Claims
- 1. A photographic element comprising a support and, coated thereon, a radiation-sensitive image recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein a photobleachable dye which has the following formula: ##STR25## wherein: a. K represents 0 or 1;
- b. m represents 0 or 1;
- c. each L represents a methine group;
- d. A represents oxygen, sulfur or N-R.sub.1 ;
- e. R.sub.1 represents an alkyl group, an alkenyl group or an aryl group;
- f. Z.sub.1 represets the nonmetallic atoms necessary to complete a cyanine dye type heterocyclic ring whose skeletal atoms consist of the oxygen, sulfur or nitrogen atom of A, carbon atoms and one other atom chosen from the group consisting of carbon, oxygen, nitrogen, selenium and sulfur atoms; and
- g. Y represents the atoms necessary to complete a phenyl or naphthyl group.
- 2. A photographic element according to claim 1 in which said support is comprised of, in addition to said photobleachable dye, a transparent polymer.
- 3. A photographic element according to claim 2 in which said photobleachable dye is homogeneously blended with said transparent polymer.
- 4. A photographic element according to claim 2 in which said support is comprised of polyethylene or poly(ethylene terephthalate).
- 5. A photographic element according to claim 2 wherein said radiation-sensitive image-recording means is a photographic silver halide image-recording means.
- 6. A photographic element according to claim 2 wherein said radiation-sensitive image-recording means is an image-recording photothermographic means.
- 7. A photothermographic element according to claim 1 in which said radiation-sensitive image-recording means is an image-recording photothermographic layer comprising
- a. an oxidation-reduction image-forming combination comprising
- i. a reducing agent and
- ii. a heavy metal salt oxidizing agent,
- b. a catalyst for the oxidation-reduction image-forming combination, and
- c. a binder.
- 8. A photographic element according to claim 1 in which R.sub.1 is an akyl group chosen from the class consisting of a sulfoalkyl group, a sulfatoalkyl group, an alkoxyakyl group, an acyloxyalkyl group, a dialkylaminoalkylene group and a cycloaminoalkylene group.
- 9. A photographic element according to claim 1 in which R.sub.1 is an aryl group which is alkyl substituted.
- 10. A photographic element according to claim 1 wherein Z.sub.1 represents the nonmetallic atoms necessary to complete a thiazole nucleus, an oxazole nucleus, a selenazole nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, an indolenine nucleus, an imidazo[4,5-b]quinoxaline nucleus, a 3H-pyrrolo[2,3-b]pyridine nucleus or a thiazolo[4,5-b]quinoline nucleus.
- 11. A photographic element according to claim 10 wherein said dye is selected from:
- a. 2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline;
- b. 2-(2,4-dinitrobenzylidene)-3-ethyl-2,3-dihydrothiazolo[4,5-b]quinoline;
- c. 2-(2,4-dinitrobenzylidene)-3-ethyl-6-nitrobenzothiazoline;
- d. 2-(2,4-dinitrobenzylidene)-1,3,3-trimethylindolenine; and
- e. 4-(2,4-dinitrobenzylidene)-1-ethylquinoline.
- 12. In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein 6-chloro-2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline.
- 13. In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 4-(2,4-dinitrobenzylidene)-2,6-diphenyl-4H-pyran.
- 14. In a photographic element comprising a support and, coated thereon, radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-4,6-diphenyl-2H-pyran.
- 15. In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-1,3-dithiolane.
- 16. In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein a photobleachable dye having the following formula: ##STR26## wherein: a. k represents 0 or 1;
- b. m represents 0 or 1;
- c. each L represents a methine group;
- d. R.sub.1 represents an alkyl group, an alkenyl group or an aryl group;
- e. Z.sub.1 represents the nonmetallic atoms necessary to complete a cyanine dye type nucleus comprising a 5- to 6-membered heretocyclic nucleus selected from the group consisting of an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, a 3,3-dialkylindolenine nucleus, and imidazo[4,5-b]quinoxaline nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, a 3H-pyrrolo-[2,3-b]pyridine nucleus and a thiazolo[4,5-b]quinoline nucleus; and
- f. Y represents the atoms necessary to complete a nitro-substituted phenyl or naphthyl group, a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having 4- and 6-position electron-withdrawing groups, or a nitro-substituted phenyl group having a 6-position electron-withdrawing group.
- 17. A photographic element according to claim 16 in which said electron-withdrawing groups are chosen from the class consisting of nitro, ethoxycarbonyl and trifluoromethyl groups.
- 18. A photographic element according to claim 1 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.20.
- 19. A photographic element according to claim 16 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.50.
CROSS-REFERENCE TO RELATED APPLICATIONS
This is a continuation application of Ser. No. 443,654, filed Feb. 19, 1974 (now abandoned), which is a continuation-in-part of application Ser. No. 260,618, filed June 7, 1972 (now abandoned), which is a continuation-in-part of application Ser. No. 176,681, filed Aug. 25, 1971 (now abandoned).
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
2255077 |
Middelton et al. |
Sep 1941 |
|
3647433 |
Contokis |
Mar 1972 |
|
3948664 |
Dkuyama et al. |
Apr 1976 |
|
Non-Patent Literature Citations (4)
Entry |
Margerum et al., J. Phys. Chem., 66, 2434-2438, (1962). |
Berson et al., Am. Chem. Soc., 77, 447-450, (1955). |
Wizinger et al., J. Prabst Chem., 153, 127-155. |
Yagupolsky et al., J. Gen. Chem. USSR 23, 497-502, (1953). |
Continuations (1)
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Number |
Date |
Country |
Parent |
443654 |
Feb 1974 |
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Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
260618 |
Jun 1972 |
|
Parent |
176681 |
Aug 1971 |
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