Claims
- 1. A pigment formulation consisting essentially of:
- a) 99.8% to 50% by weight of one or more pigments selected from the group consisting of organic or inorganic azo pigments, azaporphines, quinacridones, diketopyrrolopyrroles, flavanthrone, anthanthrone and pyranthrone substances, derivatives of naphthalenetetracarboxylic acid, perylenetetracarboxylic acid, thioindigo, dioxazine or tetrachloroisoindolinone, magnesium lake pigments, calcium lake pigments, barium lake pigments, aluminum lake pigments, manganese and nickel lakes of dyestuffs containing acid groups, and corresponding mixtures thereof and b) 0.2% to 30% by weight of one or more colorless or only slightly colored compounds of the formula (I) ##STR4## in which Q.sup.1, Q.sup.2 and Q.sup.3 independently of one another each denote a --X--A, --OR.sup.1, --SR.sup.1, halogen or --NR.sup.2 R.sup.3 radical or a radical Q of one, two or up to fifteen trivalent groups of the formula (Ia) ##STR5## each of which is bonded via the divalent group W to a free valency of the next group of the formula (Ia) or to the triazine ring of the parent substance of the formula (I) and on the other free valencies in each case to a --X--A, --OR.sup.1, --SR.sup.1, halogen or --NR.sup.2 R.sup.3 radical and which, in the case of more than two groups of the formula (Ia), are bonded to one another in linear or branched form, at least one radical of the formula --X--A being present in the compound of formula (I) and
- A stands for the radical of an aromatic ring system with 2 to 6 fused-on rings and with a total of at least 9 ring atoms, or stands for the radical of a group of 2 to 3 bonded aromatic ring systems in each case of one ring or 2 to 4 fused-on rings with in each case 5 to 7 ring atoms per ring, in which the bonded aromatic ring systems are bonded via a direct bond or a divalent group from the series consisting of --O--, --S--, --CO--, --SO--, --SO.sub.2 -- and C.sub.1 -C.sub.12 -alkylene, or stands for one of the radicals mentioned, which contain one or more substituents selected from the series consisting of C.sub.1 -C.sub.24 -alkyl, --OR', halogen, --NR'R", --COOR', --CONR'R", --NR'COR", --CN, --CF.sub.3 and --NO.sub.2, in which R' and R" independently of one another denote hydrogen or a straight-chain or branched C.sub.1 -C.sub.12 -alkyl, or together with the N atom denote a 5- or 6-membered heterocyclic radical,
- X stands for a divalent group --NR*--, --O-- or --S-- in which R* denotes a radical from the series consisting of hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -hydroxyalkyl, (C.sub.1 -C.sub.4 -alkoxy) -C.sub.1 -C.sub.6 -alkyl and C.sub.5 -C.sub.7 -cycloalkyl,
- R.sup.1, R.sup.2 and R.sup.3 independently of one another stand for the hydrogen radical, straight-chain or branched C.sub.1 -C.sub.24 -alkyl or C.sub.2 -C.sub.24 -alkenyl, C.sub.5 -C.sub.12 -cycloalkyl with one or two rings, C.sub.7 -C.sub.18 -aralkyl, heteroaryl with 1 or 2 rings and a total of 5 to 8 ring atoms, phenyl, a phenyl radical which is substituted by at least one radical form the group consisting of C.sub.1 -C.sub.12 -alkyl, halogen, --OR.sup.4, --NR.sup.4 R.sup.5, --COOR.sup.4, --CONR.sup.4 R.sup.5, --NR.sup.5 COR.sup.4, --CN, --CF.sub.3, --NO.sub.2 and --T-- (CH.sub.2).sub.p --NR.sup.o R.sup.t, in which R.sup.4 and R.sup.5 independently of one another denote hydrogen or C.sub.1 -C.sub.24 -alkyl, R.sup.o and R.sup.t independently of one another denote C.sub.1 -C.sub.24 -alkyl, p denotes a number from 1 to 6 and T denotes a direct bond or a divalent group from the series consisting of --O--, --S--, --CO--, --SO--, --SO.sub.2 --, --NR.sup.a -- --NR.sup.a CO--, --NR.sup.a SO.sub.2 --, --SO.sub.2 NR.sup.a and --CONR.sup.a and R.sup.a denotes hydrogen or C.sub.1 -C.sub.12 -alkyl group, or stands for C.sub.1 -C.sub.12 -hydroxyalkyl or polyhydroxyalkyl or stands for a C.sub.1 -C.sub.30 -alkyl radical, which is interrupted in the chain by one or more non-adjacent divalent groups of the formula --O-- or --NR.sup.v --, in which R.sup.v denotes hydrogen or C.sub.1 -C.sub.24 -alkyl, or a combination of at least two of the divalent groups and which can be substituted by a 5- or 6-membered heterocyclic ring, or
- R.sup.1 has the above mentioned meaning and R.sup.2 and R.sup.3, together with the n atom, stand for a 5- or 6-membered ring of a heterocyclic system with one or two rings, and
- W represents a divalent group of the formula --NR.sup.s --Y--NR.sup.t --, --O--Y--O--, --O--Y--NE.sup.8 --, --S--Y--S--, --O--Y--S-- or --NR.sup.s --Y--S--, wherein, in the above formulae, Y stands for a straight-chain or branched C.sub.2 -C.sub.20 -alkylene group of a C.sub.2 -C.sub.20 -alkylene group, which is interrupted by one or more groups --O--, --S--, --NR.sup.u, in which R.sup.u denotes hydrogen or C.sub.1 -C.sub.24 -alkyl, --CO--, --SO--, --SO.sub.2 --, C.sub.5 -C.sub.7 -cycloalkylene or C.sub.5 -C.sub.10 -arylene, a divalent heterocyclic ring with 5 to 7 ring atoms or a combination of the above groups, which is optionally further substituted, or stands for a divalent 1-, 2- or 3-nuclear saturated, unsaturated or aromatic carbocyclic or heterocyclic ring system with 5 to 14 ring atoms, or two of the ring systems which are linked via a direct bond or a C.sub.1 -C.sub.6 -alkylene, --O--, --S--, --CO--, --SO-- or --SO.sub.2 -- group, the ring systems being optionally further substituted, and R.sup.s and R.sup.t independently of one another denote a hydrogen radical, C.sub.1 -C.sub.24 -alkyl, C.sub.1 -C.sub.6 -hydroxyalkyl, (C.sub.1 -C.sub.4 -alkoxy)-C.sub.1 -C.sub.6 -alkyl or C.sub.5 -C.sub.7 -cycloalkyl or, together with N--Y--N, denote a heterocyclic ring,
- c) 0 to 20% by weight of an anionic, cationic or non-ionic surfactant, selected from the group consisting of alkyl sulfates, alkyl sulfonates, alkyl phosphates, alkyl benzenesulfonates, lauryl sulfate, stearyl sulfate, dodecyl sulfate, dodecyl sulfonates, octadecyl phosphates, dodecylbenzenesulfontes, sulfosuccinic acid esters, condensation products of a fatty acid and taurine or hydroxyethanesulfonic acid, resin soaps, alkoxylation products of alkylphenols, fatty alcohols, fatty amines, fatty acids, fatty acid amides, reaction products of nonylphenol, dodecylphenol, lauryl alcohol, coconut fatty alcohol, stearyl alcohol, oleyl alcohol, coconut fatty amine, tallow fatty amine, stearylamine, oleylamine, coconut fatty acid, stearic acid or oleic acid with 2 to 100 mol of ethylene oxide, reaction products of oxyethylated alkylphenols and fatty alcohols with chlorosulfonic acid and phosphorus oxychlorides, quaternary ammonium salts, hexadecyltrimethylammonium chloride, or mixtures thereof and
- d) 0 to 20% by weight of customary additives, the amounts of constituents b), c) and d) being based on the weight of the pigment or pigments.
- 2. A pigment formulation as claimed in claim 1, comprising a compound of the formula (I) in which Q.sup.1, Q.sup.2 and Q.sup.3 independently of one another each denote a radical of the formula --X--A or --NR.sup.2 R.sup.3 or a radical Q of 1 to 15 trivalent groups of the formula (Ia), each of which are bonded via a divalent group W to a free valency of the next group o the formula (Ia) or to the triazine radical of the parent substance of the formula (I) and on the other free valencies in each case to a radical --X--A or --NR.sup.2 R.sup.3 and which, in the case of more than two groups of the formula (Ia), are bonded to one another in linear or branched form, at least one radical of the formula --X--A being present in the compound of the formula (I).
- 3. A pigment formulation as claimed in claim 1, comprising a compound of the formula (I) in which A stands for the radical of an aromatic ring system with 2 or 3 fused-on rings with 9 to 14 ring atoms, or stands for the radical of a group of 2 aromatic ring systems with in each case one ring or two fused-on rings with in each case 5 to 7 ring atoms per ring, in which the bonded aromatic systems are bonded via a direct bond or a divalent group from the series comprising --O--, --CO--, --SO.sub.2 -- and --CH.sub.2 --, or stands for one of the radicals mentioned which contains one to three radicals from the series comprising C.sub.1 -C.sub.23 -alkyl, --OR', halogen, --NR'R", --COOR', --CONR'R", --NR'COR", --CN, CF.sub.3 or --NO.sub.2, in which R' and R" independently of one another denote hydrogen or C.sub.1 -C.sub.4 -alkyl or, together with the N atom, denote a heterocyclic radical, and X stands for a divalent group --NR*--, --O-- or S, in which R* denotes hydrogen or C.sub.1 -C.sub.4 -alkyl.
- 4. A pigment formulation as claimed in claim 1, comprising a compound of the formula (I) in which A represents the radical of a heteroaromatic ring system with 2 or 3 fused-on rings with a total of 9 to 14 ring atoms and nitrogen or sulfur atoms or a mixture thereof as heteroatoms, the ring system not being further substituted or containing at least one of the substituents mentioned.
- 5. A pigment formulation as claimed in claim 1, comprising a compound of the formula (I) in which R.sup.1, R.sup.2 and R.sup.3 independently of one another stand for the hydrogen radical, straight-chain or branched C.sub.1 -C.sub.12 -alkyl or C.sub.3 -C.sub.12 alk-(2-1)-enyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.7 -C.sub.12 -phenylalkyl, heteroaryl with 5 or 6 ring atoms, phenyl, a phenyl radical which is substituted by 1 to 3 radicals from the group consisting of C.sub.1 -C.sub.12 -alkyl, Cl, --OR.sup.4, --NR.sup.4 R.sup.5 and --T--(CH.sub.2).sub.p --NR.sup.o R.sup.t in which R.sup.4 and R.sup.5 independently of one another denote hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.o and R.sup.t independently of one another denote C.sub.1 -C.sub.12 -alkyl, p denotes a number from 1 to 6 and T denotes a direct bond or a divalent group from the series comprising --SO.sub.2 --, --SO.sub.2 NR.sup.a -- and --CONR.sup.a --, or stand for C.sub.1 -C.sub.6 -hydroxyalkyl or (C.sub.1 -C.sub.4 -alkoxy)-C.sub.1 -C.sub.12 -alkyl, or stand for a radical of the formula --(CR.sup.6 R.sup.7).sub.q --NR.sup.8 R.sup.9, in which q denotes a number from 1 to 6, R.sup.6 and R.sup.7 independently of one another denote hydrogen or C.sub.1 -C.sub.6 -alkyl, and R.sup.8 and R.sup.9 independently of one another denote C.sub.1 -C.sub.24 -alkyl or R.sup.8 denotes hydrogen and R.sup.9 denotes C.sub.1 -C.sub.24 -alkyl, or R.sup.8 and R.sup.9, together with the N atom, denote a 5- or 6-membered ring of a heterocyclic system, or R.sup.1 has the abovementioned meaning and R.sup.2 and R.sup.3, together with the N atom, stand for an optionally saturated, aromatic heterocyclic ring which has 5 or 6 ring atoms and which is optionally further substituted.
- 6. A pigment formulation as claimed in claim 1, comprising a compound of the formula (I) in which W represents a group of the formula --NR.sup.s --Y--NR.sup.t --, in which Y stands for a straight-chain C.sub.2 -C.sub.8 -alkylene group or a C.sub.2 -C.sub.12 -alkylene group which is interrupted by one or more divalent --O--, --S--, --NR.sup.u --, in which R.sup.u denotes hydrogen or C.sub.1 -C.sub.18 -alkyl, --CO--, --SO--, or --SO.sub.2 -- groups or a divalent heterocyclic radical with 5 to 7 ring atoms or a combination of the above groups, or stands for a divalent mono- or dinuclear carbocyclic or heterocyclic ring system with 5 to 8 ring atoms, or stands for two of the ring systems, which are linked via a direct bond or a --CH.sub.2 --, --CH(CH.sub.3)--, --C(CH.sub.3).sub.2 --, --O--, --S--, --CO--, --SO-- or --SO.sub.2 -- group, the ring systems are optionally further substituted, and R.sup.s and R.sup.t denote hydrogen or C.sub.1 -C.sub.18 -alkyl.
- 7. A pigment formulation as claimed in claim 1, comprising 0.7 to 10 mg of a compound of the formula (I) per square meter of pigment surface.
- 8. A pigment formulation as claimed in claim 5, wherein T denotes (C.sub.1 -C.sub.4 -alkoxy)-C.sub.1 -C.sub.6 -alkyl, q is a number from 1 to 3 and R.sup.6 and R.sup.7 are hydrogen.
- 9. The pigment formulation of claim 1 wherein said organic or inorganic pigment is present in an amount ranging from 97% to 70% by weight.
- 10. The pigment formulation of claim 1, wherein said compound of the formula (I) is present in an amount ranging from 1% to 20% by weight of pigment.
- 11. The pigment formulation as claimed in claim 7, wherein said compound of the formula (I) is present in an amount ranging rom 0.6 to 5 mg per square meter of pigment surface.
- 12. A pigment formulation as claimed in claim 1 consisting essentially of:
- a) 97% to 70% by weight of at least one organic pigment,
- b) 3% to 15% by weight, of a compound of the formula (I),
- c) 0 to 10% by weight, of an anionic, cationic, or nonionic surfactant, and
- d) 0 to 10% by weight, of customary additives, the amounts of the constituents b), c) and d) being based on the weight of the pigment or pigments.
Priority Claims (2)
Number |
Date |
Country |
Kind |
3731637 |
Sep 1987 |
DEX |
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3836864 |
Oct 1987 |
DEX |
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Parent Case Info
This is a continuation application of U.S. patent application Ser. No. 07/244,995, filed on Sep. 15, 1988 now abandoned.
US Referenced Citations (4)
Continuations (1)
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Number |
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244995 |
Sep 1988 |
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