The subject matter and the claimed invention were made by or on the behalf of University of Würzburg, of Würzburg, Bavaria, Germany and Huawei Technologies Co., Ltd., of Shenzhen, Guangdong Province, P.R. China, under a joint research agreement titled “Research on Micro-display Technology Based on Nano-antenna”. The joint research agreement was in effect on or before the claimed invention was made, and that the claimed invention was made as a result of activities undertaken within the scope of the joint research agreement.
This application relates to the field of display technologies, and in particular, to a pixel unit and a manufacturing method thereof.
Display products such as a micro light-emitting diode (μLED) display and an organic light-emitting diode (OLED) display have advantages such as self-luminescence, fast response, a wide angle of view, high brightness, bright colors, and lightweight and thinness, and are considered as a next-generation display technology.
In a related technology, a plurality of pixel units included in a display are usually classified into three types. A first type is a pixel unit that may emit a red light ray. A second type is a pixel unit that may emit a green light ray. A third type is a pixel unit that may emit a blue light ray. The pixel units of the three types may be arranged in a staggered manner to form a pixel array. For example, a column of the pixel array may include several pixel units. These pixel units are sequentially a pixel unit that may emit a red light ray, a pixel unit that may emit a green light ray, a pixel unit that may emit a blue light ray, a pixel unit that may emit a red light ray, . . . , a pixel unit that may emit a blue light ray, and the like.
Because it is difficult to implement light emission of the three colors by using a same material, light-emitting layers of the pixel units of the three types are manufactured by using different materials. In this case, when the pixel units of the three types are manufactured, the light-emitting layers of the pixel units of the three types need to be cut (in other words, the light-emitting layers of the pixel units of the three types cannot be integrally formed), to smoothly arrange the pixel units of the three types together in the staggered manner to form the pixel array. However, after the light-emitting layer of the pixel unit is cut, a sidewall is damaged. Consequently, light-emitting efficiency of the pixel unit is low.
Embodiments of this application provide a pixel unit and a manufacturing method thereof. Light-emitting layers of a plurality of pixel units may be integrally formed, and a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
According to a first aspect of embodiments of this application, a pixel unit is provided. The pixel unit includes:
It should be noted that a resonance band of the nano antenna may be determined by setting at least one of a material, a shape, and a size of the nano antenna in advance, and the obtained resonance band of the nano antenna may include a wavelength of a target light ray that may be emitted by the light-emitting layer. In this case, when the light-emitting layer works under an action of the first electrode and the second electrode, because the light-emitting layer has a light-emitting band, the light-emitting layer may generate a plurality of light rays (which may also be understood as a plurality of photons or a plurality of rays of light) having different wavelengths, and transmit the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna is determined, in the plurality of light rays, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna (actually, “enhanced” mentioned herein means that the nano antenna increases a radiation speed of the target light ray to increase intensity of the target light ray) and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate (actually, “suppressed” mentioned herein means that this part of light rays is not enhanced by the nano antenna, and when compared with the enhanced target light ray, this part of light rays seems to be “suppressed”). In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit a light ray of a specific color.
The pixel unit includes the substrate, the nano antenna and the first electrode connected to the nano antenna that are formed on the substrate, the light-emitting layer formed on the nano antenna and the first electrode, and the second electrode formed on the light-emitting layer. In the pixel unit, driven by voltages provided by the first electrode and the second electrode, the light-emitting layer generates the plurality of light rays having different wavelengths, and emits the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer, in the plurality of light rays generated by the light-emitting layer, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, the color of the target light ray is selected. Therefore, the pixel unit can emit the light ray of the specific color. It can be learned that, in a display constructed by the plurality of pixel units provided in embodiments of this application, each pixel unit may select, by using a nano antenna of the pixel unit, a light ray having a specific wavelength (a color) to be emitted. In this way, light-emitting layers of the plurality of pixel units may be made of a same material. In other words, the light-emitting layers of the plurality of pixel units may be integrally formed. Therefore, a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
In a possible implementation, both the first electrode and the nano antenna are of bar-shaped structures, and one end of the first electrode is connected to a middle part of the nano antenna. In the foregoing implementation, both the first electrode and the nano antenna may be configured as bar-shaped structures, and a connection part between the first electrode and the nano antenna is disposed in the middle of the nano antenna. This facilitates manufacturing of the pixel unit, and can further avoid impact of the first electrode on resonance of the nano antenna.
In a possible implementation, the first electrode and the nano antenna are disposed at a same layer. Certainly, the first electrode and the nano antenna may alternatively be disposed at different layers in a stacked manner. For example, the first electrode is disposed on the nano antenna. For another example, the nano antenna is disposed on the first electrode.
In a possible implementation, a second-order resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer. In the foregoing implementation, the light-emitting band of the light-emitting layer may be set to a range between adjacent-order resonance bands of the nano antenna. To be specific, a start wavelength of the light-emitting band of the light-emitting layer may be a wavelength between the second-order resonance band and a third-order resonance band of the nano antenna, and an end wavelength of the light-emitting band of the light-emitting layer may be a wavelength between a first-order resonance band and the second-order resonance band of the nano antenna. It can be learned that the light-emitting band of the light-emitting layer may include only the entire second-order resonance band of the nano antenna. In this case, the nano antenna may excite, from the plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths, the target light ray whose wavelength falls within the second-order resonance band of the nano antenna. This can avoid mutual interference between adjacent-order resonance of the nano antenna, and can improve purity of the light ray emitted by the pixel unit.
In a possible implementation, a polarization direction of the nano antenna during resonance is the same as a polarization direction of the target light ray. In the foregoing implementation, the polarization direction of the nano antenna during resonance may be determined by setting the shape of the nano antenna in advance, and the obtained polarization direction of the nano antenna during resonance is the same as the polarization direction of the target light ray that may be emitted by the light-emitting layer. It can be learned that the nano antenna may excite, from the plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths and different polarization directions, the target light ray whose wavelength falls within the resonance band of the nano antenna and whose polarization direction is the same as the polarization direction of the nano antenna during resonance.
In a possible implementation, a direction in which the nano antenna emits a light ray during resonance is the same as an emission direction of the target light ray obtained after the target light ray passes through the nano antenna. In the foregoing implementation, the light-emitting direction of the nano antenna during resonance (namely, the direction in which the nano antenna emits a light ray during resonance) may be determined by setting the shape of the nano antenna in advance, and the obtained light-emitting direction of the nano antenna during resonance is the same as an emission direction of the target light ray that may be emitted by the light-emitting layer (namely, the emission direction of the target light ray obtained after the target light ray passes through the nano antenna). It can be learned that the nano antenna may excite, from the plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths and different emission directions, the target light ray whose wavelength falls within the resonance band of the nano antenna and whose emission direction is the same as the light-emitting direction of the nano antenna during resonance.
In a possible implementation, the light-emitting layer includes an exciton recombination layer, to emit various light rays under the voltages applied by the first electrode and the second electrode.
In a possible implementation, the light-emitting layer further includes at least one of the following: a hole injection layer, a hole transport layer, an electron blocking layer, an electron injection layer, an electron transport layer, or a hole blocking layer. If the first electrode is an anode electrode and the second electrode is a cathode electrode, at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the nano antenna, and at least one of the electron injection layer, the electron transport layer, or the hole blocking layer is formed between the exciton recombination layer and the second electrode. If the first electrode is a cathode electrode and the second electrode is an anode electrode, at least one of the electron injection layer, the electron transport layer, or the hole blocking layer is formed between the exciton recombination layer and the nano antenna, and at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the second electrode. In the foregoing implementation, the light-emitting layer may further include one or more of the following: the hole injection layer, the hole transport layer, the electron blocking layer, the electron injection layer, the electron transport layer, or the hole blocking layer. These layers can facilitate migration of a hole or an electron, or suppress migration of the hole or the electron. It can be learned that, when the first electrode and the second electrode apply a specific voltage to the light-emitting layer, the hole and the electron move toward each other. To be specific, the hole moves from the first electrode to the second electrode (it is assumed that the first electrode is an anode electrode and the second electrode is a cathode electrode), and the electron moves from the second electrode to the first electrode. The hole and the electron recombine with each other at the exciton recombination layer to emit a light ray. This belongs to spontaneous emission. In this case, the light ray generated by the light-emitting layer is transmitted to the nano antenna, acts with the nano antenna connected to the first electrode, and then is transmitted by the nano antenna to the substrate.
In a possible implementation, a distance between the exciton recombination layer and the nano antenna is less than or equal to 20 nm. In the foregoing implementation, the distance between the exciton recombination layer and the nano antenna may be set to be less than or equal to 20 nm, to achieve an effect of strong coupling between the exciton recombination layer and the nano antenna.
In a possible implementation, the pixel unit further includes an insulating medium, and the insulating medium covers only the first electrode. In the foregoing implementation, the surface of the first electrode may be coated with the insulating medium, so that the insulating medium covers only the first electrode. In this case, the first electrode and the light-emitting layer are separated by the insulating medium. The first electrode and the light-emitting layer are not in contact with each other, and only the nano antenna is in contact with the light-emitting layer. In this way, almost all the light rays emitted by the light emitting layer are emitted to the nano antenna. In this way, impact of the first electrode on resonance of the nano antenna can be prevented, and a light-emitting position of the entire pixel unit can be limited to an area in which the nano antenna is located.
In a possible implementation, the first electrode is an anode electrode and the second electrode is a cathode electrode, or the first electrode is a cathode electrode and the second electrode is an anode electrode.
According to a second aspect of embodiments of this application, a pixel unit manufacturing method is provided. The method includes: forming, on a substrate, a nano antenna and a first electrode connected to the nano antenna; forming a light-emitting layer on the nano antenna and the first electrode that are connected, where a resonance wavelength of the nano antenna is equal to a wavelength of a target light ray that may be emitted by the light-emitting layer, and the target light ray is a light ray emitted by the pixel unit to the outside; and forming a second electrode on the light-emitting layer.
The pixel unit manufactured according to the foregoing method includes the substrate, the nano antenna and the first electrode connected to the nano antenna that are formed on the substrate, the light-emitting layer formed on the nano antenna and the first electrode, and the second electrode formed on the light-emitting layer. In the pixel unit, driven by voltages provided by the first electrode and the second electrode, the light-emitting layer generates a plurality of light rays having different wavelengths, and emits the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer, in the plurality of light rays generated by the light-emitting layer, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit the light ray of the specific color. It can be learned that, in a display constructed by a plurality of pixel units provided in embodiments of this application, each pixel unit may select, by using a nano antenna of the pixel unit, a light ray having a specific wavelength (a color) to be emitted. In this way, light-emitting layers of the plurality of pixel units may be made of a same material. In other words, the light-emitting layers of the plurality of pixel units may be integrally formed. Therefore, a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
In a possible implementation, both the first electrode and the nano antenna are of bar-shaped structures, and one end of the first electrode is connected to a middle part of the nano antenna.
In a possible implementation, the first electrode and the nano antenna are disposed at a same layer.
In a possible implementation, a second-order resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer.
In a possible implementation, a polarization direction of the nano antenna during resonance is the same as a polarization direction of the target light ray.
In a possible implementation, a direction in which the nano antenna emits a light ray during resonance is the same as an emission direction of the target light ray obtained after the target light ray passes through the nano antenna.
In a possible implementation, the forming a light-emitting layer on the nano antenna and the first electrode that are connected includes: forming an exciton recombination layer on the nano antenna and the first electrode that are connected.
In a possible implementation, the forming a light-emitting layer on the nano antenna and the first electrode that are connected further includes: forming at least one of an electron injection layer, an electron transport layer, or a hole blocking layer between the exciton recombination layer and the nano antenna, and forming at least one of a hole injection layer, a hole transport layer, or an electron blocking layer between the exciton recombination layer and the second electrode; or forming at least one of an electron injection layer, an electron transport layer, or a hole blocking layer between the exciton recombination layer and the nano antenna, and forming at least one of a hole injection layer, a hole transport layer, or an electron blocking layer between the exciton recombination layer and the second electrode.
In a possible implementation, a distance between the exciton recombination layer and the nano antenna is less than or equal to 20 nm.
In a possible implementation, the method further includes: forming an insulating medium on the first electrode, where the insulating medium covers only the first electrode.
In a possible implementation, the first electrode is an anode electrode and the second electrode is a cathode electrode, or the first electrode is a cathode electrode and the second electrode is an anode electrode.
According to a third aspect of embodiments of this application, a pixel array is provided. The pixel array includes a plurality of pixel units according to any one of the first aspect or the possible implementations of the first aspect. Light-emitting layers of the plurality of pixel units are made of a same material. Therefore, light rays emitted by the light-emitting layers of the plurality of pixel units are the same.
In a possible implementation, the light-emitting layers of the plurality of pixel units are integrally formed.
According to a fourth aspect of embodiments of this application, a display is provided. The display includes a driver chip and the pixel array according to the third aspect, and the driver chip is configured to provide a drive voltage for the pixel array.
According to a fifth aspect of embodiments of this application, an electronic device is provided. The electronic device includes a processor, a memory, and the display according to the fourth aspect.
The pixel unit provided in embodiments of this application includes the substrate, the nano antenna and the first electrode connected to the nano antenna that are formed on the substrate, the light-emitting layer formed on the nano antenna and the first electrode, and the second electrode formed on the light-emitting layer. In the pixel unit, driven by voltages provided by the first electrode and the second electrode, the light-emitting layer generates a plurality of light rays having different wavelengths, and emits the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer, in the plurality of light rays generated by the light-emitting layer, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit the light ray of the specific color. It can be learned that, in a display constructed by a plurality of pixel units provided in embodiments of this application, each pixel unit may select, by using a nano antenna of the pixel unit, a light ray having a specific wavelength (a color) to be emitted. In this way, light-emitting layers of the plurality of pixel units may be made of a same material. In other words, the light-emitting layers of the plurality of pixel units may be integrally formed. Therefore, a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
Embodiments of this application provide a pixel unit and a manufacturing method thereof. Light-emitting layers of a plurality of pixel units may be integrally formed, and a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
In the specification, claims, and accompanying drawings of this application, the terms “first”, “second”, and the like are intended to distinguish between similar objects but do not necessarily indicate a specific order or sequence. It should be understood that the terms used in such a way are interchangeable in proper circumstances, which is merely a discrimination manner that is used when objects having a same attribute are described in embodiments of this application. In addition, the terms “include”, “have”, and any other variants are intended to cover a non-exclusive inclusion, so that a process, method, system, product, or device that includes a series of units is not necessarily limited to those units, but may include other units not expressly listed or inherent to the process, method, system, product, or device.
Display products such as a μLED display and an OLED display have advantages such as self-luminescence, fast response, a wide angle of view, high brightness, bright colors, and lightweight and thinness, and are considered as a next-generation display technology.
In a related technology, to display a colorful image, the display needs pixel units that can emit a red light ray, a green light ray, and a blue light ray. Therefore, the plurality of pixel units included in the display may be classified into three types. A first type is a pixel unit that may emit a red light ray. A second type is a pixel unit that may emit a green light ray. A third type is a pixel unit that may emit a blue light ray. The pixel units of the three types may be arranged in a staggered manner to form a pixel array. For example, any column of the pixel array may include several pixel units. These pixel units are sequentially a pixel unit that may emit a red light ray, a pixel unit that may emit a green light ray, a pixel unit that may emit a blue light ray, a pixel unit that may emit a red light ray, . . . , a pixel unit that may emit a blue light ray, and the like.
Because it is difficult to implement light emission of the three colors by using a same material, light-emitting layers of the pixel units of the three types are manufactured by using different materials. In this case, when the pixel units of the three types are manufactured, the light-emitting layers of the pixel units of the three types need to be cut (in other words, the light-emitting layers of the pixel units of the three types are separately formed, instead of being integrally formed), to smoothly arrange the pixel units of the three types together in the staggered manner to form the pixel array. However, after the light-emitting layer of the pixel unit is cut, a sidewall is damaged. To be specific, after the light-emitting layer of the pixel unit is cut, a side surface exists, and current leakage occurs on the side surface of the light-emitting layer. Consequently, currents used for light emission are reduced, and overall light-emitting efficiency of the pixel unit is low.
Further, in the related technology, the light-emitting layers of the pixel units of the three types are manufactured by using different materials, and voltages required by the different materials during light emission are usually different. Therefore, for the display constructed based on the pixel units of the three types, due to a difference between the materials of the light-emitting layers and a difference between the voltages required by the materials, an overall manufacturing process of the display is very complex, and manufacturing costs are high.
Further, in the related technology, limited by the material of the light-emitting layer of the pixel unit, a spontaneous emission linewidth of the pixel unit is usually large. In other words, a band of the light ray that may be emitted by the pixel unit (the light-emitting layer of the pixel unit) is usually wide. Consequently, color purity of a light ray finally emitted by the pixel unit is inadequate. This impairs user experience.
Further, in the related technology, to meet requirements of some specific scenarios, the display needs to implement a polarization display effect or a directional display effect. In this case, a polarization filter or a directional filter is added to the pixel unit in the display, to cooperate with the pixel unit to implement a polarized light ray or a directional light ray. However, these additional filters tend to weaken intensity of the light ray emitted by the pixel unit, resulting in reduced light-emitting efficiency of the pixel unit.
To resolve the foregoing problems, embodiments of this application provide a new pixel unit, a pixel array constructed based on the new pixel unit, and a display constructed based on the pixel array. The following first describes the pixel unit provided in embodiments of this application.
The substrate is usually made of a transparent material (for example, glass or plastic). A first surface of the substrate may be used as a light-emitting surface of the entire pixel unit. The nano antenna and the first electrode are disposed on a second surface of the substrate. The first surface of the substrate and the second surface of the substrate are two opposite surfaces.
The nano antenna is similar to an antenna in the field of wireless communication, and is usually made of a metal material (for example, metal like gold, silver, aluminum, or copper) or another conductive material. The nano antenna has a resonance effect on a light ray having specific characteristics. It should be noted that these characteristics may include one or more of the following: a wavelength, polarization, a direction, and the like. In other words, when some light rays act on (hit) the nano antenna, if resonance characteristics of the nano antenna are consistent with characteristics of the light rays, the nano antenna may increase a (radiation) speed of the light rays, and further increase intensity of the light rays. If the resonance characteristics of the nano antenna are inconsistent with the characteristics of the light rays, the nano antenna suppresses the light rays.
Specifically, the material, a shape, and a size of the nano antenna determine a resonance band of the nano antenna. For a nano antenna of a specific material and in a specific shape, a size of the nano antenna is directly proportional to a resonance band of the nano antenna. In other words, a larger size of the nano antenna indicates a larger center wavelength of the resonance band of the nano antenna. For example, as shown in
The shape of the nano antenna determines a polarization direction of the nano antenna during resonance (in other words, the nano antenna undergoes resonance in a direction or some directions). Generally, an extension direction of the nano antenna is the polarization direction of the nano antenna during resonance. For a nano antenna that does not have an obvious extension direction, it may be considered that the nano antenna does not have a polarization direction during resonance. For example, as shown in
The shape of the nano antenna determines a light-emitting direction of the nano antenna during resonance (namely, a direction in which the nano antenna emits a light ray during resonance). For example, as shown in
The first electrode is usually made of a metal material (for example, metal like gold, silver, aluminum, or copper) or another conductive material. The first electrode is connected to the nano antenna. The first electrode and the nano antenna may be disposed at a same layer, and thicknesses of the first electrode and the nano antenna may be consistent (it should be noted that the first electrode and the nano antenna may alternatively be disposed at different layers in a stacked manner; for example, the first electrode is disposed on the nano antenna; and for another example, the nano antenna is disposed on the first electrode). It can be learned from the foregoing description that a first surface of the first electrode is attached to the second surface of the substrate. A first surface of the nano antenna is attached to the second surface of the substrate. A light-emitting layer is disposed on a second surface of the first electrode and a second surface of the nano antenna. The first surface of the first electrode and the second surface of the first electrode are two opposite surfaces, and the first surface of the nano antenna and the second surface of the nano antenna are two opposite surfaces.
The light-emitting layer may also be referred to as an electroluminescent laminate. It can be learned from the foregoing description that a first surface of the light-emitting layer is attached to the second surface of the first electrode. The first surface of the light-emitting layer is attached to the second surface of the nano antenna. A second electrode is disposed on a second surface of the light-emitting layer. The first surface of the light-emitting layer and the second surface of the light-emitting layer are two opposite surfaces. It can be learned that the light-emitting layer is disposed between the first electrode and the second electrode. Therefore, the light-emitting layer can generate the target light ray under a voltage jointly applied by the first electrode and the second electrode, and transmit the target light ray to the nano antenna, and then the nano antenna transmits the target light ray to the substrate, so that the substrate transmits the target light ray.
The second electrode is usually made of a metal material (for example, metal like gold, silver, aluminum, or copper) or another conductive material. It can be learned from the foregoing description that a first surface of the second electrode is attached to the second surface of the light-emitting layer. A second surface of the second electrode may remain exposed or may be provided with another component, and details are not described herein (the first surface of the second electrode and the second surface of the second electrode are two opposite surfaces).
It should be noted that a resonance band of the nano antenna may be determined by setting at least one of the material, the shape, and the size of the nano antenna in advance, and the obtained resonance band of the nano antenna may include a wavelength of the target light ray that may be emitted by the light-emitting layer. In this case, when the light-emitting layer works under an action of the first electrode and the second electrode, because the light-emitting layer has a light-emitting band, the light-emitting layer may generate a plurality of light rays having different wavelengths, and transmit the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna is determined, in the plurality of light rays, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit the light ray of the specific color.
For example, the light-emitting layer of the pixel unit may emit a light ray with a wavelength of 400 nm, a light ray with a wavelength of 401 nm, . . . , and a light ray with a wavelength of 800 nm (in other words, the light-emitting band of the light-emitting layer is 400 nm to 800 nm) to the nano antenna. Because the resonance band of the nano antenna is 640 nm to 660 nm (for example, the resonance band of the nano antenna may be set to 640 nm to 660 nm by setting the length of the nano antenna), the nano antenna may enhance the light ray with a wavelength of 640 nm, the light ray with a wavelength of 641 nm, . . . , and the light ray with a wavelength of 660 nm, and transmit the light rays to the substrate. At the same time, the nano antenna may also suppress the light ray with a wavelength of 400 nm, the light ray with a wavelength of 401 nm, . . . , the light ray with a wavelength of 639 nm, the light ray with a wavelength of 661 nm, . . . , and the light ray with a wavelength of 800 nm, to prevent these light rays from being transmitted to the substrate. In this way, the substrate may emit the light ray with a wavelength of 640 nm, the light ray with a wavelength of 641 nm, . . . , and the light ray with a wavelength of 660 nm. In other words, the pixel unit emits red light rays.
In a possible implementation, to facilitate manufacturing and avoid impact of the first electrode on resonance of the nano antenna, both the first electrode and the nano antenna may be of bar-shaped structures, and one end of the first electrode is connected to a middle part of the nano antenna. For example, as shown in
In a possible implementation, the nano antenna actually has a plurality of resonance bands, including a first-order resonance band, a second-order resonance band, and a third-order resonance band. The first-order resonance band has a largest center wavelength and a largest response amplitude, but a range of the first-order resonance band is wide. If the first-order resonance band is used to filter light rays, purity of the light ray emitted by the pixel unit may be inadequate. On the basis of this, a high-order resonance band of the nano antenna may be used to filter the light rays. A higher order of the resonance band indicates a smaller center wavelength, a smaller response amplitude, and a narrower band range. Therefore, both the response amplitude and the band range may be considered when the high-order resonance band of the nano antenna is selected. For example, for a nano antenna with a length of 120 nm, a center wavelength of a first-order resonance band of the nano antenna is 650 nm, and a center wavelength of a second-order resonance band of the nano antenna is 480 nm. A linewidth (a range) of the first-order resonance band is approximately 300 nm, while a linewidth of the second-order resonance band is only 20 nm.
To avoid mutual interference between adjacent-order resonance, the light-emitting band of the light-emitting layer may be set to a range between adjacent-order resonance bands of the nano antenna. To be specific, a start wavelength of the light-emitting band of the light-emitting layer may be a wavelength between the second-order resonance band and a third-order resonance band of the nano antenna, and an end wavelength of the light-emitting band of the light-emitting layer may be a wavelength between the first-order resonance band and the second-order resonance band of the nano antenna. For example, as shown in
It can be learned that the light-emitting band of the light-emitting layer may include only the entire second-order resonance band of the nano antenna. In this case, the nano antenna may excite, from a plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths, a target light ray whose wavelength falls within the second-order resonance band of the nano antenna. In other words, the second-order resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer. Specifically, after the light-emitting layer emits the plurality of light rays with different wavelengths to the nano antenna, in the plurality of light rays, at least one light ray whose wavelength is within the second-order resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to a substrate, so that the substrate transmits the target light ray to the outside of a pixel unit. The rest light rays whose wavelengths are outside the second-order resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate.
In a possible implementation, a polarization direction of the nano antenna during resonance may be determined by setting a shape of the nano antenna in advance, and the obtained polarization direction of the nano antenna during resonance is the same as a polarization direction of the target light ray that may be emitted by the light-emitting layer. It can be learned that the nano antenna may excite, from the plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths and different polarization directions, the target light ray whose wavelength falls within the resonance band of the nano antenna and whose polarization direction is the same as the polarization direction of the nano antenna during resonance. For example, it is assumed that a resonance band of the nano antenna is 640 nm to 660 nm, and a polarization direction of the nano antenna during resonance is a transverse direction. The light-emitting layer of the pixel unit may emit, to the nano antenna, a light ray whose wavelength is 400 nm and whose polarization direction is the transverse direction, . . . , a light ray whose wavelength is 650 nm and whose polarization direction is the transverse direction, a light ray whose wavelength is 651 nm and whose polarization direction is a longitudinal direction, . . . , and a light ray whose wavelength is 800 nm and whose polarization direction is the longitudinal direction. In this case, the nano antenna may enhance the light ray whose wavelength is 640 nm and whose polarization direction is the transverse direction, the light ray whose wavelength is 641 nm and whose polarization direction is the transverse direction, . . . , and the light ray whose wavelength is 650 nm and whose polarization direction is the transverse direction, and transmits these light rays to the substrate. At the same time, the nano antenna may also suppress the rest light rays (the rest light rays are either light rays whose wavelengths are outside 640 nm to 660 nm, or light rays whose polarization directions are not the transverse direction), to prevent these light rays from being transmitted to the substrate. In this way, the substrate may emit the light ray whose wavelength is 640 nm and whose polarization direction is the transverse direction, the light ray whose wavelength is 641 nm and whose polarization direction is the transverse direction, . . . , and the light ray whose wavelength is 650 nm and whose polarization direction is the transverse direction. In other words, the pixel unit emits light rays whose colors are red and whose polarization directions are the transverse direction.
In a possible implementation, a light-emitting direction of the nano antenna during resonance may be determined by setting the shape of the nano antenna in advance, and the obtained light-emitting direction of the nano antenna during resonance is the same as an emission direction of the target light ray that may be emitted by the light-emitting layer (the emission direction of the target light ray may also be understood as an emission direction of the target light ray obtained after the target light ray passes through the nano antenna). It can be learned that the nano antenna may excite, from the plurality of light rays that are emitted by the light-emitting layer and that have different wavelengths and different emission directions, the target light ray whose wavelength falls within the resonance band of the nano antenna and whose emission direction is the same as the light-emitting direction of the nano antenna during resonance. For example, it is assumed that a resonance band of the nano antenna is 640 nm to 660 nm, and a light-emitting direction of the nano antenna during resonance is a horizontal direction. The light-emitting layer of the pixel unit may emit, to the nano antenna, a light ray whose wavelength is 400 nm and whose polarization direction is the horizontal direction, . . . , a light ray whose wavelength is 650 nm and whose emission direction is the horizontal direction, a light ray whose wavelength is 651 nm and whose emission direction is an inclined direction, . . . , and a light ray whose wavelength is 800 nm and whose emission direction is the inclined direction. In this case, the nano antenna may enhance the light ray whose wavelength is 640 nm and whose emission direction is the horizontal direction, the light ray whose wavelength is 641 nm and whose emission direction is the horizontal direction, . . . , and the light ray whose wavelength is 650 nm and whose emission direction is the horizontal direction, and transmit these light rays to the substrate. At the same time, the nano antenna may also suppress the rest light rays (the rest light rays are either light rays whose wavelengths are outside 640 nm to 660 nm, or light rays whose emission directions are not the horizontal direction), to prevent these light rays from being transmitted to the substrate. In this way, the substrate may emit the light ray whose wavelength is 640 nm and whose emission direction is the horizontal direction, the light ray whose wavelength is 641 nm and whose emission direction is the horizontal direction, . . . , and the light ray whose wavelength is 650 nm and whose emission direction is the horizontal direction. In other words, the pixel unit emits light rays whose colors are red and whose emission directions are the horizontal direction.
In a possible implementation, the light-emitting layer includes an exciton recombination layer, and the exciton recombination layer includes one or more light-emitting materials. Specifically, the exciton recombination layer may have a plurality of structures: (1) The exciton recombination layer may include a plurality of layers of different materials, and each layer of material may emit a light ray of a specific color under an action of a voltage. For example, the exciton recombination layer may include three layers that are sequentially stacked. After the voltage is applied, the three layers may separately emit a red light ray, a green light ray, and a blue light ray. (2) The exciton recombination layer may be made of a mixed light-emitting material, and may emit a light ray in a wide band after a voltage is applied, including a red light ray, a green light ray, a blue light ray, and the like. It should be noted that the light-emitting material used to manufacture the exciton recombination layer may include at least one of the following: zinc phthalocyanine, zinc sulfide doped with copper, 8-hydroxyquinolinato aluminum, and the like.
In a possible implementation, the light-emitting layer may further include one or more of the following: the hole injection layer, the hole transport layer, the electron blocking layer, the electron injection layer, the electron transport layer, or the hole blocking layer. These layers can facilitate migration of a hole or an electron, or suppress migration of the hole or the electron. Generally, there are the following two cases: (1) If the first electrode is an anode electrode and the second electrode is a cathode electrode, at least one of the hole injection layer, the hole transport layer, or the electron blocking layer may be disposed between the exciton recombination layer and the nano antenna, and at least one of the electron injection layer, the electron transport layer, or the hole blocking layer may be further disposed between the exciton recombination layer and the second electrode. (2) If the first electrode is a cathode electrode and the second electrode is an anode electrode, at least one of the electron injection layer, the electron transport layer, or the hole blocking layer may be disposed between the exciton recombination layer and the nano antenna, and at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is disposed between the exciton recombination layer and the second electrode. For ease of description, the following uses Case (1) for description. Case (2) is similar to Case (1), and details are not described below. In Case (1), if at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is disposed between the exciton recombination layer and the nano antenna, a stacking sequence of the at least one of the hole injection layer, the hole transport layer, or the electron blocking layer may be random. This is not limited herein. Similarly, if at least one of the electron injection layer, the electron transport layer, or the hole blocking layer is disposed between the exciton recombination layer and the second electrode, a stacking sequence of the at least one of the electron injection layer, the electron transport layer, or the hole blocking layer may be random. This is not limited herein. For example, as shown in
In addition, a material of each layer included in the light-emitting layer may be shown in Table 1.
It should be understood that, in this embodiment, the materials shown in Table 1 are merely used as an example for description, and do not constitute a limitation on the material of each layer in the light-emitting layer.
In a possible implementation, to implement an effect of strong coupling between the exciton recombination layer and the nano antenna, a distance between the exciton recombination layer and the nano antenna may be set to be less than or equal to 20 nm. For example, the exciton recombination layer is in direct contact with the nano antenna. Alternatively, if at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is disposed between the exciton recombination layer and the nano antenna, a total thickness of the at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is less than or equal to 20 nm.
In a possible implementation, to prevent impact of the first electrode on resonance of the nano antenna and limit a light-emitting position of the entire pixel unit to an area in which the nano antenna is located, an insulating medium may be coated on a surface of the first electrode, so that the insulating medium covers only the first electrode. It can be learned that the first electrode and the light-emitting layer are separated by the insulating medium. The first electrode and the light-emitting layer are not in contact with each other, and only the nano antenna is in contact with the light-emitting layer. In this way, almost all the light rays emitted by the light emitting layer are emitted to the nano antenna. Still in the example shown in
In a possible implementation, the first electrode and the second electrode are a pair of electrodes. Therefore, there are the following two cases: (1) The first electrode is an anode electrode, and the second electrode is a cathode electrode. (2) The first electrode is a cathode electrode, and the second electrode is an anode electrode. It should be noted that a difference between Case (1) and Case (2) lies in that materials and thicknesses of the layers in the light-emitting layer may be different. For example, in Case (2), a material whose electron mobility is lower than whose hole mobility is preferred for the exciton recombination layer. In Case (1), a material whose electron mobility is higher than whose hole mobility is preferred for the exciton recombination layer. In this way, a recombination region of the hole and the electron is close to the nano antenna. This facilitates efficient coupling for light emission.
The pixel unit provided in embodiments of this application includes the substrate, the nano antenna and the first electrode connected to the nano antenna that are formed on the substrate, the light-emitting layer formed on the nano antenna and the first electrode, and the second electrode formed on the light-emitting layer. In the pixel unit, driven by voltages provided by the first electrode and the second electrode, the light-emitting layer generates a plurality of light rays having different wavelengths, and emits the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer, in the plurality of light rays generated by the light-emitting layer, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit a light ray of a specific color. It can be learned that, in a display constructed by a plurality of pixel units provided in embodiments of this application, each pixel unit may select, by using a nano antenna of the pixel unit, a light ray having a specific wavelength (a color) to be emitted. In this way, light-emitting layers of the plurality of pixel units may be made of a same material (in other words, light rays emitted by the light-emitting layers of the plurality of pixel units are the same). In other words, the light-emitting layers of the plurality of pixel units may be integrally formed. Therefore, a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
Further, in the display constructed by the plurality of pixel units provided in embodiments of this application, the light-emitting layers of the plurality of pixel units may be made of a same material. Therefore, a same drive voltage may be applied to the light-emitting layers of the plurality of pixel units. It can be learned that, because the light-emitting layers are made of the same material and voltages required by the material are the same, complexity of a manufacturing process of the display can be reduced, thereby effectively reducing manufacturing costs.
Further, in embodiments of this application, even if the spontaneous emission linewidth of the pixel unit is usually large, that is, the band of the light ray that may be emitted by the pixel unit (the light-emitting layer of the pixel unit) is wide, because a range of the resonance band of the nano antenna may be set to be narrow (for example, the second-order resonance band of the nano antenna is used), the nano antenna may accurately excite the target light ray whose wavelength falls within the resonance band. This improves color purity of a light ray finally emitted by the pixel unit, thereby improving user experience.
Further, in the pixel unit provided in embodiments of this application, the nano antenna may excite, from the plurality of light rays generated by the light-emitting layer, the light ray that has a specific wavelength and a specific polarization direction (or an emission direction). Therefore, the display constructed based on the pixel unit provided in embodiments of this application does not need an additional polarization filter (or a direction filter). Consequently, intensity of the light ray emitted by the pixel unit is not weakened, and light-emitting efficiency of the pixel unit can be maintained.
The foregoing describes in detail the pixel unit provided in embodiments of this application. The following describes a pixel unit manufacturing method according to an embodiment of this application.
801: Form, on a substrate, a nano antenna and a first electrode connected to the nano antenna.
In this embodiment, the nano antenna and the first electrode connected to the nano antenna may be manufactured on a (transparent) substrate. For example, as shown in
In a possible implementation, both the first electrode and the nano antenna are of bar-shaped structures, and one end of the first electrode is connected to a middle part of the nano antenna.
In a possible implementation, the first electrode and the nano antenna are disposed at a same layer.
802: Form a light-emitting layer on the nano antenna and the first electrode that are connected, where a resonance wavelength of the nano antenna is equal to a wavelength of a target light ray that may be emitted by the light-emitting layer, and the target light ray is a light ray emitted by the pixel unit to the outside.
Then, the light-emitting layer may be formed on the nano antenna and the first electrode that are connected. Specifically, the light-emitting layer may be formed in the following manner:
(1) Form an insulating medium on the first electrode, where the insulating medium covers only the first electrode. For example, as shown in
(2) Form an exciton recombination layer on the nano antenna and the first electrode that are connected, form at least one of a hole injection layer, a hole transport layer, or an electron blocking layer between the exciton recombination layer and the nano antenna, and form at least one of an electron injection layer, an electron transport layer, or a hole blocking layer between the exciton recombination layer and the second electrode. For example, as shown in
In a possible implementation, a second-order resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer.
In a possible implementation, a polarization direction of the nano antenna during resonance is the same as a polarization direction of the target light ray.
In a possible implementation, a direction in which the nano antenna emits a light ray during resonance is the same as an emission direction of the target light ray obtained after the target light ray passes through the nano antenna.
In a possible implementation, a distance between the exciton recombination layer and the nano antenna is less than or equal to 20 nm.
It should be understood that, in this embodiment, forming the insulating medium on the first electrode is merely used as an example for description. During actual application, the insulating medium may not be formed on the first electrode.
It should be further understood that, in this embodiment, at least one of a hole injection layer, a hole transport layer, or an electron blocking layer is formed between the exciton recombination layer and the nano antenna, and at least one of an electron injection layer, an electron transport layer, or a hole blocking layer is formed between the exciton recombination layer and the second electrode. This is merely for schematic description. During actual application, the following cases may alternatively exist: (1) The hole injection layer, the hole transport layer, and the electron blocking layer are not formed between the exciton recombination layer and the nano antenna, and the electron injection layer, the electron transport layer, and the hole blocking layer are not formed between the exciton recombination layer and the second electrode. (2) At least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the nano antenna, but the electron injection layer, the electron transport layer, and the hole blocking layer are not formed between the exciton recombination layer and the second electrode. (3) The hole injection layer, the hole transport layer, and the electron blocking layer are not formed between the exciton recombination layer and the nano antenna, but at least one of the electron injection layer, the electron transport layer, the hole blocking layer, or the like is formed between the exciton recombination layer and the second electrode.
It should be further understood that the foregoing merely uses an example in which the first electrode is an anode electrode and the second electrode is a cathode electrode for description. During actual application, the first electrode may alternatively be a cathode electrode, and the second electrode may alternatively be an anode electrode. In this case, after the exciton recombination layer is formed on the nano antenna and the first electrode that are connected, at least one of the electron injection layer, the electron transport layer, or the hole blocking layer may be formed between the exciton recombination layer and the nano antenna, and at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the second electrode.
It should be further understood that, in the foregoing example, the at least one of the electron injection layer, the electron transport layer, or the hole blocking layer is formed between the exciton recombination layer and the nano antenna, and the at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the second electrode. This is merely for schematic description. During actual application, the following cases may alternatively exist: (1) The electron injection layer, the electron transport layer, and the hole blocking layer are not formed between the exciton recombination layer and the nano antenna, and the hole injection layer, the hole transport layer, and the electron blocking layer are not formed between the exciton recombination layer and the second electrode. (2) At least one of the electron injection layer, the electron transport layer, or the hole blocking layer is formed between the exciton recombination layer and the nano antenna, but the hole injection layer, the hole transport layer, and the electron blocking layer are not formed between the exciton recombination layer and the second electrode. (3) The electron injection layer, the electron transport layer, and the hole blocking layer are not formed between the exciton recombination layer and the nano antenna, but at least one of the hole injection layer, the hole transport layer, or the electron blocking layer is formed between the exciton recombination layer and the second electrode.
803: Form a second electrode on the light-emitting layer.
Finally, the second electrode may be formed on the light-emitting layer, to obtain the entire pixel unit. For example, as shown in
The pixel unit manufactured according to embodiments of this application includes the substrate, the nano antenna and the first electrode connected to the nano antenna that are formed on the substrate, the light-emitting layer formed on the nano antenna and the first electrode, and the second electrode formed on the light-emitting layer. In the pixel unit, driven by voltages provided by the first electrode and the second electrode, the light-emitting layer generates a plurality of light rays having different wavelengths, and emits the plurality of light rays to the nano antenna. Because the resonance band of the nano antenna includes the wavelength of the target light ray that may be emitted by the light-emitting layer, in the plurality of light rays generated by the light-emitting layer, at least one light ray whose wavelength is within the resonance band of the nano antenna, namely, the target light ray, can be enhanced by the nano antenna and transmitted to the substrate, so that the substrate transmits the target light ray to the outside of the pixel unit. The rest light rays whose wavelengths are outside the resonance band of the nano antenna are suppressed by the nano antenna, and are difficult to be transmitted to the substrate. In this way, the pixel unit can successfully emit the target light ray. The wavelength of the target light ray is selected. In other words, a color of the target light ray is selected. Therefore, the pixel unit can emit a light ray of a specific color. It can be learned that, in a display constructed by a plurality of pixel units provided in embodiments of this application, each pixel unit may select, by using a nano antenna of the pixel unit, a light ray having a specific wavelength (a color) to be emitted. In this way, light-emitting layers of the plurality of pixel units may be made of a same material. In other words, the light-emitting layers of the plurality of pixel units may be integrally formed. Therefore, a sidewall of each pixel unit is not damaged. This can effectively improve light-emitting efficiency of all the pixel units.
Embodiments of this application further relate to a pixel array. The pixel array includes the plurality of pixel units shown in
Materials, shapes, and sizes of nano antennas of different pixel units in the plurality of pixel units may be the same or different. Therefore, resonance bands of the different pixel units may be the same or different. Similarly, polarization directions of the different pixel units during resonance may be the same or different, and light-emitting directions of the different pixel units during resonance may be the same or different.
In this way, the pixel array may simultaneously emit light rays with different wavelengths (colors), or may simultaneously emit light rays in different polarization directions (namely, different polarized light rays), or may simultaneously emit light rays in different emission directions.
For further understanding of the pixel array, the following further describes the pixel array with reference to a plurality of application examples.
Embodiments of this application further relate to a display. The display may include a driver chip and the pixel array described in any one of
Embodiments of this application further relate to an electronic device. The electronic device includes a processor, a memory, and the foregoing display.
The foregoing descriptions are merely specific implementations of this application, but are not intended to limit the protection scope of this application. Any variation or replacement readily figured out by a person skilled in the art within the technical scope disclosed in this application shall fall within the protection scope of this application. Therefore, the protection scope of this application shall be subject to the protection scope of the claims.
This application is continuation of International Application No. PCT/CN2022/106674, filed on Jul. 20, 2022, the disclosure of which is hereby incorporated by reference in its entirety.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/CN2022/106674 | Jul 2022 | WO |
| Child | 19029653 | US |