Disclosed embodiments generally relate to photovoltaic devices which include solar cells and solar modules containing solar cells. More particularly, the disclosed embodiments relate to improved solar cell structures and methods of manufacture for increased cell efficiency.
Photovoltaic devices convert photons from incident sunlight into useable electric energy, for example using semiconductor materials deposited over a substrate. The semiconductor layer(s) may be made of an n-type semiconductor material and a p-type semiconductor material. The interaction of an n-type or p-type semiconductor layer with a semiconductor layer of the opposite type creates a p-n junction which facilitates movement of electrons and holes created from absorbed photons via the photovoltaic effect, to produce electric current.
Improved efficiency for photovoltaic conversion, and greater electrical output from solar cells/modules, are desired characteristics of photovoltaic devices.
Accordingly, a need for a high-efficiency photovoltaic device and a method of manufacture arises.
The present invention provides, in a first aspect, a method for use in forming a photovoltaic device which includes forming a doped semiconductor layer on a surface of a semiconductor substrate and forming a metal film on the doped semiconductor layer. A patterned etch-resist is formed on the metal film and the resist includes a plurality of finger portions and a plurality of bus bar portions aligned in a grid pattern. A metal film is etched to form a pattern of fingers and bus bars according to the resist.
Aspects of the present invention and certain features, advantages, and details thereof, are explained more fully below with reference to the non-limiting embodiments illustrated in the accompanying drawings. Descriptions of well-known materials, fabrication tools, processing techniques, etc., are omitted so as to not unnecessarily obscure the invention in detail. It should be understood, however, that the detailed description and the specific examples, while indicating embodiments of the invention, are given by way of illustration only, and are not by way of limitation. Various substitutions, modifications, additions, and/or arrangements within the spirit and/or scope of the underlying inventive concepts will be apparent to those skilled in the art from this disclosure.
The disclosed embodiments are directed to photovoltaic devices, including photovoltaic cells and modules containing a plurality of photovoltaic cells, and method for their manufacture. The photovoltaic cells can be used as monofacial cells which receive light at one surface or as bifacial cells which can receive light from the one surface and from an opposite surface.
An important parameter which affects the efficiency and output of a solar cell is an amount of area on a light-incident surface of the solar cell which is covered (directly) or shaded (by an angle of incident sunlight) by electrodes which are required to collect and move electrical current which is generated by the solar cells. The covered area and shading from electrodes may be reduced by decreasing the size of the electrodes. For example, electrodes are often formed as fingers, and decreasing the width of the electrode fingers increases the photoactive area available on the device for receiving and converting incident light.
In one example, conventional solar cell production may use screen printing technology to print electrodes on a front surface of a photovoltaic device with such a technique often using a metal paste (e.g., silver paste). This technique may result in a comparatively broad electrode line width (e.g., in excess of 50 μm (typically about 100 μm)), and a fairly low line conductivity of the metal grid due to the use of several non-metallic components (e.g., glass frit) in the printed paste. As indicated above, increased line width may result in increased shading and less light falling on the light-incident surface of the solar cell. In addition, a firing process may result in contamination of a substrate of the cell by ingredients of the metal paste, thereby reducing the energy conversion efficiency of the device. Moreover, some metal pastes (e.g., silver) may be comparatively expensive making them unfavorable as a primary electrode material.
Initially, a substrate 1 is supplied. This substrate may be a silicon semiconductor wafer of either p or n-type doping. The substrate may be textured, for example with a random pyramid pattern to improve light trapping in the solar cell. The substrate may have dopant diffusions on either or both sides to form emitter structures or surface fields. Such dopant diffusions may be patterned, for example to form so-called selective emitter structures. The substrate may have thin film passivation layers present on either or both surfaces. Such passivation layers may for example consist of doped or intrinsic amorphous silicon layers, silicon dioxide, silicon nitride, doped or intrinsic poly-silicon, doped or intrinsic silicon carbide, aluminum oxide or any of a large variety of such passivation layers and combinations thereof.
A metal film 4 is deposited over a surface of the substrate, and the structure shown in
A patterned etch resist 3 (e.g., narrow resist line) may next be formed (e.g., using an ink jet printer) over metal film 4 to form a structure 155 as depicted in
The grid or cross-hatching pattern described above enables economical patterning of a resist (e.g., resist 3) utilized to later form a bus bar by using a same features size (i.e., line width) as utilized for the fingers, and further the native resolution of a print head (e.g., an IJ print-head) may be utilized. The native resolution of the print head used may be 360 dpi, for example. Other print heads with different resolutions may also be used. Further, a pitch between nozzles of a print head (e.g., an IJ print-head) could be 70.5 μm, for example. Printed features are advantageously an integer multiple/fraction of a native resolution. For example, a resolution of 360 dpi may provide twice the resolution or 720 dpi. In another example, one half a resolution of 360 dpi may provide 180 dpi. A finger pitch may also be a multiple of a native resolution, such as 1/16 of 360 dpi=22.5 dpi=1128 μm.
In an example of printing a resist for a bus bar (e.g., at a resolution of 360 dpi×360 dpi) a first step would be to print a resist for fingers (e.g., finger resist portions 110) and a part (e.g., vertical resist lines 107) of a cross hatched bus bar. In an example where the bus-bar dpi is equal or less than a native dpi of the print head, the necessary printing of the resist may be done in a minimum of two passes for dry-on-dry printing and in one pass for wet-on-wet printing. As depicted in
In a second step, the print-heads or substrate (e.g., substrate 1) may then be rotated 90 degrees followed by printing perpendicular features, such as bus bar resist horizontal portions (e.g., horizontal resist lines 105), being printed to result in a crosshatched pattern as depicted in the various examples of
In one example, resist 3 may be a UV curable black or other pigmented ink resist which may absorb the wavelength of a high intensity light source, such as a laser light source. Before applying resist 3 (e.g., via printing), structure 155 depicted in
After resist 3 is printed on metal film 4, resist 3 on metal film 4 may be cured under UV light to pin resist 3 in position on metal film 4. Such UV curing also causes polymerization/crosslinking of monomers, oligomers in such resists, to provide a dry, chemically, thermally or physically stable resist. Depending upon the particular resist material that is selected or used, it could be advantageous to use a low temperature curing process in the range of 70-150 C to drive out residual water, if present, from the resist and promote adhesion to the metal layer. After resist 3 is cured, metal film 4 may be etched. Patterned etch resist 3 protects portions of metal film 4 which are covered by patterned etch resist 3 during exposure of metal film 4 to a suitable metal etch solution, such as an acid solution (e.g., via a suitable metal acid etch solution, in step 308 of
In another example, a resist (e.g., resist 3) may be printed via a dry on dry process as indicated above. In this process, a series of drops are printed to define an outline of a resist (e.g., horizontal resist line 105) followed by an UV cure as described above. Spaces between the drops are then filled in with a second set of drops from a printhead followed by a second UV cure of the resist. As suggested above, such a process provides better control of a resist line width (i.e., reduced line width blowout which can occur as ink flows prior to the UV pin/cure) as compared to other processes, such as a wet process.
Etching of metal film 4 produces a structure 160, as shown in
As described, in contrast to the prior art formation of bus bars, the bus bars of the present invention may be formed in a crosshatched pattern such that portions of each bus bar are spaced from one another unlike the continuous direct printing of the prior art to form a bus bar. In particular, bus bars of the prior art are completely filled in such that no crosshatch pattern or space would exist between printed perpendicular portions thereof in contrast to the description herein. Thus, the same print heads may be used to form the resists for the fingers and bus bars of the present invention since each individual print line (e.g., for both the finger resist portions and bus bar resist portions) have a same width. In contrast to the prior art, in the present invention it would not be necessary to print additional passes relative to those described above to fill in an area occupied by the spaces defined by the crosshatch pattern described above or to utilize additional print heads, such as print heads having larger drop sizes to print wider bus bar lines. Instead, due to the cross hatched pattern of the present invention the same size resist lines may be used from a same print head for both the finger resist portions (e.g., finger resist portions 100) and bus bar resist portions (e.g., bus bar resist portions 110).
Moreover, the crosshatch pattern of the bus bar resists (e.g., bus bar resist portions 110) and resulting bus bars may reduce resist stress associated with a full area bus bar print, as in the prior art, in that such a prior art resist print may result in delamination of a bus bar relative to the fingers prior to a resist strip (e.g., a laser ablation and clean as described in co-owned application Ser. No. 14/707,697, attorney docket number 3304.016). Further, by making the bus bars out of cross-hatched finger-like features process interactions and complications are minimized (e.g., a UV cure, ablation and clean process parameters are essentially identical for the resists finger and the bus resists).
The etching of metal film 4 while resist 3 is present as described provides for an advantageous bus bar formed in a crosshatch or grid pattern with fingers connected to and extending between the bus bars. For example, after etching, bus bar portions of metal film 4 are aligned relative to each other at right angles, and fingers are aligned with a portion of such a pattern (e.g., horizontal bus bar portions formed by horizontal resist lines 105) and perpendicular to another portion (e.g., vertical bus bar portions formed by vertical resist lines 107), as described above relative to resist 3 such that the bus bars have about a same thickness and width relative to the fingers.
A material layer 212 which functions both as a passivation layer and antireflection coating, may next be formed on a front surface 162 of a structure 164, as depicted in
After material layer 212 is applied, etch resist 3 and a portion 212a (
In one example, the described removal may be accomplished with a high intensity light source, such as a laser, as described in co-owned application Ser. No. 14/707,697 (Attorney Docket No. 3304.016) shown in
Any debris associated with the breakdown of resist 3 and overlying portion 212a of material layer 212 may be removed for example, by blowing any debris away using a suitable blower as indicated, for example, in Step 311 of
Following the cleaning of structure 164 described above, a low temperature anneal may be conducted with a relatively low temperature of less than or about 500° C. to promote adhesion of metal film 4 to substrate 1 and a good electrical contact as indicated in Step 312 of
As shown in
In one embodiment, conductor 270 may be comprised of a metal stack consisting of a layer of nickel 271 applied to surface 264, a layer of copper 272 applied to the layer of nickel 271, and a layer of silver 273 applied to the layer of copper 272 as indicated, for example in
Using the techniques described above, very narrow finger and bus bar conductors may be produced. For example, conductive fingers 290 and bus bars 292 may be formed as described above for conductor 270. As shown in
Further, the use of a laser to strip a resist (e.g., step 310 of a laser ablation and clean as described in co-owned application Ser. No. 14/707,697, (Attorney docket number 3304.016) provides a solvent free strip which reduces costs and the need for solvents in the process thereby reducing the need to handle such solvents and provides environmental benefits. Also, the described process eliminates steps (e.g., application of a separate bus bar resistive portion after the formation of a finger resistive portion due to both portions being formed in a same process) compared to the prior art.
Further, the resist removal technique described (e.g., laser ablation and removal step) allows the use of resists which are compatible with relatively high temperature and/or vacuum based deposition techniques for ARC and/or passivating layers.
Also, the inkjet printing of resists as described is done with a minimum amount of complexity and cost, high throughput patterning, nozzle redundancy with a minimal number of print heads, and contact-less resist application which provides less wafer breakage and micro-cracks.
A number of embodiments have been described and illustrated. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention, which is defined solely by the scope of the appended claims.
This Application is related to U.S. patent application Ser. No. 13/265,462, filed Nov. 15, 2011 (Attorney Docket No. 3304.001A); U.S. patent application Ser. No. 13/637,176, filed Sep. 25, 2012 (Attorney Docket No. 3304.008A); U.S. Pat. No. 8,236,604, filed Feb. 15, 2011 (Attorney Docket No. 3304.010A); U.S. Patent Application No. 61/589,459, filed on Jan. 23, 2012 (Attorney Docket No. 3304.011(P)); U.S. Ser. No. 14/373,938, filed Jul. 23, 2014 (Attorney Docket No. 3304.011A); U.S. Provisional Patent Application No. 61/657,098, filed Jun. 8, 2012 (Attorney Docket No. 3304.012(P)); U.S. Ser. No. 61/718,489, filed Oct. 25, 2012 (Attorney Docket No. 3304.013(P)); PCT International Application No. PCT/US2013/066532 filed on Oct. 24, 2013 (Attorney Docket No. 3304.013AWO), and U.S. patent application Ser. No. 14/707,697, filed on May 8, 2015, (Attorney Docket No. 3304.016), which are incorporated herein by reference in their entirety.