Information
-
Patent Grant
-
6182853
-
Patent Number
6,182,853
-
Date Filed
Monday, February 22, 199927 years ago
-
Date Issued
Tuesday, February 6, 200125 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Brinks, Hofer, Gilson & Lione
-
CPC
-
US Classifications
Field of Search
US
- 220 659
- 220 634
- 220 636
- 220 635
- 220 649
- 220 675
- 220 657
- 220 656
- 220 771
- 220 752
- 220 606
- 220 605
- 220 604
- 220 405
-
International Classifications
-
Abstract
The present invention is directed to a plastic drum that includes a cylindrical shaped sidewall and a planar shaped head. A transition section is molded with and disposed between the head and the sidewall. A handling ring is positioned on the transition section and has a base that is disposed below the head and interior to the sidewall. The plastic drum is formed by the steps of: providing a mold having an inner surface that defines a cylindrical shaped sidewall, a planar shaped head, a transition section between the sidewall and the head and a handling ring; and molding a sidewall and the head, a transition section between the head and the sidewall, and a handling ring to extend from the transition section, the handling ring being positioned on the transition section below the head and interior to the sidewall.
Description
FIELD OF THE INVENTION
The present invention relates to the field of plastic drums, and in particular to a plastic drum having an integrally molded handling ring to provide a surface for lifting equipment such as a “parrot beak” to hold onto.
BACKGROUND OF THE INVENTION
Tighthead plastic drums are well accepted in the marketplace; they are used to contain and transport chemical, foodstuffs, and other liquids, both hazardous and non-hazardous. The drum ratings required for these products are dictated by DOT regulation and UN recommendations. The regulations mandate that a particular drum design must withstand breakage during certain drop tests, withstand a particular amount of deflection during loading tests and withstand leakage during pressure testing. Drop testing includes dropping a drum multiple times on its side and dropping the drum multiple times on its top corner from a height that depends on the desired drum rating. Pressure testing includes applying a hydrostatic pressure within the drum that depends on the desired drum rating. Further, in the United States, drums must be capable of being handled individually in order to be commercially successful, and therefore drums are commonly provided with handling rings.
Tighthead plastic drums are a commodity product. Performance specifications are well-known and current technology can produce a reliable product. Due to the commodity nature of these drums, minimizing cost against a relatively low fixed price ceiling is crucial to the profitability of the manufacturer. Because so much of the cost of producing a plastic drum is concentrated in the resin from which the drum is made, particular care must be taken in design and manufacturing to minimize the amount of resin used to make a drum that meets regulation requirements.
Tighthead plastic drums are shipped in ISO-containers and semi-trailers, among other modes. In these containers, sizing has been standardized so that quantity is maximized if the drums are sized properly with respect to their diameter. If not, shipping costs are increased, making the drums less commercially valuable.
Early embodiments of the tighthead plastic drums had detachable handling rings. Ordinarily, lifting devices such as parrot beaks squeeze such handling rings in order to lift and handle filled plastic drums. The drums can also be lifted and handled using other methods such as forklift tines. Eventual plastic technological advances allowed the handling ring to be constructed integrally with the drum as a single piece construction. Providing an integral handling ring avoids a heavy investment in molds and molding machines. During the molding process of integrally molded drums, the handling ring of the drum is compression molded, resulting in the formation of a weld line and also resulting in large quantities of excess material or extrudate being pushed into the interior of the drum below the weld line. Breakage of the drum often occurs in this weld area.
The tendency of a drum to break depends in part upon the location of the handling ring and the internal geometry of the drum, which to an extent is also a function of the location of the handling ring. The points of weakness where drums are generally susceptible to fracture generally occur at the transitions between sections of differing thickness, or at points where the vessel walls change direction. Further, in molding plastic it is best to avoid creating stress initiation points which can be formed in internal comers that are sharply angled or in areas with small radiuses. These stress initiation points especially render a drum susceptible to breakage when they are located in parts of the drum that are exposed to high levels of stress during an impact event.
In some cases drums are designed so that the intersection of the head and sidewall of the drum define the location of the handling ring and thus the location of the critical weld line and the extrudate material. In another design, disclosed in U.S. Pat. No. 5,033,639 (Przytulla) a handling ring is located at or integral with a point where the sidewall meets a frustoconical transition section between the head and the sidewall of the drum. A schematic representation of this configuration is shown in FIG.
11
.
FIG. 11
includes a representation showing where extrudate
7
is formed within the drum as a result of compression molding the handling ring.
The location of extrudate material, caused by the molding process, is dependent on the location of the handling ring and in this case the extrudate is in part disposed along the interior of the sidewall. The formation of extrudate material creates a heavy section at this location. Such heavy sections are generally less flexible than thinner sections because they are more crystalline, whereas the plastic in the thin sections is more amorphous. In the drum design of
FIG. 11
the heavy section is disposed in an area of high stress concentration, and thus in an impact situation will cause a drum to fracture more easily. Further, the extrudate material may have been formed so that it has stress initiators in the form of internal corners with sharp angles formed therein. In this case, the stress initiators can especially render a drum more susceptible to breakage because they are positioned in an area that is subject to high stress concentration during an impact event.
Another example of an integrally molded handling ring is disclosed in U.S. Pat. No. 5,543,107 (Malik et al.). A schematic representation of the Malik et al. handling ring is shown in FIG.
12
. Malik et al. discloses a handling ring that is located in direct contact with the flat head surface of the drum. As discussed above, this design increases the chance of breakage because the handling ring is located near a transition point of two sections of varying thickness. In addition, the handling ring is molded so that the extrudate material forms a geometry referred to as a double ogee
5
. This geometry is intended to eliminate acute angles formed in the extrudate which could act as stress initiation points. The formation of the geometry disclosed in this patent, however, requires a complex molding process. Further, such a location of the handling ring as disclosed in Malik et al. requires a relatively thick head portion of the drum in order to get enough extrudate to form the double ogee. The formation of the ogee itself and the formation of the thick head section requires more material, which adds to the cost of manufacture of the drum. In addition this design disposes the extrudate at an area of high stress concentration which has the disadvantages associated with heavy sections and stress initiation points discussed above.
Accordingly, it is desirable to provide a handling ring monolithically molded to a plastic drum that is located in a position that results in a drum that is less susceptible to fracture and that affords an internal geometry that reduces the chance of drum breakage. Further, it is desirable to provide such a handling ring that is simple and cost efficient to manufacture.
BRIEF SUMMARY OF THE INVENTION
A new and unique plastic drum has been invented that overcomes many of the deficiencies noted above.
In a first aspect the invention is a drum that includes a cylindrical shaped sidewall and a planar shaped head. A transition section is molded with and disposed between the head and sidewall. A handling ring having a base is positioned on the transition section so that the base is disposed below the head and interior to the sidewall.
In another aspect, the invention is a plastic drum formed by the steps of: providing a mold having an inner surface that defines a cylindrical shaped sidewall, a planar shaped head, a transition section between the sidewall and the head and a handling ring; and molding a sidewall and the head; a transition section between the head and the sidewall, and a handling ring to extend from the transition section, the handling ring being positioned on the transition section below the head and interior to the sidewall.
The invention provides the foregoing and other features, and the advantages of the invention will become further apparent from the following detailed description of the presently preferred embodiments, read in conjunction with the accompanying drawings. The detailed description and drawings are merely illustrative of the invention and do not limit the scope of the invention, which is defined by the appended claims and equivalents thereof.
BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS
FIG. 1
is a perspective view of a preferred embodiment of the present invention.
FIG. 2
is a partial sectional view taken along line
2
—
2
of FIG.
1
.
FIG. 3
is a partial sectional view of an alternative embodiment of the present invention.
FIG. 4
is a sectional view of the drum shown in
FIG. 1
taken along line
4
—
4
showing the drum tipped or dropped onto its side.
FIG. 5
is an exploded view of the handling ring of the drum in
FIG. 4
in an initial state of deformation.
FIG. 6
shows the handling ring of
FIG. 5
in a further state of deformation.
FIG. 7
is a schematic view illustrating the open position of a mold used to manufacture the drum of the present invention.
FIG. 8
is a schematic view of the mold of
FIG. 7
illustrating a first molding step used in making the preferred embodiment of the present invention.
FIG. 9
is a schematic view of the mold of
FIG. 7
illustrating a subsequent portion of the first step of the molding process.
FIG. 10
is a schematic view of the mold of
FIG. 7
illustrating a second molding step used to manufacture the preferred embodiment of the present invention.
FIG. 11
shows a drum from
FIG. 1
of U.S. Pat. No. 5,033,639 and further includes a representation of extrudate material formed within the drum.
FIG. 12
shows a portion of a drum as depicted in
FIG. 2
of U.S. Pat. No. 5,543,107.
DETAILED DESCRIPTION OF THE INVENTION
Referring to
FIG. 1
, there is shown a drum
1
. In one embodiment, the drum
1
is a plastic drum similar to a plastic drum designed by General Cooperage Company, of Franklin Park, Ill. The drum
1
is generally formed from a sidewall
10
, a head
20
, a bottom
24
and a transition section
40
that are monolithically molded together. In this case monolithic is defined as formed of one piece or a one-piece construction. The sidewall
10
has a generally cylindrical shaped outer surface
13
and the head
20
has a generally planar top surface
21
. The head
20
includes bung bosses
30
disposed in a recessed portion
22
of the head for lading product within the drum
1
.
As shown in
FIGS. 1 and 2
, the transition section
40
is formed in between the sidewall
10
and the head
20
. A handling ring
50
is preferably monolithically molded with and extends upward from the transition section
40
. This handling ring
50
serves to provide an appurtenance for lifting equipment to grasp the drum
1
. This handling ring
50
is positioned on the transition section
40
in a manner that reduces the chance of breakage of the drum
1
during an impact event. Also, the location of this handling ring
50
decreases the cost to manufacture the drum
1
.
Referring to
FIG. 2
, the transition section
40
has an upper end
44
and a lower end
46
. In a preferred embodiment the transition section
40
slopes downward from the head
20
to the sidewall
10
. A first portion
48
of the transition section
40
is formed between the upper end
44
and the handling ring
50
and a second portion
49
of the transition section is formed between the handling ring
50
and the lower end
46
. Referring again to
FIG. 2
, in a preferred embodiment an acute angle B is formed between a vertical axis
41
oriented along the outer surface
13
of the sidewall
10
and the outer surface of the transition section
40
. In a preferred embodiment this angle B is about 45 degrees. Alternatively, other angles may be used, such as but not limited to between approximately 30 degrees and 60 degrees.
As shown in
FIGS. 1 and 2
, recessed portions
22
of the drum
1
accommodate the bung bosses
30
. In the recessed portions
22
of the drum
1
the top portion of the transition section
40
extends to a top end
45
which corresponds to the recessed portion
22
. The geometry of the transition section
40
in this recessed portion
22
is generally the same as that discussed above.
Referring to
FIG. 2
, the handling ring
50
is monolithically formed with and extends upward from the transition section
40
. The handling ring preferably has an inner surface
51
and an outer surface
53
. In a preferred embodiment, the handling ring
50
extends around the entire transition section
40
. In a preferred embodiment, the handling ring
50
forms an obtuse angle with respect to the second portion
49
of the transition section
40
. The handling ring
50
includes a base
56
, a middle portion
57
and a head
62
. The base
56
is defined generally as the portion of the handling ring that meets the transition section
40
. The handling ring
50
inner surface
51
meets the transition section
40
at a first intersection
59
and the handling ring
50
outer surface
53
meets the transition section
40
at a second intersection
61
. In a preferred embodiment, the first intersection
59
is located below the generally planar top surface
21
, and the second intersection is located interior to the cylindrical outer surface
13
of the sidewall
10
. The head
62
includes a top surface
64
, a curved edge
66
, an outside edge
68
and a bottom surface
70
.
The first intersection
59
allows the handling ring
50
to flex over a larger area, thus allowing the handling ring
50
to absorb more energy, and reduces stress at the first intersection
59
during an impact event.
Referring again to
FIG. 2
, the handling ring
50
is generally located between the upper end
44
and the lower end
46
of the transition section
40
. The handling ring
50
is preferably located approximately at the midpoint between the upper end
44
and the lower end
46
. In a preferred embodiment the top surface
64
is located a vertical distance of 1.162 inches above the first contact point
59
. The bottom of the outside edge
68
is preferably located a distance of about 0.608 inches from the top surface
64
and the top of the outside edge
68
is preferably located a vertical distance of about 0.422 inches from the top surface.
In a preferred embodiment, the inner surface
51
of the handling ring
50
is tilted approximately 11 degrees with respect to a vertical axis
42
that is defined by the vertical dashed line shown in FIG.
2
. The outer surface
53
is preferably tilted about 12 degrees with respect to the vertical axis
42
. Alternatively, if the location of the handling ring
50
is changed these angles will change accordingly. In a preferred embodiment the outer diameter of the handling ring
50
as defined by the outermost point of the handling ring
50
, the outside edge
68
, is less than or equal to the outer most diameter of the drum
1
, which is defined by the rolling hoops
11
, shown in FIG.
1
. This dimensioning is important for storage purposes because it allows drums to be stacked immediately adjacent to each other. In a preferred embodiment the handling ring
50
forms an obtuse angle with respect to the second portion
49
of the transition section
40
.
Referring again to
FIG. 2
, a weld line
54
is illustrated by the line on the handling ring
50
. The weld line
54
in the handling ring
50
is formed as a result of the molding process, which involves pressing two pieces of molten plastic material together to form the handling ring
50
. This molding process is discussed in greater detail below.
As shown in
FIG. 2
, extrudate
80
is integrally formed at the base or root
82
of the weld line
54
. The extrudate
80
is formed from extra material being pushed into the interior of the drum
1
during the compression molding of the handling ring
50
. The extrudate
80
is distributed generally evenly in the shape of the two bumps shown in FIG.
2
. The portion of the transition section
40
where the handling ring
50
is formed, and as a result where the extrudate
80
is located, is preferably two times thicker than the average thickness of the head
20
and of the sidewall
10
.
In a preferred embodiment, the drum is made of a plastic such as high molecular weight high density polyethylene (HMWHDPE). Alternative materials such as Polyethylene Terephthalate (PET), Polycarbonate (PC), Polypropylene (PP) and Polyethylene (PE) could also be used. Additionally, these materials and others filled with fiberglass, mica, wood or paper fiber and other blends could be used.
The drum
1
is preferably up to 120 gallons in capacity. Further, the drum
1
is preferably dimensioned so as to efficiently fit into standard shipping containers. Alternatively, the drum may be anywhere between 15-120 gallons in capacity.
The advantages of the invention will now be described in the context of the effects of dropping a plastic drum
1
, which will be described with reference to
FIGS. 4-6
. Referring to
FIGS. 4 and 5
, a plastic drum filled with liquid products has either been dropped or tipped onto its side.
When a drum
1
is dropped onto its side, it generally experiences two types of forces, an external ground impact force on the sidewall
10
and internal hydraulic forces on the head, sidewall and bottom of the drum
1
. During the course of the impact the forces begin to flatten out the drum
1
and bend the handling ring
50
in an ovalized fashion as well as cause it to flex in towards the head of the drum
1
. In particular, the hydraulic forces tend to stress the joint where the sidewall
10
meets the transition section
40
and the head
20
meets the transition section
40
. As shown schematically by the arrows in
FIG. 6
, the critical stresses caused by these forces are generally located at the upper
44
and lower
46
ends of the transition section
40
.
An advantage of the present embodiment of the invention is that the handling ring
50
is located at a point between the upper
44
and lower
46
ends, as opposed to being situated at the upper end
44
or the lower end
46
of the transition section
40
. More specifically, a base
56
of the handling ring
50
is located below the generally planar top surface
21
formed by the head
20
and interior to the cylindrical outer surface
13
of the sidewall
10
. The chance of drum
1
breakage is substantially reduced by this location of the handling ring
50
because the extrudate
80
, which includes masses of crystalline material and possible stress initiation points is not located at a point where the critical stresses caused by impact are concentrated. If the handling ring
50
were located on or near the head
20
(as shown in FIG.
12
), as opposed to below the head, or if the handling ring
50
were located on or near the sidewall
10
(as shown in FIG.
11
), as opposed to interior to the sidewall
10
, the extrudate would be directly subjected to the critical stresses during an impact event, which would increase the chances of drum
1
breakage.
An additional advantage is provided by the present preferred embodiment of the invention by the fact that the upper and lower ends
44
,
46
of the transition section
40
are comprised of less material and are thinner than corresponding sections in the prior art embodiments where the handling ring is formed at the upper or lower ends of the transition section. The ends of the transition section are thinner because the extrudate material
80
formed in the interior of the drum below the handling ring
50
is located along the transition section
40
as shown in
FIG. 2
, as opposed to being located at either of the ends
44
,
46
, which would be the case if the handling ring
50
were located at the upper or lower end
44
,
46
of the transition section
40
, thereby causing thicker sections at these ends. In addition, the present embodiment of the invention permits a thinner head
20
than a head of a drum where the handling ring is formed at the upper end
44
. These thinner areas can more easily be stretched and absorb energy during an impact event, thus relieving stresses on the critical weld area
54
. Further, the thinner areas require less material or resin to manufacture and therefore result in a substantial cost savings and an overall lighter drum
1
, resulting in a savings in manufacturing and shipping costs.
A further advantage of the present preferred embodiment of the invention is that it can more effectively bear a tensile load without breaking the ring. Handling rings that are substantially perpendicular to the head have a tendency to fracture more easily when a tensile load is applied, as opposed to the handling ring
50
of the present invention which is angled and thus able to more evenly distribute tensile load forces.
The fact that the handling ring
50
of the present invention is monolithically molded substantially reduces the cost of making the drum
1
and also reduces the weight of the drum.
Referring to
FIG. 3
, a second preferred embodiment of drum
200
of the present invention is shown. The device is generally the same as drum
1
of
FIGS. 1-2
and the similar elements have similar reference numbers. The primary difference between the embodiment of
FIGS. 1-2
and the embodiment of
FIG. 3
is that in the second embodiment, the first portion
248
and the second portion
249
of the transition section
40
form curved surfaces. The curved surfaces join to form a continuous elliptical or radiused shaped transition area.
In a preferred embodiment, the drum
1
described in
FIGS. 1-2
and
4
-
6
may be made using a blow mold and a blow molding technique described below with reference to
FIGS. 7-11
.
Referring to
FIGS. 7-8
, a blow mold
90
is shown. The blow mold
90
is positioned so that a drum can be formed in an upside down position. An interior surface
92
of the blow mold
90
is sized and shaped according to the drum to be molded. An articulating mold section
94
is initially disposed below the blow mold
90
and is used to compression mold a handling ring. In a preferred embodiment the handling ring is the handling ring
50
described in
FIGS. 1 and 2
above. In a preferred embodiment the mold
90
is made of a material of substantially high thermal conductivity, such as aluminum, with inserts for special purposes made of materials such as steel and beryllium copper. Alternatively, the mold may be made of steel, nickel, titanium, wood or some other material which will withstand the stresses of blowing and compression.
As shown in
FIG. 7
, the mold is preferably divided into two halves
96
a
,
96
b
that are open in a first position. Disposed between the halves is a parison
98
. The parison
98
is preferably disposed within the mold using extrusion. The parison
98
thickness is adjusted by programming extrusion die tooling. In a preferred embodiment the parison
98
is made of a HMWHDPE material. Alternately the parison may be made of Polyethylene Terephthalate (PET), Polycarbonate (PC), Polypropylene (PP) or medium or lower linear low density Polyethylene (PE). Blow pins
100
are disposed within the parison
98
and used to supply air to expand the parison
98
.
The following steps are performed to mold a drum
1
using the blow mold
90
. First, plastic is heated to a temperature within the range of about 385-500 degrees F. and the parison
98
is extruded out over the blow pins
100
or transferred there with a parison transfer device. Next, the mold halves
96
a
,
96
b
are closed to pinch off the parison
98
, so that there is a closed parison
98
within the mold
90
. Referring to
FIG. 8
, when the mold halves
96
a
,
96
b
are almost completely closed a preblow or a first blowing step is conducted in which air is blown through the blow pins
100
to expand the parison
98
. Alternatively, other methods could be used to introduce air to expand the parison
98
, such as needle blowing.
Referring to
FIG. 9
, when the parison
98
is blown into the mold such that all of it is in contact with the mold
90
, the articulating mold section
94
is raised up into the mold
90
body. When the articulating section
94
is closed, excess material forms the extrudate material
80
shown in FIG.
2
. In a preferred embodiment, air is circulated in and out at a constant pressure. The articulating mold section
94
is preferably closed at a rate of about ½″-1″/second.
Referring to
FIG. 10
, after the articulating mold section
94
is completely closed, a second blowing step is initiated. The second step also involves cycling cooled air or other cooling gasses through the blowing
100
long enough to allow the plastic drum
1
to cool sufficiently to remove it from the mold without deleterious deformation occurring. In a preferred embodiment the air is blown in at a pressure within the range of approximately 90 to 130 psi for a duration of about 60-90 sec. Alternatively, the volume of air circulated and the duration is varied depending upon environmental factors, including material density, ambient temperatures, cooling water temperatures, mold temperatures and other factors. After the drum
1
has cooled, the mold halves
96
a
,
96
b
and the mold articulating section can be opened and the drum
1
can be removed from the mold.
Using the above described method, a drum
1
having an integrally formed handling ring
50
described above is formed. The handling ring
50
of the drum
1
formed using the above-described method is located on the transition section
40
such that it provides the advantages discussed in detail above. Additionally the drum
1
made from the foregoing method can be shipped in standard ISO-containers and semi-trailers as well as other shipping modes.
In an alternative embodiment, a handling ring may be monolithically molded to the bottom of the drum as well as the head. Alternatively, a handling ring may be monolithically molded to only the bottom of the drum.
While the embodiments of the invention disclosed herein are presently considered to be preferred, various changes and modifications can be made without departing from the spirit and scope of the invention. The scope of the invention is indicated in the appended claims, and all changes that come within the meaning and range of equivalents are intended to be embraced therein.
Claims
- 1. A drum comprising:a generally cylindrical sidewall; a generally planar head; a transition section integrally molded as one piece with and disposed between the head and the sidewall, the transition section having a lower end connected to the sidewall and an upper end connected to the head; a handling ring having a base positioned on the transition section between the upper end and the lower end, the base defining a first portion of the transition section between the upper end and the base and a second portion of the transition section between the base and the lower end, wherein the first portion is generally parallel with the second portion, and wherein the base of the handling ring forms an acute angle with respect to the first portion.
- 2. The drum of claim 1, wherein the sidewall defines a vertical axis oriented along the outer surface of the sidewall, and wherein the angle between the second portion and the vertical axis is between approximately 30 degrees and 60 degrees.
- 3. A drum, comprising:(a) a cylindrical shaped sidewall and a generally planar shaped head; (b) a transition section integrally molded as one piece with and disposed between the head and the sidewall, wherein the entire transition section is frustoconical; and (c) a handling ring having a base, the handling ring positioned on the transition section so that the base is disposed below the head and interior to the sidewall, wherein the base of the handling ring forms an obtuse angle with a portion of the transition section between the sidewall and the handling ring.
- 4. The drum of claim 3, wherein the handling ring is monolithically molded onto the transition section.
- 5. The drum of claim 3, wherein the transition section is curved.
- 6. The drum of claim 3, wherein the handling ring is positioned at a midpoint between the head and the sidewall.
- 7. The drum of claim 3, wherein a weld line is formed in the handling ring.
- 8. The drum of claim 3, wherein the handling ring forms an acute angle with respect to a portion of the transition section that is proximate the head.
- 9. The drum of claim 3, wherein the handling ring is integrally molded as one piece to the transition section.
- 10. The drum of claim 3, wherein the handling ring extends around the entire transition section.
- 11. The drum of claim 3, wherein a portion of the transition section that intersects the handling ring is approximately 2 times thicker than the average thickness of the head and the sidewall.
- 12. A drum, comprising:(a) a sidewall having a generally cylindrical outer surface, a head having a generally planar top surface, and a bottom; (b) a transition section integrally molded as one piece with and disposed between the sidewall and the head, wherein the entire transition section is frustoconical; (c) a handling ring monolithically molded with the transition section, the handling ring having an inner surface and an outer surface, wherein the base of the handling ring forms an obtuse angle with a portion of the transition section between the sidewall and the handling ring; (d) a first intersection formed where the handling ring inner surface meets the transition section, the first intersection being below the generally planar top surface; and (e) a second intersection formed where the handling ring outer surface meets the transition section, the second intersection being interior to the cylindrical outer surface.
- 13. The drum of claim 12, wherein the transition section is curved.
- 14. The drum of claim 12, wherein the handling ring forms an acute angle with respect to a portion of the transition section that is proximate the head.
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AU |
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Dec 1974 |
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DE |
| 1 0 210 679 |
Jun 1986 |
EP |
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Jan 1988 |
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May 1974 |
GB |
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GB |
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Oct 1984 |
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