Phosphoric acid beverages with calcium to phosphorus ratios of 1:1 or greater and methods of making

Information

  • Patent Application
  • 20080081088
  • Publication Number
    20080081088
  • Date Filed
    September 30, 2006
    17 years ago
  • Date Published
    April 03, 2008
    16 years ago
Abstract
Phosphoric acid-based beverages and beverage concentrates supplemented with calcium, phosphorus and optionally magnesium salts. The consumable beverage maintains a calcium/phosphorus ratio of 1:1 or greater. These stabilized phosphoric acid-based beverages have a pH 3.5-5.0 and may be artificially sweetened in addition to sucrose, fructose and other sweeteners and methods of making.
Description
DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to beverages and beverage concentrates prepared with particular edible acid salts of calcium and/or calcium and magnesium, without the addition of excessive acids, in particular phosphoric acid. As described herein, “beverage concentrate” refers to concentrated complete beverage mixtures prior to dilution to ready-to-drink beverage concentration. As described herein, “stable” and “stability” refer to beverages free of precipitation or sediment formation for the shelf life of the beverage, which as an example is typically six months at normal room temperature for soft drinks.


Lederman 47713 describes details related to the production of soluble edible acid mineral salts. However, the elemental calcium to phosphorus is significantly less than 1:1.


In the invention described herein, the salts are further particularly described as calcium and/or calcium and magnesium salts intended for supplementing phosphoric acid-based beverages prepared by combining potable water with solubilizable forms of calcium, optionally a solubilizable form of a magnesium salt and phosphoric acid to form a solution.


The solution formed from water, solubilized calcium and optionally solubilized magnesium and phosphoric acid may then optionally be dried for ease of handling and transportation. Drying methods used may be any method known to those skilled in the art, including but not limited to tray drying, drum drying, freeze drying, vacuum drying, spray drying etc. The calcium and/or calcium and magnesium salt is then reconstituted for use in the beverage production.


Production of good-tasting beverages is well-known to those skilled in the art. In this embodiment, calcium and/or calcium and magnesium edible acid mineral salts described above, a flavor system, sweetener, preservatives and other ingredients, known to those skilled in the arts are incorporated into a beverage concentrate so that the concentrate can be appropriately diluted with water and bottled as needed, or incorporated into ready-to-use beverage solutions which are then bottled as needed. It is obvious to those skilled in the art that carbonated water is used for carbonated soft drink beverages.


The following examples are intended as examples and in no way demonstrate limitations of this invention. It is recognized that commercially available materials are used in this invention and that ones skilled in the art may use the teachings herein to provide other examples. All references to serving sizes are for 8 fluid ounces.


EXAMPLE 1

A good-tasting low-calorie cherry flavored pepper beverage is prepared by making a beverage concentrate then diluting the concentrate with carbonated water. The concentrate is mixed by combining 191 gallons of 60° C. potable water with 1.7 pounds of sodium benzoate, 94 pounds of Calcium Magnesium Blend (prepared as described in Lederman) and 42 fl. Oz. of 80% H3PO4. This addition of H3PO4 provides less than one mg of additional Phosphorus to this beverage. This solution is mixed for 30 minutes with good agitation, filtered, cooled and then 2 gallons of cherry cola flavor and 62 fl. Oz. sucralose liquid concentrate (SPLENDA® sweetener) is added. The concentrate is diluted with 3 parts carbonated water and bottled. The final beverage contains 219 mg of Calcium, 87 mg of Magnesium and 189 mg of Phosphorus per serving. This beverage was found to be comparable in taste, sweetness and mouthfeel to commercially available diet pepper beverages, and remains good-tasting and clear with no sediment formation after one year storage at room temperature.


EXAMPLE 2

A good-tasting low-calorie cola beverage is prepared by making a beverage concentrate then diluting the concentrate with carbonated water. The concentrate is mixed by combining 191 gallons of 60° C. potable water with 1.7 pounds of sodium benzoate, 94 pounds of Calcium Magnesium Blend (prepared as described in Lederman) and 65 fl. Oz. of 80% H3PO4. This addition of H3PO4 provides less than one mg of additional Phosphorus to this beverage. This solution is mixed for 30 minutes with good agitation, filtered, cooled and then 2 gallons and 16 fl. Oz. of cola flavor and 82 fl. Oz. sucralose liquid concentrate (SPLENDA® sweetener) is added. The concentrate is diluted with 3 parts carbonated water and bottled. The final beverage contains 219 mg of Calcium, 87 mg of Magnesium and 189 mg of Phosphorus per serving. This beverage was found to be comparable in taste, sweetness and mouthfeel to commercially available diet cola beverages, and remains good-tasting and clear with no sediment formation after one year storage at room temperature.


EXAMPLE 3

A good-tasting low-calorie cola beverage is prepared by making a beverage concentrate then diluting the concentrate with carbonated water. The concentrate is mixed by combining 191 gallons of 60° C. potable water with 1.7 pounds of sodium benzoate, 94 pounds of Calcium Magnesium Blend (prepared as described in Lederman) and 65 fl. Oz. of 80% H3PO4. This addition of H3PO4 provides less than one mg of additional Phosphorus to this beverage. This solution is mixed for 30 minutes with good agitation, filtered, cooled and then 2 gallons and 16 fl. Oz. of cola flavor and 3.68 pounds of aspartame is added. The concentrate is diluted with 3 parts carbonated water and bottled. The final beverage contains 219 mg of Calcium, 87 mg of Magnesium and 189 mg of Phosphorus per serving. This beverage was found to be comparable in taste, sweetness and mouthfeel to commercially available diet cola beverages, and remains good-tasting and clear with no sediment formation after one year storage at room temperature.


EXAMPLE 4

A good-tasting full-calorie cola beverage is prepared by making a beverage concentrate then diluting the concentrate with carbonated water. The concentrate is mixed by combining 191 gallons of 60° C. potable water with 1.7 pounds of sodium benzoate, 94 pounds of Calcium Magnesium Blend (prepared as described in Lederman) and 65 fl. Oz. of 80% H3PO4. This addition of H3PO4 provides less than one mg of additional Phosphorus to this beverage. This solution is mixed for 30 minutes with good agitation, filtered, cooled and then 2 gallons and 16 fl. Oz. of cola flavor and 680 pounds of sucrose is added. The concentrate is diluted with 3 parts carbonated water and bottled. The final beverage contains 219 mg of Calcium, 87 mg of Magnesium and 189 mg of Phosphorus per serving. This beverage was found to be comparable in taste, sweetness and mouthfeel to commercially available full-calorie cola beverages, and remains good-tasting and clear with no sediment formation after one year storage at room temperature.


EXAMPLE 5

The following formula is an example of a composition used in the present invention. These components are processed as taught by Lederman U.S. Pat. No. 6,569,477 B2. This example is illustrative of the compositions taught in this invention and is not limiting in any sense.














Ingredients
Elemental
Ratio



















Calcium Hydroxide
32.2%
Calcium
17.4 gram
1.08


Phosphoric Acid 75%
67.8%
Phosphorous
16.1 gram
1



 100%









REFERENCES




  • 1 Beverage Digest, vol. 48, no. 7


  • 2 Jacobsen, M. F. “Liquid Candy. How Soft Drinks Are Harming Americans' Health”. Center for Science in the Public Interest, Washington, D.C. 2005.


  • 3 American Academy of Pediatrics, Policy Statement “Soft Drinks in Schools”, Pediatrics, 113:1, January 2004.


  • 4 Associated Press article, “Rapid Aging Due to Lack of Calcium. Latest Theory on Diet Reported by Columbia University Scientists”, Los Angeles Times, Jun. 24, 1932.


  • 5 http://www.umm.edu/altmed/ConsSuplements/Phosphoruscs.html


  • 621CFR 101.72


  • 7 Federal Register/Vol. 58, No. 3/Jan. 6, 1993, pg 2668.


  • 8 http://www.thecoca-colacompany.com/mail/goodanswer/soft_drink_nutrition.pdf


  • 9 Belkin, L. “The School Lunch Test”, The New York Times Magazine, Aug. 20, 2006.


  • 10 Nakel, G. M., Russell, W. E., Dake, T. W., and Heckert, D. C. “Beverages and Beverage Concentrates Nutritionally Supplemented with Calcium”, U.S. Pat. No. 4,737,375.


  • 11 Heckert, D. C. “Fruit Juice Beverages and Juice Concentrates Nutritionally Supplemented with Calcium”, U.S. Pat. No. 4,722,847.


  • 12 Chang, P. K., Lee, T. D., Olszewski, J., Edgar, B. G., Orr, R and Curtiss, H. “Calcium-Supplemented Beverages and Method of Making Same”. U.S. Pat. No. 7,052,725 B2.


  • 13 Lederman, S. N. “Highly soluble and stable mineral supplements containing calcium and magnesium and methods of making”, U.S. Pat. No. 6,569,477.


Claims
  • 1. A flavored, sweetened beverage or beverage concentrate supplemented with soluble calcium and phosphorous edible salts containing nutritionally significant levels of elemental calciuman elemental calcium to elemental phosphorus ratio is 1:1 or more, more preferably a elemental calcium to elemental phosphorus ratio is 1.1:1 or more,with a flavor system and processing aids containing elements such as caffeine, coloring ingredients, caramel, miniscule amounts of free acids and anti-foaming agents and the such,wherein the solubilized calcium and phosphorus can remain stable and solubilized in the beverage for at least 3 months more preferably 6 months.
  • 2. The beverage or beverage concentrate of claim 1 where the flavor is cola, pepper or other flavor that benefits from phosphoric acid.
  • 3. The beverage or beverage concentrate of claim 1 where the beverage provides at least 10% Recommended Daily Intake (RDI) of soluble calcium per 8 ounce serving.
  • 4. The beverage or beverage concentrate of claim 1 where the beverage provides at least 100 mg of soluble calcium per 8 ounce serving.
  • 5. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 1 wherein nutritionally significant levels of micronutrient(s) and/or macronutrient(s) supplements are added, such micronutrients including but not limited to vitamins such as C, D, or E, minerals such as Potassium, Zinc, Chromium, or Iron, and/or biologically active materials such as flavonoids, anti-oxidants, or pro-biotics, and/or such macronutrients including but not limited to protein such as whey protein, or soy protein, and/or carbohydrates such as soluble fibers or fructo-oligosaccharides.
  • 6. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 5 wherein the sweetener is a nutritive sweetener including but not limited to sucrose, high fructose corn syrup, glucose, glucose syrup, or invert sugar and/or mixtures thereof.
  • 7. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 6 wherein additional sweetness is provided by one or more sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and/or mixtures thereof.
  • 8. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 5 wherein the sweetener is one or more non-nutritive sweetener(s) including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and mixtures thereof.
  • 9. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 1 wherein the sweetener is a nutritive sweetener including but not limited to sucrose, high fructose corn syrup, glucose, glucose syrup, or invert sugar and/or mixtures thereof.
  • 10. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 9 wherein additional sweetness is provided by one or more sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and/or mixtures thereof.
  • 11. The calcium and phosphorous supplemented beverage or beverage concentrate of claim 1 wherein the sweetener is one or more non-nutritive sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and/or mixtures thereof.
  • 12. A flavored, sweetened beverage or beverage concentrate supplemented with soluble calcium, magnesium and phosphorous edible salts containing nutritionally significant levels of elemental calcium,an elemental calcium to elemental phosphorus ratio is 1:1 or more, more preferably a elemental calcium to elemental phosphorus ratio is 1.1:1 or more,with a flavor system and processing aids containing elements such as caffeine, coloring ingredients, caramel, miniscule amounts of free acids and anti-foaming agents and the such,wherein the solubilized calcium, magnesium and phosphorus can remain stable and solubilized in the beverage for at least 3 months more preferably 6 months.
  • 13. The beverage or beverage concentrate of claim 12 where the flavor is cola, pepper or other flavor that benefits from phosphoric acid.
  • 14. The beverage or beverage concentrate of claim 12 where the beverage provides at least 10% RDI of calcium per 8 ounce serving.
  • 15. The beverage or beverage concentrate of claim 12 where the beverage provides at least 100 mg of calcium and at least 40 mg of magnesium per 8 ounce serving.
  • 16. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 12 wherein nutritionally significant levels of micronutrient(s) and/or macronutrient(s) supplements are added, such micronutrients including but not limited to vitamins such as C, D, or E, minerals such as Potassium, Zinc, Chromium, or Iron, and/or biologically active materials such as flavonoids, anti-oxidants, or pro-biotics, and/or such macronutrients including but not limited to protein such as whey protein, or soy protein, and/or carbohydrates such as soluble fibers or fructo-oligosaccharides.
  • 17. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 16 wherein the sweetener a nutritive sweetener including but not limited to sucrose, high fructose corn syrup, glucose, glucose syrup, or invert sugar and/or mixtures thereof.
  • 18. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 17 wherein additional sweetness is provided by one or more sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and/or mixtures thereof.
  • 19. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 16 wherein the sweetener is one or more non-nutritive sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and mixtures thereof.
  • 20. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 12 wherein the sweetener a nutritive sweetener including but not limited to sucrose, high fructose corn syrup, glucose, glucose syrup, or invert sugar and/or mixtures thereof.
  • 21. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 20 wherein additional sweetness is provided by one or more sweeteners including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and/or mixtures thereof.
  • 22. The calcium, magnesium and phosphorous supplemented beverage or beverage concentrate of claim 12 wherein the sweetener is one or more non-nutritive sweetener(s) including but not limited to aspartame, acesulfame potassium, alitame, neotame, sodium saccharin, calcium saccharin, sodium cyclamate, calcium cyclamate, sucralose, neohesperidin dihydrochalcone, and mixtures thereof.
  • 23. A stable mineral-fortified phosphoric acid based beverage or beverage concentrate wherein the pH is 3.5-5.0, more preferably 4.0-5.0 and most preferably 4.0-4.5, sweetened at least in part with a dipeptide sweetener including but not limited to aspartame, neotame or alitame.
  • 24. A phosphoric acid-containing beverage supplemented with nutritionally significant levels of calcium in which precipitation or sedimentation of calcium salts does not occur for at least three month more preferably six months at room temperature.
  • 25. The beverage or beverage concentrate of claim 24 where the beverage provides 200 mg or less of phosphorus per serving.