PLASTICIZER AND PLASTIC PRODUCT

Abstract

A plasticizer, which is biodegradable, has a molecule including a central structure, at least two connecting structures and at least one side-chain structure. The central structure includes at least one of a benzene derivative and at least one amino acid. The connecting structures are respectively connected to the central structure, wherein the connecting structures include a first connecting structure and a second connecting structure. The first connecting structure is an amine group, and the second connecting structure is a carboxyl group. The side-chain structure is a chain of multiple carbon atoms, and the side-chain structure is connected to at least one of the first connecting structure and the second connecting structure. An amide bond is formed as the side-chain structure connected to the amine group, and an ester bond is formed as the side-chain structure connected to the carboxyl group.

Description

BACKGROUND

Technical Field

The present disclosure relates to an additive for plastic materials. More particularly, the present disclosure relates to a biodegradable plasticizer.

Description of Related Art

In order to solve the environmental problems brought on by plastic products, biodegradable plastics, such as polylactic acid (PLA), poly(butylene succinate) (PBS) and poly(butylene adipate-co-terephthalate) (PBAT), have already been developed. However, properties of this type of plastics are still not as good as petroleum-based plastics. For example, polylactic acid has excellent rigidity and high transparency, but lacks enough durability, heat resistance, impact resistance, flexibility and airtightness, which limits the applications of polylactic acid.

To deal with problems in properties, textures and costs of biodegradable plastics, conventional biodegradable additives can be added to change the flexibility and durability of biodegradable plastics. However, the enhancement of biodegradation in properties of biodegradable plastics made by adding conventional additives is still insufficient. Also, the conventional additives are likely to release and have higher cost, so there has a lot of improvements for the conventional additives. Furthermore, the conditions for degradation of biodegradable plastics are tough. For example, plastic products made of polylactic acid can completely degrade into carbon dioxide and water only under particular environmental conditions for a sufficient time, and then enter the cycle without harming the natural environment. However, it is pretty difficult for plastic products of polylactic acid naturally and completely degrading in a typical environment. In this regard, the important trend for future is to develop an additive, which can enhance the degradation rate to facilitate biodegradable plastics quickly degrading and entering the natural environment.

SUMMARY

According to one aspect of the present disclosure, a plasticizer, which is biodegradable, has a molecule including a central structure, at least two connecting structures and at least one side-chain structure. The central structure includes at least one of a benzene derivative and at least one amino acid. The at least two connecting structures are respectively connected to the central structure, wherein the at least two connecting structures include a first connecting structure and a second connecting structure. The first connecting structure is an amine group, and the second connecting structure is a carboxyl group. The at least one side-chain structure is a chain of multiple carbon atoms, and the at least one side-chain structure is connected to at least one of the first connecting structure and the second connecting structure. An amide bond is formed as the at least one side-chain structure connected to the amine group, and an ester bond is formed as the at least one side-chain structure connected to the carboxyl group. When a number of carbon atoms of the side-chain structure which is connected to the amine group is nNC, and a number of carbon atoms of the side-chain structure which is connected to the carboxyl group is nOC, the following condition is satisfied: 0≤nNC/(nNC+nOC)≤1.00, wherein each of nNC and nOC is 0 or positive integer, but nNC and nOC are not 0 at the same time.

According to another aspect of the present disclosure, a plastic product, which is biodegradable, includes the plasticizer of the aforementioned aspect and a polyester plastic, wherein the polyester plastic is a polylactic acid, a polybutylene succinate, a poly(butylene adipate-co-terephthalate) or a polyhydroxyalkanoate, and the plasticizer is mixed with the polyester plastic.

According to another aspect of the present disclosure, a plasticizer, which is biodegradable, has a molecule including at least two central structures, at least two connecting structures and a side-chain structure. Each of the central structures includes at least one of a benzene derivative and at least one amino acid. Each of the connecting structures is a carboxyl group, and each of the central structures is connected to at least one of the connecting structures. The side-chain structure is a chain of multiple carbon atoms, each of the central structures is connected to the side-chain structure through the connecting structures, and an ester bond is formed as the side-chain structure connected to each of the carboxyl groups.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure can be more fully understood by reading the following detailed description of the embodiment, with reference made to the accompanying drawings as follows:

FIG. 1 is a structural schematic view of a molecule of a plasticizer according to the let embodiment of the present disclosure.

FIG. 2 is a structural schematic view of a molecule of a plasticizer according to the 2nd embodiment of the present disclosure.

FIG. 3 is a structural schematic view of a molecule of a plasticizer according to the 3rd embodiment of the present disclosure.

FIG. 4 is a structural schematic view of a molecule of a plasticizer according to the 4th embodiment of the present disclosure.

FIG. 5 is a structural schematic view of a molecule of a plasticizer according to the 5th embodiment of the present disclosure.

FIG. 6 is a structural schematic view of a molecule of a plasticizer according to the 6th embodiment of the present disclosure.

FIG. 7 is a structural schematic view of a molecule of a plasticizer according to the 7th embodiment of the present disclosure.

FIG. 8 is a structural schematic view of a molecule of a plasticizer according to the 8th embodiment of the present disclosure.

FIG. 9 is a structural schematic view of a molecule of a plasticizer according to the 9th embodiment of the present disclosure.

FIG. 10 is a structural schematic view of a molecule of a plasticizer according to the 10th embodiment of the present disclosure.

FIG. 11 is a structural schematic view of a molecule of a plasticizer according to the 11th embodiment of the present disclosure.

FIG. 12 is a structural schematic view of a molecule of a plasticizer according to the 12th embodiment of the present disclosure.

FIG. 13 is a structural schematic view of a molecule of a plasticizer according to the 13th embodiment of the present disclosure.

FIG. 14 is a structural schematic view of a molecule of a plasticizer according to the 14th embodiment of the present disclosure.

FIG. 15 shows results of biodegradation tests of the comparison, the 29th Example and the 30th Example.

DETAILED DESCRIPTION

A plasticizer, which is biodegradable, has a molecule including a central structure, at least two connecting structures and at least one side-chain structure. The at least two connecting structures are respectively connected to the central structure, and the side-chain structure is connected to at least one of the at least two connecting structures.

The central structure includes at least one of a benzene derivative and at least one amino acid. It is favorable for maintaining the biodegradability of the plasticizer by having the benzene derivative. The amino acid can be degraded and metabolized in animal cells, so that it is favorable for enhancing the biodegradability of the plasticizer. Moreover, the central structure can be the benzene derivative, and can further include the amino acid. Furthermore, the central structure can be the amino acid, and can include at least two of the amino acid. The residue of the amino acid can be acidic, basic, hydrophilic or hydrophobic, so that it is favorable for adjusting the properties of the plasticizer according to the residue characteristics of the amino acid.

The benzene derivative can be compounds with similar structures, such as 2-aminobenzoic acid, 3-aminobenzoic acid, 4-aminobenzoic acid, 2-hydroxybenzoic acid, 3-hydroxybenzoic acid or 4-hydroxybenzoic acid.

The amino acid can be standard amino acids, essential amino acids which humans cannot synthesize, modified amino acids (such as hydroxyproline, hydroxylysine or thyroxine) or other non-standard amino acids (such as homocysteine, homoserine or ornithine). The standard amino acids and essential amino acids are listed in Table 1 below.

TABLE 1
Standard Amino Acids and Essential Amino Acids
	Amino Acid	Abbreviation	Essential Amino Acid
	Alanine	Ala	No
	Arginine	Arg	No
	Asparagine	Asn	No
	Aspartate	Asp	No
	Cysteine	Cys	No
	Glutamate	Glu	No
	Glutamine	Gln	No
	Glycine	Gly	No
	Histidine	His	Yes
	Isoleucine	Ile	Yes
	Leucine	Leu	Yes
	Lysine	Lys	Yes
	Methionine	Met	Yes
	Phenylalanine	Phe	Yes
	Proline	Pro	No
	Pyrrolysine	Pyl	No
	Selenocysteine	Sec	No
	Serine	Ser	No
	Threonine	Thr	Yes
	Tryptophan	Trp	Yes
	Tyrosine	Tyr	No
	Valine	Val	Yes

The central structure can also be glycerol (propane-1,2,3-triol) or 2-(2-hydroxyethoxy)propan-1-ol.

The at least two connecting structures include a first connecting structure and a second connecting structure. The first connecting structure is an amine group, and the second connecting structure is a carboxyl group.

If the central structure is the benzene derivative, the position of the amine group and the position of the carboxyl group can be adjacent to each other (ortho) or not adjacent (meta or para) on the benzene derivative.

The amine group can be a functional group of —NH₂, —NHR, or —NR₂. Moreover, the amine group can be a primary amine, a secondary amine, a tertiary amine or a quaternary ammonium cation. Furthermore, a hydroxyl group can be substituted for the amine group of the first connecting structure. When the side-chain structure is connected to the hydroxyl group, the connection therebetween can be split through hydrolysis reaction, so that it is favorable for enhancing the biodegradability of the plasticizer.

When the molecule of the plasticizer includes two connecting structures, the two connecting structures are respectively the first connecting structure and the second connecting structure. Moreover, the molecule of the plasticizer can include three connecting structures, which are respectively the first connecting structure, the second connecting structure and a third connecting structure. The third connecting structure can be the residue of the amino acid. For example, the amine group of the residue from lysine can be taken as the third connecting structure, or the carboxyl group of the residue from aspartate can be taken as the third connecting structure. Further, the molecule of the plasticizer can include four connecting structures, which are respectively the first connecting structure, the second connecting structure, the third connecting structure and a fourth connecting structure. The third connecting structure and the fourth connecting structure can be the same functional groups, such as the binary amine groups of the residues from arginine, or can be different functional groups. Furthermore, when the central structure includes a plurality of amino acids, the molecule of the plasticizer can include more than five connecting structures.

The side-chain structure is a chain of multiple carbon atoms. The number of carbon atoms of the side-chain structure can be 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20, etc. Moreover, the side-chain structure can include an oxygen atom to form an ether group, and the number of oxygen atoms of the side-chain structure can be 1, 2, 3, 4, 5, 6 or 7, etc.

The side-chain structure can be a saturated fatty acid. The number of carbon atoms of the saturated fatty acid can be 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35 or 36, such as acetic acid (lipid number C2:0), butyric acid (C4:0), hexanoic acid (C6:0), octanoic acid (C8:0), decanoic acid (C10:0), lauric acid (C12:0), lignoceric acid (C24:0), or hexatriacontanoic acid (C36:0).

The side-chain structure can be an unsaturated fatty acid. The number of carbon atoms of the unsaturated fatty acid can be 14, 15, 16, 17, 18, 19, 20, 21, 22, 23 or 24, and the number of double bonds of the unsaturated fatty acid can be 1, 2, 3, 4, 5 or 6, such as paullinic acid (020:1), dihomo-γ-linolenic acid (DGLA, C20:3), docosahexaenoic acid (DHA, C22:6), or tetracosenoic acid (C24:1).

The side-chain structure can be formed by continuous polymerization with ethylene glycol, polyethylene glycol (PEG), propylene glycol or polypropylene glycol (PPG) as monomers. Moreover, the side-chain structure can be formed by polymerization of the monomers selected from the group consisting of ethylene glycol, polyethylene glycol, propylene glycol and polypropylene glycol. The side-chain structure is formed by polymerization of the abovementioned monomers, the required molecular weight of the plasticizer can be controlled, and the hydrophilicity and hydrophobicity of the plasticizer are properly adjusted, so that it is favorable for the plasticizer performing the superior characteristics and enhancing the compatibility of the plasticizer mixing with the plastic.

The side-chain structure is connected to at least one of the first connecting structure and the second connecting structure, that is, the central structure is connected to the side-chain structure through the first connecting structure and/or the second connecting structure by a method of esterification, dehydration or peptide synthesis.

When the side-chain structure is connected to the amine group, an amide bond is formed, so that it is favorable for enhancing the efficiency of the plasticizer degraded by the enzyme, and further improving the biodegradability of the plasticizer. Moreover, when the side-chain structure is connected to the carboxyl group, an ester bond is formed. Furthermore, when the side-chain structure is connected to the hydroxyl group, an ether bond is formed. The ether bond can be split through hydrolysis reaction in a particular environment, so that it is favorable for enhancing the biodegradability of the plasticizer.

The plasticizer can further include at least one polar functional group connected to the side-chain structure, and the polar functional group can be located in the middle or at the end of the side-chain structure. Moreover, the polar functional group can be a carboxyl group (—COOH), a hydroxyl group (—OH), an amine group (—NH₂) or a phosphoryl group (—PO(OH)₂). Furthermore, the plasticizer can include at least two of the polar functional group, which are selected from the group consisting of the carboxyl group, the hydroxyl group, the amine group and the phosphoryl group. The polar functional group is arranged according to different requirements, so that it is favorable for enhancing the hydrophilicity of the plasticizer and the compatibility between the plasticizer and the plastic, which helps the plasticizer mix with the plastic.

When a number of carbon atoms of the side-chain structure which is connected to the amine group is nNC, and a number of carbon atoms of the side-chain structure which is connected to the carboxyl group is nOC, the following condition is satisfied: 0≤nNC/(nNC+nOC)≤1.00, wherein each of nNC and nOC is 0 or positive integer, but nNC and nOC are not 0 at the same time. Moreover, the following conditions can be satisfied: 0.01≤nNC/(nNC+nOC); nNC/(nNC+nOC)≤1.00; 0.05≤nNC/(nNC+nOC)≤0.95; 0.10≤nNC/(nNC+nOC)≤0.90; 0.15≤nNC/(nNC+nOC)≤0.80; 0.20≤nNC/(nNC+nOC)≤0.70; 0.25≤nNC/(nNC+nOC)≤0.60; 0.30≤nNC/(nNC+nOC)≤0.50; or 0.35≤nNC/(nNC+nOC)≤0.40.

A number of oxygen atoms of the side-chain structure which is connected to the amine group is nNO. A number of oxygen atoms of the side-chain structure which is connected to the carboxyl group is nOO. A number of carbon atoms of the side-chain structure which is connected to the hydroxyl group is nO′C. A number of oxygen atoms of the side-chain structure which is connected to the hydroxyl group is nO′O. nNC and nNO of the side-chain structure are counted from the nitrogen atom of the amine group. nOC, nOO, nO′C and nO′O of the side-chain structure are counted from the oxygen atom of the carboxyl group or the hydroxyl group. The carbon atoms or the oxygen atoms in the polar functional group are not included as calculating nNC, nNO, nOC, nOO, nO′C and nO′O. nO′C is taken as nOC and nO′O is taken as nOO during calculation.

When the molecular weight of the plasticizer is MwP, the following condition is satisfied: 450 Dalton ≤MwP. As the molecular weight of the plasticizer is larger, it is more difficult for the plasticizer to pass through the cell membrane, so that it is favorable for preventing the plasticizer directly passing through the cell membrane into the cell. Moreover, the following conditions can be satisfied: MwP≤2000 Dalton; 475 Dalton ≤MwP≤1000 Dalton; 500 Dalton ≤MwP; 525 Dalton ≤MwP; 550 Dalton ≤MwP; or 600 Daltons ≤MwP≤1500 Dalton.

Each of the aforementioned features of the plasticizer can be utilized in various combinations for achieving the corresponding effects.

According to another aspect of the present disclosure, a plasticizer, which is biodegradable, has a molecule including at least two central structures, at least two connecting structures and a side-chain structure. Each of the central structures is connected to at least one of the connecting structures. Each of the central structures is connected to the side-chain structure through the connecting structures, that is, the central structures are all connected to the same side-chain structure. The detailed features of the central structures, the connecting structures and the side-chain structure are the same as the abovementioned plasticizer, and an explanation in this regard will not be provided again.

According to the present disclosure, a plastic product is provided, wherein the plastic product is biodegradable. The plastic product includes the aforementioned plasticizer and a polyester plastic, wherein the polyester plastic can be a polylactic acid, a polybutylene succinate, a poly(butylene adipate-co-terephthalate) or a polyhydroxyalkanoate (PHA), and the plasticizer is mixed with the polyester plastic. The type of the polyester plastic is chosen to ensure that the plasticizer is mixed with the plastic of high compatibility, so that it is favorable for enhancing the ductility of the plastic and reducing the possibility of releasing of the plasticizer. Moreover, the polyhydroxyalkanoate can be a polyhydroxybutyrate (PHB).

1st Embodiment

FIG. 1 is a structural schematic view of a molecule of a plasticizer 100 according to the 1st embodiment of the present disclosure. In FIG. 1, the molecule of the plasticizer 100 according to the 1st embodiment includes a central structure 110, two connecting structures and a side-chain structure 130.

The central structure 110 is a benzene derivative.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 110, respectively. The first connecting structure is an amine group 121, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 130 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The side-chain structure 130 is connected to the second connecting structure to form an ester bond 122′.

2nd Embodiment

FIG. 2 is a structural schematic view of a molecule of a plasticizer 200 according to the 2nd embodiment of the present disclosure. In FIG. 2, the molecule of the plasticizer 200 according to the 2nd embodiment includes a central structure 210, two connecting structures, a side-chain structure 230 and a polar functional group 260.

The central structure 210 is a benzene derivative.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 210, respectively. The first connecting structure is an amine group 221, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 230 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 230 is connected to the second connecting structure to form an ester bond 222′.

The polar functional group 260 is connected to the side-chain structure 230.

3rd Embodiment

FIG. 3 is a structural schematic view of a molecule of a plasticizer 300 according to the 3rd embodiment of the present disclosure. In FIG. 3, the molecule of the plasticizer 300 according to the 3rd embodiment includes a central structure 310, two connecting structures and a side-chain structure 330.

The central structure 310 is a benzene derivative.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 310, respectively. The first connecting structure is an amine group 321, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 330 is formed by a first short chain 331 connected to a second short chain 332. The first short chain 331 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 332 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 330 is connected to the second connecting structure to form an ester bond 322′.

4th Embodiment

FIG. 4 is a structural schematic view of a molecule of a plasticizer 400 according to the 4th embodiment of the present disclosure. In FIG. 4, the molecule of the plasticizer 400 according to the 4th embodiment includes a central structure 410, two connecting structures and a side-chain structure 430.

The central structure 410 is a benzene derivative.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 410, respectively. The first connecting structure is an amine group (not shown in drawings), and the second connecting structure is a carboxyl group 422.

The side-chain structure 430 is a fatty acid. The side-chain structure 430 is connected to the first connecting structure to form an amide bond 421′.

5th Embodiment

FIG. 5 is a structural schematic view of a molecule of a plasticizer 500 according to the 5th embodiment of the present disclosure. In FIG. 5, the molecule of the plasticizer 500 according to the 5th embodiment includes a central structure 510, two connecting structures, two side-chain structures 530, 540 and a polar functional group 560.

The central structure 510 is a benzene derivative.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 510, respectively. The first connecting structure is an amine group (not shown in drawings), and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 530 is formed by a first short chain 531 connected to a second short chain 532. The first short chain 531 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 532 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 530 is connected to the second connecting structure to form an ester bond 522′.

The side-chain structure 540 is a fatty acid. The side-chain structure 540 is connected to the first connecting structure to form an amide bond 521′.

The polar functional group 560 is connected to the side-chain structure 530.

6th Embodiment

FIG. 6 is a structural schematic view of a molecule of a plasticizer 600 according to the 6th embodiment of the present disclosure. In FIG. 6, the molecule of the plasticizer 600 according to the 6th embodiment includes a central structure 610, two connecting structures, a side-chain structure 630 and a polar functional group 660.

The central structure 610 is an amino acid and includes a residue 611.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 610, respectively. The first connecting structure is an amine group 621, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 630 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The side-chain structure 630 is connected to the second connecting structure to form an ester bond 622′.

The polar functional group 660 is connected to the side-chain structure 630.

7th Embodiment

FIG. 7 is a structural schematic view of a molecule of a plasticizer 700 according to the 7th embodiment of the present disclosure. In FIG. 7, the molecule of the plasticizer 700 according to the 7th embodiment includes a central structure 710, two connecting structures and a side-chain structure 730.

The central structure 710 is an amino acid and includes a residue 711.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 710, respectively. The first connecting structure is an amine group 721, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 730 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 730 is connected to the second connecting structure to form an ester bond 722′.

8th Embodiment

FIG. 8 is a structural schematic view of a molecule of a plasticizer 800 according to the 8th embodiment of the present disclosure. In FIG. 8, the molecule of the plasticizer 800 according to the 8th embodiment includes a central structure 810, two connecting structures and a side-chain structure 830.

The central structure 810 is an amino acid and includes a residue 811.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 810, respectively. The first connecting structure is an amine group 821, and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 830 is formed by a first short chain 831 connected to a second short chain 832. The first short chain 831 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 832 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 830 is connected to the second connecting structure to form an ester bond 822′.

9th Embodiment

FIG. 9 is a structural schematic view of a molecule of a plasticizer 900 according to the 9th embodiment of the present disclosure. In FIG. 9, the molecule of the plasticizer 900 according to the 9th embodiment includes a central structure 910, two connecting structures and a side-chain structure 930.

The central structure 910 is an amino acid and includes a residue 911.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 910, respectively. The first connecting structure is an amine group (not shown in drawings), and the second connecting structure is a carboxyl group 922.

The side-chain structure 930 is a fatty acid. The side-chain structure 930 is connected to the first connecting structure to form an amide bond 921.

10th Embodiment

FIG. 10 is a structural schematic view of a molecule of a plasticizer 1000 according to the 10th embodiment of the present disclosure. In FIG. 10, the molecule of the plasticizer 1000 according to the 10th embodiment includes central structure 1010, two connecting structures, two side-chain structures 1030, 1040 and a polar functional group 1060.

The central structure 1010 is an amino acid and includes a residue 1011.

The two connecting structures are a first connecting structure and a second connecting structure and connected to the central structure 1010, respectively. The first connecting structure is an amine group (not shown in drawings), and the second connecting structure is a carboxyl group (not shown in drawings).

The side-chain structure 1030 is formed by a first short chain 1031 connected to a second short chain 1032. The first short chain 1031 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 1032 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 1030 is connected to the second connecting structure to form an ester bond 1022′.

The side-chain structure 1040 is a fatty acid. The side-chain structure 1040 is connected to the first connecting structure to form an amide bond 1021′.

The polar functional group 1060 is connected to the side-chain structure 1030.

11th Embodiment

FIG. 11 is a structural schematic view of a molecule of a plasticizer 1100 according to the 11th embodiment of the present disclosure. In FIG. 11, the molecule of the plasticizer 1100 according to the 11th embodiment includes a central structure 1110, three connecting structures, three side-chain structures 1130, 1140, 1150 and a polar functional group 1160.

The central structure 1110 includes two amino acids, and each of the two amino acids includes a residue 1111, 1112.

The three connecting structures are a first connecting structure, a second connecting structure and a third connecting structure and connected to the central structure 1110, respectively. The first connecting structure is an amine group (not shown in drawings), and each of the second connecting structure and the third connecting structure is a carboxyl group (not shown in drawings). The third connecting structure is connected to the residue 1111.

The side-chain structure 1130 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The side-chain structure 1130 is connected to the second connecting structure to form an ester bond 1122′.

The side-chain structure 1140 is a fatty acid. The side-chain structure 1140 is connected to the first connecting structure to form an amide bond 1121′.

The side-chain structure 1150 is formed by a first short chain 1151 connected to a second short chain 1152. The first short chain 1151 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 1152 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 1150 is connected to the third connecting structure to form an ester bond 1123′.

The polar functional group 1160 is connected to the side-chain structure 1150.

12th Embodiment

FIG. 12 is a structural schematic view of a molecule of a plasticizer 1200 according to the 12th embodiment of the present disclosure. In FIG. 12, the molecule of the plasticizer 1200 according to the 12th embodiment includes a central structure 1210, three connecting structures and three side-chain structures 1230, 1240, 1250.

The central structure 1210 includes two amino acids, and each of the two amino acids includes a residue 1211, 1212.

The three connecting structures are a first connecting structure, a second connecting structure and a third connecting structure and connected to the central structure 1210, respectively. Each of the first connecting structure and the third connecting structure is an amine group (not shown in drawings), and the second connecting structure is a carboxyl group (not shown in drawings). The third connecting structure is connected to the residue 1212.

The side-chain structure 1230 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The side-chain structure 1230 is connected to the second connecting structure to form an ester bond 1222′.

The side-chain structure 1240 is a fatty acid. The side-chain structure 1240 is connected to the first connecting structure to form an amide bond 1221′.

The side-chain structure 1250 is a fatty acid. The side-chain structure 1250 is connected to the third connecting structure to form an amide bond 1223′.

13th Embodiment

FIG. 13 is a structural schematic view of a molecule of a plasticizer 1300 according to the 13th embodiment of the present disclosure. In FIG. 13, the molecule of the plasticizer 1300 according to the 13th embodiment includes a central structure 1310, four connecting structures, three side-chain structures 1330, 1340, 1350 and a polar functional group 1360.

The central structure 1310 includes three amino acids, and each of the three amino acids includes a residue 1311, 1312, 1313.

The four connecting structures are a first connecting structure, a second connecting structure, a third connecting structure and a fourth connecting structure and connected to the central structure 1310, respectively. The first connecting structure is an amine group 1321, each of the second connecting structure and the third connecting structure is a carboxyl group (not shown in drawings), and the fourth connecting structure is an amine group (not shown in drawings). The third connecting structure and the fourth connecting structure are connected to the residue 1311 and the residue 1313, respectively.

The side-chain structure 1330 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The side-chain structure 1330 is connected to the second connecting structure to form an ester bond 1322′.

The side-chain structure 1340 is formed by a first short chain 1341 connected to a second short chain 1342. The first short chain 1341 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. The second short chain 1342 is formed by polymerization with propylene glycol or polypropylene glycol as monomers. The side-chain structure 1340 is connected to the third connecting structure to form an ester bond 1323′.

The side-chain structure 1350 is a fatty acid. The side-chain structure 1350 is connected to the fourth connecting structure to form an amide bond 1324′.

The polar functional group 1360 is connected to the side-chain structure 1330.

14th Embodiment

FIG. 14 is a structural schematic view of a molecule of a plasticizer 1400 according to the 14th embodiment of the present disclosure. In FIG. 14, the molecule of the plasticizer 1400 according to the 14th embodiment includes two central structures 1410a, 1410b, two connecting structures, a side-chain structure 1430 and two polar functional groups 1460a, 1460b.

Each of the central structures 1410a, 1410b is a benzene derivative.

Each of the central structures 1410a, 1410b is connected to the corresponding one of the connecting structures, that is, the central structure 1410a is connected to one of the connecting structures, and the central structure 1410b is connected to the other one of the connecting structures. Both of the connecting structures are carboxyl groups (not shown in drawings).

The side-chain structure 1430 is formed by polymerization with ethylene glycol or polyethylene glycol as monomers. Each of the central structures 1410a, 1410b is connected to the side-chain structure 1430 through the connecting structure to form an ester bond 1420a, 1420b.

Each of the polar functional groups 1460a, 1460b is connected to the corresponding one of the central structures 1410a, 1410b.

According to the above description of the present disclosure, the following specific examples are provided for further explanation.

In the 1st Example to the 8th Example, the side-chain structures connected to the amine group, the carboxyl group and the hydroxyl group are named as SCA, SCC and SCH, respectively. For the molecule of the plasticizer including a plurality of the side-chain structures connected to a same functional group, for example, two side-chain structures are connected to the amine group in the 1st Example, so the two side-chain structures are named as SCA1 and SCA2, respectively. The names of other side-chain structures follow the same rule, and an explanation in this regard will not be provided again.

	1st Example	2nd Example
Central Structure	Aminobenzoic Acid	Aminobenzoic Acid
Structure of Para Position
SMILES Notation	C1═CC(═CC═C1C(═O)OC	C1═CC(═CC═C1C(═O)OC
	COCCOCCO[H])N(C(CCC	C(OCC(OCC(OCC(O[H])C)
	CCCC)═O)C(CCCCCCC)═O	C)C)C)N(C(CCCCCCC)═O)[H]
InChI Notation	InChI = 1S/C29H47NO7/c1-	InChI = 1S/C27H45NO7/c1-
	3-5-7-9-11-13-27(32)30(28	6-7-8-9-10-11-26(30)28-25-
	(33)14-12-10-8-6-4-2)26-17-	14-12-24(13-15-25)27(31)
	15-25(16-18-26)29(34)37-	35-19-23(5)34-18-22(4)33-
	24-23-36-22-21-35-20-19-	17-21(3)32-16-20(2)29/h12-
	31/h15-18, 31H, 3-14, 19-	15, 20-23, 29H, 6-11, 16-1
	24H2, 1-2H3	9H2, 1-5H3, (H, 28, 30)
Molecular Formula	C29H47NO7	C27H45NO7
Molecular Weight	521.693	495.655
MwP
(g/mol, Dalton)
Structure of Ortho Position	With Steric Hindrance
Structure of Meta Position
Side-Chain Structure SCA1 Connected to Amine Group
nNC	8	8
nNO	0	0
nNC/(nNC + nNO)	1	1
Polar Functional	—	—
Group
Side-Chain Structure SCA2 Connected to Amine Group
nNC	8	0
nNO	0	0
nNC/(nNC + nNO)	1	—
Polar Functional	—	—
Group
Side-Chain Structure SCC Connected to Carboxyl Group
nOC	6	12
nOO	2	3
nOC/(nOC + nOO)	0.75	0.80
Polar Functional	OH	OH
Group
Relationship Between Numbers of Atoms of
Side-Chain Structures SCA1, SCA2 and SCC
nNCSCA1/(nNCSCA1 +	0.6	0.4
nOCSCC)
nNCSCA2/(nNCSCA2 +	0.6	0.0
nOCSCC)
nNCSCA1/(nNCSCA1 +	0.8	0.7
nOOSCC)
nNCSCA2/(nNCSCA2 +	0.8	0.0
nOOSCC)
nNOSCA1/(nNOSCA1 +	0.0	0.0
nOCSCC)
nNOSCA2/(nNOSCA2 +	0.0	0.0
nOCSCC)
nNOSCA1/(nNOSCA1 +	0.0	0.0
nOOSCC)
nNOSCA2/(nNOSCA2 +	0.0	0.0
nOOSCC)

Furthermore, in the 1st Example to the 8th Example, a number of carbon atoms and a number of oxygen atoms of the side-chain structure SCA1 are nNC_SCA1 and nNO_SCA1, respectively. A number of carbon atoms and a number of oxygen atoms of the side-chain structure SCA2 are nNC_SCA2 and nNO_SCA2, respectively. A number of carbon atoms and a number of oxygen atoms of the side-chain structure SCC are nOC_SCC and nOO_SCC, respectively. SCA1, SCA2 and SCC are only for marking the side-chain structures to clearly understand the characteristics of the side-chain structures, and do not make a difference to the calculation of carbon atoms and oxygen atoms of nNO, nNC, nOC and nOO as claimed. That is, nNC_SCA1 is taken as nNC, nNO_SCA1 is taken nNO, nNC_SCA2 is taken as nNC, nNO_SCA2 is taken as nNO, nOC_SCC is taken as nOC and nOO_SCC is taken as nOO during calculation. The information in the following tables has the same definition, and an explanation in this regard will not be provided again.

	3rd Example	4th Example
Central Structure	Aminobenzoic Acid	Hydroxybenzoic Acid
Structure of Para Position
SMILES Notation	C1═CC(═CC═C1C(═O)OC	C1═CC(═CC═C1C(═O)OC
	COCCOCCOCCOCCO[H])	COCCOCCOCCCC)OCC
	N(C(CCCCCCC)═O)[H]	OCCOCCOCCCC
InChI Notation	InChI = 1S/C25H41NO8/c1-	InChI = 1S/C27H46O9/c1-3-
	2-3-4-5-6-7-24(28)26-23-10-	5-11-29-13-15-31-17-19-33-
	8-22(9-11-23)25(29)34-21-	21-23-35-26-9-7-25(8-10-
	20-33-19-18-32-17-16-31-	26)27(28)36-24-22-34-20-
	15-14-30-13-12-27/h8-11,	18-32-16-14-30-12-6-4-2/h
	27H, 2-7, 12-21H2, 1H3, (H,	7-10H, 3-6, 11-24H2, 1-2H3
	26, 28)
Molecular Formula	C25H41NO8	C27H46O9
Molecular Weight	483.601	514.655
MwP
(g/mol, Dalton)
Structure of Ortho Position
Structure of Meta Position
Side-Chain Structure SCA1 Connected to Amine Group
nNC	8	0
nNO	0	0
nNC/(nNC + nNO)	1	—
Polar Functional	—	—
Group
Side-Chain Structure SCA2 Connected to Amine Group
nNC	0	0
nNO	0	0
nNC/(nNC + nNO)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCC Connected to Carboxyl Group
nOC	10	10
nOO	4	3
nOC/(nOC + nOO)	0.71	0.77
Polar Functional	OH	—
Group
Relationship Between Numbers of Atoms of
Side-Chain Structures SCA1, SCA2 and SCC
nNCSCA1/(nNCSCA1 +	0.4	0.0
nOCSCC)
nNCSCA2/(nNCSCA2 +	0.0	0.0
nOCSCC)
nNCSCA1/(nNCSCA1 +	0.7	0.0
nOOSCC)
nNCSCA2/(nNCSCA2 +	0.0	0.0
nOOSCC)
nNOSCA1/(nNOSCA1 +	0.0	0.0
nOCSCC)
nNOSCA2/(nNOSCA2 +	0.0	0.0
nOCSCC)
nNOSCA1/(nNOSCA1 +	0.0	0.0
nOOSCC)
nNOSCA2/(nNOSCA2 +	0.0	0.0
nOOSCC)
Side-Chain Structure SCH1 Connected to Hydroxyl Group
nO′C	—	10
nO′O	—	3
nO′C/(nO′C + nO′O)	—	0.77
Polar Functional	—	—
Group
Side-Chain Structure SCH2 Connected to Hydroxyl Group
nO′C	—	0
nO′O	—	0
nO′C/(nO′C + nO′O)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCH3 Connected to Hydroxyl Group
nO′C	—	0
nO′O	—	0
nO′C/(nO′C + nO′O)	—	—
Polar Functional	—	—
Group

	5th Example	6th Example
Central Structure	Hydroxybenzoic Acid	Propane-1,2,3-Triol
Structure of Para Position
SMILES Notation	C1═CC(═CC═C1C(═O)OC	C(C(COCCOCCOCCC)O
	C(OCC(OCC(OCCCC)C)C)	CCOCCOCCC)OCCOCC
	C)OC(COC(COC(COC(C	OCCC
	CC)C)C)C)C
InChI Notation	InChI = 1S/C34H60O9/c1-10-	InChI = 1S/C24H50O9/c1-4-
	12-18-36-26(4)19-38-28	7-25-10-13-28-16-18-31-22-
	(6)21-40-30(8)23-42-34(35)	24(33-21-20-30-15-12-27-
	32-14-16-33(17-15-32)43-	9-6-3)23-32-19-17-29-14-
	31(9)24-41-29(7)22-39-27	11-26-8-5-2/h24H, 4-23H2,
	(5)20-37-25(3)13-11-2/h14-	1-3H3
	17, 25-31H, 10-13, 18-24H2,
	1-9H3
Molecular Formula	C34H60O9	C24H50O9
Molecular Weight	612.843	482.654
MwP
(g/mol, Dalton)
Structure of Ortho Position		—
Structure of Meta Position		—
Side-Chain Structure SCA1 Connected to Amine Group
nNC	0	0
nNO	0	0
nNC/(nNC + nNO)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCA2 Connected to Amine Group
nNC	0	0
nNO	0	0
nNC/(nNC + nNO)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCC Connected to Carboxyl Group
nOC	13	0
nOO	3	0
nOC/(nOC + nOO)	0.81	—
Polar Functional	—	—
Group
Relationship Between Numbers of Atoms of
Side-Chain Structures SCA1, SCA2 and SCC
nNCSCA1/(nNCSCA1 +	0.0	—
nOCSCC)
nNCSCA2/(nNCSCA2 +	0.0	—
nOCSCC)
nNCSCA1/(nNCSCA1 +	0.0	—
nOOSCC)
nNCSCA2/(nNCSCA2 +	0.0	—
nOOSCC)
nNOSCA1/(nNOSCA1 +	0.0	—
nOCSCC)
nNOSCA2/(nNOSCA2 +	0.0	—
nOCSCC)
nNOSCA1/(nNOSCA1 +	0.0	—
nOOSCC)
nNOSCA2/(nNOSCA2 +	0.0	—
nOOSCC)
Side-Chain Structure SCH1 Connected to Hydroxyl Group
nO′C	14	7
nO′O	3	2
nO′C/(nO′C + nO′O)	0.82	0.78
Polar Functional	—	—
Group
Side-Chain Structure SCH2 Connected to Hydroxyl Group
nO′C	0	7
nO′O	0	2
nO′C/(nO′C + NO′O)	—	0.78
Polar Functional	—	—
Group
Side-Chain Structure SCH3 Connected to Hydroxyl Group
nO′C	0	7
nO′O	0	2
nO′C/(nO′C + nO′O)	—	0.78
Polar Functional	—	—
Group

	7th Example	8th Example
Central Structure	Propane-1,2,3-Triol	2-(2-Hydroxyethoxy)
		Propan-1-ol
Structure
SMILES Notation	C(C(COC(COC(COCCC)C)	C(OC(COC(COCCCC(CC)
	C)OCCOCCOCCC)OC(C	CC)C)C)C(OCC(OCCCC
	OC(COCCC)C)C	(CC)CC)C)C
InChI Notation	InChI = 1S/C28H58O9/c1-8-	InChI = 1S/C28H58O5/c1-9-
	11-29-14-15-30-16-17-33-	27(10-2)15-13-17-29-19-23
	28(22-36-26(6)20-34-24(4)	(5)31-21-25(7)33-22-26(8)
	18-31-12-9-2)23-37-27(7)21-	32-20-24(6)30-18-14-16-28
	35-25(5)19-32-13-10-3/h	(11-3)12-4/h23-28H, 9-22
	24-28H, 8-23H2, 1-7H3	H2, 1-8H3
Molecular Formula	C28H58O9	C28H58O5
Molecular Weight	538.761	474.763
MwP
(g/mol, Dalton)
Side-Chain Structure SCA1 Connected to Amine Group
nNC	0	0
nNO	0	0
nNC/(nNC + nNO)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCA2 Connected to Amine Group
nNC	0	0
nNO	0	0
nNC/(nNC + nNO)	—	—
Polar Functional	—	—
Group
Side-Chain Structure SCC Connected to Carboxyl Group
nOC	0	0
nOO	0	0
nOC/(nOC + nOO)	—	—
Polar Functional	—	—
Group
Relationship Between Numbers of Atoms of
Side-Chain Structures SCA1, SCA2 and SCC
nNCSCA1/(nNCSCA1 +	—	—
nOCSCC)
nNCSCA2/(nNCSCA2 +	—	—
nOCSCC)
nNCSCA1/(nNCSCA1 +	—	—
nOOSCC)
nNCSCA2/(nNCSCA2 +	—	—
nOOSCC)
nNOSCA1/(nNOSCA1 +	—	—
nOCSCC)
nNOSCA2/(nNOSCA2 +	—	—
nOCSCC)
nNOSCA1/(nNOSCA1 +	—	—
nOOSCC)
nNOSCA2/(nNOSCA2 +	—	—
nOOSCC)
Side-Chain Structure SCH1 Connected to Hydroxyl Group
nO′C	9	11
nO′O	2	1
nO′C/(nO′C + nO′O)	0.82	0.92
Polar Functional	—	—
Group
Side-Chain Structure SCH2 Connected to Hydroxyl Group
nO′C	7	11
nO′O	2	1
nO′C/(nO′C + nO′O)	0.78	0.92
Polar Functional	—	—
Group
Side-Chain Structure SCH3 Connected to Hydroxyl Group
nO′C	9	0
nO′O	2	0
nO′C/(nO′C + nO′O)	0.82	—
Polar Functional	—	—
Group

	9th Example	10th Example	11th Example
IUPAC Name of	Glycine	Alanine	Valine
Central Structure
Structural Formula
Molecular Weight	75.07	89.09	117.15
MwP (g/mol)
Abbreviation 1	Gly	Ala	Val
Abbreviation 2	G	A	V
Residue Property	Hydrophilic	Hydrophobic	Hydrophobic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Side-Chain Structure Being PEG and PPG
Number of	12	12	12
PEG Monomers
Number of	0	0	0
PPG Monomers
Molecular
Weight, MwP	603.7	617.7	645.8
(g/mol, Dalton)
nNC	0	0	0
nOC	24	24	24
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	2	2	2
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	0	0	0
PEG Monomers
Number of	12	12	12
PPG Monomers
Molecular	772.0	786.0	814.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	36	36	36
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	6	6	6
PEG Monomers
Number of	6	6	6
PPG Monomers
Molecular	687.9	701.9	729.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	30	30	30
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	2	2	2
PEG Monomers
Number of	5	5	5
PPG Monomers
Molecular	453.6	467.6	495.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	19	19	19
nNO	0	0	0
nOO	7	7	7
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	5	5	5
PEG Monomers
Number of	2	2	2
PPG Monomers
Molecular	411.5	425.5	453.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	16	16	16
nNO	0	0	0.
nOO	7	7	7
nNC/(nNC + nOC)	0	0	0
nOC/nOO	2	2	2
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	5	5	5
PEG Monomers
Number of	5	5	5
PPG Monomers
Molecular	585.7	599.8	627.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	25	25	25
nNO	0	0	0
nOO	10	10	10
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	4	4	4
PEG Monomers
Number of	4	4	4
PPG Monomers
Molecular	483.6	497.6	525.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	20	20	20
nNO	0	0	0
nOO	8	8	8
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	8	8	8
PEG Monomers
Number of	8	8	8
PPG Monomers
Molecular	892.1	906.1	934.2
Weight MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	40	40	40
nNO	0	0	0
nOO	16	16	16
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3	3
PEG Monomers
Number of	3	3	3
PPG Monomers
Fatty Acid	3	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	465.5	479.5	507.6
Weight, MwP
(g/mol, Dalton)
nNC	5	5	5
nOC	15	15	15
nNO	0	0	0
nOO	6	6	6
nNC/(nNC + nOC)	0.25	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	8	8	8
PPG Monomers
Fatty Acid	5	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	651.8	665.8	693.8
Weight, MwP
(g/mol, Dalton)
nNC	7	7	7
nOC	24	24	24
nNO	0	0	0
nOO	8	8	8
nNC/(nNC + nOC)	0.23	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	5	5	5
PEG Monomers
Number of	4	4	4
PPG Monomers
Fatty Acid	7	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	667.7	681.7	709.8
Weight, MwP
(g/mol, Dalton)
nNC	9	9	9
nOC	22	22	22
nNO	0	0	0
nOO	9	9	9
nNC/(nNC + nOC)	0.29	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	2	2	2
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	9	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	447.4	461.4	489.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11	11
nOC	10	10	10
nNO	0	0	0
nOO	4	4	4
nNC/(nNC + nOC)	0.52	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	5	5	5
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	11	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	607.6	621.6	649.6
Weight, MwP
(g/mol, Dalton)
nNC	13	13	13
nOC	16	16	16
nNO	0	0	0
nOO	7	7	7
nNC/(nNC + nOC)	0.45	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	5	5	5
PPG Monomers
Fatty Acid	13	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	589.5	603.5	631.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15	15
nOC	15	15	15
nNO	0	0	0
nOO	5	5	5
nNC/(nNC + nOC)	0.50	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	2	2	2
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	15	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	531.4	545.4	573.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17	17
nOC	10	10	10
nNO	0	0	0
nOO	4	4	4
nNC/(nNC + nOC)	0.63	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	0	0	0
PPG Monomers
Fatty Acid	34	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	593.1	607.2	635.2
Weight, MwP
(g/mol, Dalton)
nNC	36	36	36
nOC	0	0	0
nNO	0	0	0
nOO	0	0	0
nNC/(nNC + nOC)	1.00	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00	1.00
nNO/(nNO + nOC)	—	—	—
nNO/(nNO + nOO)	—	—	—

	12th Example	13th Example	14th Example
IUPAC Name of	Leucine	Isoleucine	Phenylala-nine
Central Structure
Structural Formula
Molecular Weight	131.17	131.17	165.19
MwP (g/mol)
Abbreviation 1	Leu	Ile	Phe
Abbreviation 2	L	I	F
Residue Property	Hydrophobic	Hydrophobic	Hydrophobic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Side-Chain Structure Being PEG and PPG
Number of	12	12	12
PEG Monomers
Number of	0	0	0
PPG Monomers
Molecular	659.8	659.8	693.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	24	24	24
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	2	2	2
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	0	0	0
PEG Monomers
Number of	12	12	12
PPG Monomers
Molecular	828.1	828.1	862.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	36	36	36
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	6	6	6
PEG Monomers
Number of	6	6	6
PPG Monomers
Molecular	744.0	744.0	778.0
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	30	30	30
nNO	0	0	0
nOO	12	12	12
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	2	2	2
PEG Monomers
Number of	5	5	5
PPG Monomers
Molecular	509.7	509.7	543.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	19	19	19
nNO	0	0	0
nOO	7	7	7
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/nNO + nOC)	0	0	0
nNO/nNO + nOO)	0	0	0
Number of	5	5	5
PEG Monomers
Number of	2	2	2
PPG Monomers
Molecular	467.6	467.6	501.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	16	16	16
nNO	0	0	0
nOO	7	7	7
nNC/nNC + nOC)	0	0	0
nOC/nOO	2	2	2
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	5	5	5
PEG Monomers
Number of	5	5	5
PPG Monomers
Molecular	641.8	641.8	675.9
Weight, MwP
(g/mol, Dalton)
nNc	0	0	0
nOC	25	25	25
nNO	0	0	0
nOO	10	10	10
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	4	4	4
PEG Monomers
Number of	4	4	4
PPG Monomers
Molecular	539.7	539.7	573.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	20	20	20
nNO	0	0	0
nOO	8	8	8
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Number of	8	8	8
PEG Monomers
Number of	8	8	8
PPG Monomers
Molecular	948.2	948.2	982.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0	0
nOC	40	40	40
nNO	0	0	0
nOO	16	16	16
nNC/(nNC + nOC)	0	0	0
nOC/nOO	3	3	3
nNO/(nNO + nOC)	0	0	0
nNO/(nNO + nOO)	0	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3	3
PEG Monomers
Number of	3	3	3
PPG Monomers
Fatty Acid	3	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	521.6	521.6	555.6
Weight, MwP
(g/mol, Dalton)
nNC	5	6	5
nOC	15	15	15
nNO	0	0	0
nOO	6	6	6
nNC/(nNC + nOC)	0.25	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	8	8	8
PPG Monomers
Fatty Acid	5	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	707.9	707.9	741.9
Weight, MwP
(g/mol, Dalton)
nNC	7	7	7
nOC	24	24	24
nNO	0	0	0
nOO	8	8	8
nNC/nNC + nOC)	0.23	0.23	0.23
nNC/nNC + nOO)	0.47	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	5	5	5
PEG Monomers
Number of	4	4	4
PPG Monomers
Fatty Acid	7	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	723.8	723.8	757.8
Weight, MwP
(g/mol, Dalton)
nNC	9	9	9
nOC	22	22	22
nNO	0	0	0
nOO	9	9	9
nNC/(nNC + nOC)	0.29	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	2	2	2
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	9	9	9
CH3(CH2), COOH,
n = ?
Molecular	503.5	503.5	537.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11	11
nOC	10	10	10
nNO	0	0	0
nOO	4	4	4
nNC/(nNC + nOC)	0.52	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	5	5	5
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	11	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	663.7	663.7	697.7
Weight, MwP
(g/mol, Dalton)
nNC	13	13	13
nOC	16	16	16
nNO	0	0	0
nOO	7	7	7
nNC/(nNC + nOC)	0.45	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	5	5	5
PPG Monomers
Fatty Acid	13	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	645.6	645.6	679.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15	15
nOC	15	15	15
nNO	0	0	0
nOO	5	5	5
nNC/(nNC + nOC)	0.50	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	2	2	2
PEG Monomers
Number of	2	2	2
PPG Monomers
Fatty Acid	15	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	587.5	587.5	621.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17	17
nOC	10	10	10
nNO	0	0	0
nOO	4	4	4
nNC/(nNC + nOC)	0.63	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00	0.00
Number of	0	0	0
PEG Monomers
Number of	0	0	0
PPG Monomers
Fatty Acid	34	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	649.2	649.2	683.3
Weight, MwP
(g/mol, Dalton)
nNC	36	36	36
nOC	0	0	0
nNO	0	0	0
nOO	0	0	0
nNC/(nNC + nOC)	1.00	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00	1.00
nNO/(nNO + nOC)	—	—	—
nNO/(nNO + nOO)	—	—	—

	15th Example	16th Example
IUPAC Name of	Tryptophan	Tyrosine
Central Structure
Structural Formula
Molecular Weight	204.23	181.19
MwP (g/mol)
Abbreviation 1	Trp	Tyr
Abbreviation 2	W	Y
Residue Property	Hydrophobic	Hydrophilic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure 1 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Representative Structure 2 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)	—
Representative Structure 3 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)	—
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	732.9	709.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	901.2	878.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	817.0	794.0
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	582.7	559.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	540.7	517.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	714.9	691.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	612.8	589.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	1021.3	998.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	594.7	571.6
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	780.9	757.9
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	6
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	796.9	773.8
Weight, MwP
(g/mol, Dalton)
nNC	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/n(NC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	576.6	553.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.62	0.52
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	6	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH
n = ?
Molecular	736.7	713.7
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	718.7	695.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	660.6	637.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	722.3	699.3
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	17th Example	18th Example
IUPAC Name of	Aspartate	Histidine
Central Structure
Structural Formula
Molecular Weight	133.1	155.16
MwP (g/mol)
Abbreviation 1	Asp	His
Abbreviation 2	D	H
Residue Property	Acidic	Basic
Representative Structure 1 as Side-Chain Structure Being PEG
Representative Structure 2 as Side-Chain Structure Being PEG		—
Representative Structure 1 as Side-Chain Structure Being PPG
Representative Structure 2 as Side-Chain Structure Being PPG		—
Representative Structure as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, H, n ≥ 3)
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	661.7	683.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	830.0	852.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	745.9	768.0
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	511.6	533.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	469.5	491.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	643.8	665.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	541.6	563.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	950.2	972.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	523.6	545.6
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH
n = ?
Molecular	709.8	731.9
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	725.7	747.8
Weight, MwP
(g/mol, Dalton)
nNC	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	505.4	527.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	665.6	687.6
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	647.6	669.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	589.4	611.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	651.2	673.2
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	19th Example	20th Example
IUPAC Name of	Asparagine	Glutamate
Central Structure
Structural Formula
Molecular Weight	132.12	147.13
MwP (g/mol)
Abbreviation 1	Asn	Glu
Abbreviation 2	N	E
Residue Property	Hydrophilic	Acidic
Representative Structure 1 as Side-Chain Structure Being PEG
Representative Structure 2 as Side-Chain Structure Being PEG	—
Representative Structure 1 as Side-Chain Structure Being PPG
Representative Structure 2 as Side-Chain Structure Being PPG	—
Representative Structure 1 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Representative Structure 2 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH,		—
n ≥ 3)
Representative Structure 3 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)		—
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	660.8	675.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	829.1	844.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	744.9	759.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	510.6	525.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	468.5	483.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	642.8	657.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	540.6	555.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	949.2	964.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	522.6	537.6
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	708.8	723.8
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	724.8	739.8
Weight, MwP
(g/mol, Dalton)
nNC	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	504.4	519.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.62
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	664.6	679.6
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.46
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	646.6	661.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	588.4	603.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH
n = ?
Molecular	650.2	665.2
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	21st Example	22nd Example
IUPAC Name of	Lysine	Glutamine
Central Structure
Structural Formula
Molecular Weight	146.19	146.15
MwP (g/mol)
Abbreviation 1	Lys	Gln
Abbreviation 2	K	Q
Residue Property	Basic	Hydrophilic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure 1 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Representative Structure 2 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH,		—
n ≥ 3)
Representative Structure 3 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)		—
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	674.8	674.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	843.1	843.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	759.0	758.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	524.7	524.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number Of	5	6
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	482.6	482.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	656.9	656.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	554.7	554.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	963.2	963.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	536.6	536.6
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH
n = ?
Molecular	722.9	722.8
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	738.8	738.8
Weight, MwP
(g/mol, Dalton)
nNO	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	518.5	518.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	678.7	678.6
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.46	0.45
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	660.6	660.6
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	602.5	602.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	664.3	664.2
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	23rd Example	24th Example
IUPAC Name of	Arginine	Serine
Central Structure
Structural Formula
Molecular Weight	174.2	105.09
MwP (g/mol)
Abbreviation 1	Arg	Ser
Abbreviation 2	R	S
Residue Property	Basic	Hydrophilic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure 1 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Representative Structure 2 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH,
n ≥ 3)
Representative Structure 3 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	702.8	633.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	871.1	802.0
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	787.0	717.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	552.7	483.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	510.6	441.5
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	684.9	615.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	582.7	513.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	991.3	922.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	3
CH3(CH2)nCOOH,
n = ?
Molecular	564.7	495.5
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	750.9	681.8
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	766.8	697.7
Weight, MwP
(g/mol, Dalton)
nNC	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.50
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	546.5	477.4
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	706.7	637.6
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	688.7	619.5
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	630.5	561.4
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	692.3	623.2
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	25th Example	26th Example
IUPAC Name of	Threonine	Methionine
Central Structure
Structural Formula
Molecular Weight	119.12	149.21
MwP (g/mol)
Abbreviation 1	Thr	Met
Abbreviation 2	T	M
Residue Property	Hydrophilic	Hydrophobic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure 1 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)
Representative Structure 2 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)		—
Representative Structure 3 as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)		—
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	647.8	677.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	816.1	846.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	731.9	762.0
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	497.6	527.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	455.5	486.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO+ nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	629.8	659.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	527.6	557.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOG	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	936.2	966.3
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid
CH3(CH2)nCOOH,	3	3
n = ?
Molecular	509.6	539.7
Weight, MwP
(g/mol, Dalton)
nNC	5	5
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.25
nNC/(nNC + nOO)	0.45	0.45
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	5
CH3(CH2)nCOOH,
n = ?
Molecular	695.8	725.9
Weight, MwP
(g/mol, Dalton)
nNC	7	7
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.23
nNC/(nNC + nOO)	0.47	0.47
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	7
CH3(CH2)nCOOH,
n = ?
Molecular	711.8	741.9
Weight, MwP
(g/mol, Dalton)
nNC	9	9
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.29
nNC/(nNC + nOO)	0.50	0.60
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	9
CH3(CH2)nCOOH,
n = ?
Molecular	491.4	521.5
Weight, MwP
(g/mol, Dalton)
nNC	11	11
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.52
nNC/(nNC + nOO)	0.73	0.73
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	11
CH3(CH2)nCOOH,
n = ?
Molecular	651.6	681.7
Weight, MwP
(g/mol, Dalton)
nNC	13	13
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.45
nNC/(nNC + nOO)	0.65	0.65
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	13
CH3(CH2)nCOOH,
n = ?
Molecular	633.6	663.7
Weight, MwP
(g/mol, Dalton)
nNC	15	15
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.50
nNC/(nNC + nOO)	0.75	0.75
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	15
CH3(CH2)nCOOH,
n = ?
Molecular	575.4	605.5
Weight, MwP
(g/mol, Dalton)
nNC	17	17
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.63
nNC/(nNC + nOO)	0.81	0.81
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	34
CH3(CH2)nCOOH,
n = ?
Molecular	637.2	667.3
Weight, MwP
(g/mol, Dalton)
nNC	36	36
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	1.00
nNC/(nNC + nOO)	1.00	1.00
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

	27th Example	28th Example
IUPAC Name of	Cysteine	Proline
Central Structure
Structural Formula
Molecular Weight	121.16	115.13
MwP (g/mol)
Abbreviation 1	Cys	Pro
Abbreviation 2	C	P
Residue Property	Hydrophilic	Hydrophobic
Representative Structure as Side-Chain Structure Being PEG
Representative Structure as Side-Chain Structure Being PPG
Representative Structure as Side-Chain Structure Being Fatty Acid (CH3(CH2)nCOOH, n ≥ 3)		—
Side-Chain Structure Being PEG and PPG
Number of	12	12
PEG Monomers
Number of	0	0
PPG Monomers
Molecular	649.8	643.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	24	24
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	0	0
PEG Monomers
Number of	12	12
PPG Monomers
Molecular	818.1	812.1
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	36	36
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	6	6
PEG Monomers
Number of	6	6
PPG Monomers
Molecular	734.0	727.9
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	30	30
nNO	0	0
nOO	12	12
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	2	2
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	499.7	493.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	19	19
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Molecular	457.6	451.6
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0	0
nOC/nOO	2	2
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	5	5
PEG Monomers
Number of	5	5
PPG Monomers
Molecular	631.8	625.8
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	25	25
nNO	0	0
nOO	10	10
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	4	4
PEG Monomers
Number of	4	4
PPG Monomers
Molecular	529.7	523.7
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	20	20
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Number of	8	8
PEG Monomers
Number of	8	8
PPG Monomers
Molecular	938.2	932.2
Weight, MwP
(g/mol, Dalton)
nNC	0	0
nOC	40	40
nNO	0	0
nOO	16	16
nNC/(nNC + nOC)	0	0
nOC/nOO	3	3
nNO/(nNO + nOC)	0	0
nNO/(nNO + nOO)	0	0
Side-Chain Structure Being PEG, PPG and Fatty Acid
Number of	3	3
PEG Monomers
Number of	3	3
PPG Monomers
Fatty Acid	3	0
CH3(CH2)nCOOH,
n = ?
Molecular	511.6	421.5
Weight, MwP
(g/mol, Dalton)
nNC	5	0
nOC	15	15
nNO	0	0
nOO	6	6
nNC/(nNC + nOC)	0.25	0.00
nNC/(nNC + nOO)	0.45	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	8	8
PPG Monomers
Fatty Acid	5	—
CH3(CH2)nCOOH,
n = ?
Molecular	697.9	579.8
Weight, MwP
(g/mol, Dalton)
nNC	7	0
nOC	24	24
nNO	0	0
nOO	8	8
nNC/(nNC + nOC)	0.23	0.00
nNC/(nNC + nOO)	0.47	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	4	4
PPG Monomers
Fatty Acid	7	—
CH3(CH2)nCOOH,
n = ?
Molecular	713.8	567.7
Weight, MwP
(g/mol, Dalton)
nNC	9	0
nOC	22	22
nNO	0	0
nOO	9	9
nNC/(nNC + nOC)	0.29	0.00
nNC/(nNC + nOO)	0.50	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	9	—
CH3(CH2)nCOOH,
n = ?
Molecular	493.5	319.4
Weight, MwP
(g/mol, Dalton)
nNC	11	0
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.52	0.00
nNC/(nNC + nOO)	0.73	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	5	5
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	11	—
CH3(CH2)nCOOH,
n = ?
Molecular	653.6	451.6
Weight, MwP
(g/mol, Dalton)
nNC	13	0
nOC	16	16
nNO	0	0
nOO	7	7
nNC/(nNC + nOC)	0.45	0.00
nNC/(nNC + nOO)	0.65	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	5	5
PPG Monomers
Fatty Acid	13	—
CH3(CH2)nCOOH,
n = ?
Molecular	635.6	405.5
Weight, MwP
(g/mol, Dalton)
nNC	15	0
nOC	15	15
nNO	0	0
nOO	5	5
nNC/(nNC + nOC)	0.50	0.00
nNC/(nNC + nOO)	0.75	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	2	2
PEG Monomers
Number of	2	2
PPG Monomers
Fatty Acid	15	—
CH3(CH2)nCOOH,
n = ?
Molecular	577.5	319.4
Weight, MwP
(g/mol, Dalton)
nNC	17	0
nOC	10	10
nNO	0	0
nOO	4	4
nNC/(nNC + nOC)	0.63	0.00
nNC/(nNC + nOO)	0.81	0.00
nNO/(nNO + nOC)	0.00	0.00
nNO/(nNO + nOO)	0.00	0.00
Number of	0	0
PEG Monomers
Number of	0	0
PPG Monomers
Fatty Acid	34	0
CH3(CH2)nCOOH,
n = ?
Molecular	639.2	115.1
Weight, MwP
(g/mol, Dalton)
nNC	36	0
nOC	0	0
nNO	0	0
nOO	0	0
nNC/(nNC + nOC)	1.00	—
nNC/(nNC + nOO)	1.00	—
nNO/(nNO + nOC)	—	—
nNO/(nNO + nOO)	—	—

FIG. 15 shows results of biodegradation tests of the comparison, the 29th Example and the 30th Example. The biodegradation tests (ASTM 5338) of the plasticizers with different molecular structures are performed below. The comparison, the 29th Example and the 30th Example are tested, and the degrees of degradation under different days are listed in the following table.

	Comparison	29th Example	30th Example
Central	Citric Acid	Amino Acid	Bezene Derivative
Structure	Derivative	Derivative
Product	Acetyl Tributyl	Dioctyl	Ethylene Glycol
Name	Citrate	DL-Aspartate	Disalicylate
Structural Formula
Reactant 1		Aspartate	Salicylic Acid
Reactant 2		Octanol	Ethylene Glycol
days	Degree of Degradation (%)
0	0	0	0
3	1.53	6.70	3.21
7	13.22	8.53	1.97
12	20.84	20.53	1.09
15	25.38	26.53	1.87
19	26.71	35.22	4.13
24	28.89	44.08	6.63
28	30.29	48.75	13.13
33	29.64	51.62	17.63
36	33.87	53.72	26.70
40	33.87	55.78	33.47
45	34.64	57.19	38.10
49	39.24	58.41	43.93
54	39.81	59.35	47.28
58	41.33	59.61	60.14
63	42.10	59.85	67.90
67	41.59	60.34	69.50
71	42.04	62.58	71.37
75	42.47	63.96	72.99
81	42.89	63.75	73.19
85	44.19	62.72	73.19
89	44.65	64.14	73.53
93	44.65	65.04	78.89
98	44.24	65.04	78.51
102	44.86	66.44	78.14
105	44.36	66.44	78.50
109	43.39	66.25	81.63
114	44.42	66.04	81.09
118	44.11	66.80	84.55
124	44.11	66.80	84.55
128	44.73	67.01	86.04
132	44.88	66.81	86.55
137	45.54	66.81	86.81
140	45.19	66.81	86.58
144	45.51	66.01	86.58
147	45.18	64.81	87.69
151	45.18	64.62	88.54
155	45.18	64.23	88.54
158	45.00	65.50	87.80
161	45.00	66.30	87.80
165	45.00	66.92	87.80
168	44.78	65.84	88.40
172	43.19	67.51	89.55
175	43.19	69.97	89.91
179	42.55	71.93	91.46

According to the present disclosure, the biodegradable plasticizer is developed by investigating a novel molecular structure. The plasticizer has the abilities of improving the plastic texture, meeting the requirements for widespread applications, and further enhancing the degradation and cycle of the plastic. The plasticizer includes the first connecting structure and the second connecting structure, includes the benzene derivative and/or the amino acid as the central structure, and is grafted with the side-chain structure of the chain with multiple carbon atoms. The plasticizer can further include the polar functional group to adjust the hydrophilicity and hydrophobicity of the plasticizer. The plasticizer, which reaches desire durability, heat resistance, impact resistance and flexibility, and is harmless to human body, hard to release and low-cost, is developed to meet the target of high biodegradability.

The foregoing description, for purpose of explanation, has been described with reference to specific embodiments and examples. It is to be noted that Tables show different data of the different examples; however, the data of the different examples are obtained from experiments. The embodiments and examples were chosen and described in order to best explain the principles of the disclosure and its practical applications, to thereby enable others skilled in the art to best utilize the disclosure and various embodiments or examples with various modifications as are suited to the particular use contemplated. The embodiments and examples depicted above and the appended drawings are exemplary and are not intended to be exhaustive or to limit the scope of the present disclosure to the precise forms disclosed. Many modifications and variations are possible in view of the above teachings,

Claims

1. A plasticizer, which is biodegradable, a molecule of the plasticizer comprising: a central structure comprising at least one of a benzene derivative and at least one amino acid;at least two connecting structures respectively connected to the central structure, wherein the at least two connecting structures comprise: a first connecting structure, which is an amine group; anda second connecting structure, which is a carboxyl group; andat least one side-chain structure, wherein the at least one side-chain structure is a chain of multiple carbon atoms, the at least one side-chain structure is connected to at least one of the first connecting structure and the second connecting structure, an amide bond is formed as the at least one side-chain structure connected to the amine group, and an ester bond is formed as the at least one side-chain structure connected to the carboxyl group;wherein a number of carbon atoms of the side-chain structure which is connected to the amine group is nNC, a number of carbon atoms of the side-chain structure which is connected to the carboxyl group is nOC, and the following condition is satisfied: 0≤nNC/(nNC+nOC)≤1.00;wherein each of nNC and nOC is 0 or positive integer, but nNC and nOC are not 0 at the same time.

2. The plasticizer of claim 1, wherein the central structure is the benzene derivative.

3. The plasticizer of claim 2, wherein the central structure further comprises the at least one amino acid.

4. The plasticizer of claim 1, wherein the central structure is the at least one amino acid.

5. The plasticizer of claim 4, wherein a residue of the at least one amino acid is acidic.

6. The plasticizer of claim 5, wherein the at least one amino acid is aspartate.

7. The plasticizer of claim 4, wherein the central structure comprises at least two of the amino acid.

8. The plasticizer of claim 1, wherein a hydroxyl group is substituted for the amine group of the first connecting structure, and an ether bond is formed as the at least one side-chain structure connected to the hydroxyl group.

9. The plasticizer of claim 1, wherein a molecular weight of the plasticizer is MwP, and the following condition is satisfied: 450 Dalton ≤MwP.

10. The plasticizer of claim 1, further comprising: at least one polar functional group connected to the at least one side-chain structure, wherein the at least one polar functional group is a carboxyl group, a hydroxyl group, an amine group or a phosphoryl group.

11. The plasticizer of claim 10, wherein the plasticizer comprises at least two of the polar functional group, which are selected from the group consisting of the carboxyl group, the hydroxyl group, the amine group and the phosphoryl group.

12. A plastic product, which is biodegradable, comprising: the plasticizer of claim 1; anda polyester plastic, wherein the polyester plastic is a polylactic acid, a polybutylene succinate, a polybutylene adipate-co-terephthalate) or a polyhydroxyalkanoate;wherein the plasticizer is mixed with the polyester plastic.

13. A plasticizer, which is biodegradable, a molecule of the plasticizer comprising: at least two central structures, wherein each of the central structures comprises at least one of a benzene derivative and at least one amino acid;at least two connecting structures, wherein each of the connecting structures is a carboxyl group, and each of the central structures is connected to at least one of the connecting structures; anda side-chain structure, wherein the side-chain structure is a chain of multiple carbon atoms, each of the central structures is connected to the side-chain structure through the connecting structures, and an ester bond is formed as the side-chain structure connected to each of the carboxyl groups.