Photonic crystal fibers

Information

  • Patent Grant
  • 6631234
  • Patent Number
    6,631,234
  • Date Filed
    Thursday, November 8, 2001
    22 years ago
  • Date Issued
    Tuesday, October 7, 2003
    20 years ago
Abstract
A photonic crystal fiber including a plurality of longitudinal holes (220), in which at least some of the holes have a different cross-sectional area in a first region (200) of the fiber, that region having been heat-treated after fabrication of the fiber, from their cross-sectional area in a second region of the fiber (190), wherein the optical properties of the fiber in the heat-treated region (200) are altered by virtue of the change in cross-sectional area of holes (230) in that region (200).
Description




This invention relates to the field of photonic crystal fibers.




A photonic crystal fiber is a special form of optical fiber. Single-mode optical fibers are widely used in applications such as telecommunications and sensing. Such fibers are typically made entirely from solid transparent materials such as glass and each fiber typically has the same cross-sectional structure along its length. The transparent material in one part (usually the middle) of the cross-section has a higher refractive index than the rest and forms an optical core within which light is guided by total internal reflection. We refer to such a fiber as a standard fiber.




There are many well-established techniques and machines for handling and processing standard fibers; for example, cleavers use a hard knife-edge to break a fiber, giving a clean end-face, and fusion splicers use a hot electric arc to join two fibers together at their ends. One process, fusion-tapering, is used to make a variety of fiber devices for performing some function on light passing along a fiber. In that process, a fiber is locally heated until it softens and then it is stretched so as to narrow the fiber locally in the heated region. Light passing along the fiber is affected by the narrowness of the treated region. In a typical tapered single-mode fiber, the light spreads out from the core and occupies more of the surrounding cladding. If the fiber is sufficiently narrowed, the light spreads out from the core completely and is then guided by the outer boundary of the entire fiber. The fiber is typically heated by immersion in a gas flame, proximity to an electrical heater or exposure to an intense laser beam.




A tapered fiber that is cleaved at the narrowest point of the taper can act as a beam expander because the light wave has a greater cross-section at the cleave than it has in the untreated fiber. Such a beam expander can assist the launching of light into the fiber and extraction of light from the fiber.




A fiber that is tapered so that light is locally guided at its outer boundary can act as a local optical sensor. In the tapered region, the light is sensitive to the medium surrounding the fiber, whereas elsewhere it is insensitive because it is buried in the central core.




Two or more fibers that are tapered together in parallel contact can act as a fiber beam-splitter (or directional coupler), in which at least some of the light in one fiber transfers across to the other fiber in the narrowed region.




In the last few years a non-standard type of optical fiber has been demonstrated, called the photonic-crystal fiber (PCF). Typically, this is made from a single solid, and substantially transparent, material, such as fused silica glass, within which is embedded a periodic array of air holes, running parallel to the fiber axis and extending the full length of the fiber. A defect in the form of a single missing air hole within the regular array forms a region of raised refractive index, which acts as a waveguiding fiber core within which light is guided, in a manner analogous to total-internal-reflection guiding in standard fibers. Another mechanism for guiding light is based on photonic-band-gap effects rather than total internal reflection. Photonic-band-gap guidance can be obtained by suitable design of the array of air holes. Light of some propagation constants can be confined to the core and will propagate therein.




Photonic-crystal fiber can be fabricated by stacking glass capillaries and canes on a macroscopic scale into the required shape, and then holding them in place while fusing them together and drawing them down into a fiber.




The PCF has a number of technologically significant properties; for example, it can support a single-mode over a very broad range of wavelengths, it can have a large mode area and thus carry high optical powers, and it can have a large normal dispersion at the telecommunications wavelength of 1.55 microns. PCFs are typically not circularly symmetric, as a result of the stack-and-draw method typically used to make them.




Technological application of PCFs would be facilitated by handling and processing techniques parallel to those described above for standard fibers. Unfortunately, some of those techniques are not appropriate for PCFs; for example, an attempt to fusion splice two PCFs together causes the air inside them to expand explosively, destroying the fiber ends being joined.




It is an object of the invention to provide PCF optical devices analogous to standard fiber devices. It is another object of the invention to provide a process for producing such devices.




According to the invention there is provided a photonic crystal fiber including a plurality of longitudinal holes, in which at least some of the holes have a different cross-sectional area in a first region of the fiber, that region having been heat-treated after fabrication of the fiber, from their cross-sectional area in a second region of the fiber, wherein the optical properties of the fiber in the heat-treated region are altered by virtue of the change in cross-sectional area of the holes in that region.




The words “after fabrication” should be taken to mean any time after the fiber has been drawn.




The heat treatment processes that can be used are typically the same as those described above for fusion tapering of standard fibers. As with standard fibers, the heat treatment can be accompanied by stretching, to narrow the fiber down. In contrast to standard fibers, however, changes in optical properties can result without stretching the fiber at all; that is because heat treatment can allow some or all of the holes in the fiber to collapse partially or completely under the influence of surface tension. That can be achieved either with or without simultaneous stretching. Furthermore, if some of the holes are pressurized, they can be made to expand instead of collapse, and differential pressurization of the holes can, in principle, be used to create any pattern of hole collapse and expansion. As with the tapering of standard fibers, for most applications, the transitions between untreated fiber and the middle of the heat treated region must be sufficiently gradual that an acceptably small amount of light is lost along the transition—the so-called criterion for adiabaticity.




It may be that at least some of the holes have expanded in the heat-treated region.




It may be that at least some, or all, of the holes have collapsed at least partially, or completely, in the heat-treated region.




The pattern of hole collapse and/or expansions may be not circularly symmetric. The birefringence of the fiber may be altered by the lack of circular symmetry.




The fiber may have been narrowed in the heat-treated region.




The photonic crystal fiber may be included in an optical device.




The photonic crystal fiber may be included in a mode-field transformer, the transformer being arranged so that a guided mode propagating through the transformer will have its field distribution changed by propagation through the heat-treated region of the photonic crystal fiber. The shape and size of the field distribution of the guided mode in a PCF depends on the relative sizes of the air holes and their separations from each other. Thus a PCF that has been heat treated to change the sizes of the holes (or narrow down the entire fiber) can act as a mode field transformer.




The photonic crystal fiber may be included in a multi mode to single mode transformer or mode filter, in which the untreated regions of the fiber are multi mode and the heat-treated region is single mode for at least one wavelength of light. Light propagating through the treated region will be forced into a single mode and will remain substantially single mode when it passes into the untreated region, which is capable of supporting other modes; those other modes will, in an ideal fiber, remain unexcited.




The photonic crystal fiber may be included in a fiber input- or output-coupler, in which the photonic crystal fiber is cleaved in the heat-treated region. Such devices can be used to enhance the coupling of light into or out of the end of the fiber if the fiber is cleaved in the region of the heat treatment.




The fiber input- or output-coupler may be arranged so that, when a mode is propagating through the coupler, the mode pattern at the cleaved face will substantially match the mode shape of an external optical element. The external optical element may be a diode laser. Making the mode elliptical or rectangular will allow more efficient launching of light into the fiber from a diode laser source. Indeed, simply expanding the mode size will make easier launching of light from other sources into the fiber.




The fiber coupler may be included in a fiber splice, in which the fiber coupler is joined to one or more other fibers. The joining may, for example, be effected by fusion, by an adhesive or by abutment.




At least one of the one or more other fibers included in the fiber splice may be selected from the following: a cleaved photonic crystal fiber; a fiber coupler, as described above; a standard fiber; or a standard fiber that has been tapered by stretching during heat treatment and then cleaved. Controlled hole collapse provides a way of fusion splicing pairs of PCFs together. First the troublesome air holes are eliminated by their complete collapse in a portion of each fiber, as described above. It is not necessary to stretch the fibers. The fibers are cleaved at the portions where the holes have collapsed, and can then be fusion spliced, since there are no holes to explode and the mode fields will match. (If the fibers are not identical, one or both of them can be stretched so that their outer diameters match. Their mode fields will then be identical.) As an alternative to fusion splicing, two PCFs that have matched mode fields can be mechanically spliced using an adhesive in the conventional way.




A standard fiber tapered to the point where the light is guided by its outer boundary has a similar mode field to a PCF whose holes have collapsed completely and which has also been stretched to the same final diameter. The splice will then be low in loss.




A photonic crystal fiber according to the invention may be arranged so that interaction of light, propagating in the photonic crystal fiber, with the external environment is enhanced or suppressed in the heat-treated region. Such a photonic crystal fiber may be included in an optical device, such as, for example, a mode-field transformer. The interaction may facilitate measurement of a measurand of the fiber's external environment. The interaction may, for example, be with an external optical element. The optical element may comprise one or more other optical fibers. At least one of the one or more other optical fibers may be a photonic crystal fiber according to the invention or a standard fiber. The spreading out of the mode field caused by collapse of air holes will increase the intensity of the field at the outer boundary of the fiber. Light at the boundary is free to interact with the environment around the fiber. Interactions with the external environment can therefore be enhanced (or suppressed) by hole collapse (or expansion). If the light can interact with a particular property in the environment (for example, the external refractive index), the treated fiber will act as an environmental sensor. If a suitable optical element is placed next to the fiber, optical devices can be built based on the interaction with that element. In particular, the optical element can be at least one other fiber, which may be a PCF or a standard fiber and may have been fused to the first fiber during the heat treatment, in a similar process to the fabrication of fused directional couplers in standard fibers.




At least two fibers in the optical device may have been at least partly fused together by heat treatment.




Similarly, variation of the mode field can be used to control the interaction of the light in the core with any structure that has been introduced into the rest of the fiber. Examples of such structures are diffraction gratings, doped regions (which may be optically pumped to provide gain), or indeed additional guiding cores. Devices that can be based on such interactions include directional couplers, spectral filters, sensors and lasers or optical amplifiers. A photonic crystal fiber according to the invention may be arranged so that interaction of light, propagating in the photonic crystal fiber, with a structure (deliberately) introduced elsewhere in the fiber is enhanced or suppressed in the heat-treated region. Such a photonic crystal fiber may be included in an optical device. The introduced structure may, for example, be one of the following: at least one other core region in the photonic crystal fiber; a grating; or a region of doped material.




The optical device may be included in another optical device such as a directional coupler, a spectral filter, an optical sensor, a laser or an optical amplifier (which may in turn include a directional coupler).




Also according to the invention there is provided a method of producing a photonic crystal fiber, including the following steps: fabricating a photonic crystal fiber having a plurality of longitudinal holes; and heat-treating a region of the fiber so that at least some of the holes in that region have a different cross-sectional area from their cross-sectional area in regions of the fiber which have not been heat-treated, the optical properties of the fiber in the heat-treated region being altered by changing the cross-sectional area of holes in that region.




At least some of the holes may be pressurized during the heat treatment. All of the holes may be pressurized during the heat treatment.




The heat treatment may cause at least some, or all, of the air holes within the fiber to collapse completely in the treated region.




It may be that the heat treatment is not applied in a circularly symmetric manner, so that a pattern of hole collapse and/or expansion that is not circularly symmetric results. The birefringence of the fiber may thereby be altered in the heat-treated region. The polarisation properties of a PCF depend on the structure in the vicinity of the core. Controlled variation of air hole sizes and overall fiber diameter can therefore be used to modify the birefringence of the fiber.




The fiber may be narrowed locally by stretching during the heat treatment.




The heat treatment may change the physical and/or chemical state of at least some of the material within the fiber.











An embodiment of the invention will now be described, by way of example only, with reference to the accompanying drawings, of which





FIG. 1

is a schematic cross-sectional view through a standard fiber.





FIGS. 2



a


and


2




b


are schematic views showing heat treatment of a standard fiber.





FIG. 3

is a schematic cross-sectional view through a photonic crystal fiber of the prior art.





FIG. 4

is a schematic cross-sectional view through another photonic crystal fiber of the prior art.





FIG. 5

is a schematic view of an arrangement for carrying out heat-treatment of a fiber.





FIG. 6

is a schematic view showing the effect of heat treatment on a photonic crystal fiber.





FIG. 7

is a schematic view of a directional coupler or beam-splitter.





FIG. 8

is a schematic longitudinal section through a fiber splice.





FIG. 9

is a schematic longitudinal cross-section through a multi-core fiber.





FIG. 10

is a schematic view of (a) an untreated photonic crystal fiber and (b) a photonic crystal fiber which has been heat-treated to produce birefringence.











Standard fibers, such as the one shown, for example, in

FIG. 1

, in their simplest form comprise essentially a cylindrical core


10


and concentric cylindrical cladding


20


. Typically, both the core and the cladding will be made of the same material, usually silica, but each is doped with other materials in order to raise the refractive index of the core


10


and lower the refractive index of the cladding


20


. Light, of appropriate wavelengths, is confined to the core


10


, and guided therein, by total internal reflection at the core-cladding boundary


15


.




It is known to heat-treat and stretch standard fibers in order to produce a stretched and narrowed region with optical properties different from those of the rest of the fiber (

FIGS. 2



a


and


b


). In

FIG. 2



a


, the fiber is shown held by clamps


30


and is pulled in opposing directions parallel to is longitudinal axis


40


. Heat


50


is applied to the fiber. The result of that treatment is shown in

FIG. 2



b


: a waist


60


is formed in the fiber. The cross-sectional area of the core


10


is greatly reduced and the cladding


20


is also significantly narrowed. There is a transitional region


70


between the waist


60


and the rest of the fiber


80


.




A typical photonic crystal fiber, shown in

FIG. 3

, comprises a strand of transparent bulk material


90


(e.g. silica) with a lattice of holes


100


, which run along its length. The holes are arranged at the vertices and centres of tesselating regular hexagons. The holes have a regular period, broken by the omission of one hole near the centre of the fiber. The region


110


of the fiber surrounding the site of the missing hole has the refractive index of the bulk material


90


. The refractive index of the remainder of the fiber is attributable to the refractive index of both the bulk material


90


and the air in the holes


100


. The refractive index of air is lower than that of, for example, silica and, consequently, the ‘effective refractive index’ of the material with the holes is lower than that of the region


110


surrounding the missing hole. The fiber can therefore confine light approximately to the region


110


, in a manner analogous to waveguiding by total internal reflection in standard fibers. The region


110


is therefore referred to as the ‘core’ of the photonic crystal fiber.




In another form of photonic crystal fiber, photonic band gap guidance acts to confine light to the fiber ‘core’. In the example of such a fiber shown in

FIG. 4

, there is a matrix of holes


120


in bulk material


90


. The holes are arranged at the vertices (but not the centres, cf.

FIG. 3

) of regular hexagons. The regularity of the matrix is again broken by a defect, but it is, in the illustrated example, an additional hole


130


at the centre of one of the lattice hexagons, that hexagon being near the centre of the fiber. The area surrounding the additional hole


130


can again be referred to as the core of the fiber. Disregarding (for the moment) hole


130


, the periodicity of holes in the fiber. results in there being a band-gap in the propagation constants of light which can propagate in the fiber. The addition of hole


130


effectively creates a region that can support propagation constants different from those supported in the rest of the fiber. If some of the propagation constants supported in the region of hole


130


fall within the band-gap of propagation constants forbidden in the rest of the fiber then light having those propagation constants will be confined to the core and propagate therein. Note that because the hole


130


is a low-index defect (it results in air being where bulk material would otherwise be), total internal reflection effects are not responsible for that waveguiding.




A set-up suitable for use in heat-treatment of a, photonic crystal fiber is illustrated in FIG.


5


. The fiber


140


is clamped to stages


150


, which are in a fixed position; there is no deliberate stretching of the fiber


140


. A burner stage


160


, having a burner arm


170


is arranged so that a flame


180


heats a portion of fiber


140


between the stages


150


. It should be noted that many other heating mechanisms are suitable for carrying out the invention, including, for example, heating with an electric heater or the beam of a carbon dioxide laser.




An example of the effects of heat treatment on a photonic crystal fiber are shown in FIG.


6


. There is a heat-treated region


200


, an untreated region


190


and a transition region


210


. In the example shown, portions


230


of holes in the heat-treated region


200


can be seen to have partially collapsed, when compared with portions


220


in the untreated region


190


. The cross-sectional area of each of at least some of the holes therefore varies along the length of that hole. The overall diameter of the fiber will also reduce slightly, although the cross-sectional area of glass


240


in the untreated region


190


will be much the same as that of glass


250


in the treated region


200


.





FIG. 7

shows the structure of an optical device that could be made using the photonic crystal fiber of the invention, namely a directional coupler or beam-splitter. A region


280


,


290


in each of two photonic crystal fibers


260


,


270


is heat-treated according to the invention. Regions


280


,


290


are fused together, for example simultaneously with the heat treatment or by further heat treatment. Light in the heat-treated regions


280


,


290


extends into the cladding region of the fiber, because hole collapse has weakened or destroyed the refractive index difference between the cladding and the core. Light propagating in, for example, fiber


260


will be coupled into fiber


270


where the fibers are fused together in regions


280


,


290


.




Splicing of a photonic crystal fiber


330


to a standard fiber


420


is shown in FIG.


8


. Each fiber is heat-treated stretched and cleaved to produce tapered regions


340


,


380


. In tapered region


340


of the photonic crystal


330


, holes


300


are substantially eliminated. In tapered region


380


of standard fiber


420


, both core


410


and cladding


400


taper whilst retaining their independent identities. The two fibers are joined by fusion splice


360


.




Light mode


320


propagating in defect core region


310


spreads out to fill the full width of tapered region


340


. Mode


350


in that region matches mode


370


in the tapered region


380


of standard fiber


420


. Away from the tapered region


380


, light is in the usual mode


390


of standard fiber


420


.





FIG. 9

shows a multi-core photonic crystal fiber


440


. That Figure (like

FIGS. 6

,


8


and


10


), shows a few holes only; there will be, of course, many holes in a real fiber. Holes


430


surround two cores


480


,


490


; those cores do not interact optically in untreated regions of the fiber. In heat-treated region


450


, holes


430


have partially collapsed. In that region, light propagating in either core


480


,


490


can interact with light propagating in the other core. The heat-treated region


450


can then act as a localised directional coupler.




The hexagonal symmetry of holes


500


about the core


510


of the fiber of FIG.


10


(


a


) can be broken by selective collapse of holes


520


by heat treatment to produce the two-fold rotational symmetry of FIG.


10


(


b


). The birefringence of the fiber may be thus altered in the heat-treated region, as a fiber having such a symmetry will, in general, be birefringent.



Claims
  • 1. A photonic crystal fiber including a plurality of longitudinal holes, in which at least some of the holes have a different cross-sectional area in a first region of the fiber, that region having been heat-treated after fabrication of the fiber, from their cross-sectional area in a second region of the fiber, wherein the optical properties of the fiber in the heat-treated region are altered by virtue of the change in cross-sectional area of holes in that region.
  • 2. A photonic crystal fiber as claimed in claim 1, in which at least some of the holes have expanded in the heat treated region.
  • 3. A photonic crystal fiber as claimed in claim 1, in which all of the holes have expanded in the heat treated region.
  • 4. A photonic crystal fiber as claimed in claim 1, in which at least some of the holes have partially collapsed in the heat-treated region.
  • 5. A photonic crystal fiber as claimed in claim 1, in which at least some of the holes have collapsed completely in the heat-treated region.
  • 6. A photonic crystal fiber as claimed in claim 1, in which all of the holes have collapsed completely in the heat-treated region.
  • 7. A photonic crystal fiber as claimed in claim 1, in which the pattern of hole collapse and/or expansion is not circularly symmetric.
  • 8. A photonic crystal fiber as claimed in claim 7, in which the birefringence of the fiber is altered by the lack of circular symmetry.
  • 9. A photonic crystal fiber as claimed in claim 1, in which the fiber has been narrowed in the heat-treated region.
  • 10. An optical device including a photonic crystal fiber as claimed in claim 1.
  • 11. A mode-field transformer, including a photonic crystal fiber as claimed in claim 1, the transformer being arranged so that a guided mode propagating through the transformer will have its field distribution changed by propagation through the heat-treated region of the photonic crystal fiber.
  • 12. A multi mode to single mode transformer or mode filter, including a photonic crystal fiber as claimed in claim 1, in which the untreated regions of the fiber are multi mode and the heat-treated region is single mode for at least one wavelength of light.
  • 13. A fiber input- or output-coupler, including a photonic crystal fiber as claimed in claim 1, in which the photonic crystal fiber is cleaved in the heat-treated region.
  • 14. A fiber input- or output-coupler according to claim 13, the coupler being arranged so that, when a mode is propagating through the coupler, the mode pattern at the cleaved face will substantially match the mode shape of an external optical element.
  • 15. A fiber input- or output-coupler according to claim 14, in which the external optical element is a diode laser.
  • 16. A fiber splice, including a fiber input- or output-coupler according to claim 13, in which the fiber coupler is joined to one or more other fibers.
  • 17. A fiber splice according to claim 16, in which the fiber coupler is joined to one or more other fibers by fusion.
  • 18. A fiber splice according to claim 16, in which the fiber coupler is joined to one or more other fibers by an adhesive.
  • 19. A fiber splice according to claim 16, in which the fiber coupler is joined to one or more other fibers by abutment.
  • 20. A fiber splice according to claim 16, in which at least one of the one or more other fibers is a cleaved photonic crystal fiber.
  • 21. A fiber splice according to claim 20, in which at least one of the one or more other fibers is a fiber coupler according to claim 13.
  • 22. A fiber splice according to claim 16, in which one or more of the other fibers is a standard fiber.
  • 23. A fiber splice according to claim 22, in which at least one of the one or more other fibers that is a standard fiber has been tapered by stretching during heat treatment and then cleaved.
  • 24. A photonic crystal fiber as claimed in claim 1, which is arranged so that interaction of light, propagating in the photonic crystal fiber, with the external environment is enhanced or suppressed in the heat-treated region.
  • 25. An optical device including a photonic crystal fiber according to claim 24.
  • 26. An optical device according to claim 25, in which the optical device is a mode-field transformer.
  • 27. An optical device according to claim 25, in which the interaction facilitates measurement of a measurand of the fiber's external environment.
  • 28. An optical device according to claim 25, in which the interaction is with an external optical element.
  • 29. An optical device according to claim 28, in which the optical element comprises one or more other optical fibers.
  • 30. An optical device according to claim 29, in which at least one of the one or more other optical fibers is a photonic crystal fiber according to claim 24.
  • 31. An optical device according to claim 28, in which at least one of the at least one other optical fibers is a standard fiber.
  • 32. An optical device according to claim 29, in which at least two fibers have been at least partly fused together by heat treatment.
  • 33. A photonic crystal as claimed in claim 1, which is arranged so that interaction of light, propagating in the photonic crystal fiber, with a structure introduced elsewhere in the fiber is enhanced or suppressed in the heat-treated region.
  • 34. An optical device including a photonic crystal fiber according to claim 33.
  • 35. An optical device according to claim 34, in which the introduced structure is at least one other core region in the photonic crystal fiber.
  • 36. An optical device according to claim 34, in which the introduced structure is a grating.
  • 37. An optical device according to claim 34, in which the introduced structure is a region of doped material.
  • 38. A directional coupler including an optical device as claimed in claim 33.
  • 39. A spectral filter including an optical device as claimed in claim 33.
  • 40. An optical sensor including an optical device as claimed in claim 33.
  • 41. A laser or optical amplifier including an optical device as claimed in claim 33.
  • 42. A laser or optical amplifier including a directional coupler according to claim 38.
  • 43. A method of producing a photonic crystal fiber, including the following steps:(a) fabricating a photonic crystal fiber having a plurality of longitudinal holes; (b) heat-treating a region of the fiber so that at least some of the holes in that region have a different cross-sectional area from their cross-sectional area in regions of the fiber which have not been heat-treated, the optical properties of the fiber in the heat-treated region being altered by changing the cross-sectional area of holes in that region.
  • 44. A method according to claim 43, in which at least some of the holes are pressurized during the heat treatment.
  • 45. A method according to claim 44, in which all of the holes are pressurized during the heat treatment.
  • 46. A method according to claim 43 in which the heat treatment causes at least some of the holes within the fiber to collapse at least partially in the treated region.
  • 47. A method according to claim 43, in which the heat treatment causes at least some of the holes within the fiber to collapse completely in the treated region.
  • 48. A method according to claim 47, in which the heat treatment causes all of the holes within the fiber to collapse completely in the treated region.
  • 49. A method according to claim 43, in which the heat treatment is applied in a non-circularly-symmetric manner, so that a pattern of hole collapse and/or expansion that is not circularly symmetric results.
  • 50. A method according to claim 49, in which the birefringence of the fiber is altered in the heat-treated region.
  • 51. A method according to claim 43, in which the fiber is narrowed locally by stretching during the heat treatment.
  • 52. A method according to claim 43, in which the heat treatment changes the physical and/or chemical state of at least some of the material within the fiber.
Priority Claims (1)
Number Date Country Kind
9903918 Feb 1999 GB
PCT Information
Filing Document Filing Date Country Kind
PCT/GB00/00599 WO 00
Publishing Document Publishing Date Country Kind
WO00/49435 8/24/2000 WO A
US Referenced Citations (3)
Number Name Date Kind
5802236 DiGiovanni et al. Sep 1998 A
6515305 Gopinath Feb 2003 B2
6522433 Kelsey et al. Feb 2003 B2
Foreign Referenced Citations (2)
Number Date Country
0 810 453 Dec 1997 EP
0016141 Mar 2000 WO
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