Claims
- 1. An improved fuel composition comprising a major proportion of a liquid hydrocarbyl fuel selected from gasoline, diesel or fuel oil, and a minor proportion of a multifunctional antiwear/antioxidant additive product of reaction prepared by (a) reacting an O,O-dihydrocarbyl phosphorodithiioic acid with a vinyl pyrrolidone to form phosphorodithioate-derived pyrrolidones as described below: ##STR2## where R.sub.1 and R.sub.2 are C.sub.3 to about C.sub.30 hydrocarbyl and where R.sub.3, R.sub.4 and R.sub.5 are hydrogen or C.sub.1 to about C.sub.60 hydrocarbyl and wherein the reaction is carried out at temperatures varying from ambient to about 250.degree. C. under pressures varying from ambient to about 100 psi or is autogenous for a time sufficient to obtain the desired additive product of reaction and where the reaction is carried out in molar ratios of reactants which vary from equimolar to more than equimolar to less than equimolar.
- 2. The composition of claim 1 wherein the reactants are di-(2-ethylhexy)phosphorodithioic acid and 1-vinyl-2-pyrrolidinone.
- 3. The composition of claim 1 wherein the phosphorodithioic acid is first formed by reacting a C.sub.3 to about a C.sub.30 alcohol or a C.sub.6 to about a C.sub.30 alkylated phenol with phosphorus pentasulfide in a molar ratio of alcohol or phenol to phosphorus pentasulfide of about 3 to 1 to about 5 to 1 and thereafter reacting in equimolar ratios the resultant phosphorodithioic acid with N-vinyl-2-pyrrolidone.
- 4. The composition of claim 3 wherein said alcohol is 2-methyl-1-propanol.
- 5. The composition of claim 1 wherein the fuel contains from about 0.001 to about 10 wt % based on the total weight of the composition of the additive product of reaction.
- 6. The composition of claim 1 containing in addition to said fuel and said additive from 0 to about 20 wt % of an additive package comprising viscosity index improvers, friction modifiers, antiwear/ extreme pressure agents and anticorrosion agents.
Parent Case Info
This is a division of application Ser. No. 07/985,044 filed on Dec. 3, 1992 now U.S. Pat. No. 5,324,441.
US Referenced Citations (7)
Divisions (1)
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Number |
Date |
Country |
Parent |
985044 |
Dec 1992 |
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