This application claims priority from Japanese Patent Application No. 2005-043119, filed Feb. 18, 2005, the entire contents of which is incorporated herein by reference.
The invention relates to a piping structure of a fuel cell stack.
A solid polyelectrolyte-type fuel cell contains a membrane electrode assembly comprising an electrolyte membrane that includes an ion-exchange membrane, a fuel electrode placed on a surface of the electrolyte membrane, and an air electrode placed on another surface of the electrolyte membrane. A unit fuel cell may be formed by installing a separator, which serves as a passage for supplying fuel gas and oxidant gas, respectively, to the fuel electrode and the air electrode of the membrane electrode assembly. Since a unit fuel cell generates less than approximately 1 V (volt), several unit fuel cells may be layered to form a fuel cell stack. The fuel cell stack may then be installed within a device, such as a vehicle, to provide power to the device.
In a unit fuel cell, a reaction occurs on a fuel electrode side, in which hydrogen converts into hydrogen ions and electrons (H2→2H++2e−), and a reaction occurs on an air electrode side, in which water is generated by supplying oxygen to hydrogen ions permeating the electrolyte membrane and electrons circulating in the external circuit (2H++2e−+(½)O2→H2O). In order for these reactions to be appropriately completed, the hydrogen ions are humidified in order to pass through the electrolyte membrane to the air electrode side of the fuel cell. In addition, the generated water must be drained out of gas passages within the fuel cell and, specifically, out of an oxidant gas passage so as not to inhibit the supply of oxidant gas to the air electrode. Furthermore, in order to effectively cool the fuel cell from heat derived during the reaction in the air electrode, air must not accumulate in a coolant fluid passage within the fuel cell.
Conventionally, a coolant fluid pipe outlet is positioned above a level of a penetration manifold of the fuel cell to improve ventilation ability within the coolant fluid pipe. In addition, pipe outlet positions for oxidant gas and fuel gas are positioned lower than the penetration manifold in order to improve drainability. However, this technology merely specifies the position of a connector for each fluid with the penetration manifold of the fuel cell stack. Therefore, air may accumulate in the coolant fluid passage within the fuel cell stack, which may lead to deterioration of breathability and cooling performance within the fuel cell stack.
In general, the invention is directed to a piping structure of a fuel cell stack that discharges gas from a coolant fluid outlet pipe before the gas accumulates in a coolant fluid passage within the fuel cell stack. In addition, the piping structure drains fluid from a fuel gas outlet pipe and an oxidant gas outlet pipe before the fluid accumulates in a fuel gas passage and an oxidant gas passage, respectively, within the fuel cell stack. In this way, the piping structure described herein improves cooling performance of the coolant fluid as well as power generation performance and life of the fuel cell stack.
For example, the piping structure includes a coolant fluid outlet connector positioned on a manifold of the fuel cell stack that connects a coolant fluid passage within the fuel cell stack and a coolant fluid outlet pipe that drains a coolant fluid from the coolant fluid passage. The coolant fluid outlet connector is positioned on the manifold of the fuel cell stack above a level of the coolant fluid passage within the fuel cell stack to enable gas to be discharged from the coolant fluid outlet pipe. In this way, the coolant fluid outlet pipe may discharge gas from the coolant fluid passage while draining the coolant fluid from the coolant fluid passage that maintains an upward flow of the coolant fluid.
In addition, the piping structure includes inlet connectors and outlet connectors for each of the coolant fluid, the oxidant gas, and the fuel gas. The inlet and outlet connectors are positioned on the manifold of the fuel cell stack such that each of the connectors is not positioned directly above or below another one of the connectors. In this way, the piping structure enables various sensors to be installed within inlet pipes and outlet pipes substantially adjacent to the inlet connectors and the outlet connectors, respectively, of the fuel cell stack.
In one embodiment, the invention is directed to a piping structure of a fuel cell stack comprising a coolant fluid inlet connector and a coolant fluid outlet connector positioned on a manifold of the fuel cell stack, and a coolant fluid passage within the fuel cell stack that connects to the coolant fluid inlet connector and the coolant fluid outlet connector. The piping structure also comprises a coolant fluid inlet pipe that connects to the coolant fluid inlet connector to supply a coolant fluid to the coolant fluid passage, and a coolant fluid outlet pipe that connects to the coolant fluid outlet connector to drain the coolant fluid from the coolant fluid passage. The coolant fluid outlet connector is positioned on the manifold of the fuel cell stack above a level of the coolant fluid passage within the fuel cell stack to enable gas to be discharged from the coolant fluid outlet pipe.
In another embodiment, the invention is directed to a method of manufacturing a piping structure of a fuel cell stack comprising positioning a coolant fluid inlet connector and a coolant fluid outlet connector on a manifold of the fuel cell stack, and connecting a coolant fluid passage within the fuel cell stack to the coolant fluid inlet connector and the coolant fluid outlet connector. The method also comprises connecting a coolant fluid inlet pipe to the coolant fluid inlet connector to supply a coolant fluid to the coolant fluid passage, and connecting a coolant fluid outlet pipe to the coolant fluid outlet connector to drain the coolant fluid from the coolant fluid passage. The method further includes positioning the coolant fluid outlet connector on the manifold of the fuel cell stack above a level of the coolant fluid passage within the fuel cell stack to enable gas to be discharged from the coolant fluid outlet pipe.
The details of one or more embodiments of the invention are set forth in the accompanying drawings and the description below. Other features, objects, and advantages of the invention will be apparent from the description and drawings, and from the claims.
Fuel cell stack 2 may be formed by horizontally layering several unit fuel cells. Fuel cell stack 2 generates power by supplying a fuel gas, e.g., hydrogen gas, to an anode of each unit fuel cell within fuel cell stack 2, and supplying an oxidant gas and air to a cathode of each unit fuel cell within fuel cell stack 2. The fuel gas and the oxidant gas cause an electrochemical reaction in an electrolyte membrane between the anode and the cathode of each unit fuel cell within fuel cell stack 2. In addition, each unit fuel cell within fuel cell stack 2 includes a coolant fluid passage for cooling the unit fuel cell, which may become heated during the electro-chemical reaction.
A coolant fluid inlet pipe 4 supplies a coolant fluid to fuel cell stack 2 and a coolant fluid outlet pipe 6 that drains the coolant fluid from fuel cell stack 2. An oxidant gas inlet pipe 3 supplies the oxidant gas to fuel cell stack 2 and an oxidant gas outlet pipe 8 discharges the oxidant gas from fuel cell stack 2. A fuel gas outlet pipe 5 discharges a fuel gas from fuel cell stack 2 and a fuel gas inlet pipe 7 supplies the fuel gas to fuel cell stack 2. As shown in
In the illustrated embodiment, oxidant gas inlet pipe 3 is connected to an upper level portion on a first side of manifold 9 of fuel cell stack 2. Coolant fluid inlet pipe 4 is connected to a middle level portion on the first side of manifold 9 of fuel cell stack 6 such that it does not overlap with oxidant gas inlet pipe 3. Fuel gas outlet pipe 5 is connected to a lower level portion on the first side of manifold 9 of fuel cell stack 2 such that is does not overlap with oxidant gas inlet pipe 3 and coolant fluid inlet pipe 4. Coolant fluid outlet pipe 6 is connected to an upper level portion on a second side of manifold 9 of fuel cell stack 2. Fuel gas inlet pipe 7 is connected to a middle level portion on the second side of manifold 9 of fuel cell stack 2 such that is does not overlap with coolant fluid outlet pipe 6. Oxidant gas outlet pipe 8 is connected to a lower level portion on the second side of manifold 9 of fuel cell stack 6 such that it does not overlap with fuel gas inlet pipe 7 and coolant fluid outlet pipe 6.
Each of sensors 13-18 comprises a detection device used to detect pressure and temperature of the fluid flowing in one of pipes 3-8. Each of sensors 13-18 include a detection part that may be installed facedown within the respective one of pipes 3-8. The facedown installation prevents accumulation of water within the detection part, which also prevents freezing in the case of low-temperature environments, and allows for control of defects in gas pressure within pipes 3-8.
The fuel cell system may be installed underneath a floor of a vehicle, for example, by positioning connectors for fuel gas outlet pipe 5 and oxidant gas outlet pipe 8 on a lower level portion of manifold 9 of fuel cell stack 2. In this way, fuel gas outlet pipe 5 and oxidant gas outlet pipe 8 drain fluid out of fuel cell stack 2. Therefore, the fluid does not accumulate within fuel gas outlet pipe 5 and oxidant gas outlet pipe 8, which may prevent damage to the outlet pipes due to freezing in a low-temperature environment.
In addition, positioning the connectors on the lower level portion of manifold 9 may reduce the start time of fuel cell stack 2. For example, in this case, fluid accumulated in a gas outlet connector on manifold 9 of fuel cell stack 2 may be drained by installing a means of discharging the fuel gas and the oxidant gas within the gas outlet connector and mixing the fluid with the discharged gas. This prevents adverse effects on power generation of fuel cell stack 2 due to fluid accumulation in a gas outlet connector. In other embodiments, equivalent results may be achieved by installing the fuel cell system near a front of a vehicle.
For example, coolant fluid inlet pipe 4 (
In the illustrated embodiment, coolant fluid outlet passage 23 is positioned within fuel cell stack 2 above the level of coolant fluid passage 32 within fuel cell 31. Accordingly, the coolant fluid flows upward from coolant fluid passage 32 within fuel cell 31 to coolant fluid outlet passage 23 to enable the gas within coolant fluid passage 32 to be discharged into coolant fluid outlet passage 23.
For example, oxidant gas inlet pipe 3 (
Unconsumed oxidant gas and steam generated during the reaction enter an oxidant gas outlet passage 43 within fuel cell stack 2. Oxidant gas outlet pipe 8 (
In the illustrated embodiment, oxidant gas outlet passage 43 is positioned within fuel cell stack 2 above the level of oxidant gas passage 52 within fuel cell 51. Accordingly, the oxidant gas flows downward from oxidant gas passage 52 within fuel cell 51 to oxidant gas outlet passage 43 to enable the fluid within oxidant gas passage 52 to be drained into oxidant gas outlet passage 43.
For example, fuel gas inlet pipe 7 (
Unconsumed fuel gas enters a fuel gas outlet passage 63 within fuel cell stack 2. Fuel gas outlet pipe 5 (
In the illustrated embodiment, fuel gas outlet passage 63 is positioned within fuel cell stack 2 above the level of fuel gas passage 72 within fuel cell 71. Accordingly, the fuel gas flows downward from fuel gas passage 72 within fuel cell 71 to fuel gas outlet passage 63 to enable the fluid within fuel gas passage 72 to be drained into fuel gas outlet passage 63.
As described above, piping structure 1 of fuel cell stack 2 includes coolant fluid outlet connector 24 that connects coolant fluid outlet pipe 6, used for draining the coolant fluid from fuel cell stack 2, to fuel cell stack 2. Coolant fluid outlet connector 24 is positioned on manifold 9 of fuel cell stack 2 above a level of coolant fluid passage 32 within fuel cell stack 2. Therefore, the coolant fluid within fuel cell stack 2 may flow upward from coolant fluid passage 32 to coolant fluid outlet connector 24. In this way, piping structure 1 enables gas within coolant fluid passage 32 to be discharged from fuel cell stack 2 without accumulating within coolant fluid passage 32. Discharging the gas from coolant fluid passage 32 within fuel cell stack 2 improves the cooling performance of the coolant fluid and the power generation performance and life of fuel cell stack 2.
In addition, piping structure 1 of fuel cell stack 2 includes fuel gas outlet connector 64 that connects fuel gas outlet pipe 5, used for discharging the fuel gas from fuel cell stack 2, to fuel cell stack 2. Fuel gas outlet connector 64 is positioned on manifold 9 of fuel cell stack 2 below a level of fuel gas passage 72.within fuel cell stack 2. Therefore, the fuel gas within fuel cell stack 2 may flow downward from fuel gas passage 72 to fuel gas outlet connector 64. In this way, piping structure 1 enables fluid within fuel gas passage 62 to be drained from fuel cell stack 2 without accumulating within fuel gas passage 72. Draining the fluid from fuel gas passage 72 within fuel cell stack 2 prevents defects in the power generation of fuel cell stack 2 due to flooding.
Furthermore, piping structure 1 of fuel cell stack 2 includes oxidant gas outlet connector 44 that connects oxidant gas outlet pipe 8, used for discharging the oxidant gas from fuel cell stack 2, to fuel cell stack 2. Oxidant gas outlet connector 44 is positioned on manifold 9 of fuel cell stack 2 below a level of oxidant gas passage 52 within fuel cell stack 2. Therefore, the oxidant gas within fuel cell stack 2 may flow downward from oxidant gas passage 52 to oxidant gas outlet connector 54. In this way, piping structure 1 enables fluid within oxidant gas passage 52 to be drained from fuel cell stack 2 without accumulating within oxidant gas passage 52. Draining the fluid from oxidant gas passage 52 within fuel cell stack 2 prevents defects in the power generation of fuel cell stack 2 due to flooding.
In the illustrated embodiment, coolant fluid outlet pipe 6 and oxidant gas outlet pipe 8 are positioned on the same side of manifold 9 of fuel cell stack 2, and fuel gas outlet pipe 5 is positioned on a different side of manifold 9 of fuel cell stack 2. This arrangement enables a rise in temperature of the coolant fluid passing by an outlet of the cathode in which flooding may occur, and prevents concentration of the fluid that causes flooding. In addition, when each fluid flows horizontally within fuel cell stack 2, a distance between a stack gateway manifold and manifold 9 of fuel cell stack 2 can be reduced, which enables a reduction in weight and cost of piping structure 1 of fuel cell stack 2.
As shown in
Furthermore, one of sensors 13-18 may be installed within the respective one of pipes 3-8 substantially adjacent to the connector for the pipe positioned on manifold 9 of fuel cell stack 2. Properly installing sensors 13-18 within pipes 3-8 may reduce effects of pressure damages due to changes in layout of pipes 3-8, and may also reduce the possibility of errors between sensor readout numbers and actual values. Therefore, gas conditions within fuel cell stack 2 may be accurately controlled based on sensor readout values, which can improve the life and power generating performance of fuel cell stack 2. Furthermore, a detection part of each of sensors 13-18 faces downward when installed within pipes 3-8 to prevent fluid from pooling in the detection part and possibly freezing in a low-temperature environment. In addition, installing sensors 13-18 within pipes 3-8 with detection parts facing downward allows further control over gas pressure during power generation in fuel cell stack 2.
For example, coolant fluid inlet pipe 4 (
In this case, coolant fluid outlet connector 94 is positioned on the upper level portion of manifold 90, which is above a level of each of coolant fluid outlet passages 93a-93c within the set of fuel cell stacks 82a-82c. Therefore, the coolant fluid flows upward from coolant fluid outlet passages 93a-93c into coolant fluid outlet connector 94. In this way, gas, e.g., air, within coolant fluid outlet passages 93a-93c may be discharged into coolant fluid outlet pipe 6 (
In the illustrated embodiment, each of coolant fluid outlet passages 93a-93c are positioned within the set of fuel cell stacks 82a-82c above the level of the respective one of coolant fluid passages 102a-102c within fuel cells 101a-101c. Accordingly, the coolant fluid flows upward from coolant fluid passages 102a-102c within fuel cells 101a-101c to coolant fluid outlet passages 93a-93c to enable the gas within coolant fluid passages 102a-102c to be discharged into coolant fluid outlet passages 93a-93c.
For example, oxidant gas inlet pipe 3 (
Unconsumed oxidant gas and steam generated during the reaction enter each of oxidant gas outlet passages 113a-113c within the set of fuel cell stacks 82a-82c. Oxidant gas outlet pipe 8 (
In the illustrated embodiment, each of oxidant gas outlet passages 113a-113c are positioned within the set of fuel cell stacks 82a-82c below the level of the respective one of oxidant gas passages 122a-122c within fuel cells 121a-121c. Accordingly, the oxidant gas flows downward from oxidant gas passages 122a-122c within fuel cells 121a-121c to oxidant gas outlet passages 113a-113c to enable the fluid within oxidant gas passages 122a-122c to be drained into oxidant gas outlet passages 113a-113c.
For example, fuel gas inlet pipe 7 (
Unconsumed fuel gas enters each of fuel gas outlet passages 133a-133c within the set of fuel cell stacks 82a-82c. Fuel gas outlet pipe 5 (
In the illustrated embodiment, each of fuel gas outlet passages 133a-133c are positioned within the set of fuel cell stacks 82a-82c below the level of the respective one of fuel gas passages 132a-132c within fuel cells 131a-131c. Accordingly, the fuel gas flows downward from fuel gas passages 132a-132c within fuel cells 131a-131c to fuel gas outlet passages 133a-133c to enable the fluid within fuel gas passages 142a-142c to be drained into fuel gas outlet passages 133a-133c.
As described above, piping structure 81 of the set of fuel cell stacks 82a-82c includes coolant fluid outlet connector 94 positioned on manifold 90 of the set of fuel cell stacks 82a-82c above a level of coolant fluid passages 102a-102c within the set of fuel cell stacks 82a-82c. Therefore, the coolant fluid within the set of fuel cell stacks 82a-82c may flow upward from coolant fluid passages 102a-102c to coolant fluid outlet connector 94. In this way, piping structure 81 enables gas within coolant fluid passages 102a-102c to be discharged from the set of fuel cell stacks 82a-82c without accumulating within coolant fluid passages 102a-102c. Discharging the gas from coolant fluid passages 102a-102c within the set of fuel cell stacks 82a-82c improves the cooling performance of the coolant fluid and the power generation performance and life of the set of fuel cell stacks 82a-82c.
In addition, piping structure 81 of the set of fuel cell stacks 82a-82c includes fuel gas outlet connector 134 positioned on manifold 90 of the set of fuel cell stacks 82a-82c below a level of fuel gas passages 142a-142c within the set of fuel cell stacks 82a-82c. Therefore, the fuel gas within the set of fuel cell stacks 82a-82c may flow downward from fuel gas passages 142a-142c to fuel gas outlet connector 134. Furthermore, piping structure 81 of the set of fuel cell stacks 82a-82c includes oxidant gas outlet connector 114 positioned on manifold 90 of the set of fuel cell stacks 82a-82c below a level of oxidant gas passages 122a-122c within the set of fuel cell stacks 82a-82c. Therefore, the oxidant gas within the set of fuel cell stacks 82a-82c may flow downward from oxidant gas passages 122a-122c to oxidant gas outlet connector 114. In this way, piping structure 81 enables fluid within fuel gas passages 142a-142c and oxidant gas passages 122a-122c to be discharged from the set of fuel cell stacks 82a-82c without accumulating within fuel gas passages 142a-142c and oxidant gas passages 122a-122c. Draining the fluid from fuel gas passages 142a-142c and oxidant gas passages 122a-122c within the set of fuel cell stacks 82a-82c prevents defects in the power generation of the set of fuel cell stacks 82a-82c due to flooding.
Various embodiments of the invention have been described. These and other embodiments are within the scope of the following claims.
Number | Date | Country | Kind |
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2005-043119 | Feb 2005 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/IB2006/000299 | 2/15/2006 | WO | 00 | 7/30/2007 |