the standard of the Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAN-2 is about 29 J, and the friction sensitivity is more than 360 N.
In another embodiment, an adopted compound serving as the energetic material is (C6H14N2)[NH4(NO3)3] (which is recorded as DAN-4). An 2θ angle locating the characteristic peaks of a powder X-ray diffraction pattern (Cu-Kα X-ray) of the compound at the room temperature is about: 10.3±0.5°, 17.7±0.5°, 20.4±0.5°, 23.9±0.5°, 24.8±0.5°, 27.0±0.5°, 29.7±0.5°, 30.5±0.5°, 32.2±0.5° and 37.0±0.5°. A differential scanning calorimetry result shows that heat released at 170° C. is 1098 J/g.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 2. A schematic diagram of a three-dimensional crystal structure is shown in
[a]R1 = Σ||Fo| − |Fc||/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2|/Σw[(Fo)2]2}1/2
Infrared Spectral Characterization of DAP-1:
An infrared spectrum of DAP-1 is as shown in
Thermal Stability Characterization of DAP-1:
A thermogravimetric curve of DAP-1 is as shown in
Differential Scanning Calorimeter (DSC) of DAP-1:
A DSC curve of DAP-1 is as shown in
Impact, Friction, Thermal and Electrostatic Sensitivity Characterization of DAP-1:
Impact, friction and thermal sensitivity are tested according to the GJB772A-97 standard. The impact sensitivity is tested by a 601.1 explosive probability method. During the test (a hammer weight is 10 kg, and a drop height is 500 mm), the explosive probability of TNT is 9/25, but the explosive probability of DAP-1 is 0 percent. The friction sensitivity is tested by a 602.1 explosive probability method. During the test (2.45 MPa, and a swing angle of 80 degrees), the explosive probability of PETN is 2/25, but the explosive probability of DAP-1 is 0 percent. A thermal sensitivity test method is a 606.1 burst point 5 s-delay method. It measures that DAP-1 dramatically explodes at 340° C., which indicates that the burst point of DAP-1 is 340° C. An electrostatic sensitivity test method is the third section of an industrial initiating explosive material test method WJ/T 9038.3-2004: electrostatic spark sensitivity test. A half trigger voltage V50 of 25 mg of the test sample is 4.77 kV (a standard deviation is 0.21 kV), and half trigger energy E50 is 0.53 J, namely the electrostatic spark sensitivity of DAP-1 is 21.2 J.
According to a test method of Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-1 is about 17 J, and the friction sensitivity is about 36 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound DAP-1 are Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of DAP-1 is about 1.53 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 3.11 kcal/cm3 obtained by conversion of a crystal density at 223 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, DAP-1 has the detonation velocity of about 8.85 km/s and the detonation pressure of about 37.31 GPa, which are comparable to corresponding values of the active-duty energetic materials (HMX: the detonation velocity of 9.10 km/s and the detonation pressure of 39.50 GPa; RDX: the detonation velocity of 8.80 km/s and the detonation pressure of 33.80 GPa).
The Amount of Gas Produced by DAP-1 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-1 may produce 12 moles of gas substances after complete explosion in the oxygen-free environment, with 3 moles of elemental carbon and 1 mole of solid sodium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-1 per mole produces 1 mole of solid sodium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 4.
[a]R1 = Σ||Fo| − |Fc||/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]2}1/2
Thermal Stability Characterization of DAP-2:
A thermogravimetric curve of DAP-2 is as shown in
Differential Scanning Calorimeter (DSC) of DAP-2:
A DSC curve of DAP-2 is as shown in
Impact and Friction Sensitivity Characterization of DAP-2:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-2 is about 16 J, and the friction sensitivity is about 42 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound DAP-2 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of DAP-2 is about 1.46 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 3.01 kcal/cm3 obtained by conversion of a crystal density at 223 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, DAP-2 has the detonation velocity of about 8.64 km/s and the detonation pressure of about 35.73 GPa.
The Amount of Gas Produced by DAP-2 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-2 may produce 12 moles of gas substances after complete explosion in the oxygen-free environment, with 3 moles of elemental carbon and 1 mole of solid potassium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-2 per mole produces 1 mole of solid potassium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 6.
[a]R1 = Σ||Fo| − |Fc||/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]2}1/2
Thermal Stability Characterization of DAP-3:
A thermogravimetric curve of DAP-3 is as shown in
Differential Scanning Calorimeter (DSC) of DAP-3:
A DSC curve of DAP-3 is as shown in
Impact and Friction Sensitivity Characterization of DAP-3:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-3 is about 22 J, and the friction sensitivity is about 28 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound DAP-3 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of DAP-3 is about 1.33 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 2.92 kcal/cm3 obtained by conversion of a crystal density at 223 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, DAP-3 has the detonation velocity of about 8.43 km/s and the detonation pressure of about 35.14 GPa.
The Amount of Gas Produced by DAP-3 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-3 may produce 12 moles of gas substances after complete explosion in the oxygen-free environment, with 3 moles of elemental carbon and 1 mole of solid rubidium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-3 per mole produces 1 mole of solid rubidium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 8.
[a]R1 = Σ||Fo| − |Fc||/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]2}1/2
Thermal Stability Characterization of DAP-4:
A thermogravimetric curve of DAP-4 is as shown in
Differential Scanning Calorimeter (DSC) of DAP-4:
A DSC curve of DAP-4 is as shown in
Impact and Friction Sensitivity Characterization of DAP-4:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-4 is about 23 J, and the friction sensitivity is about 36 N.
The Amount of Gas Produced by DAP-4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-4 may produce 14.25 moles of gas substances after complete explosion in the oxygen-free environment, with 3.75 moles of elemental carbon remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-4 produces no solid residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 10.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2
Thermal Stability Characterization of DAP-O22:
A thermogravimetric curve of DAP-O22 is as shown in
Differential Scanning Calorimeter (DSC) of DAP-O22:
A DSC curve of DAP-O22 is as shown in
Impact and Friction Sensitivity Characterization of DAP-O22:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-O22 is about 11 J, and the friction sensitivity is about 14 N.
The Amount of Gas Produced by DAP-O22 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-O22 may produce 13 moles of gas substances after complete explosion in the oxygen-free environment, with 2 moles of elemental carbon and 1 mole of solid potassium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-O22 per mole produces 1 mole of solid potassium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction graph at the room temperature is as shown in
The Amount of Gas Produced by DAP-O12 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-O12 may produce 12.5 moles of gas substances after complete explosion in the oxygen-free environment, with 2.5 moles of elemental carbon and 1 mole of solid potassium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-O12 per mole produces 1 mole of solid potassium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Differential Scanning Calorimeter (DSC) of DAP-O24:
A DSC curve of DAP-O24 is as shown in
Impact and Friction Sensitivity Characterization of DAP-O24:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-O24 is about 4 J, and the friction sensitivity is about 32 N.
The Amount of Gas Produced by DAP-O24 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-O24 may produce 15.25 moles of gas substances after complete explosion in the oxygen-free environment, with 2.75 moles of elemental carbon remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-O24 produces no solid residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 14.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2
Thermal Stability Characterization of PAP-1:
A thermogravimetric curve of PAP-1 is as shown in
Differential Scanning Calorimeter (DSC) of PAP-1:
A DSC curve of PAP-1 is as shown in
The Amount of Gas Produced by PAP-1 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of PAP-1 may produce 11.5 moles of gas substances after complete explosion in the oxygen-free environment, with 0.5 moles of elemental carbon and 1 mole of solid sodium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, PAP-1 per mole produces 1 mole of solid sodium chloride residues after complete explosion.
Synthesis Method 1:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 15.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2.
Differential Thermal Analysis (DTA) of PAP-4:
A DTA curve of PAP-4 is as shown in
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound PAP-4 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of PAP-4 is about 1.43 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 2.47 kcal/cm3 obtained by conversion of a crystal density at 298 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, PAP-4 has the detonation velocity of about 8.63 km/s and the detonation pressure of about 32.4 GPa.
Differential Scanning Calorimeter (DSC) of PAP-4:
A DSC curve of PAP-4 is as shown in
The Amount of Gas Produced by PAP-4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of PAP-4 may produce 13.75 moles of gas substances after complete explosion in the oxygen-free environment, with 1.25 moles of elemental carbon remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, PAP-4 per mole produces no solid residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 17.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2.
Infrared Spectral Characterization of DAN-2:
An infrared spectrum of DAN-2 is as shown in
Thermal Stability Characterization of DAN-2:
A thermogravimetric curve of DAN-2 is as shown in
Differential Scanning Calorimeter (DSC) of DAN-2:
A DSC curve of DAN-2 is as shown in
Impact and Friction Sensitivity Characterization of DAN-2:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAN-2 is about 29 J, and the friction sensitivity is about 360 N.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 19.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2
Thermal Stability Characterization of DAN-4:
A thermogravimetric curve of DAN-4 is as shown in
Differential Scanning Calorimeter (DSC) of DAN-4:
A DSC curve of DAN-4 is as shown in
The Amount of Gas Produced by DAN-4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen and water, and solid substances such as elemental carbon (considering that oxygen atoms are preferentially combined with hydrogen atoms to form water). Therefore, 1 mole of DAN-4 may produce 12 moles of gas substances after complete explosion in the oxygen-free environment, with 6 moles of elemental carbon remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4NO3) is mixed, DAN-4 per mole produces no solid residues after complete explosion. Particularly, without halogen elements, DAN-4 does not produce hydrogen halide gas after explosion, thereby reducing characteristic signals in actual application, and relieving environmental pollution.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 21.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2;
Differential Thermal Analysis (DTA) of PAP-2:
A DTA curve of PAP-2 is as shown in
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound PAP-2 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of PAP-2 is about 1.50 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 3.03 kcal/cm3 obtained by conversion of a crystal density at 284 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, PAP-2 has the detonation velocity of about 8.78 km/s and the detonation pressure of about 36.6 GPa.
The Amount of Gas Produced by PAP-2 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as metal chlorides and elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of PAP-2 may produce 11.5 moles of gas substances after complete explosion in the oxygen-free environment, with 0.5 moles of elemental carbon and 1 mole of solid potassium chloride remaining. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, PAP-2 per mole produces 1 mole of solid potassium chloride residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 22.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2.
Differential Thermal Analysis (DTA) of DAP-O4:
A DTA curve of DAP-O4 is as shown in
Impact and Friction Sensitivity Characterization of DAP-O4:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-O4 is about 17.5 J, and the friction sensitivity is about 5 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound DAP-O4 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of DAP-O4 is about 1.48 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is higher than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 2.73 kcal/cm3 obtained by conversion of a crystal density at 298 K, which is also higher than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, PAP-M4 has the detonation velocity of about 8.90 km/s and the detonation pressure of about 35.7 GPa.
The Amount of Gas Produced by DAP-O4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-O4 may produce 14.75 moles of gas substances after complete explosion in the oxygen-free environment, with 3.25 moles of elemental carbon. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-O4 produces no solid residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 23.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2.
Differential Thermal Analysis (DTA) of PAP-M4:
A DTA curve of PAP-M4 is as shown in
Impact and Friction Sensitivity Characterization of PAP-M4:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of PAP-M4 is about 30 J, and the friction sensitivity is about 6 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound PAP-M4 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of PAP-M4 is about 1.23 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is lower than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 2.16 kcal/cm3 obtained by conversion of a crystal density at 298 K, which is also lower than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, PAP-M4 has the detonation velocity of about 8.63 km/s and the detonation pressure of about 32.4 GPa.
The Amount of Gas Produced by PAP-M4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of PAP-M4 may produce 14.25 moles of gas substances after complete explosion in the oxygen-free environment, with 2.75 moles of elemental carbon. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, PAP-M4 produces no solid residues after complete explosion.
Synthesis Method:
The powder X-ray diffraction diagram at the room temperature is as shown in
Single-Crystal Structure Characterization Test:
Detailed crystal test data are as shown in Table 24.
[a]R1 = Σ∥Fo] − |Fc∥/Σ|Fo|, [b]wR2 = {Σw[(Fo)2 − (Fc)2]2/Σw[(Fo)2]}1/2.
Differential Thermal Analysis (DTA) of DAP-M4:
A DTA curve of DAP-M4 is as shown in
Impact and Friction Sensitivity Characterization of DAP-M4:
According to a test method of a Federal Institute for Material Research and Testing (BAM), the impact sensitivity of DAP-M4 is about 7.5 J, and the friction sensitivity is about 10 N.
Detonation Heat, Detonation Pressure and Detonation Velocity Values of the Energetic Compound DAP-M4 Obtained Theoretically by the DFT:
A decomposition heat value (decomposition enthalpy value ΔHdet) of DAP-M4 is about 1.20 kcal/g calculated on the basis of the DFT (J. Am. Chem. Soc. 2012, 134, 1422), which is lower than those of active-duty energetic materials HMX (1.26 kcal/g) and RDX (1.27 kcal/g). An energy density is 2.15 kcal/cm3 obtained by conversion of a crystal density at 223 K, which is also lower than those of the active-duty energetic materials HMX (2.38 kcal/cm3) and RDX (2.29 kcal/cm3). According to a Kamlet-Jacob formula, DAP-M4 has the detonation velocity of about 8.08 km/s and the detonation pressure of about 28.8 GPa.
The Amount of Gas Produced by DAP-M4 Per Mole Number
For judgment on products obtained by complete explosion of the energetic material in an oxygen-free environment, according to a document (J. Am. Chem. Soc. 2012, 134, 1422; J. Phys. Chem. A. 2014, 118, 4575; Chem. Eur. J. 2016, 22, 1141), final decomposition products include gaseous substances such as nitrogen, halogen hydride, water and carbon dioxide, and solid substances such as elemental carbon (if oxygen atoms are not enough to completely convert all carbon atoms into the carbon dioxide). Therefore, 1 mole of DAP-M4 may produce 14.75 moles of gas substances after complete explosion in the oxygen-free environment, with 5.25 moles of elemental carbon. Under a condition that an enough amount of oxidant (such as commonly used NH4ClO4) is mixed, DAP-M4 produces no solid residues after complete explosion.
The perovskite-type energetic compound of the present application features high detonation heat, high energy density, high detonation velocity, high detonation pressure, high safety and extremely low impact, friction and electrostatic sensitivities, with non-volatile, non-decomposed and non-hygroscopic characteristics. The compound can be prepared in batches from cheap and readily-available raw materials through simple synthetic process which gives no by-products.
The perovskite-type energetic compound of the present application can produce some effects which are unexpectable in the prior art when used as energetic materials such as explosives. Although perchlorate anion is an energetic ligand, most of the perchlorate-containing compounds at present cannot be used as practical energetic materials due to various disadvantages (see “High Energy Materials: Propellants, Explosives and Pyrotechnics”, p. 28, Jai Prakash Agrawal, Wiley-VCH Press, 2010). For example, common perchlorate salts such as sodium perchlorate and lithium perchlorate are highly hygroscopic in nature, and potassium perchlorate was used as a pro-oxidant for flash bombs, but later it was found to have excessive impact sensitivity and easy to explode during transportation. The theoretical detonation heat of ammonium perchlorate, which is still classified as an explosive, is only 1972 J/g, which is far below the detonation heat level of the energetic compound of the present application. However, even if the perovskite-type compound of the present application contains such explosive ligands, it can still maintain the excellent thermal stability and non-hygroscopic characteristic, which makes it an energetic material with high safety and easy storage. At the same time, due to the rich energetic ligands, the alternatively arranged oxidizing energetic anions and reducing organic cations in the space, high crystal density, powerful instantaneous burst capability, high energy density, and high detonation heat, detonation pressure and detonation velocity, the perovskite-type energetic compound, as explosives, has made a great leap in performance compared with the prior art.
The above-mentioned embodiments are preferred embodiments of the present application, but the embodiments of the present application are not limited by the above-mentioned embodiments. Any other variations, modifications, replacements, combinations and simplifications that are made without departing from the spiritual essence and theory of the present application shall all be equivalent substitute modes and fall within the protection scope of the present application.
| Number | Date | Country | Kind |
|---|---|---|---|
| 201610665880.3 | Aug 2016 | CN | national |
This application is a continuation-in-part of U.S. application Ser. No. 16/099,486, filed Nov. 7, 2018, which is a National Stage of International Application No. PCT/CN2017/097136, filed Aug. 11, 2017, and which claims the benefit of priority based on Chinese Patent Application No. 201610665880.3 filed Aug. 12, 2016, the contents of all of which are incorporated herein by reference in their entireties.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4552598 | Lee et al. | Nov 1985 | A |
| Number | Date | Country |
|---|---|---|
| 101570459 | Nov 2009 | CN |
| 103396281 | Nov 2013 | CN |
| 104733617 | Jun 2015 | CN |
| 105514276 | Apr 2016 | CN |
| 105777458 | Jul 2016 | CN |
| 106278771 | Jan 2017 | CN |
| 2005-179168 | Jul 2005 | JP |
| 99122472 | Sep 2001 | RU |
| 2522611 | Apr 2012 | RU |
| 9836938 | Aug 1998 | WO |
| 2014191767 | Dec 2014 | WO |
| 2016113321 | Jul 2016 | WO |
| 2018028685 | Feb 2018 | WO |
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| Number | Date | Country | |
|---|---|---|---|
| 20210269375 A1 | Sep 2021 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16099486 | US | |
| Child | 17132109 | US |
