The present invention relates to optical waveguides using photonic crystals.
In recent years, research and development of new optical fibers referred to as holey fibers or photonic crystal fibers have progressed at a dramatic pace. In conventional optical fibers, the light is confined to the core portion by a simple refractive index difference. In contrast, these new optical fibers are characterized by having a complicated two-dimensional structure in their cross section. For example, the light can be confined in the core portion by establishing a refractive index difference between the cladding portion and the core portion by reducing the effective refractive index in the cladding portion through the arrangement of holes in the cladding portion. Alternatively, the light can be confined in the core portion by forming a photonic band gap with respect to the guided light in the core portion through making the cladding portion of a photonic crystal. Optical fibers are constituted by such means.
It is possible to change the characteristics of holey fibers and photonic crystal fibers considerably through their structure, so that applications such as dispersion compensation optical fibers with increased wavelength dispersion, optical fibers with large non-linear optical effects and zero dispersion optical fibers with zero dispersion in the visible spectrum have been proposed. Moreover, the complicated two-dimensional structures can be fabricated for example by heating and stretching a plurality of quartz pipes that are bundled together (see for example “O Plus E”, vol. 23, No. 9, p. 1061, 2001)
In the holey fibers and photonic crystal fibers that have been proposed so far, single mode propagation with the 0-th mode is used for the guided light propagating through the core portion. In single mode propagation, there are extremely little changes of the refractive index with respect to the frequency. Consequently, it is not possible to attain the characteristics of group velocity anomalies or very large dispersion. Therefore, even though single mode propagation is a necessary condition to prevent wavelength dispersion due to multi-mode propagation, at the same time it also poses restrictions with regard to the core cross section area and the optical fiber performance.
It is an object of the present invention to solve the problems of the prior art and to provide a photonic crystal optical waveguide that can propagate the desired band propagation light.
A photonic crystal optical waveguide in accordance with the present invention includes a optical waveguide portion having a core made of a photonic crystal with a structure having a periodic refractive index in at least one direction perpendicular to a propagation direction of guided light and having a uniform refractive index in the propagation direction of the guided light, and a cladding arranged in contact with the core, in order to confine the guided light in the core, and an incident-side phase modulation portion arranged in close proximity or in contact with an incident surface of the core.
A photonic crystal optical waveguide according to an embodiment of the present invention can propagate waves associated with specific higher-order photonic bands. Thus, the function of the photonic crystal can be utilized with high efficiency.
In a photonic crystal optical waveguide according to a preferred embodiment of the present invention, there is a photonic band in the propagation direction of the light in the core, the incident-side phase modulation portion phase-modulates incident guided light and lets it propagate through the core of the optical waveguide portion, and the core propagates all or at least half of the energy of the phase-modulated guided light as a wave associated with higher-order photonic bands of said photonic bands. Thus, higher-order band propagation light with little loss due to first-order band propagation light can be caused to propagate through the core. Therefore, it is possible to use the photonic crystal optical waveguide as a dispersion compensation element or as an optical delay element, for example.
The incident-side phase modulation portion may be a phase grating having a refractive index period that is adjusted to the refractive index period of the core.
The incident-side phase modulation portion may be a phase grating having the same structure as the core, and having the same refractive index period as the core.
Preferably, the incident-side phase modulation portion is a portion separated by cutting an end portion vicinity on the incident surface side of the core. Thus, the incident-side phase modulation portion can be fabricated easily.
Moreover, the core may let a wave associated with the second coupled photonic band from the lowest order of the phase-modulated guided light propagate.
Also, it is preferable that the photonic crystal optical waveguide further comprises an emerging-side phase modulation portion arranged in close proximity or in contact with an emerging surface of the core from which the guided light emerges. Thus, the light emerging from the core can be changed into a plane wave.
Also, the emerging-side phase modulation portion may have a structure converting the light emerging from the emerging surface of the core into a plane wave.
The emerging-side phase modulation portion may be a phase grating having a refractive index period that is adjusted to the refractive index period of the core.
The emerging-side phase modulation portion may be a phase grating having the same structure as the core, and having the same refractive index period as the core.
Preferably, the emerging-side phase modulation portion is a portion separated by cutting an end portion vicinity on the emerging surface side of the core. Thus, the emerging-side phase modulation portion can be fabricated easily.
Also, it is preferable that the cladding is made of a photonic crystal having a periodic refractive index in at least one direction perpendicular to a propagation direction of the guided light and having a uniform refractive index in the propagation direction of the guided light. Thus, leaking of the light from the core can be prevented even when the effective refractive index of the core is low.
The core may comprise an active material having an optical non-linear effect. Thus, it is possible to provide an optical element with a large non-linear optical effect.
The core may be made of a multilayer film layer having a periodic refractive index in one or two directions perpendicular to the propagation direction of the guided light and having a uniform refractive index in the propagation direction of the guided light.
Preferably, the optical waveguide portion has a fiber shape with a substantially circular cross section, and the core is fiber-shaped with the cladding formed around the core, and the core and the cladding have a uniform refractive index in the propagation direction of the guided light. Thus, it is possible to provide a fiber-shaped dispersion compensation element or optical delay element, for example.
The refractive index periods of the core and the cladding may be symmetric with respect to the center axis of the optical waveguide portion, which is parallel to the propagation direction of the guided light.
Preferably, the optical waveguide portion comprises a fiber-shaped homogenous substance with a substantially circular cross section, a plurality of cavities are formed in the homogenous substance along its longitudinal direction, the plurality of cavities are formed symmetric to the center axis of the optical waveguide portion, which is parallel to the propagation direction of the guided light. Thus, it is possible to provide a fiber-shaped dispersion compensation element or optical delay element, for example.
All or some of the cavities may be filled with a fluid substance. The cavities may be filled with an acrylic monomer as the fluid substance, and irradiated with UV light from the outside to be polymerized into acrylic polymer.
The refractive index in the cross section of the optical waveguide portion may change periodically and in concentric circles with respect to a distance from the center axis of the optical waveguide portion, which is parallel to the propagation direction of the guided light.
The following is a detailed explanation of embodiments of the present invention.
First, the propagation of light in a photonic crystal is explained.
In
The photonic bands of the one-dimensional photonic crystal 1 shown in
In the multilayer structure 5 of the period a in which layers of the material 5a and the material 5b are layered in alternation, the results of the band calculation for the first to third bands, calculated by the plane wave method for the Z-axis direction (same for X-axis direction), are shown in
In
Now, if incident light 2 with a vacuum wavelength of kB1 incident on the one-dimensional photonic crystal 1, then there are wave vectors kB1 and kB3 corresponding to the first and third bands. It should be noted that the second band is “uncoupled” with respect to the propagation in the Z-axis direction, so that it can be ignored. Consequently, a wave of first band propagation light with a wavelength λB1=2π/kB1 and a wave of third band propagation light with a wavelength λB3=2π/kB3 propagate in the Z-axis direction through the one-dimensional photonic crystal 1. Light of coupled bands that are not the lowest-order band (first band), such as the third band light in
The foregoing was an explanation of TE polarized light with reference to
Here, the numeric value obtained by dividing the wavelength of light in vacuum (λA, λB, etc.) by the corresponding wavelength in the one-dimensional photonic crystal (λA1, λB3, etc.) is defined as the “effective refractive index.” As can be seen from
It is well known that the value obtained by differentiating the band curves by kz (that is, the slope of the tangent at the band curves) in the band diagrams shown in
Incident light 12 is incident on one end of the photonic crystal optical waveguide 17. The incident light 12 is coupled into the homogenous optical waveguide 16, and is coupled from the homogenous optical waveguide 16 into the one-dimensional photonic crystal 15. The light propagates in the longitudinal direction (Z-axis direction), and emerges as emitted light 13 from the other end of the photonic crystal optical waveguide 17. When this light is higher-order band propagation light, then a group velocity anomaly of this higher-order band propagation light occurs in the one-dimensional photonic crystal 15. Thus, the photonic crystal optical waveguide 17 can be used as an optical delay element, for example.
However, there are a number of problems in using the photonic crystal optical waveguide 17 or the optical fiber 21 shown in
Moreover, in
Furthermore, when the effective refractive index of the higher-order band propagation light becomes smaller than the refractive index of the surrounding medium (cladding) in contact with the one-dimensional photonic crystal 1, then the guided light 4 leaks out into the cladding. Thus, light may not be guided in the one-dimensional photonic crystal 1 at the core. In particular when the effective refractive index of the higher-order band propagation light is less than 1, there is the problem that it is not possible to prevent the leaking of light, even when the cladding is air.
As shown in
By comparison, in the higher-order band propagation light, “nodes 4c” at which the electric field amplitude becomes zero occur near the boundary of the material 5a and the material 5b, as shown in
Consequently, for incident light of a wavelength at which a plurality of bands contribute, there are a plurality of propagated light modes, which overlap and form a complex electric field pattern. For example, with the incident light with a vacuum wavelength of kB shown in
However, research by the inventors has shown that when incident light that has been subjected to a phase modulation is coupled into a photonic crystal with photonic bands in the propagation direction of the guided light, then it is possible to propagate only certain higher-order band propagation light. The photonic crystal optical waveguides according to embodiments of the present invention utilize this.
Referring to the drawings, the following is an explanation of photonic crystal optical waveguides according to embodiments of the present invention.
The one-dimensional photonic crystal 1 is the same as the one shown in
The phase grating 6 is arranged in close proximity or in contact with an end face of the one-dimensional photonic crystal 1 on which the light is incident. It is also possible that a space 18 is formed between the phase grating 6 and the one-dimensional photonic crystal 1, for example.
The effect that the phase grating 6 has on the incident light (plane wave) is to cause a difference of about half a wavelength in the period a in the Y-axis direction. When the incident light 7, which is a plane wave, is incident on the phase grating 6, then an electric field pattern that is similar to the higher-order band propagation light in the one-dimensional photonic crystal shown in
This means that when a suitable phase-modulated wave having the same period in the same direction as the periodic structure of the photonic crystal is coupled into that photonic crystal, then it is possible to attain a propagation of light in specific bands only.
A phase grating 6 is used as the phase modulation portion, and the following is a more specific explanation of the parameters for the phase modulation portion.
The simplest phase modulation portion is a phase grating having the same period as the periodic multilayer films of the core constituted by the one-dimensional photonic crystal 1. The phase grating 6 can be configured by layering a material 5c and a material 5d with different refractive indices periodically in alternation, as shown in
For example, it is preferable to optimize the thicknesses tC and tD in the Y-axis direction of the material 5c and the material 5d in
tA+tB=tC+tD
is satisfied, and that the center in the Y-axis direction of the material 5a and the material 5c matches the center in the Y-axis direction of the material 5b and the material 5d, respectively. Thus, the periods of the phase grating 6 and the one-dimensional photonic crystal 1 are synchronized to be the same.
It is preferable that also the thickness G of the space 18 between the phase grating 6 and the one-dimensional photonic crystal 1 is chosen to be in a suitable range, because it affects the guided light.
Moreover, if the period a (=tA+tB) of the multilayer structure 5 is not greater than the vacuum wavelength λ0 of the incident light 7, and an air layer is taken as the space 18 in the gap between the two, then the ±1-order diffraction light due to the phase grating 6 cannot propagate and the reflection light increases. One way to prevent this is to fill the space 18 with a medium with a large refractive index so as to increase the refractive index of the space 18. More specifically, a medium with a refractive index nG should be filled into the space 18, where nG is given by the following equation:
λ0/nG<a
Here, if the condition λ0/nG<a is given, then it is preferable that the thickness G of the space 18 is not more than up to 5 times the wavelength (λ0/nG) within the medium. When the thickness G is too large, then the ±1-order diffraction light and the -1-order diffraction light become too far away from one another, and the portion where interference waves are formed diminishes.
Even when the condition λ0/nG<a is given, if the thickness G of the space 18 is almost zero (a tenth of λ0/nG or less), then there are cases in which coupling of evanescent waves becomes possible.
It is also possible to form the phase grating 6 by cutting the one-dimensional photonic crystal 1 near the end face 1a on the incident side and separating it from the one-dimensional photonic crystal 1. The groove formed by this cutting between the one-dimensional photonic crystal 1 and the phase grating 6 thus becomes the space 18. In this case, adjusting the thickness of the cut portion (the thickness L of the phase grating 6) and the width of the groove (width G of the space 18) can ensure that only certain higher-order band propagation light is propagated. Needless to say, the groove may be an air layer, or it may be filled with a homogenous medium.
Furthermore,
It is possible to attain a similar effect as with the above-described photonic crystal optical waveguides by taking the optical fiber 21 with a two-dimensional photonic crystal shown in
Also in this case, when the effective refractive index of the higher-order band propagation light becomes smaller than the refractive index of the cladding 23 formed around the core 22, then propagated light may leak due to refraction from the core 22. In particular when the effective refractive index of the higher-order band propagation light is not greater than 1, it is not possible to prevent the leakage of light when the cladding is air.
In order to prevent the leakage of guided light from the core due to a lowering of the effective refractive index and to confine the guided light in the core, it is preferable to provide a reflective layer 32, such as a metal film, as a cladding around the core made of the photonic crystal, as shown in
However, when reflective layers 32 are used for the cladding, problems may occur, such as a lowering of the strength of the photonic crystal optical waveguide 30 serving as the multilayer structure or attenuation due to insufficient reflectance at the reflective layers 32.
The following is an explanation of preferable conditions for the case that a photonic crystal 11 is used for the cladding.
The positions within the Brillouin zones signify the wave vector within the photonic crystal, and the contour lines signify bands corresponding to specific normalized frequencies a/λ0 (or a′/λ0). Incidentally,
A dashed line 43 indicating the size of the arrow 42 representing the wave vector of the higher-order band propagation light and a dashed line 44 indicating the size of the dashed arrow 41 representing the wave vector of the first band propagation light are drawn to
Therefore, the optical waveguide portion may be configured taking a one-dimensional photonic crystal 1 with the period a as the core and arranging a photonic crystal 11 with a period a′ on both sides thereof as the cladding, as shown in
The material and the structure of the photonic crystal 11 used for the cladding may differ from that of the one-dimensional photonic crystal 1 used for the core. However, in view of the effort involved in fabricating the multilayer structure, it is preferable to use the same material for both, and to make the refractive index period of the photonic crystal 11 used for the cladding smaller. Needless to say, it is necessary to design the photonic crystal optical waveguide after confirming by band calculation that the wave vectors in the core do not exist in the cladding.
It should be noted that according to
Ordinarily, to determine the confinement with a band diagram, a photonic crystal with an infinite periodic structure is assumed. Therefore, if the confining photonic crystal has only for example three periods in practice, then the confinement may become insufficient, and the guided light leak to the outside. Needless to say, providing an unnecessarily large number of periods is undesirable with regard to cost as well as durability and precision of the multilayer film. In practice, it is preferable to determine the number of periods that is necessary at a minimum experimentally or through electromagnetic simulation.
The cases described so far related to confining higher-order band propagation light in a one-dimensional photonic crystal. Also in the case of two-dimensional photonic crystal optical fibers, it is possible to realize a confinement by enclosing the core portions with photonic crystals for cladding.
It is also possible to realize a photonic crystal optical waveguide according to an embodiment of the present invention by using these photonic crystals 50a and 50b for at least one of the core, the cladding and the phase grating.
The following is a more detailed explanation of the conditions to be satisfied by the present embodiment.
Although not shown in
Moreover, a so-called “photonic crystal group velocity anomaly” occurs in the light propagated in the higher-order propagation bands, so that an increased non-linear effect can be expected. In the present embodiment, no energy is taken up by the first band light in which there is substantially no group velocity anomaly, so that it is possible to attain an increased effect of optical non-linearities by including non-linear optical material in the core portion of the multilayer film or the photonic crystal optical fiber. (See Optical Fiber Communication 2002/Conference and Exhibit Technical Digest ThK4 (p. 468))
For example, in the one-dimensional photonic crystal 15 serving as the core, as shown in
As for the material of the photonic crystal used in the present embodiment, there is no particular limitation as long as its transparency can be ensured in the wavelength range used. Suitable materials for the one-dimensional case are silica, silicon nitride, silicon, titanium oxide, tantalum oxide, niobium oxide and magnesium fluoride, which are ordinarily used as the material for multilayer films and which have excellent durability and film-manufacturing costs. With these materials, a multilayer film structure can be formed easily by well-known methods, such as sputtering, vacuum deposition, ion assisted deposition or plasma CVD, for example. In the case of a two-dimensional photonic crystal fiber, the simplest configuration is one with air holes arranged in a quartz fiber.
As the ratio of the refractive indices between the materials constituting the photonic crystal becomes large, also the wavelength dispersion, for example, tends to increase. Consequently, it is preferable that the photonic crystal is constituted by a combination of high refractive index and low refractive index materials, for applications in which such characteristics are necessary. As for refractive index ratios that can be used in practice, when air, which has a refractive index of 1, is used as the low refractive index material and InSb, which has a refractive index of 4.21, is used as the high refractive index material, then a refractive index ratio greater than 4 can be attained (see “BISHOKOGAKU HANDBOOK” (Microoptics Handbook), p. 224, Asakura Shoten, 1995) When the refractive index ratio of the materials constituting the photonic crystal becomes small, then the difference in the characteristics depending on the polarization direction tends to become small, so that it is advantageous to combine materials with a small refractive index ratio to realize non-dependency on polarization. However, when the refractive index ratio becomes very small, then the modulation effect becomes weak and the expected effects may not be attained, so that it is preferable to ensure a refractive index ratio of at least 1.2.
The space by which the optical waveguide portion and the phase grating portion are separated can be formed by first layering a multilayered film and fabricating a multilayer structure, and then successively performing the ordinary steps of applying a resist layer, patterning, etching and removing the resist layer. The groove portion shown in
By selecting suitable materials, it is possible to use the photonic crystal optical waveguide of the present embodiment for light of a typically used wavelength range of about 200 nm to 20 μm, and to attain satisfactory characteristics. Moreover, the present embodiment has been explained for light, but it can be applied not only for light but for electromagnetic radiation in general.
It should be noted that this is also the same for the space between the photonic crystal and the phase modulation portion if a phase modulation portion is arranged on the side of the emergent end of the photonic crystal.
The photonic crystal optical waveguide 69 has a substrate 61. a one-dimensional photonic crystal 66 serving as the core arranged on the substrate 61, and a phase grating 66a and a phase grating 66b arranged at the end faces on the incident side and the emergent side of the one-dimensional photonic crystal 66, with a space 68a and a space 68b arranged between the one-dimensional photonic crystal 66 and the phase grating 66a and the phase grating 66b. It should be noted that in practice, reflective layers (see
The one-dimensional photonic crystal 66 can be fabricated, for example, by forming a periodic multilayer film on the entire surface of the substrate 61, and then etching away all of the multilayer film except for a line-shaped portion. It should be noted that the one-dimensional photonic crystal 66 has a uniform refractive index in the direction in which the light propagates, and has a periodic refractive index in the layering direction.
The incident light 62 (signal light) is coupled from an optical fiber or the like into the homogenous optical waveguide 67a. This signal light propagates through the homogenous optical waveguide 67a, passes through the phase grating 66a and is fed to the one-dimensional photonic crystal 66. A space 68a is formed between the phase grating 66a and the one-dimensional photonic crystal 66. As described above, the signal light is incident on the one-dimensional photonic crystal 66 serving as the core after passing through the phase grating 66a, so that the guided light propagating through the one-dimensional photonic crystal 66 is only higher-order band propagation light.
The higher-order band propagation light that is propagated through the one-dimensional photonic crystal 66 emerges from the emerging face of the one-dimensional photonic crystal 66 into the space 68b, is incident on the phase grating 66b and is again converted into a plane wave by the phase grating 66b. The light that has been converted into a plane wave is fed from the phase grating 66b to the birefringent element 64, the phase shifts due to the polarization modes are compensated, and the light is fed into the homogenous optical waveguide 67b. The emerging light 63 that emerges after passing through the homogenous optical waveguide 67b is then coupled into an optical fiber, for example.
As noted above, the group velocity of the higher-order band propagation light changes considerably depending on the wavelength of the incident light, so that this photonic crystal optical waveguide 69 can be used for applications such as dispersion compensation elements or optical delay elements of signal light for optical communication. Moreover, propagated light with slow group velocity increases the non-linear optical effects, as noted above. The following lists a number of ways in which it can be used as an element with a much larger non-linear optical effect than in conventional elements. For example, it is possible to increase the non-linear optical effect by doping the portion of the one-dimensional photonic crystal 66 with microscopic particles of a substance having a non-linear optical effect. More specifically, it is possible to disperse microscopic particles and use the effect of quantum dots.
As another method, it is possible to increase the non-linear optical effect by placing a thin-film layer including a substance exhibiting a non-linear optical effect at every single period of the one-dimensional photonic crystal 66. More specifically, it is possible to fabricate at least one side of the thin-film layers by a sol-gel method, and to let them include an organic pigment or an organic substance with photorefractivity.
Another method is to increase the non-linear optical effect by taking a material with non-linear effect for the material from which the one-dimensional photonic crystal 66 is made. More specifically, the material of the one-dimensional photonic crystal may be a substance with large non-linearity, such as LiNbO3 or the like.
The TE polarization components and the TM polarization components of the plane wave incident on the photonic crystal optical waveguide 69 on the incident side have different group velocities and wavelengths in the waveguide, so that there is a phase difference, an intensity difference, and a difference in the non-linear effect. However, by letting the wave pass through the photonic crystal optical waveguide 69 on the emerging side, which has the same structure and length as the photonic crystal optical waveguide 69 on the incident side and is only rotated by 90° relative to it, the phase difference, the intensity difference, and the difference in the non-linear effect are canceled. Consequently, there are no polarization-dependent differences in the optical waveguide element 70 in
Instead of the one-dimensional photonic crystal 66 shown in
It should be noted that, as shown in
The optical fiber 79 serving as the optical waveguide portion of the photonic crystal optical waveguide is made of a core 71 having a two-dimensional photonic crystal structure, and a cladding 72 formed around that. It should be noted that the refractive index is uniform in the direction in which light is propagated. Phase lattices 76a and 76b matching the period of the core 71 are placed at the two ends of the optical fiber 79. The incident light (plane wave, not shown in the drawings) propagates through the core 71 as higher-order band propagation light, and is restored to a plane wave on the emerging side. The lattice elements on both sides are the same, so that the optical fiber can be used in both directions.
It should be noted that it is preferable that the refractive index period of the core 71 and the cladding 72 is symmetric with respect to the center axis of the optical fiber 79. This has the advantage that polarization mode dependent differences do not occur.
The photonic crystal of the cladding 72 of the optical fiber 79 has a period and a structure that are different from the photonic crystal of the core 71, and serves the role of confining the guided light in the core 71 through photonic band gaps. It should be noted that it is sufficient if the cladding 72, which is made of a photonic crystal, has a thickness at which the light is confined in the core 71, and it is not necessary to form the photonic crystal all the way to the outer circumference of the optical fiber 79.
The light guided by the optical fiber 79 is higher-order band light, so that there is a much greater group velocity anomaly than with conventional optical fibers using single mode propagation with the lowest order band. Consequently, it is possible to attain a strong dispersion compensation effect and non-linear optical effect.
Moreover, the core 71 has a periodic structure and its size is not limited, so that it is easy to realize a core 71 with a large diameter, and the connection of fibers can be simplified.
The optical fiber 89 has a periodic refractive index distribution in the radial direction. The optical fiber 89 is constituted by a core 81 and a cladding 82 which are made of a two-dimensional photonic crystal having a periodic and concentric circular refractive index period with respect to the distance from the center axis. It should be noted that the refractive index is uniform in the direction in which light is propagated. Phase lattices 86a and 86b matching the period of the core 81 are placed at the two ends of the optical fiber 89. The incident light (not shown in the drawings), which is a plane wave, propagates through the core 81 as higher-order band propagation light, and is again restored to a plane wave on the emerging side. The phase gratings 86a and 86b on both sides are the same, so that the incident and the emerging directions also can be reversed.
The cladding 82 has a refractive index period that is different from that of the core 81, and serves the role of confining the guided light in the core 81 through photonic band gaps.
The optical fiber 89 is symmetric with respect to the optical axis, so that there is the advantage that there are no polarization mode dependent differences. The effect due to the group velocity anomalies and the fact that there are no restrictions regarding the size of the core portion are the same as in the optical fiber 79 of
Also, the optical fibers 79 and 89 in
It should be noted that the configurations shown in detail in the foregoing embodiments are mere examples, and that the present invention is not limited by these specific examples. For example, the photonic crystal serving as the core of the optical waveguide of the present embodiments has a refractive index that is uniform in the direction in which light is propagated, and has a periodic refractive index in at least one direction perpendicular to the propagation direction. Also, there should be photonic bands in the direction in which the guided light propagates.
As explained above, the present invention can be applied widely to optical elements that can utilize such effects as dispersion compensation and optical non-linearity caused by group velocity anomalies of higher-order band propagation light.
Number | Date | Country | Kind |
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2002-198337 | Jul 2002 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP03/08639 | 7/8/2003 | WO | 10/17/2005 |