The present disclosure relates to a semiconductor light-detecting device, and particularly to a semiconductor light-detecting device including a first absorption layer, a second absorption layer and a first semiconductor layer.
This application claims the right of priority based on TW application Serial No. 112106689, filed on Feb. 23, 2023, and the content of which is hereby incorporated by reference in its entirety.
A semiconductor optoelectronic device mainly involves the conversion between light and electricity. A light-emitting device, such as a light-emitting diode (LED) or a laser diode (LD), can convert electricity to light, and a photovoltaic cell (PVC) or a light-detecting device, such as photodiode (PD), can convert light to electricity. LEDs have been widely applied to illumination and light sources of various electronic devices, and LDs have also been applied to projectors and proximity sensors extensively. PVCs can be applied to power plants and power generation centers for use in space, and PDs can be applied to fields of light sensing and communication. With the expansion of the functions of personal electronic devices, the light-detecting device is gradually being used in fields of ranging, security and physiological monitoring, and the requirements for accuracy in the wavelength range of light detection are getting higher and higher.
The present disclosure provides a light-detecting device. The light-detecting device includes a base, a first absorption layer, a second absorption layer and a first semiconductor layer. The first absorption layer is located on the base and has a first band gap. The second absorption layer is located between the first absorption layer and the base and has a second band gap and a first dopant. The first semiconductor layer is located between the first absorption layer and the second absorption layer and has a third band gap. The second band gap is equal to or greater than the first band gap, and a third band gap greater than the first band gap and the second band gap. The first absorption layer does not include the first dopant.
The present disclosure further provides a photo-detecting module. The photo-detecting module includes a light-emitting device, the light-detecting device, a carrier electrically connecting to the light-emitting device and the light-detecting device, and an encapsulation structure covering the light emitting device and the light-detecting device.
The foregoing aspects and many of the attendant advantages of the present disclosure will become more readily appreciated as the same becomes better understood by reference to the following detailed description, when taken in conjunction with the accompanying drawings, wherein:
The following embodiments will be described with accompany drawings to disclose the concept of the present disclosure. In the drawings or description, same or similar portions are indicated with same or similar numerals. Furthermore, a shape or a size of a member in the drawings may be enlarged or reduced. Particularly, it should be noted that a member which is not illustrated or described in drawings or description may be in a form that is known by a person skilled in the art.
A person skilled in the art can realize that addition of other components based on a structure recited in the following embodiments is allowable. For example, if not otherwise specified, a description similar to “a first layer/structure is on or under a second layer/structure” may include an embodiment in which the first layer/structure directly (or physically) contacts the second layer/structure, and may also include an embodiment in which another structure is provided between the first layer/structure and the second layer/structure, such that the first layer/structure and the second layer/structure do not physically contact each other. In addition, it should be realized that a positional relationship of a layer/structure may be altered when being observed in different orientations.
In the present disclosure, if not otherwise specified, the general formula InGaP represents Inx0Ga1-x0P, wherein 0<x0<1; the general formula AlInP represents Alx1In1-x1P, wherein 0<x1<1; the general formula AlGaInP represents Alx2Gax3In1-x2-x3P, wherein 0<x2<1 and 0<x3<1; the general formula InGaAsP represents Inx4Ga1-x4Asx5P1-x5, wherein 0<x4<1, 0<x5<1; the general formula AlGaInAs represents Alx6Gax7In1-x6-x7 As, wherein 0<x6<1 and 0<x7<1; the general formula InGaAsN represents Inx8Ga1-x8Asx9N1-x9, wherein 0<x8<1 and 0<x9<1; the general formula InGaAs represents Inx10Ga1-x10 As, wherein 0<x10<1; the general formula AlGaAs represents Alx11Ga1-x11 As, wherein 0<x11<1. The content of each element may be adjusted for different purposes, for example, for adjusting the band gap, or the cut-off wavelength of a light-detecting device. However, the present disclosure is not limited thereto.
In addition, if not otherwise specified, a description similar to “a first layer/structure is on or under a second layer/structure” may include an embodiment in which the first layer/structure directly (or physically) contacts the second layer/structure, and may also include an embodiment in which another structure is provided between the first layer/structure and the second layer/structure, such that the first layer/structure and the second layer/structure do not directly contact each other. Furthermore, it should be realized that a positional relationship of a layer/structure may be altered when being observed in different orientations.
The base 10 includes a first surface 10a and a second surface 10b opposite to the first surface 10a. The semiconductor stack 20 is located on the first surface 10a of the base 10 and includes a first absorption layer 21, a second absorption layer 22 located between the first absorption layer 21 and the base 10, and a first semiconductor layer 23 located between the first absorption layer 21 and the second absorption layer 22. In one embodiment, the first electrode 50 is disposed on the first absorption layer 21 to electrically connect to the first absorption layer 21, and the second electrode 60 is disposed on the second surface 10b of the base 10 to electrically connect to the second absorption layer 22 through the base 10. As such, the electrical signal generated by the light-detecting device 100 can be output through the first electrode 50 and the second electrode 60. In one embodiment, the light-detecting device 100 further includes a second semiconductor layer 24 located on the first absorption layer 21 and a third semiconductor layer 25 located between the second absorption layer 22 and the base 10. The first electrode 50 can be disposed on the second semiconductor layer 24. In one embodiment, the base 10 and the third semiconductor layer 25 or the second absorption layer 22 are lattice-matched to each other. The term “lattice-matched” refers to a ratio of the difference between the lattice constants of two adjacent layers to the average of the lattice constants of two adjacent layers is smaller than or equal to 0.1%.
The first semiconductor layer 23, the second semiconductor layer 24 and the third semiconductor layer 25 may include the same or different materials. The first semiconductor layer 23 and the third semiconductor layer 25 have a first conductivity type and a first dopant, the second semiconductor layer 24 has a second conductivity type and a second dopant, and the second conductivity type is different from the first conductivity type. For example, the first conductivity type and the second conductivity type can be n-type and p-type, or p-type and n-type respectively. In one embodiment, the second semiconductor layer 24 further includes an unmodified region 241 and a first modified region 242. The unmodified region 241 has the first conductivity type and a third dopant, and the first modified region 242 has the second dopant and the third dopant. The first dopant and the third dopant can be the same or different, and the first dopant and the third dopant are different from the second dopant.
In one embodiment, in the first modified region 242, a doping concentration of the second dopant is greater than a doping concentration of the third dopant so that the first modified region 242 has the second conductivity type. The unmodified region 241 without the second dopant has the first conductivity type. The first dopant in the first semiconductor layer 23 and the third semiconductor layer 25 respectively has a first doping concentration and a second doping concentration, and the first doping concentration is the same or less than the second doping concentration. In one embodiment, the first doping concentration can be between 1017 and 2×1018/cm3, and the second doping concentration can be between 1017 and 5×1018/cm3. The third dopant in the second semiconductor layer 24 has a third doping concentration less than the first doping concentration and the second doping concentration. In one embodiment, the third doping concentration can be smaller than 5×1016/cm3. The second dopant in the second semiconductor layer 24 has a fourth doping concentration. In one embodiment, the fourth doping concentration can be between 2×1017 and 5×1019/cm3. In one embodiment, the first semiconductor layer 23 can be a single-layer or multi-layer structure, and the first dopant concentration may have a gradient change or a layer-by-layer change. More specifically, in one embodiment, the first dopant concentration of the first semiconductor layer 23 may be gradually increased or decreased in a direction from the base 10 to the semiconductor stack 20. In another embodiment, the first semiconductor layer 23 may include a first sublayer and a second sublayer (not shown). The first doping concentrations of the first sublayer and the second sublayer may be different, and may be gradually increased or decreased.
The first absorption layer 21 is located between the first semiconductor layer 23 and the second semiconductor layer 24. The second absorption layer 22 is located between the first semiconductor layer 23 and the third semiconductor layer 25. The first absorption layer 21 of the light-detecting device 100 absorbs and converts the incident light into the electrical signal. In one embodiment, the first absorption layer 21 is undoped or unintentionally doped, and the second semiconductor layer 24, the first absorption layer 21 and the first semiconductor layer 23 form a p-i-n type light detecting device. The term “unintentional doped” refers to a situation that a doped element or a dopant naturally diffuse into the first absorption layer 21. For example, the first absorption layer 21 may include the first dopant from the first semiconductor layer 23 or/and the third dopant from the second semiconductor layer 24. When the first absorption layer 21 is unintentional doped, the sum of the doping concentrations of the first dopant and the third dopant in the first absorption layer 21 is less than 1016/cm3. The second absorption layer 22 has a fourth dopant and the same first conductivity type as the first semiconductor layer 23 and the third semiconductor layer 25. The fourth dopant and the first dopant can be the same or different. In one embodiment, the fourth dopant in the second absorption layer 22 has a fifth doping concentration. In one embodiment, the fifth doping concentration can be between 5×1017/cm3 and 5×1018/cm3, that is, the doping concentration of the second absorption layer 22 is greater than that of the first absorption layer 21. The first dopant, the second dopant, the third dopant and the fourth dopant can respectively be zinc (Zn), beryllium (Be), magnesium (Mg), carbon (C), silicon (Si), germanium (Ge), tin (Sn), sulfur(S), selenium (Se), or tellurium (Te).
The materials of the first absorption layer 21 and the second absorption layer 22 can have the same or different band gaps to absorb light in the same or different wavelength ranges. In one embodiment, the first absorption layer 21 has a first thickness T1 and a first band gap Eg1, the second absorption layer 22 has a second thickness T2 and a second band gap Eg2, and the first band gap Eg1 is equal to or greater than the second band gap Eg2. Therefore, the first absorption layer 21 and the second absorption layer 22 can respectively absorb light with an energy greater than the first band gap Eg1 and the second band gap Eg2. In other words, the first absorption layer 21 has a first cut-off wavelength λ1 and can absorb light with a wavelength smaller than the first cut-off wavelength λ1. The second absorption layer 22 has a second cut-off wavelength λ2 and can absorb light with a wavelength smaller than the second cut-off wavelength λ2, and λ1≤λ2. According to actual applications, the first absorption layer 21 and the second absorption layer 22 can include materials with an band gap of 3.10 ev to absorb light with a wavelength below 400 nm (such as ultraviolet light); or materials with an band gap of 2.14 ev to absorb light with a wavelength below 580 nm (such as green light, blue light and ultraviolet light); or materials with an band gap of 0.73 ev to absorb light with wavelengths below 1700 nm (such as infrared light, red light, green light, blue light and ultraviolet light).
The first semiconductor layer 23 has a third thickness T3 and a third band gap Eg3, the second semiconductor layer 24 has a fourth thickness T4 and a fourth band gap Eg4, and the third semiconductor layer 25 has a fifth thickness T5 and a fifth band gap Eg5. The third band gap Eg3, the fourth band gap Eg4 and the fifth band gap Eg5 are greater than the first band gap Eg1 or/and the second band gap Eg2, and the third band gap Eg3, the fourth band gap Eg4 and the fifth band gap Eg5 can be the same or different. In other words, the first semiconductor layer 23, the second semiconductor layer 24 and the third semiconductor layer 25 respectively have a third cut-off wavelength λ3, a fourth cut-off wavelength λ4 and a fifth cut-off wavelength λ5, and the third cut-off wavelength λ3, the fourth cut-off wavelength λ4 and the fifth cut-off wavelength λ5 are less than the first cut-off wavelength λ1 and the second cut-off wavelength λ2 (λ3, λ4, λ5<λ1, λ2). That is, the wavelength range of light in which the first semiconductor layer 23, the second semiconductor layer 24 and the third semiconductor layer 25 can absorb is smaller than the wavelength range of light in which the first absorption layer 21 and the second absorption layer 22 can absorb.
As shown in
For example, when the target wavelength range of the light-detecting device 100 is between 1300 nm and 1600 nm for detecting infrared light, the first band gap Eg1 of the first absorption layer 21 should not be greater than 0.77 eV, and the fourth band gap Eg4 of the second semiconductor layer 24 should not be greater than 0.96 eV. Assuming that the incident light includes a first light with a wavelength within the target wavelength range and a second light with a wavelength outside the target wavelength range (for example, between 400 nm and 1300 nm). As the incident light enters the incident plane 243, the second light can be absorbed by the second semiconductor layer 24, and the first light penetrates the second semiconductor layer 24 and is absorbed by the first absorption layer 21. Through selection of the band gaps of the first absorption layer 21 and the second semiconductor layer 24, the photocurrent generated by absorbing the light with a wavelength outside the target wavelength range in the first absorption layer 21 can be reduced. Thus, noise caused by the light with a wavelength outside the target wavelength range can be reduced.
On the other hand, in addition to entering the light-detecting device 100 through the incident plane 243, light may also enter and be absorbed by the first absorption layer 21 through a side surface of the light-detecting device 100 or reflection of the base 10. Since the incident light that does not enter from the incident plane 243 cannot pass through the second semiconductor layer 24, a portion of the incident light with a wavelength outside the target wavelength range may still be absorbed by the first absorption layer 21 and cause noise. In this embodiment, the second absorption layer 22 is disposed between the first absorption layer 21 and the base 10, so that the incident light entering from other positions except the incident plane 243 is absorbed by the second absorption layer 22 before reaching the first absorption layer 21. In addition, the second absorption layer 22 with the fourth dopant has a higher carrier concentration (electrons or holes) with respective to the undoped first absorption layer 21, so that electrons and holes generated by light absorption of the second absorption layer 22 are easy to recombine with the native carriers of the second absorption layer 22. Thus, the photocurrent output by the second absorption layer 22 is much less than the photocurrent output by the first absorption layer 21. That is to say, the electrical signal output by the light-detecting device 100 is mainly from the first absorption layer 21 instead of the second absorption layer 22, which enables the light-detecting device 100 to detect light with directionality. Furthermore, in one embodiment that the first band gap Eg1 is less than the second band gap Eg2, the second cutoff wavelength λ2 of the second absorption layer 22 is larger than the first cutoff wavelength λ1 of the first absorption layer 21, so that the second absorption layer 22 can absorb light in a wider wavelength range to further reduce the interference of light outside the target wavelength range. Therefore, the second absorption layer 22 can reduce noise and improve signal-to-noise ratio (S/N) of the light-detecting device 100.
In one embodiment, the first thickness T1 of the first absorption layer 21 can be between 1000 nm and 4000 nm. The second thickness T2 of the second absorption layer 22 can be between 500 nm and 3000 nm to achieve better light absorption and noise reduction effects. In one embodiment, the ratio of the first thickness T1 to the second thickness T2 is between 0.33 and 8. In one embodiment, the third thickness T3, the fourth thickness T4 and the fifth thickness T5 are all smaller than the first thickness T1 or/and the second thickness T2 to shorten the transmission path of the photocurrent and improve the detection sensitivity. In one embodiment, the third thickness T3 can be less than 1000 nm, the fourth thickness T4 can be between 500 nm and 1500 nm, and the fifth thickness T5 can be less than 1000 nm.
As shown in
The contact structure 30 is disposed on the incident plane 243 of the second semiconductor layer 24. Referring to
As shown in
In one embodiment, the base 10, the first absorption layer 21, the second absorption layer 22, the first semiconductor layer 23, the second semiconductor layer 24, the third semiconductor layer 25 and the contact structure 30 can be a III-V compound semiconductor material, and can be a binary III-V semiconductor, a ternary III-V semiconductor or a quaternary III-V semiconductor, such as AlGaInAs, AlGaInP, AlInGaN, AlAsSb, InGaAsP, InGaAsN, AlGaAsP, GaAs, InGaAs, AlGaAs, AlInAs, GaAsP, GaP, InGaP, AlInP, GaN, InP, InGaN or AlGaN.
As shown in
Referring to
The first electrode 50 and the second electrode 60 can have a single-layer or multi-layer structure and include metal materials, such as aluminum (Al), chromium (Cr), copper (Cu), tin (Sn), gold (Au), and nickel. (Ni), titanium (Ti), platinum (Pt), lead (Pb), zinc (Zn), cadmium (Cd), antimony (Sb), cobalt (Co), beryllium (Be), germanium (Ge) or alloys which include the aforementioned metal materials.
The light-detecting device 100 may optionally include an anti-reflective layer 70 or/and a filter layer 80. As shown in
The filter layer 80 is disposed on the second semiconductor layer 24, the first electrode 50 and the passivation layer 40, and covers the first modified region 242, the first electrode 50 and the passivation layer 40. The filter layer 80 can allow the light with a wavelength in the target wavelength range pass and filter the light with a wavelength outside the target wavelength range, so as to further reduce noise caused by absorption of the light with a wavelength outside the target wavelength range. In one embodiment, a first opening O1 is formed in the anti-reflection layer 70 and the filter layer 80. As shown in
The passivation layer 40 and the anti-reflection layer 70 can include insulating materials, such as tantalum oxide (TaOx), aluminum oxide (AlOx), silicon oxide (SiOx), titanium oxide (TiOx), silicon nitride (SiNx), silicon oxynitride (SiOxNy), niobium pentoxide (Nb2O5) or spin-on glass (SOG). The filter layer 80 can be a single-layer structure or a multi-layer structure. For example, the filter layer 80 can be a multi-layer dielectric film formed by high refractive index materials and low refractive index materials that are alternately stacked (such as a combination of TiO2/a-Si/SiO2), or it can be a polymer layer with a specific light absorption spectrum.
Referring to
In one embodiment, the anti-reflection layer 70 or/and the filter layer 80 also extends downward from the incident plane 243 to cover the side surface 201 and the passivation layer 40. As such, the light entering the semiconductor stack 20 from the side surface 201 can pass through the filter layer 80 first and reduces absorption of the light outside the target wavelength range. The semiconductor stack 20 can be reduced from the first width W1 to the sixth width W6 through an etching process. In other embodiments, any layer of the semiconductor stack 20 or the base 10 can be selectively exposed by controlling parameters of the etching process. For example, the etching process can be stopped when reaching the third semiconductor layer 25, so that a part of the third semiconductor layer 25 can be exposed (not shown). Then the passivation layer 40, the anti-reflection layer 70 and the filter layer 80 cover the side surface 201 and an exposed surface of the third semiconductor layer 25 (not shown). The positions, relative relationships, and material compositions of other layers or structures as well as structural variations in the light-detecting device 102 have been described in detail in previous embodiments, and are not repeatedly described herein.
In one embodiment, in addition to covering the incident plane 243, the passivation layer 40 extends downward to cover a side surface of the first absorption layer 21, a side surface of the second semiconductor layer 24 and the third surface 231 to protect the semiconductor stack 20 from external environment. In one embodiment, the anti-reflection layer 70 or/and the filter layer 80 also extends downward from the incident plane 243 to cover the side surface of the first absorption layer 21, the side surface of the second semiconductor layer 24, the third surface 231 and the second electrode 60, and a second opening O2 is formed in the anti-reflection layer 70 and the filter layer 80. The second opening O2 is disposed corresponding to the second electrode 60 in the vertical direction, so that the second electrode 60 can connect to the external wires through the second opening O2. In one embodiment, a contact layer (not shown) can be optionally disposed between the second electrode 60 and the first semiconductor layer 23 to form ohmic contact and improve the performance of photocurrent detection. The positions, relative relationships, and material compositions of other layers or structures as well as structural variations in the light-detecting device 103 have been described in detail in previous embodiments, and are not repeatedly described herein.
The carrier 300 includes first circuit structures 310a, 310b electrically connected to the first electrode 50 and the second electrode 60 of the light-detecting device 100 respectively to receive electrical signals (such as current or voltage) generated by the light-detecting device 100. The carrier 300 includes second circuit structures 320a, 320b electrically connected to the third electrode 55 and the fourth electrode 65 of the light-emitting device 200 respectively to drive the light-emitting device 200 to emit the light. The photo-detecting module 1000 may be incorporated in a mobile device, and may be used as a proximity sensor or a structured light scanner.
The embodiments of the present disclosure will be described in detail below with reference to the drawings. In the descriptions of the specification, specific details are provided for a full understanding of the present disclosure. The same or similar components in the drawings will be denoted by the same or similar symbols. It is noted that the drawings are for illustrative purposes only and do not represent the actual dimensions or quantities of the components. Some of the details may not be fully sketched for the conciseness of the drawings.
Number | Date | Country | Kind |
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112106689 | Feb 2023 | TW | national |