Claims
- 1. An electroless gold plating composition comprising:a) one or more water soluble gold compounds; b) one or more gold complexing agents; c) one or more organic stabilizer compounds of the formula R—SO2—Y wherein R is (C1-C18)alkyl, aryl, or heteroaryl and Y is hydrogen or a monovalent cation; and d) one or more uniformity enhancers.
- 2. The composition of claim 1 wherein the gold compound is an alkali metal gold thiosulfate compound.
- 3. The composition of claim 1 wherein the one or more water soluble gold compounds are present in an amount of 0.1 to 60 g/L.
- 4. The composition of claim 3 wherein the one or more water soluble gold compounds are present in an amount of 0.5 to 15 g/L.
- 5. The composition of claim 1 wherein R is phenyl, tolyl, xylyl, naphthyl, or bisphenol A.
- 6. The composition of claim 1 wherein Y is hydrogen or sodium.
- 7. The composition of claim 1 wherein the one or more organic stabilizer compounds are present in an amount of at least 2 g/L.
- 8. The composition of claim 1 wherein the gold complexing agent is a thiosulfate salt.
- 9. The composition of claim 1 wherein the one or more uniformity enhancers are selected from the group consisting of oxalic acid, ascorbic acid, citric acid, malic acid, glycolic acid, malonic acid, lactic acid, oxalactic acid, tartaric acid, phthalic acid, adipic acid, succinic acid and glutaric acid.
- 10. The composition of claim 1 wherein the uniformity enhancer is oxalic acid.
- 11. The composition of claim 1 wherein the uniformity enhancer is present in an amount of 0.1 to 50 g/L.
- 12. The composition of claim 11 wherein the uniformity enhancer is present in an amount of 1 to 15 g/L.
- 13. The composition of claim 1 wherein the composition is substantially free of cyanide ion and sulfite ion.
- 14. An electroless gold plating composition consisting essentially of:a) one or more water soluble gold compounds; b) one or more gold complexing agents; c) one or more organic stabilizer compounds of the formula R—SO2—Y wherein R is (C1-C18)alkyl, aryl, or heteroaryl and Y is hydrogen or a monovalent cation; and d) one or more uniformity enhancers.
- 15. An electroless gold plating composition consisting essentially of:a) one or more water soluble gold compounds; b) one or more gold complexing agents selected from the group consisting of thiosulfuric acid or an alkali metal thiosulfate salt; c) one or more organic stabilizer compounds of the formula R—SO2—Y wherein R is (C1-C18)alkyl, aryl, or heteroaryl and Y is hydrogen or a monovalent cation; and d) oxalic acid.
- 16. A method of electrolessly depositing gold on a substrate comprising the step of contacting a substrate with the composition of claim 1.
- 17. A method pf depositing gold on a metal that is less electropositive than gold comprising contacting a substrate containing a metal that is less electropositive than gold with the composition of claim 1.
- 18. A method of manufacturing an electronic device comprising depositing a gold layer comprising the step of contacting an electronic device substrate with a composition comprising:a) one or more water soluble gold compounds; b) one or more gold complexing agents; c) one or more organic stabilizer compounds of the formula R—SO2—Y wherein R is (C1-C18)alkyl, aryl, or heteroaryl and Y is hydrogen or a monovalent cation; and d) and one or more carboxylic acid uniformity enhancers; for a period of time sufficient to deposit the desired gold layer.
- 19. The method of claim 18 wherein the electronic device substrate comprises a metal that is less electropositive than gold.
- 20. The method of claim 18 wherein the electronic device substrate is selected from the group consisting of printed wiring board substrates, integrated circuits, lead frames, pads on wafers and ceramic packages.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims the benefit under 35 U.S.C. § 119(e) of U.S. Provisional Application Nos. 60/350,084 filed Oct. 25, 2001 and 60/339,659 filed Dec. 12, 2001, the entire contents of which applications are incorporated herein by reference.
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Provisional Applications (2)
|
Number |
Date |
Country |
|
60/350084 |
Oct 2001 |
US |
|
60/339659 |
Dec 2001 |
US |