Plastic container for carbonated beverages

Information

  • Patent Grant
  • 6276546
  • Patent Number
    6,276,546
  • Date Filed
    Monday, August 2, 1999
    25 years ago
  • Date Issued
    Tuesday, August 21, 2001
    23 years ago
Abstract
A plastic container comprises a lower base forming portion that includes a plurality of circumferentially spaced downwardly convex segments (126) and a plurality of intervening, circumferentially spaced, totally convex, hollow foot forming portions (121) that extend radially from the central bottom portion (120) and downwardly from the downwardly convex segments to form a clearance (124) for the central bottom portion. The downwardly convex segments have smoothly curved cross sections, in radially extending planes through their central regions and coplanar with the container's longitudinal axis (120a). The clearance forming portion (123) of each foot forming portion includes a compound curved offset formed with opposing radii of curvature lying in a range of about 15% to over about 30% of foot contact diameter, the compound curved offset curving downwardly and outwardly about a center of curvature (131) below the bottom forming portion before curving about a center of curvature (130) above the bottom forming portion.
Description




FIELD OF THE INVENTION




This invention relates to plastic containers for fluids under pressure, such as carbonated soft drinks, beer and the like. More particularly, this invention relates to bottoms for plastic bottles for carbonated beverages that can provide a stable container of minimal height and resistance to distention, crazing and stress cracking.




BACKGROUND OF THE INVENTION




Plastic containers that can reliably contain carbonated beverages generating internal pressures as high as 100 psi or more and that can be inexpensively manufactured in attractive shapes pose a technical problem that has received substantial attention by those working in this art.




The spherical shape, which has the greatest ratio of volume to surface area, provides an optimum uniform distribution of wall stresses generated by internal pressures and thus achieves the maximum reliable and effective strength for a given wall material thickness, and, indeed, internal pressures within non-spherically-shaped containers tend to urge the non-spherically-shaped containers toward a spherical shape. A spherical shape is, however, unacceptable as a commercial beverage container because, among other obvious reasons, a sphere has no stable base, is difficult to handle, and cannot effectively use shelf and storage space of retail and wholesale purveyors and manufacturers.




Workers in the art have sought to develop cylindrical plastic beverage containers that can reliably and attractively contain carbonated beverage products, can be easily handled, can be inexpensively manufactured, and have stability when filled and unfilled, and an extensive variety of container designs have been developed by those working in the art to meet these needs.




Such containers have most frequently been manufactured from plastic materials such as polyethylene terephthalate (PET) by, for example, blow molding a parison of PET into a mold formed in the shape of the container. The biaxial expansion of PET by blow molding imparts rigidity and strength to the formed PET material, and blow molded PET can provide economically acceptable wall thicknesses, an attractive container with clarity in relatively intricate designs, sufficient strength to contain pressures up to 100 psi and more, and resistance to gas passage that may deplete contained beverages of their carbonation.




One factor that is, however, frequently over looked in container designs of those working in the art is the propensity of PET to succumb to the deleterious effects of stress cracking and crazing, which is manifest as almost imperceptible streaks in the plastic but ultimately can become complete cracks due to stress and other environmental factors. Relatively unstretched portions of a plastic container that have low degrees of crystallinity due to the lack of biaxial expansion, such as the central bottom portion, are particularly susceptible to crazing and stress cracking. The relatively unstretched central portion of the container bottom is also frequently provided with a plurality of depending feet that are formed with distention-resistant but stress concentrating areas, and the composite effect on such areas of stress and strain due to the internal pressure of the container and external environmental factors, such as exposure to stress cracking agents (e.g., caustics, water, oils and generally any plastic solvent or softening agent), can lead to crazing, stress cracking and container bottom failure.




One commercial cylindrical beverage container that seeks to avoid such problems is formed with a full hemispherical bottom portion and provided with a separate plastic base member fastened over the hemispherical bottom portion to provide a stable base for the container. Such containers are in common use for large multi-liter containers for carbonated beverages, even though the provision of a separate plastic base member imposes increased container height, and increased manufacturing and material costs on the cost of each container. Offsetting somewhat the increased costs imposed by the addition of a separate base piece, is the fact that use of a hemispherical bottom portion can permit a reduction in the bottom wall thickness, tending to maximize the containable pressure for a given wall thickness in the bottom portion and reducing the cost of the plastic material in the container portion.




Those working in the art have also generated commercial containers including “champagne” type bases including concave, or “domed” eversion-resisting central bottom portions merging with the cylindrical container sidewalls at an annular ring which forms a stable base for the container. The central domed portion of a champagne-based plastic container generally creates clearance for the gate area of the container which is intended to resist deformation due to the internal pressure of the container but is sensitive to stress cracking. Unfortunately, containers with champagne bases require a greater wall thickness in the base portion to resist the distending and everting forces of the internal pressure and form stress concentrations at the annular base-forming transition between the concave central bottom portion and cylindrical sidewall that are prone to stress cracking and rupture when the container is dropped. One container design addressing this problem is disclosed in U.S. Pat. No. 4,249,666.




Notwithstanding their champagne bases, it is not uncommon, however, particularly during hot summer months, for the bottoms of such commercial containers to distend and increase the internal volume enough to significantly lower the fluid level, creating an unacceptable product presentation to the consumer, and in some cases to expand beyond their intended bases, creating unstable and unacceptable “rockers”.




More recently, the use of hemispherical bottom portions and concave champagne-like bottom portions have been combined by workers in the art in designs in which a plurality of feet are formed in the bottom of a blow molded container. These designs frequently seek eversion-resistant concave central bottom portions formed by a plurality of surrounding feet that are interconnected by a plurality of generally downwardly convex hemispheric rib portions. Many of such container designs providing footed bottles are in commercial usage.




Such container designs, however, are still subject, in the absence of relatively thick bottom wall portions, to distention of their concave central portions due to high internal pressures that can create “rockers” and significantly increased interior container volume with lower fluid levels, all of which are unacceptable to purchasers. Efforts to increase the eversion and distention resistance of the concave bottom portions of such footed containers with thinner bottom wall thicknesses have frequently led to bottom portions including small radii of curvature and discontinuous and abrupt transitions between adjoining surfaces that provide stress concentration, crazing and stress cracking sites. Some container designs, for example, those of U.S. Pat. Nos. 4,865,206 and 5,353,954, have addressed the problem of stress concentration, stress cracking and impact resistance. None of these container designs is entirely satisfactory in view of cost, manufacturability and reliability.




It is also desirable that such plastic containers provide maximal volumes with minimal heights, easily handled diameters and maximal height cylindrical sidewalls to provide large surface areas for product labelling. The achievement of such desiderata dictates that the bottom portions of such plastic containers consume minimal portions of the container height, which is inconsistent with the use of downwardly convex hemispheric rib portions between the cylindrical sidewall and the central portion of the bottom.




SUMMARY OF THE INVENTION




The invention provides plastic containers for carbonated beverages with low cost and weight, manufacturable from plastic material by blow molding with minimal plastic material in their walls, with maximal volumes with minimal heights in easily handled diameters, with maximal height cylindrical sidewall portions, with excellent stability in both filled and unfilled conditions because of their wide foot spans and their resistance to distention of their bottom portions, and with durability because of their relative freedom from excessively high stress concentrations, crazing and stress cracking.




The invention provides a plastic container base with hollow feet-forming portions and intervening downwardly convex, smoothly curving bottom segments which can provide, through a container bottom section of minimal height, substantially maximal container volume for a given container height, a maximal cylindrical sidewall labelling height, and a lower center of gravity and wide foot print for greater container stability, when filled and unfilled, and with minimal stress concentrations and risk of stress cracking and substantial resistance to distention due to internal pressure.




In accordance with the invention, the container bottom portion is formed with a plurality of hollow foot-forming portions and a plurality of intervening downwardly convex radially extending strap-like segments that are smoothly curved over, primarily, their portions extending from the center of the container bottom to adjacent the cylindrical sidewall. By smoothly curved, we mean the portions of the downwardly convex strap-like segments that extend outwardly and upwardly from the container center to adjacent the container sidewall comprise, in cross-sections in planes coplanar the containers longitudinal axis and their central regions, curves formed with a constant radius of curvature, or with a continuously varying radius of curvature, or compound curves formed with a plurality of curved sections having differing radii of curvature that are free of non-tangential mergers (i.e., the curved sections are tangent at their points of merger). In smaller containers, the downwardly convex smoothly curved cross-sections can be circular, providing spherical segments. In larger containers, the downwardly convex smoothly curved segments can comprise in cross-section preferably hyperbolic portions developed to be tangent at the longitudinal axis of container to a plane parallel with the plane common to the container feet, and approach tangently to the vertical cross-section of the cylindrical sidewall at their upper portions, or elliptical portions developed to tangent to a plane parallel with the plane common to the container feet at the longitudinal axis of the container and tangent to the vertical cross-section of the cylindrical sidewall at their upper portions. In such larger containers, which include, for example, containers having a volume, for example, in excess of about 0.6 to about 1 liter, or containers having a maximum diameter, for example, in excess of about 8 centimeters (about 3 inches), bottom portions that are formed with smoothly curved downwardly convex segments with hyperbolic or elliptical cross-sections in their central portions can reduce the height of the bottom container portion by a maximal fraction of an inch, can be substantially free of excessive stress concentrations with reduced crazing and risk of stress fractures, and when combined with hollow feet-forming portions, as described below, can support the internal container pressures generated with carbonated beverages without unacceptable distention of the bottom portion and provide containers with increased volume per unit of container height, larger labelling surfaces, a lower container center of gravity, and increased container stability when both filled and unfilled.




One plastic container of the invention comprises an upper mouth-forming portion, a cylindrical sidewall portion and a lower bottom-forming portion that includes a plurality of circumferentially-spaced, downwardly convex segments extending downwardly from the cylindrical sidewall and a plurality of intervening, circumferentially-spaced, totally convex, hollow foot-forming portions that extend radially from the central bottom portion and downwardly from the downwardly convex segments to form a clearance for a concave central bottom portion.




In such containers each of the circumferentially spaced, downwardly convex segments has a smoothly curved cross-section, in a plane through its central region and coplanar with the longitudinal axis of the container. In some preferred containers with diameters less than about 3.27 inches, the smoothly curved cross-section is circular, and in some preferred containers with diameters greater than about 3.27 inches, the smoothly curved cross-section is hyperbolic or elliptical. In addition, in some preferred containers, the downwardly convex segments can be flared at their upper extents where they merge with the container sidewall, for example, expanding outwardly by over 200 percent, and frequently up over 400 percent, in sidewall mergers that are relatively free of stress concentration.




In preferred such containers, the clearance-forming portions of the foot-forming bottom portions can include compound-curved offsets formed with opposing radii of curvature of a substantial fraction of an inch, preferably a maximal substantial fraction of an inch, the compound-curved offset curving downwardly and outwardly from the central bottom portion, about a center of curvature below the bottom-forming portion before curving about a center of curvature above the bottom-forming portion. The opposing radii of curvature preferably lie in a range of about 15 percent to about 30 percent of the contact diameter of the foot-forming bottom portion.




A preferred plastic container of the invention, comprises, in addition to an upper mouth-forming portion and a cylindrical sidewall portion all about a central longitudinal axis, a lower base-forming portion including a plurality of hollow foot-forming portions extending outwardly from the central portion of the lower base-forming portion to form a plurality of feet, each foot-forming portion including between said central portion of the base-forming portion and its foot, a bottom clearance-forming portion including a compound-curved offset formed by opposing radii of curvature of a substantial fraction of an inch, said compound-curved offset curving downwardly from said central portion about a radius of curvature below the bottom of the base-forming portion before curving about a radius of curvature above the bottom of the base-forming portion, and further comprises a plurality of smoothly curved, downwardly convex segments between adjacent pairs of hollow foot-forming portions, each of said downwardly convex segments extending upwardly between said adjacent hollow foot-forming portions and, preferably, expanding outwardly at its upper end to merge into said cylindrical sidewall portion. In smaller containers, such as 20 ounce containers having a sidewall with a diameter less than about 3.27 inches, e.g., about 2.90 inches, the downwardly convex segments can have circular cross-sections in their central portions, and in larger containers, such as two liter containers having a sidewall with a diameter greater than about 3.27 inches, e.g., about 4.28 inches, the downwardly convex segments can have hyperbolic cross-sections in their central portions. Furthermore, in preferred such containers the opposing radii of curvature of said bottom clearance forming portions are a maximal substantial fraction of an inch.




In describing the invention, “totally convex” means that, as viewed from the exterior of the container, a surface is defined in its curved portion, or portions, by radii that extend from the interior surface of the container away from the eye of the observer, and such radii are referred to herein as “internal radii”. “External radii”, are, therefore, radii extending from the exterior surface of the container toward the eye of such an observer. “Opposing radii” means radii extending from opposite sides of a surface and defining tangent circles (i.e., a combination of an external and an internal radius that merge tangentially to form a compound-curved surface). In addition, references to cross-sections of container portions means that cross-section that lies in a plane that includes (i.e., is coplanar) with the longitudinal axis of the container, unless otherwise defined.




Further embodiments, features and advantages of the invention will become apparent from the drawings and the following more detailed description of a preferred embodiment of the invention.











DETAILED DESCRIPTION OF THE DRAWINGS





FIG. 1

is a side view of a container of the invention;





FIG. 2

is a bottom view of the container of

FIG. 1

;





FIG. 3

is a perspective view of the container of

FIGS. 1 and 2

from below the container to illustrate a container base of this invention;





FIG. 4

is a partial perspective view from below of one foot-forming portion of the base of this invention as illustrated in

FIGS. 1-3

;





FIG. 5

is a cross-sectional view of the bottom of the container of

FIGS. 1-4

taken at a plane coplanar with the longitudinal axis of the container and through the center of a foot-forming portion, as indicated by line


5





5


of

FIG. 2

;





FIG. 6

is a partial cross-sectional view of a spherical segment of the container bottom of

FIGS. 1-5

taken at the partial plane


6





6


of

FIG. 5

;





FIG. 7A

is a cross-sectional view of a foot-forming portion of the containers of

FIGS. 1-6

with a series of orthogonal cross-sectional planes


7


B to further illustrate the foot-forming portion;





FIG. 7B

comprises a series of cross-sections taken orthogonal to

FIG. 7A

at the series of planes


7


B;





FIG. 8

is a side view of a preferred smaller container of the invention;





FIG. 9A

is a bottom view of the container of

FIG. 8

;





FIG. 9B

is an enlarged view of

FIG. 9A

to illustrate a preferred flaring of the downwardly convex, strap-like segments of the bottom;





FIG. 9C

is a partial cross-sectional view of the downwardly convex strap-like segments of the container bottom in

FIGS. 8-11

taken at the partial plane


9


c—


9




c


of

FIG. 11

;





FIG. 10

is a perspective view of the container of

FIGS. 8 and 9

from below the container to further illustrate a container base of this invention;





FIG. 11

is a cross-sectional view of the bottom of the container of

FIGS. 8-10

taken at a plane coplanar with the longitudinal axis of the container and through the central portion of a foot-forming portion, as indicated by line


11





11


of

FIG. 9B

;





FIG. 12

is a side view of a preferred larger container of the invention;





FIG. 13

is a cross-sectional view of the container of

FIG. 12

taken at a plane coplanar with the container's longitudinal axis and the central portions of one of its downwardly convex bottom segments and one of its hollow foot-forming portions;





FIG. 14

is a perspective view of the container of

FIGS. 12 and 13

from below the container to further illustrate a container base of this invention; and





FIG. 15A

illustrates the cross-sections of smoothly curved downwardly convex segments of the container of

FIGS. 12-14

,





FIG. 15B

illustrates the cross-sections of smoothly curved downwardly convex elliptical segments.





FIG. 15C

illustrates the cross-sections of smoothly curved downwardly convex compound segments.











DETAILED DESCRIPTION OF THE INVENTION





FIGS. 1-7B

illustrate a container


10


of this invention in the form of a plastic carbonated beverage bottle which can have a capacity of two liters.




As shown in

FIGS. 1 and 3

, such a container


10


includes an upper neck and mouth-forming portion


11


, a cylindrical sidewall portion


12


extending around the longitudinal axis


10




a


of the container, and a lower base-forming portion


13


. The upper portion


11


provides a neck-forming transition


14


leading to the container mouth


15


. The transition portion


14


of a container of the invention may take any conveniently usable and moldable shape such as a frustoconical, hemispherical, ogive or other shape as may be selected by a container designer. The finish


16


of the container adjacent the mouth


15


is shown as threaded to accept a threaded cap commonly used to close carbonated beverage bottles; however, the mouth-forming portions of containers of the invention may be provided with means to accommodate other closures than threaded closures, as apparent to those working in the art.




As shown in

FIGS. 1-5

and


7


A, the bottom portion


13


of the container


10


includes a central portion


20


and a plurality of foot-forming portions


21


formed about the central portion for supporting the container


10


. The foot-forming portions


21


extend downwardly and are spaced between a plurality of convex, circumferentially-spaced, spherically-shaped segments


26


that extend downwardly from the cylindrical sidewall


12


. As indicated further below, such spherically-shaped segments are not preferred for larger containers such as two liter containers because they contribute an undesirable height to the bottom portion of such larger containers. The lower base-forming portion


13


of the container and its bottom, as provided with a plurality of hollow foot-forming portions


21


, provides a stable container base and bottom clearance and rigidity to maintain the container stability when unfilled or filled without occurrence of stress concentrations, crazing and stress cracking.




Foot-forming portions


21


of containers of the invention are shown in greater detail in the cross-sectional drawing of

FIG. 5

, the perspective drawing of

FIG. 4

, and the cross-sectional drawings

FIGS. 7A and 7B

. Each foot-forming portion


21


includes a clearance-forming portion


23


extending from the longitudinal axis


10




a


of the container to adjacent each of the supporting feet


22


. As described in greater detail below and as shown in

FIGS. 3-5

, the clearance-forming portion


23


of each foot-forming portion


21


provides a substantial clearance height


24


between the central portion


20


of the container bottom and the plane


25


of the supporting feet


22


and includes a distention resistant, compound-curved offset


23




b


formed with opposing radii of curvature and curving downwardly and outwardly first about a center of curvature


31


below, and then about a center of curvature


30


above, the compound-curved intermediate portion


23




b


to contribute a substantial portion (e.g., 30 to 50 percent) of the clearance height.




As more clearly shown in FIG.


4


and the cross-section of

FIG. 5

, a preferable clearance forming portion


23


of foot-forming portion


21


, in extending radially and downwardly from the central longitudinal axis


10




a


, comprises three contiguous regions along its lowermost surface. The three lowermost regions are a slightly downwardly curved, central, spherical portion


23




a


centered on the longitudinal axis


10




a


, the compound-curved offset


23




b


, and an outermost, and a lowermost slightly descending portion


23




c


extending outwardly from the compound-curved offset portion


23




b


to a supporting foot


22


and merging into an outer curved portion


23




d


extending from the supporting foot


22


upwardly and outwardly toward the container sidewall


12


.




As shown best in

FIGS. 5 and 7A

, clearance


24


is provided by the descending surface portions


23




a


and


23




c


and the offset ramp-like intermediate portion


23




b


. In this preferred container of the invention, the angle of descent


28


(

FIG. 5

) of clearance-forming portions


23




c


is preferably about 10 degrees to 15 degrees, although other angles of descent may be used in the invention depending upon the diameter of the container, the internal pressure to be contained and the bottom clearance required. As shown in

FIG. 5

, compound-curved offset portion


23




b


is preferably formed with opposing radii of curvature


30


and


31


of a substantial fraction of an inch. A “substantial fraction of an inch”, as used in this application, means from about 0.1 inch to about 0.6 inch. In containers of the invention, the offset portion


23




b


between central portion


23




a


and portion


23




c


can contribute a substantial fraction of an inch to, and a substantial portion of, the clearance distance


24


and can also contribute distention-resistance in the foot-forming portion


21


of the container. The outwardly and upwardly extending bottom surface portion


23




d


extending from the supporting feet


22


are also preferably formed with radii of curvature


38


of a substantial fraction of an inch.




As shown in

FIGS. 2-4

,


7


A and


7


B, each of the plurality of foot-forming portions


21


preferably extends radially, circumferentially and downwardly between the intervening, generally spherical segments


26


of a spherical bottom configuration


27


. The surface portions indicated as


23




a


,


23




b


,


23




c


and


23




d


in the perspective view of

FIG. 4

correspond to the four regions


23




a


,


23




b


,


23




c


and


23




d


of the cross-sections of

FIGS. 5 and 7A

. As shown in

FIGS. 2-4

, surface portions


23




c


are, preferably, substantially planar. “Substantially planar” portions of containers of this invention comprise those relatively flat wall portions having minimum radii of curvature of several times the radius of the cylindrical container sidewall in orthogonal directions.




Thus, as illustrated by the perspective view of

FIG. 4

, the foot-forming portions


21


of the invention (only one of which is illustrated in

FIG. 4

) preferably expand circumferentially as they extend radially outwardly and include saddle-shaped transitions extending downwardly a substantial fraction of an inch from the concave central spherical portion


23




a


to the substantially planar third portions


23




c


of their clearance-forming portions. The saddle-shaped transitions are preferably formed with an external radii


31


(

FIG. 5

) of a substantial fraction of an inch, and internal radii, in planes orthogonal to the longitudinal container axis, of at least a substantial fraction of an inch that extend from the interior of the foot-forming portions


21


toward their centers (see, for example, r


71


and r


72


of FIG.


7


B). The saddle-shaped transitions curve smoothly into the substantially planar third portions


23




c


, with internal radii of curvature


30


, and the saddle-shaped transitions, in combination with the curved transitions provide a substantial, distention resistant, offset of the central bottom portion


23




a


, and a substantial clearance height


24


between the feet


22


and the central bottom portion


23




a.






As shown in

FIGS. 1-4

and most clearly in

FIG. 4

, and as indicated in

FIGS. 7A and 7B

, the foot-forming portions


21


of the invention are substantially totally convex. As illustrated in

FIGS. 7A and 7B

, at cross-sections taken at planes


71


-


82


through the foot-forming portions


21


and across the longitudinal axis


10




a


and parallel to the plane


25


of the feet


22


, the walls of the foot-forming portion are formed by surfaces curving outwardly from the container interior about internal radii (e.g., r


71


and r


72


) extending within the foot-forming portions


21


at each cross-section


71


through


82


, and the walls thus form substantially totally convex foot-forming portions (as can be seen from the perspective view of FIG.


4


).




As indicated in

FIGS. 1-4

and


6


, the foot-forming portions


21


include substantially planar side panels


34


that blend into and join the spherical segments


26


of the container bottom. As indicated in

FIGS. 1-4

and


7


B, the outer surface portions


35


of foot-forming portions


21


are joined to the side panels


34


by curved transitions


34




a


that also preferably have a radius of curvature of substantial fraction of an inch. In addition, the outer surface portions


35


of the foot-forming portions


21


preferably have radii of curvature


36


in cross sections lying in planes coplanar with the longitudinal axis of the container substantially greater than the radius of the cylindrical sidewall


12


, although surfaces


35


may be frustoconical surfaces merging into the cylindrical sidewall with an appropriate radius of curvature.




Such containers of this invention can provide both good resistance against base movement and resistance to crazing and stress cracking. In such containers of the invention, the central bottom portion


20


, that is, the uppermost bottom surface


23




a


, does not move axially downward to such a degree that it becomes a contact surface for the container, and the foot contact diameter


40


remains largely unchanged even when the central region of the container bottom is distended under pressurization. Because of the plurality of totally convex offset transition portions


23




b


, containers of the invention can provide a greater clearance distance


24


between the central portion


20


of the bottom and the plane


25


of the supporting feet


22


, reducing further the tendency for the creation of “rocker” bottles. In containers of the invention, foot-forming portions


21


are totally convex walls, formed by an internal radii of substantial fraction of an inch, creating the offset transition portions


23




b


to significantly reduce stress concentration in this relatively unexpanded central area of the container bottom and provide the bottle with improved stress crack performance without a loss of stability.





FIGS. 8-11

illustrate a presently preferred container of this invention in the form of plastic carbonated beverage bottle with a capacity of 20 ounces and a maximum container diameter of less than about 3.27 inches. The bottom portion of the container is drawn with a “wire frame” format to assist in the visualization of the invention.




As shown in

FIGS. 8 and 10

, such a container


100


includes an upper neck and mouth forming portion


101


, a cylindrical sidewall portion


102


and a lower base part forming portion


103


, all extending around a longitudinal axis


100




a


of the container. Tile upper portion


101


provides a neck-forming transition


104


leading to container mouth


105


. The transition portion


104


of the container of the invention may take any conveniently usable and moldable shape, such as frustoconical, hemispherical, ogive or other shape as may be selected by the container designer. The finish


106


of the container adjacent the container mouth


105


may take any usable form that may accommodate means for closing the container, as is apparent to those working in the art. The lower base-forming portion


103


of the container, provides a stable container base and container stability and improved freedom from stress concentrations, crazing and stress cracking when filled with a carbonated beverage.




As shown in

FIGS. 8-11

, the bottom portion


103


of the container


100


includes a central portion


120


and a plurality of hollow foot-forming portions


121


formed about the central portion for supporting the container


100


. The foot-forming portions


121


extend downwardly from, and are spaced between, a plurality of downwardly convex, spherically shaped segments


126


that extend upwardly between the adjacent hollow foot-forming portions and expand outwardly at their upper ends


126




a


to merge into the cylindrical sidewall portion


102


. Each foot-forming portion


121


includes a clearance forming portion


123


extending from the central portion


120


of the container bottom to a supporting foot


122


. The plurality of supporting feet


122


so formed lie on a contact diameter


122




a


(

FIG. 11

) that provides stable support for the container.




As shown in

FIG. 11

, and described in greater detail below, the clearance forming portion


123


of each foot-forming portion


121


provides a substantial clearance height


124


between the central portion


120


of the container bottom and the plane


25


of the supporting feet


122


and includes, preferably, a distension resistant, compound-curved offset


123


formed with opposing radii of curvature and curving downwardly and outwardly first about a center of curvature


131


below, and then about a center of curvature


130


above, the bottom surface the compound-curved offset portion


123


contributing the clearance height


124


. The opposing radii of curvature are preferably within a range of about 15 percent to about 30 percent of the contact diameter in preferred embodiments of the invention, and may also lie within range of about 10 percent to about 20 percent of the outside diameter of the container in some embodiments.




As shown in FIG.


10


and more clearly in

FIG. 11

, the central portion


120


of the bottom portion


103


of the two liter container


100


can comprise a downwardly convex spherical surface


120


subtending a solid angle


129


, preferably of about 50 degrees, as measured from a center


129




a.






In the embodiment illustrated in

FIGS. 8-11

where the downwardly convex segments are generally spherical segments with circular cross-sections, the circular cross-sections can share a common radius with the central spherical bottom portion


120


and extend therefrom upwardly between the hollow foot-forming portions


121


and flare or expand outwardly at their upper ends


126




a


in merging with the container sidewall portion


102


. The downwardly convex segments


126


flare outwardly in merging with the container sidewall


102


and generally carry their share of the load in tension, and contribute a minimal stress concentration in merging with the container sidewall portion


102


. In the embodiment of

FIGS. 8-11

, the downwardly convex portions


126


carry a greater portion of the forces imposed on the container bottom than, for example, the segments


26


of the container of

FIGS. 1-7

, in a manner that minimizes stress, contributes to maintenance of the clearance distance


124


, and reduces stress/strain gradients.




As indicated in

FIGS. 8-10

and shown in greater detail in

FIG. 9B

, the generally spherical, downwardly convex segments


126


flare outwardly as they extend upwardly for merger with the container sidewall portion


102


, increasing in their angular extent by over 200 percent and preferably, by over 300 percent and up to about 400 to 500 percent. For example, as shown in

FIG. 9B

, the central portions


126




b


of the generally spherical, downwardly convex segments


126


can subtend an angle of about 7 to 8 degrees, and at their upper ends


126




a


where they merge into the container sidewall, the segments


126


can subtend an angle of about 20 to 30 degrees and preferably 30 degrees or over. The upper portions


126




a


of the downwardly convex, generally spherical segments


126


reduce the circumferential extent of the merger of the expansive outer portions


135


that result from the radial and circumferential expansion at the hollow foot-forming portions


121


.





FIG. 9C

is a partial cross-sectional view of the container bottom taken at a partial plane corresponding to the line


9




c





9




c


of

FIG. 11

to illustrate the cross-section of the central portions


126




b


of the downwardly convex, generally spherical segments


126


in planes that are generally tangential to a circle having its center on the longitudinal axis


120




a


at the container. The central portions


126




b


merge into portion


126




d


with external radii of a substantial fraction of an inch. The angle


126




c


formed by the container bottom transition from the strap-like portions


126


to the expansive outer portions


135


may be, for example, about 50 degrees.




The downwardly convex segments


126


act like a plurality of straps extending from the cylindrical sidewall to the central bottom portion


120


transferring a portion of the force imposed on the bottom portion


103


as a result of the contents and internal pressure of the container to the container sidewall portion


102


in tension. The strap-like segments


126


eliminate the rigidifying rib-like portions frequently employed between the foot-forming portions of prior art containers, and reduce the high stress concentration regions associated with the use of such bottom portions formed with small radii curvature in an effort to rigidify the bottom, for example, in the container of

FIGS. 1-7

, by eliminating the sharply curved transition where the portions


26


of the container intersect and meet the cylindrical sidewall


12


of the container


10


. As shown in

FIGS. 1 and 3

, the portions


26


of the container of

FIGS. 1-7

do not flare or expand as they extend upwardly for merger with the sidewall portion


12


of the container


10


. As shown in

FIG. 6

, the portions


26


are configured to rigidify the bottom portion


13


by bearing the loads imposed by the contents of the container and its internal pressure in compression.




Thus, in the preferred smaller container embodiment of

FIGS. 8-11

, the segments


126


are widened, using a spherical shape as a design basis and expanded at their upper ends


126




a


for merger with the sidewall. Localized stresses at the merger of the segments


126


with the sidewall portion


102


are substantially reduced. As shown in

FIGS. 1 and 3

, the portions


26


of the container of

FIGS. 1-7

meet the cylindrical portion


12


of the container at a relative high angle of incidence and are blended at their interfaces with small radius fillets. In the preferred embodiment of

FIGS. 8-11

, the stresses and strains at the upper most portions of the segments


126


are significantly reduced and the load is more uniformly distributed through the plurality of segments


126


. The strap-like segments


126


deviate from the ribs


26


of the container of

FIGS. 1-7

, which function as stiff members (such as C channels) where deformation is controlled through resistance to bending, and instead function as a straps in a state of tension where strain is controlled by uniform expansion under pressure.




The foot-forming portions


121


of the container of

FIGS. 8-11

, like the foot-forming portions


21


of the container of

FIGS. 1-7

, extend radially outwardly and downwardly from the central portion


120


to the supporting feet


122


, and form between the supporting feet


122


and the central portion


120


, the compound-curved, clearance-forming portion


123


. The foot-forming portions


121


likewise expand circumferentially to expansive outer portions


135


. As shown in

FIG. 11

, the compound-curved, clearance-forming portion


123


is preferably formed with opposing equal radii of curvature


130


and


131


which preferably lie in a range of about 15 percent to over about 30 percent of the contact diameter for the container feet, for example, in one container having a contact diameter with a contact diameter of 1.982 inch, opposing radii of curvature can have a maximal substantial fraction of an inch, e.g., about 0.6 inch to about 0.72 inch.




In the containers of

FIGS. 8-11

, the offset portions


123


between the central portion


120


and the feet


122


can contribute a clearance distance


124


of a substantial fraction of an inch, and in combination with the flaring strap-like segments


126


can contribute distension resistance in the foot-forming portions


121


of the container. As contrasted with the container of

FIGS. 1-7

, the central portion


120


of the bottom portion


103


comprises a downwardly convex spherical surface


120


supported by the plurality of downwardly convex, generally spherical segments


126


and the plurality of clearance forming portions


123


a substantial fraction of an inch above the supporting feet


122


. The preferred embodiment of

FIGS. 8-11

does not include the slightly downwardly curved, central spherical portion


123




a


of the container of

FIGS. 1-7

and the plurality of foot-forming portions


121


do not include planar portions corresponding to portions


123




c


of the

FIGS. 1-7

, but instead, obtains the clearance distance


124


from forming compound-curved offset portions


123


with opposing radii of curvature


130


and


131


lying in a range of about 15 percent to over about 30 percent of the foot contact diameter.




These changes between the bottom portion


103


of the preferred embodiment of

FIGS. 8-11

and the bottom portion


13


of the container of

FIGS. 1-7

improve resistance to stress cracking in the amorphous gate area of the container which is generally in the central portions (


20


,


120


) of the bottom portion of the container adjacent its longitudinal axis (


10




a


,


100




a


). By providing the bottom portion


103


with a downwardly convex, spherical central portion


120


and employing such opposing radii to provide the clearance forming portions


123


, stresses in the amorphous gate area are reduced and the higher stress regions in the bottom central portion


120


are moved outwardly from the longitudinal axis


100




a


to a more oriented and less amorphous region of the bottom


103


.




EXAMPLE I




In a carbonated beverage bottle for containing 20 ounces, a plastic container of the invention can have an overall height of about 8.5 inches, for filling within about 1.63 inches of the mouth. Any finish


106


can be used with containers of the invention; one preferable finish for a carbonated beverage bottle can comprise a threaded opening, with a PCO-28 finish. The right circular cylindrical sidewall


102


can have a maximum diameter


102




a


of on the order of 2.89 inches and a reduced label panel diameter of 2.67 inches, and the neck-forming transition


104


between the cylindrical sidewall and the bottle mouth


105


can be, as shown, an ogive shape extending downwardly from about an inch below the mouth


105


of the bottle to blend into the cylindrical sidewall


102


approximately 3.03 inches below the mouth


105


. Where the radius of curvature


139


of the hemispherical bottom portion


120


and the segments


126


equals about 1.75 inches and the clearance height


124


equals about 0.145 inches, the lower base-forming portion


103


of such a bottle can extend from the plane


25


of the supporting feet


122


upwardly a distance


103




a


about 1.01 inches.




The radius of curvature


139


of the convex spherical central portion


20


and the generally spherical, downwardly convex segments


126


can be about 1.75 inches and extend from a center located on the longitudinal axis


100




a


of the container at a distance


139




a


of about 1.895 inches above the plane


25


of the supporting feet


122


. The convex spherical central portion


120


can subtend a solid angle


129


at about 50 degrees, taken from a center


129




b


located a distance


129




a


of 0.55 inch above the plane of the feet


122


and the longitudinal axis


100




a


. The opposing radii of curvature


130


and


131


can be equal and about 0.600 inch. The radius of curvature


131


can extend from a center located below the bottom wall and outwardly a distance


137


of about 0.368 inch from central longitudinal axis


100




a


of the container and located a distance


143


about 0.425 inch below the plane


25


of its feet


122


, and the radius of curvature


30


can extend from a center located above the bottom wall and outwardly a distance


144


of about 0.991 inches from the center longitudinal axis


100




a


of the container and located a distance about 0.600 inches above the plane


25


of feet


122


. The centers of the radii of curvature


130


and


131


can thus be located so that the offsetting transition surfaces


123


formed thereby merge smoothly (i.e., tangentially) with the spherical surface portion


120


formed by the radius of curvature


129


and with the outer surface portions of the feet


122


that are formed by interior radii


128


. Together, the surfaces formed by radii of curvature


130


and


131


provide clearance distance


124


. The supporting feet


122


lie on a contact diameter of about 1.982 inches about the longitudinal axis


100




a


of the container and provide a stable support for the bottle. The radius of curvature


138


of the outermost foot-forming surface


135


leading to cylindrical sidewall


102


, is about 2.00 inch.




In the preferred embodiment of

FIGS. 8-11

, localized stress in the area where the segments


126


merge with the cylindrical sidewall


102


is reduced by about 12 percent, and with the use of opposing radii about 30 percent of the contact diameter of the container in forming the clearance forming portion of


123


of the bottom, stresses in the gate area are reduced from 19 to 43 percent, and strains from 33 to 60 percent, and the areas of maximum stress concentration were relocated away from the central axis


100




a


of the container.





FIGS. 12-14

illustrate another presently preferred larger


200


container of this invention in the form of plastic carbonated beverage bottle with a capacity of two liters and a diameter greater than about 3.27 inches, for example, about 4.28 inches.

FIGS. 12 and 14

are also drawn in “wire frame” format to assist in visualization of the invention and

FIG. 13

illustrates a cross-section of the container of

FIG. 12

taken at a plane coplanar with its central axis longitudinal


200




a


and through the central portions of one of its downwardly convex bottom segments


226


and one of its hollow foot-forming portion


221


.




As shown in

FIGS. 12-14

, the container


200


includes an upper neck and mouth forming portion


201


, a cylindrical sidewall portion


202


and a lower base-forming portion


203


, all extending around the longitudinal axis


200




a


of the container (FIG.


13


). The upper portion


201


includes a neck-forming transition


204


leading to a container mouth


205


. The transition portion


204


of the container may take any conveniently usable and moldable shape, such as frustoconical, hemispherical, ogive or other shape as may be selected by the container designer. The finish


206


of the container adjacent the container mouth


205


may take any usable form that may accommodate means for closing the container as will be apparent to those skilled in the art.




As with the containers illustrated and described above, the invention resides in the lower base-forming portion


203


of the container. The hollow foot-forming portions


221


of the container


200


are preferably substantially like the hollow foot-forming portions described above for the container of

FIGS. 8-11

. As shown in

FIGS. 13 and 15A

, the downwardly convex sections


226


of the container of

FIGS. 12-14

have cross-sections in their central portions which are preferably hyperbolic and which flare outwardly over 200 percent in merging substantially tangentially into the cylindrical sidewall portion


202


at their upper ends and which form the central portion


220


of the base-forming portion


203


between the plurality of hollow foot-forming portions


221


. Because downwardly convex sections


226


have a hyperbolic cross-section, the bottom portion


203


of the container can comprise a minimal portion of the container height, can provide a maximal container volume for a given container height, can provide a maximal cylindrical sidewall height for labelling, can provide a lower container center of gravity and improved container stability and reduced stress concentrations, crazing and stress cracking.




EXAMPLE II




Such a carbonated beverage bottle


200


of the invention for containing two liters can have an overall height of about 11.8 inches, for filling within about 1.2 inches of the mouth


205


. Any finish


206


can be used with containers of the invention; one preferable finish for a carbonated beverage can comprise a threaded opening with a PCO-28 finish. The right cylindrical sidewall


202


can have a diameter on the order of about 4.28 inches, and a neck-forming transition


204


between the cylindrical sidewall


202


and the bottle container mouth


205


can be, as shown, an ogive-like shape extending downwardly from an inch or so below the mouth


205


to blend into the cylindrical sidewall


202


approximately 4 inches below the mouth


202


. As illustrated in

FIGS. 13 and 15A

, the lower base-forming portion


203


of such a bottle can extend from the plane


25


of the supporting feet


222


upwardly a distance


203




a


of about 2 inches to the place where the hollow feet forming portions


221


and downwardly convex hyperbolic segments


226


merge into the cylindrical sidewall


202


. The downwardly convex hyperbolic segments


226


can also flare outwardly (i.e., expand circumferentially) about 200 percent between the central bottom portion


220


and their merger with the cylindrical sidewall portion


202


. The outer surfaces


235


of the hollow foot-forming portions


221


have radii of curvature of about 5.75 inches which are located so the outer surfaces


235


merge tangentially into the cylindrical sidewall portions and merge tangentially into the radii


228


(FIG.


15


). The hyperbolic cross-section formed by the downwardly convex section


226


is generally asymptotic with the cross-section of the circular sidewall section


202


at its top and is tangent at its bottom with a plane parallel with, and located a distance


224


of and about 0.30 inches above, the plane


25


of the container feet


222


and can have a coefficient of curvature of about 0.75.




The hollow foot-forming portions


221


can include clearance-forming portions


223


extending from the central portion


220


of the container bottom to their feet area


222


. The clearance-forming portions are, preferably, formed by opposing radii


230


,


231


of about 0.900 inches, and the container feet


222


thus formed provide a contact diameter of


222




a


of about 2.95 inches. The sections of the foot-forming portions


221


between the feet


222


and their outer surfaces


235


are preferably formed with an internal radii of curvature


228


of about 0.42 inch, with their centers located on a circle with a diameter equal to the foot contact diameter


222




a


and positioned to provide tangency with the plane


25


of the feet


222


. The solid angle


229


is preferably 40 degrees




As illustrated above, the preferred container bottoms of the invention include downwardly convex segments between their hollow foot-forming portions that are smoothly curved, such as the segments with circular cross-sections of the containers of

FIGS. 1-11

and the segments with hyperbolic cross-sections of the container of

FIGS. 12-14

. The downwardly curved segments may have other smoothly curved cross-sections, such as illustrated by the elliptical cross-section


326


shown in FIG.


15


B and the compound curved cross-section


426


shown in FIG.


15


C. Such smooth curves can be developed from high order polynomial equations and developed with CAD/CAM systems such as “EUCLID” by Matra Data Vision, 2 Highland Drive, Tewksbury, Mass. 01876.




The invention can thus provide plastic containers for carbonated beverages with low cost and weight manufacturable from plastic material by blow molding with minimal plastic material in their walls, with maximal volumes with minimal heights in easily handled diameters, with maximal height cylindrical sidewall portions, with excellent stability in both filled and unfilled conditions because of their wide foot spans and their resistance to distention of their bottom portions and with durability because of their relative freedom from excessively high stress concentrations, crazing and stress cracking.




While a presently known preferred embodiment of the invention has been described above, those skilled in the art will recognize that other embodiments of the invention may be devised within the scope of the following claims.



Claims
  • 1. A blow molded plastic container for carbonated beverages, comprising an upper mouth-forming portion, a cylindrical sidewall portion and a lower base-forming portion, all about a central longitudinal axis,said lower base-forming portion comprising a plurality of hollow foot-forming portions extending outwardly from the central portion of the lower base-forming portion to form a plurality of feet lying substantially on a contact diameter, each foot-forming portion including between said central portion of the base-forming portion and its foot, a bottom clearance-forming portion including a compound-curved offset of a substantial fraction of an inch formed by opposing radii of curvature, said compound-curved offset curving downwardly from said central portion about a radius of curvature below the bottom of the base-forming portion before curving about a radius of curvature above the bottom of the base-forming portion, and further comprising a plurality of downwardly convex segments between adjacent pairs of hollow foot-forming portions, each of said downwardly convex segments extending upwardly between said adjacent hollow foot-forming portions, the downwardly convex segments having cross-sections, in a radially extending plane in its central portion coplanar with the longitudinal axis of the container, with a coefficient of curvature of from about 0.68 to about 0.75, and flaring outwardly to merge into said cylindrical sidewall portion at its upper end.
  • 2. The plastic container of claim 1 wherein said central portion is downwardly convex.
  • 3. The plastic container of claim 2 wherein each foot-forming portion increases circumferentially in size as it extends radially.
  • 4. The plastic container of claim 1 wherein all internal radii of the hollow foot-forming portions are a substantial fraction of an inch.
  • 5. The plastic container of claim 1 wherein the opposing radii are equal.
  • 6. The plastic container of claim 1 wherein each of the hollow foot-forming portions merges into the adjoining downwardly convex segments with straps having curvatures of a substantial fraction of an inch.
  • 7. The plastic container of claim 1 wherein the opposing radii of curvature of said bottom clearance forming portions lie in a range of about 15 percent to over about 30 percent of the contact diameter.
  • 8. The plastic container of claim 1 wherein the opposing radii of curvature of said bottom clearance forming portion, lie in a range of less than about 10 percent to over about 20 percent of the outside diameter of the container.
  • 9. The container of claim 1 wherein the diameter of the cylindrical sidewall is more than about 3.27 inches.
  • 10. A plastic container comprising a cylindrical sidewall, an upper mouth-forming portion and a lower bottom-forming portion, all about a central longitudinal axis,said bottom-forming portion comprising a plurality of downwardly convex, hollow foot-forming portions extending radially and downwardly from a plurality of intervening downwardly convex segments and forming a plurality of feet supporting the container on a contact diameter, each of said foot-forming portions comprising a bottom clearance-forming portion between its supporting foot and the central longitudinal axis, each bottom clearance-forming portion including a compound-curved offset of a substantial fraction of an inch formed by opposing radii of curvature lying in a range of about 15 percent to over about 30 percent of the contact diameter, each said compound-curved offset curving downwardly about a center of curvature below the bottom-forming portion before curving about a center of curvature above the bottom-forming portion, each of said downwardly convex segments expanding outwardly and upwardly between adjacent foot-forming portions in merging with said cylindrical sidewall, the downwardly convex segments having cross-sections, in a radially extending plane in its central portion coplanar with the longitudinal axis of the container, with a coefficient of curvature of from about 0.68 to about 0.75.
  • 11. The container of claim 10 wherein the diameter of the cylindrical sidewall is more than about 3.27 inches and the smoothly curved cross-section is generally elliptical.
  • 12. A blow molded plastic container for carbonated beverages, comprising an upper mouth-forming portion, a cylindrical sidewall and a lower base-forming portion, all about a central longitudinal axis, including a plurality of circumferentially-spaced, downwardly convex segments and a plurality of intervening and circumferentially-spaced, convex, hollow foot-forming portions expanding radially outwardly from the longitudinal axis of the container to expansive outer surfaces merging with the sidewall and downwardly from the circumferentially-spaced, downwardly convex segments, each said foot-forming portion providing a bottom clearance-forming portion, and each downwardly convex segment having a cross-section, in a radially extending plane in its central portion coplanar with the longitudinal axis of the container, with a coefficient of curvature of from about 0.68 to about 0.75 and expanding outwardly and upwardly by more than 200 percent in merging with the sidewall.
  • 13. The container of claim 12 wherein the diameter of the cylindrical sidewall is more than about 3.27 inches.
  • 14. The plastic container of claim 12 where each bottom clearance-forming portion includes a compound-curved offset formed between the longitudinal axis and the container sidewall by opposing radii of curvature in a range of about 15 percent to over about 30 percent of a diameter about the longitudinal axis at which the foot-forming portions contact a supporting surface, said compound-curved offset first curving downwardly about a center of curvature below the bottom-forming portion before curving about a center of curvature above the bottom-forming portion.
  • 15. The plastic container of claim 12 wherein each downwardly convex segment expands outwardly and upwardly by at least about 400 percent in merging with the sidewall.
  • 16. The plastic container of claim 12 wherein the lower base-forming portion comprises a central downwardly convex central portion between the plurality of foot-forming portions.
  • 17. A plastic container comprising a generally cylindrical sidewall portion, an upper mouth-forming and bottom portion, all about central longitudinal axis,said bottom portion including a plurality of spaced totally convex, hollow foot-forming portions extending radially and downwardly from a central bottom portion to form supporting feet adjacent the periphery of the container and a plurality of compound-curved bottom clearance forming portions, said bottom portion further including a plurality of spaced, downwardly convex segments between said plurality of hollow foot-forming portions, said downwardly convex segments having cross-sections in a radially extending plane in its central portion coplanar with the longitudinal axis of the container, with a coefficient of curvature of from about 0.68 to about 0.75 and flaring outwardly and upwardly in merging with the generally cylindrical sidewall portion.
  • 18. The plastic container of claim 17 wherein said foot-forming portions have, in their central planes coplanar with the longitudinal axis, compound-curved cross-sections defined by two opposing radii.
  • 19. The plastic container of claim 18 wherein the two opposing radii lie in a range of about 15 percent to over about 30 percent of the diameter about the longitudinal axis at which the foot-forming portions contact a supporting surface.
  • 20. The plastic container of claim 18 wherein the two opposing radii lie in a range of about 10 percent to about 20 percent of the diameter of the cylindrical side wall portion of the container.
  • 21. The plastic container of claim 19 wherein the two opposing radii lie in a range of about 30 percent to about 36 percent of the contact diameter.
  • 22. The plastic container of claim 17 wherein the downwardly convex segments flare outwardly and upwardly to more than twice their extents in merging with the generally cylindrical sidewall portion.
  • 23. The plastic container of claim 18 wherein the downwardly convex segments flare outwardly and upwardly to more than four times their extents in merging with the generally cylindrical sidewall, and the two opposing radii lie in a range of about 15 percent to over about 30 percent of a diameter about the longitudinal axis at which the foot-forming portions contact a supporting surface.
  • 24. The plastic container of claim 23 wherein the two-opposing radii lie in a range of about 30 percent about 36 percent of the contact diameter.
  • 25. The container of claim 17 wherein the diameter of the cylindrical sidewall is more than about 3.27 inches.
  • 26. A blow molded plastic container for a carbonated beverage comprising an upper mouth-forming portion, a cylindrical sidewall portion, and a lower base-forming portion, all about a central longitudinal axis, said lower base-forming portion comprising a plurality of hollow foot-forming portions extending outwardly and downwardly from a central base portion and further comprising a plurality of smoothly curved downwardly convex segments extending upwardly from the central base portion between adjacent hollow foot-forming portions, the downwardly convex segments having cross-sections, in a radially extending plane in its central portion coplanar with the longitudinal axis of the container, with a coefficient of curvature of from about 0.68 to about 0.75 and flaring outwardly at their upper ends and merging into the cylindrical sidewall portion.
  • 27. The container of claim 26 wherein the diameter of the cylindrical sidewall is more than about 3.27 inches.
Parent Case Info

This application is a 371 of PCT/US97/23442 filed Dec. 17, 1997 and a CIP of Ser. No. 08/771,169 filed Dec. 20, 1996, now abandoned.

PCT Information
Filing Document Filing Date Country Kind 102e Date 371c Date
PCT/US97/23442 WO 00 8/2/1999 8/2/1999
Publishing Document Publishing Date Country Kind
WO98/28193 7/2/1998 WO A
US Referenced Citations (1)
Number Name Date Kind
5603423 Lynn et al. Feb 1997
Continuation in Parts (1)
Number Date Country
Parent 08/771169 Dec 1996 US
Child 09/331545 US