Patent Grant
7358672
This Application is a U.S. National Phase Application of PCT International Application PCT/JP2004/018850.
The present invention relates to a plasma display panel for plasma display device known as a large-screen, flat and lightweight display device.
The plasma display panel (hereafter referred to as PDP) generates ultra-violet ray in gas discharge, and excites phosphors to emit light by the ultra-violet ray to perform image displaying.
The plasma display panels are roughly divided into AC powered and DC powered in driving method, and into surface discharge and counter discharge in discharging method. Currently, however, surface discharge AC powered with three-electrode structure has become the mainstream technology due to capabilities for high definition display, large-sized screen, simple structure and easy manufacturing method.
The AC powered PDP consists of a front substrate and a rear substrate. The front substrate is a substrate made of glass or the like on which: display electrodes including scan electrodes and sustain electrodes; light-shields between adjacent display electrodes; a dielectric layer covering the electrodes; and a protective layer to cover the layers further, are formed. The rear substrate is a substrate made of glass or the like on which: a plurality of address electrodes crossing the display electrodes on the front substrate; a dielectric layer covering the electrodes; and ribs on the dielectric layer are formed. The front substrate and rear substrate are positioned facing each other so as to form discharge cells at crossings of discharge electrodes and data electrodes, and the discharge cells are provided with phosphor layers internally.
The display electrode is provided with a transparent electrode and a bus electrode. The bus electrode has a black electrode to block incoming light reflection and a low resistance metal-rich electrode.
More recently, the PDP attracts increasing attention among flat panel display technologies and is used widely as a display device for a place crowded with many people or to enjoy images at a large screen home-theater. This is because the PDP can respond to display faster and can be produced in large sizes easier than LCD, with wide viewing angles and a high picture quality due to self-lighting.
As to the configuration of black electrodes to compose the display electrode and the light-shield provided between the display electrodes, an example is disclosed in Japanese Patent Unexamined Publication No. 2002-83547: these electrodes are formed of a plurality of layers on the substrate and one of a plurality of the layers is a black layer, having a higher sheet resistance than the other layers, which forms the light-shields as well as the black electrodes integrally.
However, when the black layer is commonly used to the light-shield, a smaller resistance of the black layer would increase capacitance in the light-shield, causing an increase in power consumption. Contrarily, a larger resistance of the black layer would increase the resistance of transparent electrode composing the display electrode, causing a critical problem of poor image quality.
The PDP disclosed in the present invention has a pair of substrates that include at least one transparent front substrate and are positioned to face each other so that discharge spaces are formed between the substrates.
The front substrate has display electrodes provided with scan electrodes and sustain electrodes, and light-shields formed on non-discharge areas between the display electrodes.
The rear substrate has phosphor layers to emit light by discharge. The display electrode has a transparent electrode and a bus electrode. The bus electrode includes a plurality of electrode layers and at least one of the electrode layers is a black layer with a product of a resistivity and a layer thickness of not larger than 2 Ωcm2. The light-shield is a black layer with a resistivity of not smaller than 1×106 Ωcm.
The configuration can prevent poor discharge due to voltage drops of the bus electrode in the black electrode and due to interferences of voltage wave shapes from the light-shield, enabling to reduce man-hour of the PDP manufacturing process and to provide a PDP with a high picture quality.
Now, the PDP used in the exemplary embodiments of the present invention are described with reference to drawings.
PDP 1 comprises front substrate 2 and rear substrate 5 positioned to face each other so that narrow discharge spaces 16 are formed as shown in
Transparent electrodes 4a and 5a are for instance indium tin oxide (ITO) layer provided on glass substrate 3 by electron beam evaporation. A flat ITO layer is formed on glass substrate 3 before patterning resists on the layer to form transparent electrodes 4a and 5a by etching. SnO2 can be adopted also as a material for transparent electrodes 4a and 5a.
Bus electrodes 4b and 5b are composed of a plurality of electrode layers, and at least one of the electrode layers is a black layer formed from a black material common to light shield 7. The black material is a mixture of: a black pigment (black oxides such as Cr—Co—Mn series, Cr—Fe—Co series or the like); a glass frit (PbO—B2O3—SiO2 series, Bi2O3—B2O3—SiO3 series or like); and a conductive material. A photosensitive black paste composed of the black material added with a photo-polymerization initiator, photo-hardening monomer, organic solvent or the like forms the black layer by the screen-printing method or the like. Moreover, the electrode layers or conductive layers are provided on the black layers. Specifically, the material used for the conductive layers is a photosensitive Ag-based paste including: a conductive material having Ag or the like; a glass frit (PbO—B2O3—SiO2 series, Bi2O3—B2O3—SiO3 series or the like); a photo-polymerization initiator; a photo-hardening monomer; and an organic solvent or the like. A layer of the photosensitive Ag-based paste formed on the black layers by screen-printing is patterned to form the conductive electrode layers by the photolithography.
Since formed from the black material common to bus electrode 4b and 5b, light shield 7 can be formed at the same time when the black layers are formed on transparent electrode 4a and 5a, thereby enabling to reduce man-hours of the PDP manufacturing process and to improve material usage rate. That is, a layer of the black material, a material for the black layer and light shield 7 as well, is formed on non-discharge area located between display electrodes 6 adjacent to each other. The black layers of bus electrodes 4b and 5b, and light shield 7 can be formed at the same time by patterning bus electrodes 4b and 5b, and light shield 7 respectively. Here, the black layer can be colored not only in true black but also in any blackish color such as gray color.
Subsequently, display electrodes 6 and light shield 7 formed as above are covered by dielectric layer 8. Dielectric layer 8 is formed from a paste containing lead-based glass materials coated by for instance screen printing and is dried before sintering. Then, dielectric layer 8 is covered by protective layer 9 to complete front substrate 2. Protective layer 9 composed of for instance MgO is formed by vacuum evaporation or sputtering.
Next, rear substrate 10 has address electrodes 12 formed on glass 11 arranged in stripe-shaped. Specifically, a material for address electrodes 12, a photosensitive Ag-based paste or the like, is applied to form a layer on glass substrate 11 by screen printing or the like and then the layer patterned by lithography or the like before sintering.
Subsequently, address electrodes 12 formed as above are covered by dielectric layer 13. Dielectric layer 13 is formed from a paste containing lead-based glass materials coated by for instance screen-printing and dried before sintering. Instead of printing the paste, laminating a precursor to dielectric layer molded in film-like before sintering can form the dielectric layer.
Next, ribs 14 are formed arranged in stripe-shaped. Ribs 14 can be formed from a layer, composed of a photosensitive paste containing mainly aggregates such as Al2O3 and glass frits and applied by die-coating or screen-printing, patterned by photo-lithography before sintering. Additionally, ribs can be formed from the paste, containing lead-based glass materials, coated repeatedly in a certain intervals by for instance screen-printing and dried before sintering. Here, gap dimensions between ribs 14 shall be of the order of 130 to 240 μm in the case of for instance 32 to 50 inch HD-TV.
Phosphor layers 15R, 15G and 15B having phosphor powders red (R), green (G) and blue (B) respectively are formed in a groove between two ribs 14. Each color of phosphor layer 15R, 15G and 15B is formed by; coating and drying a paste-like phosphor suspension composed of a phosphor powder and organic binders; and subsequently sintering it to burn off the organic binders at the temperature of 400 to 590° C., allowing the phosphor particles to adhere.
Front substrate 2 and rear substrate 10 produced as described above are positioned facing each other so that display electrodes 6 of front substrate 2 generally cross address electrodes 12 of rear substrate 10, and sealants such as sealing glasses applied into peripheral portions are sintered for instance at 450° C. or so for 10 to 20 minutes to form an air-tight sealing layer (not shown). Then, the inside of discharge spaces 16, once pumped to a high vacuum (for instance 1.1×10−4 Pa), are filled with a discharge gas for instance Ne—Xe 5% at the pressure of 66.5 kPa (500 torr) to complete PDP 1.
By the configuration shown in
Additionally, the materials for the black layer include black pigments, conductive substances and frit glass in this exemplary embodiment, wherein ruthenium oxide can be used as a conductive substance to control the resistivity of the black layer by the additive amount. Some metals can also be used as a conductive substance (for instance, silver powder) to control the resistivity of the black layer by the additive amount.
The structure and electric property of display electrode 6 and light-shield 7 are described more in detail.
Black layer 18a of bus electrode 4b and 5b is formed from the same material as light-shield 7, and black layer 18a and black layer 18b are formed connected. That is, display electrodes 6 adjacent to each other are connected via black layer 18a and black layer 18b of light-shield 7.
The product of the resistivity of black layer and layer thickness shall be not larger than 2 Ωcm2, and the resistivity of light-shield 7 composed of black layer 18b shall be not smaller than 1×106 Ωcm, in the exemplary embodiments of the present invention.
When adjacent display electrodes 6 are electrically connected each other via light-shield 7, the resistivity of smaller than 1×106 Ωcm for black layer 18b of light-shield 7 would cause for instance a part of current flowing through one of display electrodes 6 to flow into another adjacent display electrode 6 through light-shield 7. Eventually, voltage wave shapes of a display electrode will interfere with voltage wave shapes of another display electrode, causing to prevent required voltage wave shapes from sending to discharge cells
The materials for the black layers, however, have a high resistivity of larger than 1×106 Ωcm so that black layers 18b have a resistance high enough enable to overcome such problems practically, in the exemplary embodiments of the present invention.
Additionally, a higher resistivity for black layer 18a formed from the same material as light-shield 7 would cause a phenomenon for discharge cells not to supply voltage required, due to voltage drops occurring in black layer 18b at the current flow from conductive layer 19 to transparent electrodes 4a and 5a. The phenomenon will begin to occur at larger than 0.5 Ωcm2 for the product of the resistivity and layer thickness, and becomes noticeable at larger than 2 Ωcm2. The specified value of not larger than 2 Ωcm2 for the product of a resistivity and layer thickness in the present invention, however, is high enough to overcome such problems practically.
Following is the reason why the product of resistivity and layer thickness is adopted to define the electrical resistance for black layer 18a, although the electrical resistance is generally defined by the resistivity or sheet resistance.
The relation between the resistance and resistivity of the black electrode is given by the formula
R=ρ×t/S,
where R is the resistance, ρ the resistivity, t the layer thickness and S the electrode area.
As described above, though the resistivity can be calculated by the resistance, layer thickness and electrode area, the resistivity value would be smaller than the resistivity of black layer 18b of light-shield 7 formed from apparently the same material from the following reasons.
That is, black layer 18a and conductive layer 19 both formed by thick layer manufacturing processes would produce uneven layer thickness with sometimes thinner portions, causing the portions with low resistance partially. Conductive substances of conductive layers 19 diffused into black layers 18a would reduce the resistivity of black layers 18a. Moreover, when patterning bus electrodes 4b and 5b by exposing for development, over-etching black layer 18a in developing process could lose black layer 18a provided under conductive layer 19, causing transparent electrode 4a to touch conductive layer 19 directly.
Although resistance R can be given from the measurement of voltage vs. current characteristics, and electrode area S from the measurement of exterior dimensions, to measure the layer thickness and resistivity of black layer 18a accurately is very difficult due to the above reasons. In the present invention, therefore, the electrical properties shall be specified by the product of the resistivity and layer thickness. The product is calculated easily with the resistance R and electrode area S given by the measurement method described later.
Slit 20 is formed by patterning after black layer 18a and light-shield 7 of bus electrodes 4b and 5b are formed integrally.
Since display electrode 6 and light-shield 7 are insulated electrically in the second exemplary embodiment, voltage wave-shape of one display electrode 6 will never interfere with another display electrode 6. The configuration enables to select a lower resistance material for black layer 18a composing bus electrode 4b and 5b, and for black layer 18b composing light-shield 7.
However, a low resistance of black layer 18b of light-shield 7 would increase the capacitance of a space between display electrodes 6 adjacent to each other via light-shield 7 (shown in space A in
Now, the measurement method of the product of the resistivity and layer thickness of black layers 18a and 18b, or the measurement method of the resistivity is described in detail.
Firstly, the measurement method of the product of the resistivity and layer thickness of black layers 18a of bus electrodes 4b and 5b is described with reference to
The manufacturing method of a measuring sample is described first. Flat layer 32 is formed on glass substrate 31 as a transparent electrode. No patterning is necessary in this process (
Resistance value (R) of the gap between electrode patterns adjacent to each other are measured by using probes 36A and 36B of resistance-measuring-equipment 37 as shown in
Next, the measurement method for the resistivity of the black layer of light-shield is described with reference to
Firstly, a photo-sensitive black paste is coated on glass substrate 41 by the printing method or the like and then is dried to form dried black flat layer 42 (
Resistance (R2) of the gap between conductive electrodes 47 adjacent to each other are measured by using probes 45A and 45B of resistance-measuring-equipment 46 as shown in
ρ2=R2×d2×L2/G2,
to calculate the resistivity ρ2 of the black layer of light-shield.
Although the calculation results will include partial resistance components of black layer 42 under conductive layer 47 practically, it can be neglected if G2 is made up large enough than W2.
Table 1 shows the comparison of the power consumption and display characteristics varying the properties of black layer 18a and 18b at non-brightness for the PDP, provided with slit 20 between black layer 18b of light-shield 7 and display electrode 6 to insulate light-shield 7 from display electrode 6 electrically, described in the second exemplary embodiment.
In table 1, the resistivity of black layers 18a and 18b are controlled by varying the content of ruthenium-based oxide, used as a conductive material, for sample No. 2 to 5. Silver powder is added to ruthenium-based oxide for sample No.1 and no conductive material is used for No. 6. Sample No. 7 is a conventional example where the light-shield and black layer of bus electrode are manufactured by using different materials respectively.
The power consumption at non-brightness means a power consumed to display black in full-screen to compare with the conventional example No.7. The starting characteristic shows whether each PDP can start at the voltage on which conventional example No. 7 operates fully.
Sample no. 1 and no. 2 provided with light-shield having resistivity lower than 2×104 Ωcm show a larger power consumption at non-brightness than conventional example no. 7, and the power consumption at non-brightness increases with decreasing resistivity of light-shield as shown in table 1. Additionally, the power consumption at non-brightness saturates with the resistivity higher than 1×105 Ωcm for the light-shield.
The product of the resistivity of black electrode and layer thickness higher than 0.5 Ωcm2 causes a phenomenon of a little decrease in brightness in a portion of the screen due to a voltage drop to be supplied to the discharge spaces. The phenomenon becomes more noticeable in sample no. 5 and no. 6 where the product of the resistivity of black layer and layer thickness increases higher than 2 Ωcm2, so that non-brightness portions or decreases in brightness are observed in whole screen.
However, sample no. 3 and no. 4 of the present invention show nice results in both the power consumption at non-brightness and starting characteristic.
The present invention as described above can reduce man-hour of PDP manufacturing process and can provide PDP apparatus capable of displaying high quality images. The technology will be useful for large-sized screen display.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2003-417803 | Dec 2003 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2004/018850 | 12/10/2004 | WO | 00 | 8/18/2005 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2005/059945 | 6/30/2005 | WO | A |
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|---|---|---|---|
| 4424251 | Sugishita et al. | Jan 1984 | A |
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| 6664029 | Imai et al. | Dec 2003 | B1 |
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| 9-160243 | Jun 1997 | JP |
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| 2003-151450 | May 2003 | JP |
| 2003-187692 | Jul 2003 | JP |
| Number | Date | Country | |
|---|---|---|---|
| 20060145623 A1 | Jul 2006 | US |
