Plant protecting adjuvant containing topped or peaked alcohol alkoxylates and conventional alcohol alkoxylates

Abstract

An plant protecting composition comprising a biocide component and an adjuvant component wherein the adjuvant component includes at least one surfactant selected from the group consisting of topped alcohol alkoxylates and peaked alcohol alkoxylates and combinations thereof in combination with a conventional alcohol alkoxylate.

Description

BACKGROUND OF THE INVENTION

This invention relates to plant protecting compositions containing adjuvant compositions, and in particular, to adjuvant compositions that contain a topped or peaked alcohol ethoxylate or combinations thereof in combination with a conventional alcohol ethoxylate.

Adjuvants are commonly used in plant protecting compositions to facilitate biocidal action or to facilitate or modify characteristics of the biocidal formulations or spray solutions. In order to enhance or modify the chemical and/or physical characteristics of certain pesticides, adjuvants are added to form a mixture for spraying. Since spray application can be critical to the performance of the agricultural chemical, adjuvants are added to reduce application problems such as chemical stability, incompatibility, solubility, suspension, foaming, drift, evaporation, volatilization, phytotoxicity, surface tension, droplet size and coverage. They can, depending on their type, enhance wetting, translocation, spreading, sticking, emulsifying, dispersing and biological activity. Adjuvants include wetting agents, crop oil concentrates, spreaders, stickers, buffering agents, foaming and anti-foaming agents, dispersing agents and drift control agents. Over 200 EPA-registered pesticides have specific recommendations on their labels for adjuvant use. For example, they are recommended to enhance biological activity of the pesticide and to reduce, minimize or eliminate spray application problems as previously noted. There are several different types of adjuvants recommended. To achieve consistent and effective results, the user must first select the desired type of adjuvant and then the appropriate product within that specific type for use with a particular biocide and then use that product at recommended rates. Adjuvants can be added to the biocide formulation (commonly called “ready-to-dilute”) or at the applicator stage when the pesticide formulation is diluted with water or a suitable carrier into a spray tank (commonly called “tank mix”).

Nonionic surfactants have been used as activator adjuvants to facilitate biocide penetration wetting, spreading, dispersing, solubilizing, emulsifying and other surface modifying properties to bring about enhanced biocidal action. These surfactants have also been used as spray-modifier adjuvants to facilitate sticking or spreading of wettable biocidal powders or to modify the drift properties of the biocide. Examples of common nonionic surfactants used as spray adjuvants can be found in Adjuvants for Herbicides (Weed Science Society of America 1982), which is incorporated herein by reference.

A common nonionic surfactant used as an adjuvant is an alkyl aryl oxylate such as nonyl ethoxylate phenol, also known as nonoxynol-10. Although nonoxynol-10 is effective, suitable alternatives are continually being sought.

An acceptable alternative is a conventional aliphatic alcohol alkoxylate, commonly called an alcohol alkoxylate, such as alcohol ethoxylates. Alcohol ethoxylates or ethylene oxide adducts are nonionic surfactants having functional properties such as wetting, foaming, emulsifying, and dispersing abilities as well as solubilization and detergent abilities. While the use of alcohol ethoxylates alone as adjuvants has been satisfactory, there is an ongoing effort to make adjuvants with improved herbicidal performance.

Surprisingly, it has been found that the addition of an adjuvant composition containing topped or peaked alcohol alkoxylates, or combinations thereof in combination with conventional alcohol alkoxylates to certain post emergent biocidal mixtures increases the efficacy of these biocides beyond that of recognized standards.

SUMMARY OF THE INVENTION

The present invention relates to a plant protecting composition comprising an effective amount of agricultural biocide and from about 1% to about 40% of an adjuvant composition comprising a combination of nonionic surfactants selected from the group consisting of topped alcohol alkoxylates and peaked alcohol alkoxylates and combinations thereof with conventional alcohol alkoxylates. Preferably, the topped and peaked alcohol alkoxylates include alcohol ethoxylates, alcohol propoxylates, propoxylated and ethoxylated alcohols and combinations thereof. More preferably, the adjuvant composition includes primary aliphatic alcohol alkoxylates. The plant protecting composition may also contain other surfactants and additives so long as they do not detract from the improved results obtained from the adjuvant of the present invention.

The present invention further includes a method for increasing the efficacy of an agricultural biocide formulation comprising the step of providing an adjuvant comprising a nonionic surfactant selected from the group consisting of topped alcohol alkoxylates and peaked alcohol alkoxylates and combinations thereof with conventional alcohol alkoxylates. In one embodiment, the adjuvant composition and a biocide component are added to a tank mix. In another embodiment, the adjuvant is combined with the biocide component in a ready-to-dilute formulation.

Unexpectedly, it has been found that the adjuvant of the present invention improves the efficacy of certain post emergent agricultural biocide formulations beyond that of recognized standards.

It is noted that, unless otherwise stated, all percentages given in this specification and the appended claims refer to percentages by weight.

These and other advantages and features of the present invention will be better understood upon review of the following detailed description of the preferred embodiments.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The present invention relates to a plant protecting composition containing an adjuvant composition comprising a nonionic surfactant component selected from the group consisting of topped alcohol ethoxylates and peaked alcohol ethoxylates and combinations thereof with conventional alcohol alkoxylates.

Alcohol alkoxylates useful in the present invention are those containing an aliphatic hydrocarbon chain and an polyoxyalkylene chain.

The hydrocarbon chain may be derived from an aliphatic alcohol. Examples of alcohol alkoxylates useful as nonionic surfactants usually include those containing a fatty alcohol chain having a carbon length of from about C 8 to about C 20 . The oxyalkylene chain of the compound can have a length of from C 2 to about C 10 . Alcohol alkoxylates useful as nonionic surfactants will preferably contain a oxyalkylene chain consisting mainly of ethylene oxide units (commonly called alcohol ethoxylates), propylene oxide units (commonly called alcohol propoxylates) or a combination thereof (commonly called propoxylated and ethoxylated alcohols).

Alcohol alkoxylates are generally prepared by alkoxylating the aliphatic alcohol with the oxyalkylene in the presence of a catalyst such as potassium oxide or sodium oxide. Examples of alcohol ethoxylates and alcohol propoxylates useful as nonionic surfactants include C 8 -C 18 alcohols with 1-15 moles of ethylene oxide (EO) or propylene oxide (PO) units per mole of alcohol. The distribution of ethoxylation or propoxylation, as the case may be, is quite broad and a sizable amount of free alcohol is left in the product. Common conventional alcohol ethoxylates are listed under the chemical classification of “ethoxylated alcohols” in McCutcheon's Emulsifiers & Detergents , Annual 1992. Common conventional alcohol propoxylates as well as propoxylated and ethoxylated alcohols are listed under the chemical classification “propoxylated & ethoxylated fatty acids, alcohol or alkyl phenols” in McCutcheon's. The relevant portions of McCutcheon's are incorporated herein by reference.

Certain alcohol alkoxylates useful in the present invention are selected from the group consisting of topped alcohol alkoxylates, peaked alcohol alkoxylates and combinations thereof.

Topped alcohol alkoxylates refer to a distribution containing C 6 or higher carbon chain monofunctional and polyfunctional alcohols. Topped alcohol alkoxylates include both linear and branched alcohol alkoxylates. Topped alcohol alkoxylates have free alcohol and low mole alkoxylate entities removed physically by conventional separation processes such as extraction and distillation. Particularly preferred topped alcohol alkoxylates contain primary alcohol alkoxylates having C 6 or greater carbon chains.

Peaked alkoxylates refers to a narrow, high mole adduct distribution from the ethoxylation of linear or branched alcohols. Peaked alkoxylates have a more narrow and highly peaked alkoxylation distribution that results in a low amount of residual free alcohol, a lower amount of lower oxyalkylene adducts and a lower amount of higher oxyalkylene adducts in the product. Peaked alcohol alkoxylates are obtained through the use of different catalysts and/or manufacturing conditions. Examples of the preparation of peaked alcohol ethoxylates include U.S. Pat. No. 4,210,764 to Yang et al. and U.S. Pat. No. 5,118,650 to King, the disclosures of which are incorporated herein by reference.

The preferred peaked alcohol alkoxylates of the present invention include alcohol alkoxylates having a residual free alcohol content of less than about three percent. Particularly preferred peaked alcohol alkoxylates are C 6 -C 20 alcohol ethoxylates, C 6 -C 20 alcohol propoxylates, C 6 -C 20 propoxylated and ethoxylated alcohols and combinations thereof. The more preferred peaked alcohol alkoxylates are C 8 -C 16 alcohol ethoxylates containing from about 2 to about 20 moles of ethylene oxide (EO) per molecule, C 8 -C 16 alcohol propoxylates containing from about 2 to about 20 moles of propylene oxide (PO) per molecule, C 8 -C 16 propoxylated and ethoxylated alcohols.

The more preferred topped and peaked alcohol alkoxylates are the biodegradable aliphatic alcohol alkoxylates, in particular primary aliphatic alcohol alkoxylates, and more preferably linear primary alcohol alkoxylates.

The adjuvant composition of the present invention may also contain other ingredients found in commercial adjuvants so long as they do not detract from the beneficial effects of the present invention. Examples of optional ingredients include additional surfactants, viscosity modifiers, stabilizing agents, pH modifiers, corrosion inhibitors, and the like. Examples of such optional ingredients can be found in U.S. Pat. No. 5,084,087 to Hazen et al., which is incorporated herein by reference.

The adjuvant composition of the present invention may be combined with one or more biocide components in various forms. For example, the adjuvant composition can be added to tank mixes with the biocide component(s). Alternatively, the adjuvant composition of the subject invention can be incorporated into a ready-to-dilute formulation containing the biocide component(s). Common forms of ready-to-dilute formulation include, for example, dispersible powders, nondispersible powders, oil solubles, liquid concentrates or aqueous solutions.

The agricultural biocide component can be, for example, a fungicide, herbicide, insecticide, nematocide, acaricide and mixtures thereof. By “agricultural biocide” it is meant any biocide, pesticide, or herbicide. The type of the biocide component used is not critical to the use of the adjuvant composition according to the invention. Examples of common biocides are listed in U.S. Pat. No. 4,793,850 to Koester et al. and in U.S. Pat. No. 4,851,421 to Iwasaki et al., the entire disclosures of which are incorporated herein by reference.

The plant protection composition resulting from the combination of adjuvant and biocide component contains an effective amount of biocide component. The “effective amount” can be experimentally determined and depends upon the type and form of biocide used. For example, a ready-to-dilute plant protecting composition may include from about 1 to about 95% biocide, by weight of the composition. Ready-to-dilute formulations in the dry flowable powder form usually contains greater than about 90% biocide, while other powdered formulations can contain less than 30% biocide. In addition, ready-to-dilute formulations in the form of emulsifiable concentrates can contain up to about 40% biocide, while the concentration of biocide in suspension concentrates can be about 60%.

The adjuvant composition of the present invention can be added to a tank mix generally in amounts of from 0.0001 to about 10% of the tank mix. Preferably, the adjuvant composition is from 0.001% to about 5% by weight of the tank mix. More preferably, the adjuvant composition can be added to the tank mix in amounts of from 0.005% to about 2% by weight of the formulation. Most preferably, the adjuvant composition is from 0.01% to about 0.5% by weight of the formulation. In a preferred embodiment, the adjuvant 1.0 composition of the present invention has a Hydrophilic-Lipophilic Balance (HLB) that matches the HLB of the active biocide component. The adjuvant composition of the present invention can be added to the ready-to-dilute biocide formulation generally in amounts of from 1 to 40 percent of the tank mix so as to result in tank mix concentration specified above.

The adjuvant composition of the present invention can also be combined with the biocide component along with other ingredients such as other surfactants and adjuvants. Examples of these optional ingredients include, but are not limited to solvents, co-solvents, preservatives, corrosion inhibitors, thickening agents and buffering agents.

The advantages and other characteristics of the present inventions are best illustrated by the following examples.

EXAMPLES

In the examples, the performance of compositions containing commonly used surfactants were compared with those of compositions containing topped or peaked alcohol ethoxylates. Table I lists the chemical description of the various surfactants used.

TABLE I
Surfactant        Chemical Description
Alfonic 610-50R   ethoxylated linear alcohols (50% EO)
Alfonic 810-60    ethoxylated linear alcohols (60% EO)
Alfonic 1412-60   ethoxylated linear alcohols (60% EO)
APSA-80           ethoxylated nonyl phenol
Genapol UD 079    C                                                                        11                                                                     linear alcohol ethoxylate containing an
                  average of 7 moles EO/mole alcohol
Genapol 26 L 60 N peaked C                                                                        12-16                                                                     linear primary alcohol
                  containing an average of 7 moles EO
Genapol UD 070N   peaked C                                                                        11                                                                     linear alcohol ethoxylate
                  containing an average of 7 moles EO
Genapol UD 080N   peaked C                                                                        11                                                                     linear alcohol ethoxylate
                  containing an average of 8 moles EO
Neodol 1-7        C                                                                        11                                                                     linear primary alcohol ethoxylate
                  containing an average of 7 moles EO/mole
                  alcohol
Neodol 23-6.5T    topped C                                                                        12                                                                    -C                                                                        13                                                                     linear alcohol ethoxylate
                  containing an average of 6.5 moles EO/mole
                  alcohol
Neodol 23-9       C                                                                        12                                                                    -C                                                                        13                                                                     linear alcohol ethoxylate containing
                  an average of 9 moles EO/mole alcohol
Neodol 91-6       C                                                                        9                                                                    -C                                                                        11                                                                     linear primary alcohol ethoxylate
                  containing an average of 6 moles EO/mole
                  alcohol
Nonoxynol 10      ethoxylated nonyl phenol (10% EO)
Novel II 1412-70  peaked C                                                                        12                                                                    -C                                                                        14                                                                     linear primary alcohol ethoxylate
                  (70% EO)
Novell II 1012-7  peaked C                                                                        10-12                                                                     linear alcohol ethoxylate
                  containing an average of 7 moles EO
Novel II 1012-5.5 peaked C                                                                        10-12                                                                     linear alcohol ethoxylate
                  containing an average of 5.5 moles EO
Silwet            silicon glycol copolymer
Toximul 8304      alcohol ethoxylate blend containing an
                  average of 6 moles EO/mole alcohol
Triton XL-80N     short-chain secondary alcohol alkoxylate
                  blend containing ethylene oxide and
                  propylene oxide
X-77              commercial product based on Nonoxynol-10

Following is a list of adjuvants and their manufacturers from which they may be obtained. Alfonic 610-50R, Alfonic 810-60, Alfonic 1412-70, Novel II 1412-70, Novel II 1216CO-7, Novel II 1012-7, Novel II 1012-5.5 can be obtained from CondeaVista. Genapol UD 070, Genapol UD 070, Genapol UD 070N, Genapol 26-L-60N, and Genapol UD 080N can be obtained from Clariant Corporation. Neodol 1-7, Neodol 23-6.5T, Neodol 23-9, and Neodol 91-6 can be obtained from The Shell Chemical Company. Silwet can be obtained from Osi. Toximul 8304 can be obtained from Stepan Chemical Company. Triton XL-80N can be obtained from Union Carbide. Accent Pinnacle can be obtained from DuPont. Beacon can be obtained from Ciba. Roundup can be obtained from Monsanto. Pursuit can be obtained from American Cyanamid. Gramoxone Extra can be obtained from Zeneca.

EXAMPLE 1

Weed control evaluation was performed on sprayable herbicide formulations containing a series of alternate surfactants to replace Nonoxynol-10, the accepted industry standard.

The results of this greenhouse study are shown in Table II. Table II provides the weed control rating in percentage. As shown in Table II, Neodol 23-6.5T, a topped alcohol ethoxylate, out-performed Nonoxynol 10 on the BeaconJ and RoundupJ herbicide brands in Giant Foxtail and Seedling Johnsongrass. Moreover, Neodol 23-6.5T, the topped alcohol ethoxylate was the only alcohol ethoxylate that performed close to Nonoxynol-10.

The amount of herbicide used corresponding to the herbicides is Table II is shown in the immediately following chart.

Chart of Herbicides
Herbicide Amount
Accent    3.5 g a.i./ha at 25 gpa
Beacon    2.0 g a.i./ha at 25 gpa on seedling
          Johnson grass and 14.8 g a.i./ha on
          giant foxtail
Roundup   0.3 lb./acre at 25 gpa
Pursuit   24.7 g a.i./ha at 25 gpa
Pinnacle  1.9 g a.i./ha at 25 gpa

In the above chart, “a.i.” means “active ingredient, “ha” is the abbreviation for hectare, and “gpa” means “gallons per acre spray volume.”

TABLE II
WEED CONTROL RATING (YEAR 1)
Herbicide	ACCENT	ACCENT	BEACON	BEACON	ROUNDUP
Weed	Giant	Seedling	Giant	Seedling	Giant	PURSUIT	PINNACLE	Total Average
Specie	Foxtail	Johnsongrass	Foxtail	Johnsongrass	Foxtail	Velvet leaf	Velvet leaf	Rating
Adjuvant
(at 0.5%)
Nonoxynol	81	75	66	72	88	71	61	73.4
10
NeodoL	76	66	71	78	98	43	50	68.9
23-6.5T
Neodol	74	74	53	69	79	39	41	61.3
91-6
Neodol	71	68	65	64	79	36	42	60.7
1-7
Genapol	70	72	61	68	76	36	34	59.6
UD079
Triton	74	73	44	73	79	34	39	59.4
XL-80N
X-77	65	63	58	54	59	53	45	56.7
Toximul	68	55	36	50	83	34	34	51.4
8304
Alfonic	61	49	53	56	79	31	28	51.0
610-50R
Alfonic	63	43	29	59	73	38	33	48.3
810-60
Coupled	63	34	33	51	64	29	29	43.2
Ethoxylate
Herbicide	4	13	14	6	61	23	8	18.4
Alone
No	0	0	0	0	0	0	0	0
Treatment

EXAMPLE 2

Weed control evaluation was performed on sprayable herbicide formulations containing a peaked alcohol ethoxylate (Novel 11 1412-70) and compared to formulations containing Nonoxynol-10.

Table III provides the weed control rating in percentage. In this test, herbicides containing the peaked alcohol ethoxylate out-performed those that contained Nonoxynol-10 in weed control experiments on five herbicides and four weed species.

The amount of herbicide used corresponding to the herbicides in Table III is shown in the immediately following chart.

Chart of Herbicides
Herbicide Amount
Accent    3.5 g a.i./ha at 25 gpa
Beacon    2.0 g a.i./ha at 25 gpa on seedling
          Johnson grass and 14.8 g a.i./ha on
          giant foxtail
Roundup   0.3 lb./acre at 5 gpa on velvet leaf
          and lambs quarters, and 0.15 lb.
          a.i./A on foxtail and Johnson grass
Pursuit   24.7 g a.i./ha at 25 gpa
Pinnacle  1.9 g a.i./ha at 25 gpa

In the above chart, “a.i.” means “active ingredient, “ha” is the abbreviation for hectare, and “gpa” means “gallons per acre spray volume.”

TABLE III
WEED CONTROL RATING (YEAR 2)
		Accent		Beacon	Round-	Roundup	Pin-	Pinnacle		Pursuit	Round-	Roundup
Herbicide	Accent	Seedling	Beacon	Seedling	up	Seedling	nacle	Common	Pursuit	Common	up	Common	Total
Weed	Giant	Johnson-	Giant	Johnson-	Giant	Johnson-	Velvet	Lambs-	Velvet	Lambs-	Velvet	Lambs-	Average
Specie	Foxtail	grass	Foxtail	grass	Foxtail	grass	leaf	quarters	leaf	quarters	leaf	quarters	Rating
Adjuvant
(at 0.5%)
Novel II	63	70	62	66	95	85	60	78	76	61	88	89	74.4
1412-70
Nonoxy-	71	71	66	65	88	64	56	76	64	55	68	88	69.3
nol-10
X-77	53	56	57	44	84	65	44	66	59	40	73	90	60.9
Herbicide	5	4	4	4	88	60	13	13	23	10	73	81	31.4
Alone
Untreated	0	0	0	0	0	0	0	0	0	0	0	0	0

Table IV contains the weed control rating in percentage. It is surprising that several peaked linear alcohol ethoxylates outperformed non-peaked alcohol ethoxylate, X-77.

	TABLE IV
											Gramoxone
	Accent			Pursuit			Pinnacle		Roundup		Extra
	Velvet-	Gt	Lambs-	Velvet-	Gt	Lambs-	Velvet-	Lambs-	Gt	Lambs-	Lambs-
	leaf	Foxtail	quarters	leaf	Foxtail	quarters	leaf	quarters	Foxtail	quarters	quarters	Average
Novel II	50	68	61	59	62	48	80	76	91	71	86	68.4
1412-70
Genapol	39	57	53	4	55	44	46	75	78	86	51	55.3
26-L-60N
Genapol	36	56	43	39	59	43	38	73	65	61	39	50.2
UD 080N
X-77	40	47	51	41	48	43	39	69	46	70	53	49.7
Genapol	19	49	46	41	56	46	39	74	58	68	38	48.5
UD 707N
Novel II	22	56	46	40	52	50	45	66	58	58	31	47.6
1012-7
Novel II	25	47	43	39	48	43	40	74	49	60	31	45.6
1012-5.5
Herbicide	10	5	9	25	10	9	17	11	53	52	26	20.6
Alone
No	0	0	0	0	0	0	0	0	0	0	0	0
Treatment

The amount of herbicide used corresponding to the herbicides in Table IV is shown in the immediately following chart. The surfactant comprised 0.25% of the spray volume.

Chart of Herbicides
Herbicide       Amount
Accent          0.03125 lbs/acre at 25 gpa on
                velvetleaf and lambsquarters and
                0.003125 lbs/acre at 25 gpa on giant
                Foxtail
Gramoxone Extra 0.156 lbs/acre at 25 gpa
Roundup         0.25 lbs/acre at 5 gpa on
                lambsquarters and 0.1 lbs/acre on
                foxtail
Pursuit         0.022 lbs/acre at 25 gpa
Pinnacle        0.0016 lbs/acre at 25 gpa

In the above chart, “a.i.” means “active ingredient, “ha” is the abbreviation for hectare, and “gpa” means “gallons per acre spray volume.”

In a total of 74 field trial runs in which a nonoxynol-10 based spray adjuvant was compared with a peaked alcohol ethoxylate formulation, there was no significantly different average weed control between the two formulations. The nonoxynol-10 formulation had a weed control rating of 81.5% compared to the peaked formulations weed control of 80.5%. Both formulations, the peaked and non peaked, gave weed control that was significantly better than the herbicide alone which had a weed control of 71.8 percent. It is surprising and one would generally expect that crop yield would follow weed control. The surprising result is that the peaked adjuvant formulation had a higher crop yield than the nonoxynol-10 or herbicide treatment alone. The peaked adjuvant formulation had a normalized yield of 106.9%. The nonoxynol-10 formulation gave a normalized yield of 105.3%, which is 1.6% less than the peaked adjuvant formulation. This result is surprising in that the peaked formulation gave comparable weed control to the nonoxynol-10 formulation and gave a higher crop yield over a broad range of crops and herbicides.

Thus, in a preferred embodiment of the present invention, the plant protecting composition comprises a biocide in combination with an adjuvant composition comprised essentially of a nonionic surfactant component selected from the group consisting of topped alcohol ethoxylates, peaked alcohol ethoxylates, topped alcohol propoxylates, peaked alcohol propoxylates, topped propoxylated and ethoxylated alcohols, peaked propoxylated and ethoxylated alcohols and combinations thereof and in combination with conventional alcohol alkoxylates, wherein the peaked surfactants contain less than about 3% residual free alcohol.

Additionally, the plant protecting composition may contain approximately 9% isopropanol, approximately 0.5% sodium benzoate, acetic acid, soft water and other components in addition to the peaked or topped alcohol alkoxylates and combinations thereof in combination with conventional alcohol alkoxylates.

A formulation of one preferred embodiment is shown in the Table V set forth immediately below.

TABLE V
FORMULATION
Compound                         Percentage
Toximul 8304 isodecyl Alcohol plus 6 40
moles of Ethylene Oxide conventional
Alcohol Ethoxylate
Novell 11 1216 CO-7 C                                                                        12,14 and 16 40
alcohol with 7 moles EO peaked
alcohol ethoxylate
Isopropanol                      9
Sodium Benzoate                  0.5
Acetic Acid                      as needed to obtain pH of 7
Soft water                       quantity sufficient

Of course, it should be understood that a wide range of changes and modifications can be made to the embodiments described above. It is therefore intended that the foregoing description illustrates rather than limits this invention, and that it is the following claims, including all equivalents, which define this invention.

Claims

1. A plant protecting composition comprising an agricultural biocide and an adjuvant composition comprising a primary component selected from the group consisting of a peaked C12-C16 linear primary alcohol containing an average of 7 moles of ethylene oxide a peaked C12-C14 linear primary alcohol ethoxylate (70% ethylene oxide), and mixtures thereof.

2. The composition of claim 1 further comprising a topped alcohol alkoxylate having a C6 or greater alkyl group.

3. A method for increasing the efficacy of an agricultural biocide formulation including a biocide component comprisingproviding an adjuvant composition selected from the group consisting of a peaked C12-C16 linear primary alcohol containing an average of 7 moles of ethylene oxide, a peaked C12-C14 linear primary alcohol ethoxylate (70% ethylene oxide), and mixtures thereof.

4. The method of claim 3 further comprising a topped alkoxylate having a C6 or greater alkyl group.