Claims
- 1. A sulfur-, nitrogen- and phosphorus-containing composition made by reacting one or more phosphorus acid compounds of the formula ##STR24## wherein each X is independently oxygen or divalent sulfur, M is a hydrogen, an equivalent of a metal of ammonium cation, R is hydrogen or a hydrocarbyl, hydrocarbyloxy, or hydrocarbyl mercapto group of about one to about thirty carbon atoms, and R' is XM or R, with the proviso that the total number of carbon atoms in both R and R' is at least two, with
- (B) one or more sulfo- and nitrogen-containing compounds of the general formulae: ##STR25## wherein y is one or two, each R.sup.3 is independently hydrogen or lower alkyl group of one to seven carbon atoms, R.sup.2 is di- or trivalent hydrocarbyl group having one to eighteen carbon atoms, R.sup.4 is a trivalent hydrocarbyl group having one to eighteen carbon atoms, and Q is selected from the group consisting of --OH --OR.sup.3, --OM, --O(Alkylene-O).sub.n --R.sup.3, --N(R.sup.3).sub.2, --NR.sup.3 (Alkylene-NR.sup.3).sub.n R.sup.3, --OH(R.sup.3).sub.4, and --ONR.sub.3.sup.3 -(AlkyleneNR.sup.3).sub.n R.sup.3, wherein n has an average value of about one to about ten, M is as defined in (A) and te alkylene group has from one to ten carbon atoms.
- 2. A sulfo-, nitrogen- and phosphorus-containing composition selected from those corresponding to the formulae: ##STR26## and mixtures of two or more such additives wherein z is one or two, R, R', R.sup.2, R.sup.3, R.sup.4, X, Q and y are set forth in claim 1.
- 3. The composition of claim 1 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms and each X is oxygen.
- 4. The composition of claim 2 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms and each X is oxygen.
- 5. The composition of claim 1 wherein each X is a divalent sulfur atom and R and R' are independently C.sub.1 -C.sub.18 alkoxy groups.
- 6. The composition of claim 1 wherein (B) is of the general formula ##STR27##
- 7. The composition of claim 1 wherein M is hydrogen, a Group I, II(A), II(B) metal cation or mixtures thereof.
- 8. The composition of claim 1 wherein Q is selected from the group consisting of --NR.sup.3 (Alkylene-NR.sup.3).sub.n R.sup.3 and --ONR.sub.3.sup.3 --(Akylene-NR.sup.3).sub.n R.sup.3 and mixtures thereof.
- 9. The composition of claim 2 wherein Q is selected from the group consisting of --NR.sup.3 (Alkylene-NR.sup.3).sub.n R.sup.3 and --ONR.sub.3.sup.3 --(Alkylene-NR.sup.3).sub.n R.sup.3 and mixtures thereof.
- 10. The composition of claim 1 wherein Q is --O(Alkylene--O).sub.n R.sup.3.
- 11. The composition of claim 2 wherein Q is --O(Alkylene--O).sub.n R.sup.3.
- 12. A process for preparing a sulfur-, nitrogen- and phosphorous-containing composition which comprises reacting one or more phosphorus compounds of the formula ##STR28## wherein each X is independently oxygen or divalent sulfur, M is a hydrogen, an equivalent of a metal or ammonium cation, R is hydrogen or a hydrocarbyl, hydrocarbyloxy, or hydrocarbyl mercapto group of about one to about 30 carbon atoms, and R' is XM or R, with the proviso that the total number of carbon atoms in both R and R' is at least two, with
- B. one or more sulfo- and nitrogen-containing compounds of the general formulae ##STR29## wherein y is one or two, each R.sup.3 is independently hydrogen or lower alkyl group of one to seven carbon atoms, R.sup.2 is di- or trivalent hydrocarbyl group having one to eighteen carbon atoms, R.sup.4 is a trivalent hydrocarbyl group having one to eighteen carbon atoms, and Q is selected from the group consisting of --OH, --OR.sup.3, --OM, --O(Alkylene-O).sub.n --R.sup.3, --N(R.sup.3).sub.2, --NR.sup.3 (Alkylene-NR.sup.3).sub.n R.sup.3, --OH(R.sup.3).sub.4, and -ONR.sub.3.sup.3 -(Alkylene-NR.sup.3).sub.n R.sup.3, wherein n has an average value of about one to about ten, M is as defined in (A) and the alkylene group has from one to ten carbon atoms.
- 13. The process of claim 12 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms and each X is oxygen.
- 14. The process of claim 12 wherein each X is a divalent sulfur atoms and R and R' are independently C.sub.1 -C.sub.18 alkoxy groups.
- 15. The process of claim 12 wherein Q is selected from the group consisting of M, wherein M is a Group I, II(A), or II(B) metal cation and ONR.sub.3.sup.3 --(Alkylene NR.sup.3).sub.n R.sup.3.
- 16. The composition of claim 1 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms and each X is a divalent sulfur atom.
- 17. The composition of claim 2 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about 18 carbon atoms and each X is a divalent sulfur atom.
- 18. The composition of claim 1 wherein (B) is of the general formula ##STR30##
- 19. The composition of claim 18 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms.
- 20. The composition of claim 18 wherein each X is a divalent sulfur atom.
- 21. The composition of claim 2 corresponding to one or more compounds of the general formula. ##STR31##
- 22. The composition of claim 21 wherein R' is the same as R and R is a hydrocarbyloxy group containing one to about eighteen carbon atoms.
- 23. The composition of claim 22 wherein each X is a divalent sulfur atom.
- 24. The composition of claim 1 wherein M is selected from the group consisting of hydrogen, lithium, sodium potassium, magnesium, calcium, brium, and mixtures thereof.
- 25. The composition of claim 2 wherein R is hydrogen, a Group I, II(A), II(B) metal cation, or mixtures thereof.
- 26. The composition of claim 18 wherein M is a Group I, II(A), II(B) metal cation or mixtures thereof.
- 27. The composition of claim 21 wherein M is hydrogen, a Group I, II(A), II(B) metal cation or mixtures thereof.
- 28. The composition of claim 1 wherein Q is --OM and M of Q is selected from the group consisting of hydrogen, Group I, II(A), II(B) metal cations, NH.sup.+.sub.4 and mixtures thereof.
REFERENCE TO RELATED APPLICATIONS:
This application is a continuation-in-part of U.S. application Ser. No. 634,390 filed Nov. 24, 1975, now U.S. Pat. No. 4,026,812 which in turn is a division of Ser. No. 424,246 filed Dec. 12, 1973, now U.S. Pat. No. 3,926,821.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4000188 |
Dear et al. |
Dec 1976 |
|
4014926 |
Dear et al. |
Mar 1977 |
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Divisions (1)
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Number |
Date |
Country |
Parent |
424246 |
Dec 1973 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
634390 |
Nov 1975 |
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