The present invention relates to a phosphor substrate, a light emitting substrate, and a lighting device.
Patent Document 1 discloses an LED lighting equipment including a substrate on which a light emitting element (LED element) is mounted. In this LED lighting equipment, a reflective material is provided on a surface of the substrate to improve light emitting efficiency.
[Patent Document 1] Chinese Patent Publication No. 106163113
However, in a case of a configuration disclosed in Patent Document 1, it is not possible to adjust light emitted by the LED lighting equipment by the reflective material to light having a light emission color different from the light emitted by the light emitting element.
An object of the present invention is to provide a phosphor substrate capable of adjusting light emitted from the phosphor substrate, in a case where a light emitting element is mounted, to light having an emission color different from light emitted by the light emitting element.
A phosphor substrate according to a first aspect of the present invention is a phosphor substrate having at least one light emitting element mounted on one surface, and includes an insulating substrate, at least one pair of electrode pair which is disposed on one surface of the insulating substrate and bonded to the light emitting element, and a phosphor layer which is disposed on one surface of the insulating substrate and includes a phosphor in which a light emission peak wavelength, in a case where light emitted by the light emitting element is used as excitation light, is in a visible light region.
A phosphor substrate according to a second aspect of the present invention is a phosphor substrate having a plurality of light emitting elements mounted on one surface, and includes an insulating substrate, a plurality of electrode pairs which are disposed on one surface of the insulating substrate and bonded to the plurality of light emitting elements, and a phosphor layer which is disposed on one surface of the insulating substrate and includes a phosphor in which a light emission peak wavelength, in a case where light emitted by the plurality of light emitting element is used as excitation light, is in a visible light region.
In the phosphor substrate according to a third aspect of the present invention according to the phosphor substrate according to the second aspect, each of the plurality of electrode pairs is a part of an electrode layer disposed on one surface of the insulating substrate, and a region of the one surface of the insulating substrate, where the electrode layer is disposed is a region which is equal to or more than 60% of the one surface of the insulating substrate.
In the phosphor substrate according to a fourth aspect of the present invention according to the phosphor substrate according to the third aspect, at least a part of the phosphor layer is disposed in a region other than a region of the one surface of the insulating substrate where the plurality of electrode pairs are disposed.
In the phosphor substrate according to a fifth aspect of the present invention according to the phosphor substrate according to the third or fourth aspect, at least a part of the phosphor layer is disposed in a region of the electrode layer other than the plurality of electrode pairs.
In the phosphor substrate according to a sixth aspect of the present invention according to the phosphor substrate according to any one of the second to fifth aspects, a region of the one surface of the insulating substrate, where the phosphor layer is disposed, is a region that is equal to or more than 80% of the one surface of the insulating substrate.
In the phosphor substrate according to a seventh aspect of the present invention according to the phosphor substrate according to any one of the first to sixth aspects, the phosphor layer is a CASN phosphor containing Eu, and at least a surface of the at least one electrode pair is formed to contain copper.
In the phosphor substrate according to an eighth aspect of the present invention according to the phosphor substrate according to any one of the first to seventh aspects, the light emitting element is formed as a chip sized package (CSP) in which an LED is incorporated.
In the phosphor substrate according to a ninth aspect of the present invention according to the phosphor substrate according to the eighth aspect, a correlated color temperature of the phosphor is set to a correlated color temperature which is different from a correlated color temperature of a phosphor contained in the CSP.
Here, the “correlated color temperature of the phosphor” means a correlated color temperature of the light emission color of the phosphor (hereinafter, the same applies).
In the phosphor substrate according to a tenth aspect of the present invention according to the phosphor substrate according to the eighth aspect, a correlated color temperature of the phosphor is set to a correlated color temperature which is the same as a correlated color temperature of a phosphor contained in the CSP.
Alight emitting substrate according to the first aspect of the present invention includes the phosphor substrate according to any one aspect of the first to tenth aspects, and at least one light emitting element bonded to the at least one electrode pair.
In the light emitting substrate according to the second aspect of the present invention according to the light emitting substrates according to the first aspect, the light emitting element is formed as a chip sized package (CSP) in which an LED is incorporated.
In the light emitting substrate according to a third aspect of the present invention according to the light emitting substrate according to the second aspect, a correlated color temperature of the phosphor is set to a correlated color temperature which is different from a correlated color temperature of a phosphor contained in the CSP.
In the light emitting substrate of a fourth aspect of the present invention according to the light emitting substrate of the second aspect, a correlated color temperature of the phosphor is set to a correlated color temperature which is the same as a correlated color temperature of a phosphor contained in the CSP.
A lighting device of the present invention includes the light emitting substrate according to any one of the first to fourth aspects, and a power source which supplies electric power for causing the light emitting element to emit light.
According to the phosphor substrate according to the first and seventh aspects of the present invention, it is possible to adjust light emitted from the phosphor substrate, in a case where a light emitting element is mounted, to light having an emission color different from light emitted by the light emitting element.
In addition, in the phosphor substrate according to the second to tenth aspects of the present invention, it is possible to reduce glare while adjusting light emitted from the phosphor substrate, in a case where a light emitting element is mounted, to light having an emission color different from light emitted by the light emitting element. Further, the phosphor substrate according to the tenth aspect of the present invention can also exhibit an effect of alleviating a chromaticity variation of the mounted light emitting element by the phosphor layer.
In addition, in the light emitting substrate of the present invention, it is possible to adjust light emitted from the phosphor substrate to light having an emission color different from light emitted by the light emitting element.
The objects described above, other objects, features and advantages will be further clarified by the preferred embodiments which will be described later and the accompanying drawings below.
«Overview»
Hereinafter, a configuration and function of a light emitting substrate 10 of the present embodiment will be described with reference to
«Configuration and Function of Light Emitting Substrate of Present Embodiment»
The light emitting substrate 10 of the present embodiment is rectangular as an example, when seen from the front surface 31 and the rear surface 33. In addition, the light emitting substrate 10 of the present embodiment includes a plurality of light emitting elements 20, a phosphor substrate 30, and electronic components (not shown) such as a connector, a driver IC, and the like. That is, in the light emitting substrate 10 of the present embodiment, the plurality of light emitting elements 20 and the electronic components are mounted on the phosphor substrate 30.
The light emitting substrate 10 of the present embodiment has a function of emitting light, in a case where power is supplied from an external power source (not shown) by directly attaching a lead wire or through a connector. Accordingly, the light emitting substrate 10 of the present embodiment is used as a main optical component in, for example, a lighting device (not shown).
<Plurality of Light Emitting Elements>
As an example, each of the plurality of light emitting elements 20 is formed as a Chip Scale Package (CSP) in which a flip chip LED 22 (hereinafter, referred to as an LED 22) is incorporated (see
<Phosphor Substrate>
The phosphor substrate 30 of the present embodiment includes an insulating layer 32 (an example of an insulating substrate), an electrode layer 34, a phosphor layer 36, and a rear surface pattern layer 38 (see
In addition, as shown in
[Insulating Layer]
Hereinafter, main features of the insulating layer 32 of the present embodiment will be described.
As described above, a shape thereof is, for example, rectangular when seen from the front surface 31 and the rear surface 33.
A material thereof is, for example, an insulating material containing a bismaleimide resin and a glass cloth.
A thickness thereof is, for example, 100 μm to 200 μm.
Coefficients of thermal expansion (CTE) thereof in a vertical direction and a horizontal direction are, for example, equal to or less than 10 ppm/° C. in a range of 50° C. to 100° C., respectively. From another point of view, each of the coefficients of thermal expansion (CTE) in the vertical direction and the horizontal direction is, for example, 6 ppm/K. This value is substantially the same as that of the light emitting element 20 of the present embodiment (90% to 110%, that is, within ±10%).
A glass transition temperature thereof is, for example, higher than 300° C.
A storage elastic modulus is, for example, greater than 1.0×1010 Pa and smaller than 1.0×1011 Pa in a range of 100° C. to 300° C.
[Electrode Layer]
The electrode layer 34 of the present embodiment is a metal layer provided on the front surface 31 side of the insulating layer 32. The electrode layer 34 of this embodiment is, for example, a copper foil layer (a layer formed of Cu). In other words, the electrode layer 34 of the present embodiment is formed so that at least the surface thereof contains copper.
The electrode layer 34 has a pattern provided on the insulating layer 32, and is electrically connected to a terminal (not shown) to which a connector (not shown) is bonded. The electrode layer 34 supplies electric power supplied from an external power source (not shown) through the connector to the plurality of light emitting elements 20 at the time of configuring the light emitting substrate 10. Accordingly, a part of the electrode layer 34 is the plurality of electrode pairs 34A to which the plurality of light emitting elements 20 are bonded. In addition, as described above, since the plurality of light emitting elements 20 of the light emitting substrate 10 of the present embodiment are regularly arranged over the entire front surface 31, the plurality of electrode pairs 34A are also arranged over the entire front surface 31 (see
A region of the front surface 31 of the insulating layer 32 where the electrode layer 34 is disposed (occupied area of the electrode layer 34) is, for example, a region (area) that is equal to or more than 60% of the front surface 31 of the insulating layer 32 (see
[Phosphor Layer]
As shown in
The phosphor layer 36 of the present embodiment is, for example, an insulating layer containing a phosphor and a binder, which will be described later. The phosphor contained in the phosphor layer 36 is fine particles held in a state of being dispersed in a binder, and has a property of exciting the light emitted from the LED 22 of each light emitting element 20 as excitation light. Specifically, the phosphor of the present embodiment has a property that the light emission peak wavelength when the light emitted by the light emitting element 20 is used as excitation light is in a visible light region. The binder may be, for example, an epoxy-based binder, an acrylate-based binder, or a silicone-based binder, and may have an insulating property equivalent to that of the binder contained in a solder resist.
(Specific Example of Phosphor)
Here, the phosphor contained in the phosphor layer 36 of the present embodiment is, for example, at least one or more phosphors selected from the group consisting of an α-type sialon phosphor containing Eu, a β-type sialon phosphor containing Eu, a CASN phosphor containing Eu, and a SCASN phosphor containing Eu. The phosphor described above is an example of the present embodiment, and may be a phosphor other than the phosphor described above, such as YAG, LuAG, BOS, and other visible light-excited phosphors.
The α-type sialon phosphor containing Eu is represented by general formula: MxEuySi12−(m+n)Al(m+n)OnN16−n. In the above general formula, M is at least one or more elements containing at least Ca selected from the group consisting of Li, Mg, Ca, Y, and lanthanide elements (here, excluding La and Ce), and in a case where a valence of M is a, ax+2y=m, x satisfies 0<x≤1.5, 0.3≤m<4.5, and 0<n<2.25.
The β-type sialon phosphor containing Eu is a phosphor in which divalent europium (Eu2+) is dissolved as a light emitting center in β-type sialon represented by general formula: Si6−zAlzOzN8−z (z=0.005 to 1).
In addition, examples of a nitride phosphor include a CASN phosphor containing Eu, a SCASN phosphor containing Eu, and the like.
The CASN phosphor containing Eu (an example of a nitride phosphor) is, for example, a red phosphor which is represented by the formula CaAlSiN3:Eu2+ in which Eu2+ is used as an activator and a crystal formed of alkaline earth silicate is used as a base. In the definition of the CASN phosphor containing Eu in the present specification, the SCASN phosphor containing Eu is excluded.
The SCASN phosphor containing Eu (an example of a nitride phosphor) is, for example, a red phosphor which is represented by the formula (Sr, Ca)AlSiN3:Eu2+ in which Eu2+ is used as an activator and a crystal formed of alkaline earth silicate is used as a base.
[Rear Surface Pattern Layer]
The rear surface pattern layer 38 of the present embodiment is a metal layer provided on the rear surface 33 side of the insulating layer 32. The rear surface pattern layer 38 of this embodiment is, for example, a copper foil layer (a layer formed of Cu).
As shown in
The rear surface pattern layer 38 is, for example, an independent floating layer. In addition, the rear surface pattern layer 38 overlaps with the region that is equal to or more than 80% of the electrode layer 34 disposed on the front surface 31, for example, in a thickness direction of the insulating layer 32 (phosphor substrate 30).
The above is the description of the configuration of the light emitting substrate 10 and the phosphor substrate 30 of the present embodiment.
«Method for Manufacturing Light Emitting Substrate of Present Embodiment»
Next, a method for manufacturing the light emitting substrate 10 of the present embodiment will be described with reference to
<First Step>
<Second Step>
<Third Step>
<Fourth Step>
<Fifth Step>
The above is the description of the method for manufacturing the light emitting substrate 10 of the present embodiment.
«Light Emitting Operation of Light Emitting Substrate of Present Embodiment»
Next, the light emitting operation of the light emitting substrate 10 of the present embodiment will be described with reference to
First, in a case where an operation switch (not shown) for operating the plurality of light emitting elements 20 is turned on, the power supply is started from the external power source (not shown) to the electrode layer 34 through the connector (not shown), the plurality of light emitting elements 20 emit light L radially, and some light L reaches the front surface 31 of the phosphor substrate 30. Hereinafter, the behavior of the light L will be described separately according to a traveling direction of the emitted light L.
Some light L emitted from each light emitting element 20 is emitted to the outside without being incident to the phosphor layer 36. In this case, a wavelength of the light L remains as the same as the wavelength of the light L, in a case of being emitted from each light emitting element 20.
In addition, the light of the LED 22 itself in some light L emitted from each light emitting element 20 is incident to the phosphor layer 36. Here, the “light of the LED 22 itself in some light L” described above is light of the emitted light L that is not color-converted by the phosphor (phosphor sealing layer 24) of each light emitting element 20 (CSP itself), that is, light of the LED 22 itself (for example, blue (wavelength is approximately 470 nm) color). Then, in a case where the light L of the LED 22 itself collides with the phosphor dispersed in the phosphor layer 36, the phosphor excites and emits excitation light. Here, the reason why the phosphor is excited is that the phosphor dispersed in the phosphor layer 36 uses a phosphor (visible light excited phosphor) having an excitation peak in blue light. Along with this, a part of the energy of the light L is used for exciting the phosphor, so that the light L loses a part of the energy. As a result, the wavelength of the light L is converted (wavelength conversion is performed). For example, depending on the type of phosphor in the phosphor layer 36 (for example, in a case where a red CASN is used as the phosphor), the wavelength of light L becomes longer (for example, 650 nm or the like). In addition, the excitation light in the phosphor layer 36 may be emitted from the phosphor layer 36 as it is, but some of the excitation light goes to the lower electrode layer 34. Then, some of the excitation light is emitted to the outside by reflection on the electrode layer 34. As described above, in a case where the wavelength of the excitation light by the phosphor of the phosphor layer 36 is equal to or more than 600 nm, the reflection effect can be expected, even if the electrode layer 34 is formed of Cu. The wavelength of the light L differs from the above example depending on the type of the phosphor in the phosphor layer 36, but in any case, the wavelength conversion of the light L is performed. For example, in a case where the wavelength of the excitation light is less than 600 nm, a reflection effect can be expected, if the electrode layer 34 or its surface is formed of, for example, Ag (plating). In addition, a white reflective layer may be provided on the lower side (insulating layer 32 side) of the phosphor layer 36. The reflective layer is provided with, for example, a white coating material such as a titanium oxide filler.
As described above, the light L emitted by each light emitting element 20 (the light L emitted radially by each light emitting element 20) is irradiated to the outside together with the excitation light through a plurality of optical paths as described above. Therefore, in a case where a light emission wavelength of the phosphor contained in the phosphor layer 36 and a light emission wavelength of the phosphor (phosphor sealing layer 24) that seals (or covers) the LED 22 of the light emitting element 20 (CSP) are different from each other, the light emitting substrate 10 of the present embodiment emits a bundle of the light L, in a case of being emitted by each light emitting element 20, by setting it as a bundle of the light L containing the light L at a wavelength different from the wavelength of the light L, in a case of being emitted by each light emitting element 20, together with the excitation light. For example, the light emitting substrate 10 of the present embodiment emits a bundle of the light L, in a case of being emitted by each light emitting element 20, by setting it as a bundle of the light L containing the light L at a wavelength longer than the wavelength of the light L, in a case of being emitted by each light emitting element 20, together with the excitation light.
Meanwhile, in a case where a light emission wavelength of the phosphor contained in the phosphor layer 36 and a light emission wavelength of the phosphor (phosphor sealing layer 24) that seals (or covers) the LED 22 of the light emitting element 20 (CSP) are the same as each other (in a case of the same correlated color temperature), the light emitting substrate 10 of the present embodiment emits a bundle of the light L, in a case of being emitted by each light emitting element 20, by setting it as a bundle of the light L containing the light L at a wavelength same as the wavelength of the light L, in a case of being emitted by each light emitting element 20, together with the excitation light.
The above is the description of the light emitting operation of the light emitting substrate 10 of the present embodiment.
«Effect of Present Embodiment»
Next, the effect of the present embodiment will be described with reference to the drawings.
<First Effect>
The first effect will be described by comparing the present embodiment with a comparative embodiment (see
In the case of the light emitting substrate 10A of the comparative embodiment, the light L emitted from each light emitting element 20 and incident to the front surface 31 of the substrate 30A is reflected or scattered without converting the wavelength. Accordingly, in the case of the substrate 30A of the comparative embodiment, it is not possible to adjust the light to light having light emission color different from the light emitted by the light emitting element 20, in a case where the light emitting element 20 is mounted. That is, in a case of the light emitting substrate 10A of the comparative embodiment, it is not possible to adjust the light to light having light emission color different from the light emitted by the light emitting element 20.
On the other hand, in a case of the present embodiment, the phosphor layer 36 is provided on the front surface 31 of the insulating layer 32. Accordingly, some of the light L emitted from each light emitting element 20 is incident to the phosphor layer 36, wavelength-converted by the phosphor layer 36, and irradiated to the outside. In this case, some of the light L radially emitted from each light emitting element 20 is incident to the phosphor layer 36 to excite the phosphor contained in the phosphor layer 36 and generate the excitation light.
Here,
The first test is a test to obtain a result by investigating a relationship between a current (mA) and a correlated color temperature (K) of the plurality of light emitting elements 20, in a case where the power is supplied to the light emitting substrate 10 including the plurality of light emitting elements 20 having the correlated color temperature approximately at 2200 K to 2300 K to generate light. Here, HE (1) and HE (2) indicate a case where the structure of the electrode layer 34 is the same as that of the present embodiment, and FLT (1) and FLT (2) indicate a case where thicknesses of the pair of electrode pair 34A and the wiring portion 34B of the electrode layer 34 are the same (modification example). As the result of
In addition, the second test is a test to obtain a result by investigating a relationship between a current (mA) and a correlated color temperature (K) of the plurality of light emitting elements 20, in a case where the power is supplied to the light emitting substrate 10 including the plurality of light emitting elements 20 having the correlated color temperature approximately at 2900 K to 3000 K to generate light. Here, HE (1) indicates a case where the structure of the electrode layer 34 is the same structure as that of the present embodiment, and FLT (1) and FLT (2) indicate a case where thicknesses of the pair of electrode pair 34A and the wiring portion 34B of the electrode layer 34 are the same (modification example). As the result of
Therefore, according to the phosphor substrate 30 of the present embodiment, in a case where the light emitting element 20 is mounted, it is possible to adjust the light L emitted from the phosphor substrate 30 to light having a light emission color different from the light L emitted by the light emitting element 20. Along with this, according to the light emitting substrate 10 of the present embodiment, it is possible to adjust the light L emitted from the phosphor substrate 30 to the light L having a light emission color different from the light L emitted by the light emitting element 20. From another point of view, according to the light emitting substrate 10 of the present embodiment, it is possible to irradiate the outside with light L having a light emission color different from the light L emitted by the light emitting element 20.
Meanwhile, in a case where a light emission wavelength of the phosphor contained in the phosphor layer 36 and a light emission wavelength of the phosphor (phosphor sealing layer 24) that seals (or covers) the LED 22 of the light emitting element 20 (CSP) are the same as each other (in a case of the same correlated color temperature), the light emitting substrate 10 of the present embodiment emits a bundle of the light L, in a case of being emitted by each light emitting element 20, by setting it as a bundle of the light L containing the light L at a wavelength same as the wavelength of the light L, in a case of being emitted by each light emitting element 20, together with the excitation light. In this case, it is possible to exhibit the effect of alleviating a chromaticity variation of the mounted light emitting element 20 by the phosphor layer 36.
<Second Effect>
In the case of the comparative embodiment, as shown in
On the other hand, in a case of the present embodiment, as shown in
Therefore, according to the present embodiment, it is possible to reduce the glare, compared to the comparative embodiment.
In particular, this effect is effective, in a case where the phosphor layer 36 is provided over the entire surface of the insulating layer 32, specifically, in a case where a region of the front surface 31 of the insulating layer 32 where the phosphor layer 36 is disposed is a region that is 80% or more of the front surface 31.
<Third Effect>
In addition, in the present embodiment, as described above, the phosphor layer 36 is provided between the adjacent light emitting elements 20 (see
<Fourth Effect>
In addition, in a case of the present embodiment, for example, the phosphor contained in the phosphor layer 36 is a CASN phosphor containing Eu, and the phosphor layer 36 is provided on the wiring portion 34B formed of Cu. Accordingly, for example, in a case where each light emitting element 20 emits white light L, the excitation light from the CASN phosphor contained in the phosphor layer 36 has an improved light emission efficiency due to reflection by Cu constituting a lower layer electrode (in the configuration of the present embodiment, there is a light reflection effect of Cu). Then, in the present embodiment, by the effect, it is possible to adjust the white light L to a warmer color light (color in which the correlated color temperature is shifted to the lower temperature side) (see
<Fifth Effect>
In addition, as described above, the plurality of light emitting elements 20 use a heat sink (not shown) and a cooling fan (not shown) during the light emitting operation to dissipate heat (cool) the phosphor substrate 30 to be, for example, room temperature to 50° C. to 100° C. Accordingly, the heat generated in a case of light emission of the LED 22 is diffused to the entire substrate to enhance the heat-drawing effect on the housing. In a case of the present embodiment, a region of the front surface 31 of the insulating layer 32 where the electrode layer 34 is disposed (occupied area of the electrode layer 34) is, for example, a region (area) that is equal to or more than 60% of the front surface 31 of the insulating layer 32 (see
Accordingly, the electrode layer 34 (wiring portion 34B) of the present embodiment functions as a heat radiating plate for heat generated from the plurality of light emitting elements 20, in addition to the function as an electric path for power supply. Therefore, the light emitting element 20 (LED 22) can stably emit light L in a situation where it is not easily affected by heat.
The above is the description of the effect of the present embodiment.
As described above, the present invention has been described with reference to the embodiments and examples described above, but the present invention is not limited to the embodiments and examples described above. The technical scope of the present invention also includes, for example, the following embodiments (modification example).
For example, in the description of the present embodiment, an example of the light emitting element 20 is a CSP. However, an example of the light emitting element 20 may be other than the CSP. For example, it may simply be equipped with a flip chip. In addition, it can also be applied to the substrate itself of a COB device.
In addition, in the description of the present embodiment, the plurality of light emitting elements 20 are mounted on the phosphor substrate 30 and the light emitting substrate 10 includes the plurality of light emitting elements 20 (see
In addition, in the description of the present embodiment, the rear surface pattern layer 38 is provided on the rear surface 33 of the phosphor substrate 30 (see
In addition, in the description of the present embodiment, the phosphor layer 36 is, for example, disposed on a portion of the front surface 31 of the insulating layer 32 and the electrode layer 34, other than the plurality of electrode pairs 34A (see
In addition, in the description of the present embodiment, it has been described that CS-3305A manufactured by Risho Kogyo Co., Ltd. is used as the motherboard MB in manufacturing the phosphor substrate 30 and the light emitting substrate 10. However, this is merely an example, and different motherboard MBs may be used.
The light emitting substrate 10 of the present embodiment (including the modification example thereof) can be applied to a lighting device in combination with other constituent elements. Other constituent elements in this case are a power source that supplies electric power for causing the light emitting element 20 of the light emitting substrate 10 to emit light, and the like.
This application claims priority based on Japanese Patent Application No. 2018-244542 filed on Dec. 27, 2018, the entire disclosure of which is incorporated herein.
Number | Date | Country | Kind |
---|---|---|---|
2018-244542 | Dec 2018 | JP | national |
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/JP2019/049687 | 12/18/2019 | WO |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2020/137760 | 7/2/2020 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
7391060 | Oshio | Jun 2008 | B2 |
7825575 | Sawanobori et al. | Nov 2010 | B2 |
8143634 | Park et al. | Mar 2012 | B2 |
8232709 | Betsuda et al. | Jul 2012 | B2 |
8558438 | Zimmerman et al. | Oct 2013 | B2 |
8563338 | Park et al. | Oct 2013 | B2 |
8680546 | Konishi et al. | Mar 2014 | B2 |
8704258 | Tasaki et al. | Apr 2014 | B2 |
8772807 | Lin | Jul 2014 | B2 |
8796713 | Lin | Aug 2014 | B2 |
8835970 | Konishi et al. | Sep 2014 | B2 |
9006006 | Konishi | Apr 2015 | B2 |
9178125 | Konishi et al. | Nov 2015 | B2 |
9341563 | Amari | May 2016 | B2 |
9461224 | Konishi et al. | Oct 2016 | B2 |
9553245 | Kamada | Jan 2017 | B2 |
9574050 | Tasaki et al. | Feb 2017 | B2 |
9673364 | Nakabayashi | Jun 2017 | B2 |
9681502 | Oyamada et al. | Jun 2017 | B2 |
9728691 | Liaw | Aug 2017 | B2 |
9874318 | Su et al. | Jan 2018 | B2 |
9960332 | Konishi et al. | May 2018 | B2 |
9978915 | Weng et al. | May 2018 | B2 |
10128421 | Nakabayashi | Nov 2018 | B2 |
10230032 | Baike | Mar 2019 | B2 |
10347798 | Dai et al. | Jul 2019 | B2 |
10522729 | Nakabayashi | Dec 2019 | B2 |
10533094 | Tasaki et al. | Jan 2020 | B2 |
10755856 | Kim et al. | Aug 2020 | B2 |
10797209 | Chen et al. | Oct 2020 | B2 |
10825695 | Baike | Nov 2020 | B2 |
10916496 | Kita | Feb 2021 | B2 |
20050139851 | Sato | Jun 2005 | A1 |
20070064131 | Sawanobori et al. | Mar 2007 | A1 |
20070259206 | Oshio | Nov 2007 | A1 |
20090050909 | Chen et al. | Feb 2009 | A1 |
20090072256 | Park et al. | Mar 2009 | A1 |
20090217970 | Zimmerman et al. | Sep 2009 | A1 |
20090315057 | Konishi et al. | Dec 2009 | A1 |
20100238648 | Tsukahara | Sep 2010 | A1 |
20110089805 | Betsuda et al. | Apr 2011 | A1 |
20120080702 | Lin | Apr 2012 | A1 |
20120080703 | Lin | Apr 2012 | A1 |
20120138997 | Tasaki et al. | Jun 2012 | A1 |
20120142127 | Park et al. | Jun 2012 | A1 |
20130011617 | Tasaki et al. | Jan 2013 | A1 |
20130161662 | Imai | Jun 2013 | A1 |
20140159092 | Konishi et al. | Jun 2014 | A1 |
20140361331 | Konishi et al. | Dec 2014 | A1 |
20150001563 | Miki | Jan 2015 | A1 |
20150008462 | Weng et al. | Jan 2015 | A1 |
20150021642 | Nakabayashi | Jan 2015 | A1 |
20150049481 | Oyamada et al. | Feb 2015 | A1 |
20150060911 | Chien et al. | Mar 2015 | A1 |
20150155441 | Alexeev | Jun 2015 | A1 |
20150185137 | Amari | Jul 2015 | A1 |
20150228869 | Yoo et al. | Aug 2015 | A1 |
20150276152 | Su et al. | Oct 2015 | A1 |
20160005939 | Andrews | Jan 2016 | A1 |
20160013387 | Konishi et al. | Jan 2016 | A1 |
20160064628 | Fujii et al. | Mar 2016 | A1 |
20160161067 | Depts et al. | Jun 2016 | A1 |
20160190408 | Kamada | Jun 2016 | A1 |
20160219690 | Itoh | Jul 2016 | A1 |
20160359095 | Konishi et al. | Dec 2016 | A1 |
20170025582 | Dai et al. | Jan 2017 | A1 |
20170025588 | Weng et al. | Jan 2017 | A1 |
20170054063 | Liaw | Feb 2017 | A1 |
20170084799 | Ouderkirk et al. | Mar 2017 | A1 |
20170114226 | Tasaki et al. | Apr 2017 | A1 |
20170196060 | Watanabe | Jul 2017 | A1 |
20170229621 | Chen et al. | Aug 2017 | A1 |
20170236981 | Nakabayashi | Aug 2017 | A1 |
20170317250 | Konishi et al. | Nov 2017 | A1 |
20180033929 | Baike | Feb 2018 | A1 |
20190035716 | Kita | Jan 2019 | A1 |
20190081222 | Nakabayashi | Mar 2019 | A1 |
20190172989 | Baike | Jun 2019 | A1 |
20190227672 | Nishimura | Jul 2019 | A1 |
20200091384 | Nakabayashi | Mar 2020 | A1 |
20200092994 | Toshimitsu et al. | Mar 2020 | A1 |
20200095430 | Tasaki et al. | Mar 2020 | A1 |
20200350122 | Kim et al. | Nov 2020 | A1 |
20220052233 | Konishi | Feb 2022 | A1 |
20220085253 | Konishi | Mar 2022 | A1 |
Number | Date | Country |
---|---|---|
1967888 | May 2007 | CN |
101606247 | Dec 2009 | CN |
102074558 | May 2011 | CN |
103346241 | Oct 2013 | CN |
103579480 | Feb 2014 | CN |
103904072 | Jul 2014 | CN |
203839375 | Sep 2014 | CN |
106163113 | Nov 2016 | CN |
106356439 | Jan 2017 | CN |
109075131 | Dec 2018 | CN |
3 546 895 | Oct 2019 | EP |
3546825 | Oct 2019 | EP |
H10-151794 | Jun 1998 | JP |
2000-11953 | Jan 2000 | JP |
2001-148509 | May 2001 | JP |
2001-148512 | May 2001 | JP |
2003-258311 | Sep 2003 | JP |
2006-049799 | Feb 2006 | JP |
2006-261688 | Sep 2006 | JP |
2007-080994 | Mar 2007 | JP |
2008-066691 | Mar 2008 | JP |
2009-071264 | Apr 2009 | JP |
2009-267289 | Nov 2009 | JP |
2010-034487 | Feb 2010 | JP |
2012-094578 | May 2012 | JP |
2012-146942 | Aug 2012 | JP |
2012-186274 | Sep 2012 | JP |
2012186274 | Sep 2012 | JP |
2013-012607 | Jan 2013 | JP |
2013-115368 | Jun 2013 | JP |
2014-003065 | Jan 2014 | JP |
2014-220431 | Nov 2014 | JP |
2015-037170 | Feb 2015 | JP |
2015-038963 | Feb 2015 | JP |
2015-103632 | Jun 2015 | JP |
2015-198252 | Nov 2015 | JP |
2015-216139 | Dec 2015 | JP |
2016-69401 | May 2016 | JP |
2016-122693 | Jul 2016 | JP |
2016-139632 | Aug 2016 | JP |
2016-525798 | Aug 2016 | JP |
2017-041621 | Feb 2017 | JP |
2017-058635 | Mar 2017 | JP |
2017-175118 | Sep 2017 | JP |
2018-18979 | Feb 2018 | JP |
2018-082027 | May 2018 | JP |
2018-191006 | Nov 2018 | JP |
2019-093339 | Jun 2019 | JP |
10-2013-0104975 | Sep 2013 | KR |
200903843 | Jan 2009 | TW |
200910630 | Mar 2009 | TW |
201214786 | Apr 2012 | TW |
M496850 | Mar 2015 | TW |
201532304 | Aug 2015 | TW |
201709563 | Mar 2017 | TW |
2010150880 | Dec 2010 | WO |
2013153739 | Oct 2013 | WO |
2014181757 | Nov 2014 | WO |
2018059599 | Apr 2018 | WO |
Entry |
---|
Kuboyama et al.; “An approach to the thermal expansion coefficient of IC chips and excellent cost performace;” Rishio News; 2014; pp. 7-9; No. 192. |
Mar. 24, 2020 Search Report issued in International Patent Application No. PCT/JP2019/049691. |
Mar. 17, 2020 Search Report issued in International Patent Application No. PCT/JP2019/049689. |
Mar. 3, 2020 Search Report issued in International Patent Application No. PCT/JP2019/049690. |
Mar. 17, 2020 Search Report issued in International Patent Application No. PCT/JP2019/049688. |
Mar. 17, 2020 Search Report issued in International Patent Application No. PCT/JP2019/049687. |
U.S. Appl. No. 17/414,643, filed Jun. 16, 2021 in the name of Konishi. |
U.S. Appl. No. 17/415,443, filed Jun. 17, 2021 in the name of Konishi. |
U.S. Appl. No. 17/415,448, filed Jun. 17, 2021 in the name of Konishi. |
U.S. Appl. No. 17/415,433, filed Jun. 17, 2021 in the name of Konishi. |
Jan. 19, 2022 extended Search Report issued in European Patent Application No. 19905946.0. |
Jan. 18, 2022 extended Search Report issued in European Patent Application No. 19901970.4. |
Jan. 18, 2022 extended Search Report issued in European Patent Application No. 19904664.0. |
Jan. 18, 2022 extended Search Report issued in European Patent Application No. 19904987.5. |
Mar. 11, 2022 Extended European Search Report issued in European Application No. 19905139.2. |
Sep. 26, 2023 Notice of Allowance issued in U.S. Appl. No. 17/415,433. |
Oct. 18, 2023 Office Action issued in U.S. Appl. No. 17/415,443. |
Oct. 14, 2022 Search Report issued in European Patent Application No. 19901970.4. |
Jul. 18, 2023 Office Action Issued in Japanese Patent Application No. 2020-563143. |
Mar. 30, 2023 Office Action and Search Report issued in Taiwanese Patent Application No. 108147182. |
Mar. 6, 2023 Office Action and Search Report issued in Taiwanese Patent Application No. 108147178. |
Feb. 5, 2024 Office Action issued in Chinese Patent Application No. 201980085497.2. |
Mar. 1, 2024 Office Action issued in Taiwanese Patent Application No. 108147178. |
Tang An et al., “White LED Study on the luminescence properties of red phosphor”, Intellectual Property Publishing House, Aug. 31, 2016, pp. 2-6. |
Nov. 1, 2023 Office Action issued U.S. Appl. No. 17/415,448. |
Oct. 31, 2023 Office Action issued in Japanese Patent Application No. 2020-563142. |
Oct. 31, 2023 Office Action issued in Japanese Patent Application No. 2020-563145. |
Dec. 28, 2023 Office Action issued in U.S. Appl. No. 17/414,643. |
Dec. 22, 2023 Office Action issued in Chinese Patent Application No. 201980083426.9. |
Jan. 19, 2024 Office Action issued in Taiwanese Patent Application No. 108147166. |
Dec. 5, 2023 Notice of Allowance issued in Japanese Patent Application No. 2020-563143. |
Apr. 25, 2024 Notice of Allowance received in U.S. Appl. No. 17/414,643. |
Apr. 15, 2024 Corrected Notice of Allowability issued in U.S. Appl. No. 17/415,443. |
Apr. 1, 2024 Notice of Allowance issued in U.S. Appl. No. 17/415,443. |
May 7, 2024 Notice of Allowance issued in Japanese Patent Application No. 2020-563141. |
Number | Date | Country | |
---|---|---|---|
20220059730 A1 | Feb 2022 | US |