Patent Application
20220258085
The present disclosure relates to polymer-based films or sheets. More specifically, the present disclosure relates to foldable or pleatable polymeric or plastic sheets containing apertures.
The presence of polymeric or plastic films or sheets can be found in virtually all aspects of everyday modern life. From their use as barriers for weeds or mulch in the garden, to roofing and insulation of buildings, to air or liquid filters for heating, ventilation or air conditioning (HVAC) or semiconductor assembly, these polymeric sheets find applicability in both simple, low technologies as well as complex, high technologies. Because of their relatively low cost and abundant supply, the volume of polymeric material used annually continues to increase. As a result, the amount of used or discarded plastic also continues to build up as harmful waste to our natural ecosystem.
In order to minimize the damage caused to the environment by excessive plastic waste build up, many manufacturers now turn to biodegradable polymers or plastics which can provide the same benefits but would be able to naturally degrade under normal environmental conditions over a certain period of time. Some of the concerns raised with the replacement of conventional, non-biodegradable plastics or polymers with biodegradable plastics or polymers is whether there is sufficient hardness or tensile strength for the intended use, and the ease and cost of manufacture.
To address these concerns, improved biodegradable polymeric or plastic materials are continuously desired. Further, it is desirable to be able to provide polymeric or plastic films or sheets which are able to meet industry needs while also requiring overall less material, and thereby increase efficiency as well as reduce waste.
The present disclosure addresses the aforementioned concerns by providing a polymeric plasticized film or sheet having one or more apertures to reduce the amount of material needed, as well as overall weight, per desired volume of material required. The polymeric plasticized film or sheet may also be capable of folding and keeping the crease for a desired amount of time. The polymeric plasticized film or sheet may be biodegradable.
According to an exemplary embodiment, a gas filter may be provided having a polymeric sheet as a substrate. The polymeric sheet may comprise at least one polymer, and a material capable of acting as a plasticizer. The sheet may have one or more apertures, and further have at least one crease to form a pleat within the sheet. In addition, the material may have a tensile modulus in the range of about 1.75 to 1.35 GPa when measured in accordance with ASTM E111-97 method for determining Tensile Modulus.
In some embodiments, the sheet has the configuration of a mesh, netting, fabric, knit, or weave. The one or more apertures may be provided as pores or perforations. These pores or perforations may further be diamond shaped.
Further, the sheet may include a plurality of pleats extending across its surface. The pleats may be uniformly spaced across the surface of the sheet, or the pleats may be non-uniformly spaced across the surface of the sheet.
At least one polymer may be a biopolymer and/or a biodegradable polymer. In some embodiments, the at least one polymer may be selected from the group consisting of polymers from biomass, polymers obtained by microbial production, polymers chemically synthesized using monomers obtained from agro-resources, bio-polymers whose monomers and polymers are both obtained by chemical synthesis from fossil resources, polylactic acid (PLA), poly(hydroxyalkanoates) (PHAs), polybutylene adipate terephthalate (PBAT), polybutylene succinate (Bio-PBS), polyvinyl alcohol (PVOH), ethylene vinyl alcohol (EVOH), and polycaprolactone (PCL).
The plasticizer material may also be a biopolymer. In some embodiments, the plasticizer material may be selected from the group consisting of polymers from biomass, polymers obtained by microbial production, polymers chemically synthesized using monomers obtained from agro-resources, bio-polymers whose monomers and polymers are both obtained by chemical synthesis from fossil resources, polyethylene glycol (PEG), polybutylene adipate terephthalate (PBAT), polybutylene succinate (Bio-PBS), polycaprolactone (PCL), and triacetin.
In some embodiments, the ratio of polymer to plasticizer material is in the range of about 95:5 to 55:45. In other embodiments, the ratio of polymer to plasticizer material is in the range of about 90:10 to 60:40. The sheet may have a thickness in the range of about 1 Mil (25.4 μm) to about 40 Mil (1,016 μm), and in some embodiments, may be in the range of about 1 Mil to about 20 Mil (or 25 μm to 508 μm). In some embodiments, an ideal thickness for the material may range from about 1.5 Mil to about 5 Mil (or 38.1 μm to 127 μm).
A method of manufacturing the polymeric sheet of the gas filter is also provided. The method may comprise providing at least one polymer, the polymer being biodegradable, providing a material capable of acting as a plasticizer, the plasticizer being biodegradable, forming a sheet of polymeric plasticized material from the at least one polymer and plasticizer, the sheet containing one or more apertures, and forming at least one pleat in the sheet by creasing the sheet without the addition of heat.
In some embodiments, the sheet of polymeric plasticized material may be formed as a mesh, netting, fabric, knit, or weave. For example, the sheet of polymeric plasticized material may be formed as a mesh, and the apertures may comprise diamond shaped openings.
In some embodiments, a plurality of pleats may be formed uniformly spaced apart across the surface of the sheet. In other embodiments, a plurality of pleats may be formed non-uniformly spaced apart across the surface of the sheet.
In accordance with another exemplary embodiment, a polymeric sheet is provided. The polymeric sheet may comprise at least one polymer, and a material capable of acting as a plasticizer, the sheet having one or more apertures for flow of gas or liquid therethrough, and further being capable of forming at least one pleat in the sheet by creasing the sheet without the addition of heat. The material may have a tensile modulus in the range of about 1.75 to 1.35 GPa when measured in accordance with ASTM E111-97 method for determining Tensile Modulus. The ratio of polymer to plasticizer material of the sheet may range from about 95:5 to about 55:45, and in some embodiments, may range from about 90:10 to 60:40.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the disclosure. Additional features of the disclosure will be set forth in part in the description which follows or may be learned by practice of the disclosure.
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate several embodiments of the disclosure and together with the description, serve to explain the principles of the disclosure.
This description and the accompanying drawings illustrate exemplary embodiments and should not be taken as limiting, with the claims defining the scope of the present disclosure, including equivalents. Various mechanical, compositional, structural, and operational changes may be made without departing from the scope of this description and the claims, including equivalents. In some instances, well-known structures and techniques have not been shown or described in detail so as not to obscure the disclosure. Like numbers in two or more figures represent the same or similar elements. Furthermore elements and their associated aspects that are described in detail with reference to one embodiment may, whenever practical, be included in other embodiments in which they are not specifically shown or described. For example, if an element is described in detail with reference to one embodiment and is not described with reference to a second embodiment, the element may nevertheless be claimed as included in the second embodiment. Moreover, the depictions herein are for illustrative purposes only and do not necessarily reflect the actual shape, size, or dimensions of the system or illustrated components.
It is noted that, as used in this specification and the appended claims, the singular forms “a,” “an,” and “the,” and any singular use of any word, include plural referents unless expressly and unequivocally limited to one referent. As used herein, the term “include” and its grammatical variants are intended to be non-limiting, such that recitation of items in a list is not to the exclusion of other like items that can be substituted or added to the listed items.
The present disclosure provides a polymeric plasticized film or sheet having one or more apertures to reduce the amount of material needed, as well as overall weight, per desired volume of material required. Additionally, the polymeric plasticized film or sheet may also be capable of folding and keeping the crease for a desired amount of time. The polymeric plasticized material which forms the film or sheet of the present disclosure may comprise at least one polymer, and a material capable of acting as a plasticizer with the at least one polymer. The polymeric plasticized film may be biodegradable.
In one embodiment, at least one of the polymers may be a biopolymer, or bio-based polymer. By biopolymer or bio-based polymer, what is meant is that the polymer breaks down under standard conditions within a certain timeframe, Suitable materials for the biopolymer or bio-based polymer may include: polymers from biomass, polymers obtained by microbial production, polymers chemically synthesized using monomers obtained from agro-resources, bio-polymers whose monomers and polymers are both obtained by chemical synthesis from fossil resources, polylactic acid (PLA), poly(hydroxyalkanoates) (PHAs), polybutylene adipate terephthalate (PBAT), polybutylene succinate (Bio-PBS), polyvinyl alcohol (PVOH), ethylene vinyl alcohol (EVOH), polycaprolactone (PCL), and the like, for example.
The material capable of acting as a plasticizer may also be a biopolymer, or bio-based polymer, and may be a bio-plasticizer. Suitable materials for the plasticizer may include: polymers from biomass, polymers obtained by microbial production, polymers chemically synthesized using monomers obtained from agro-resources, bio-polymers whose monomers and polymers are both obtained by chemical synthesis from fossil resources, polyethylene glycol (PEG), polybutylene adipate terephthalate (PBAT), polybutylene succinate (Bio-PBS), polycaprolactone (PCL), triacetin, and the like, for example.
As previously discussed, it is desirable to provide a polymer plasticized film or sheet that may be porous or perforated, in order to reduce the mass and weight needed for a desired volume of material. For example, in one embodiment, the film or sheet of polymer plasticized material may be provided in the form a netting, mesh, weave, knit, fabric, or other construct having one or more apertures or openings like pores or perforations. These pores or perforations may have a defined geometric shape, such as for example, a diamond, square, rhombus, circle, oval, or other similar configuration. Of course, it is understood that the pores or perforations may also have irregular geometric shapes as well. In some embodiments, the pores or perforations may be punched or cut out of the film or sheet of polymer plasticized material. For instance, elongate, X-, V- or C-shaped slits may be cut into the film or sheet such that, when the film or sheet is stretched or expanded, or rolled over itself, the slits expand to form the openings, pores or perforations.
Furthermore, as mentioned earlier, it is also desirable to be able to provide this polymer plasticized film or sheet having one or more apertures with folds. By folds, what is meant is that the film or sheet may be pleated, crimped, ridged, fluted, channeled, furrowed, grooved, crinkled, puckered, creased, crumpled, or otherwise corrugated in such a way as to have rows of folds. These rows of folds may be formed as a series of waves. The folds or pleats may be uniformly spaced across the film or sheet of polymer plasticized material, or they may be non-uniformly spaced across the film or sheet of polymer plasticized material.
Of relevance, it is desirable to be able to fold or pleat the film or sheet under ambient temperature conditions, without the requirement for additional heat. This type of cold pleating is particularly beneficial from a manufacturing perspective because the pleating or folding process of the film or sheet can be done at through-put speed, without the need to hold the film or sheet a certain amount of time under heat, in order to achieve the desired amount and level of folds or pleats. In addition, the integrity of the materials may be ensured since no concern of degradation due to the application of heat is involved.
In order to determine a suitable biodegradable polymer plasticized material that could achieve the desired results of the present disclosure, various materials of differing polymer to plasticizer ratios were tested for strength (tensile modulus in GPa) as well as for its ability to hold a fold or pleat for a certain period of time. The results are provided below.
Unfold Testing
What has been determined is that suitable ratios appear to be somewhere between 95:5 and 55:45, or 90:10 and 60:40. These polymer plasticized materials provided the adequate tensile strength (i.e., in the range of about 1.75 to 1.35 GPa when measured in accordance with ASTM D882 method for determining Tensile Strength) as well as ability to hold the pleat or fold such that the sheet can be crumpled, folded, wound, rolled, or otherwise compressed, into a desired volume for certain applications.
Table 2 above represents the material thicknesses of various samples of polymeric plasticized films or sheets of the present disclosure. It is contemplated that the material's thickness may vary from about 1 Mil (25.4 μm) to about 40 Mil (1,016 μm), and as shown in the table above, may be in the range of about 1 Mil to about 20 Mil (or 25 μm to 508 μm). In some embodiments, an ideal thickness for the material may range from about 1.5 Mil to about 5 Mil (or 38.1 μm to 127 μm).
Pleated, porous or perforated polymeric plasticized films or sheets may be used in a variety of different applications. The films or sheets may be laminated to other materials or substrates, and serve in a structural supportive capacity. The films or sheets may be a substitute for metal supports, such as metal netting or meshes, for example.
The film or sheet of polymer plasticized material may include pores, as shown. The porosity of the material may be in the range of about 40% to about 95%. In some embodiments, the film or sheet may comprise a mesh, and the pores may be shaped like diamonds, squares, or rhombuses. For instance, the mesh may be a net comprising a first set of substantially parallel filaments crossed with a second set of substantially parallel filaments to form a plurality of parallelograms having angles of 90 degrees, or a range of angles from 40 to 115 degrees, to form diamond-shaped pores. As shown in
Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the embodiment disclosed herein. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the embodiment being indicated by the following claims.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US20/34946 | 5/28/2020 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 62853354 | May 2019 | US |
