1. Field of the Invention
The present invention relates to a pneumatic tire, a producing method of the pneumatic tire, and a forming apparatus of a rubber strip winding body capable of discharging static electricity in a vehicle to a road surface even if silica-mixed rubber material is used for a rubber strip in a tire in which a tread rubber portion forming a tread-ground contact surface is made of rubber strip winding body.
2. Description of the Related Art
To satisfy both low rolling resistance and wet grip performance of a tire, it is conventional proposed to mix silica instead of carbon black as a filler of a tread rubber. However, since silica has poor conductivity, electric resistance of the tire is increased and static electricity is accumulated in a vehicle. This causes many electrical malfunctions including radio interference such as radio noise.
To prevent the static electricity from being accumulated, a structure (so-called base pen structure) shown in
In recent years, as shown in
On the other hand, this strip wind method has a problem that since the rubber strip (d) is continuously wound, it is difficult to apply this method to the base pen structure.
It is an object of the present invention to provide a pneumatic tire and a producing method of the pneumatic tire capable efficiently producing tire while taking advantage of merits of the strip wind method, excellently satisfying both low rolling resistance and wet grip performance, and suppressing electric resistance of a tread portion to a low level. It is another object of the invention to provide a forming apparatus of a rubber strip winding body capable of efficiently producing a rubber strip winding body used for the method.
A pneumatic tire of the present invention comprises a conductive tread conductive part which is disposed on an inner side of a tread portion and which is capable of being electrically continuous with a rim, and
Since the pneumatic tire of the invention has such a structure, it is possible to efficiently produce a tread rubber portion while taking advantage of merit of the strip wind method. It is possible to excellently satisfy both the low rolling resistance and the wet grip performance by using silica-mixed rubber as the rubber strip. Since the conductive film disposed on at least one surface of the rubber strip forms the conductive path, electric resistance of the tire can be reduced to low level, and it is possible to prevent static electricity in a vehicle from being accumulated.
FIGS. 4 (A) and 4 (B) are schematic sectional views of a base rubber layer forming step and a tread rubber portion forming step S2;
FIGS. 8 (A) and 8 (B) are schematic sectional views of a tread portion used for explaining background art.
An embodiment of the present invention will be explained together with illustrated examples.
In
The carcass 6 is formed of one or more carcass plies 6A (one carcass ply 6A in this example) in which a carcass cord is arranged at an angle of 70 to 90° with respect to a circumferential direction of the tire. The carcass ply 6A comprises toroidal ply bodies 6a extending between the bead cores 5 and 5, and a folded-back portion 6b extending from inner sides of the ply body 6a in an axial direction of the tire around the bead cores 5 and 5. The ply bodies 6a and the folded-back portion 6b are continuously formed. A bead-reinforcing bead apex rubber 8 is disposed between the ply body 6a and the folded-back portion 6b. The bead apex rubber 8 extends radially outward from the bead core 5.
The tread reinforcing cord layer 10 includes at least a belt 7 disposed radially outside of the carcass 6. In this example, the tread reinforcing cord layer 10 comprises the belt 7 and a band 9 superposed on an outer side of the belt 7. The belt 7 comprises two or more (two in this example) belt plies 7A and 7B in which band cords are arranged at an angle of 15 to 40° with respect to the circumferential direction of the tire. The band cords are intersecting between the plies, thereby enhancing the rigidity of the belt 7, and reinforcing substantially the entire width of the tread portion 2 with hoop effect. The band 9 comprises one or more band plies 9A (one band ply 9A in this example) in which the band cords are spirally wound at an angle of 5° or less with respect to the circumferential direction of the tire. The band ply 9A restrains the belt 7 and enhances the steering stability and high speed endurance. As the band ply 9A, a pair of left and right edge band plies for covering only an outer end of the belt 7 in the axial direction of the tire, and a full band ply which covers substantially the entire width of the belt 7 are known, and they can be used alone or in combination. In this example, the band 9 comprises one full band ply.
In the carcass ply 6A, the belt plies 7A and 7B and the band ply 9A, like the conventional tire, topping rubbers for covering the cords are made of conductive rubber composites using carbon black as rubber filler. The rubber composite has volume-intrinsic electrical resistance value of less than 1.0×108 (Ω·cm). With this, excellent conductive properties are given to the carcass 6, the belt 7 and the band 9 respectively. The “volume-intrinsic electrical resistance value of rubber” is a value measured using an electric resistance measuring device of ADVANTESTER8340A under conditions that voltage of 500 V is applied to a 15 cm2 rubber sample having 2 mm thickness at temperature of 25° C. and at humidity of 50%.
A sidewall rubber 3G which is adjacent to the outside of the carcass 6 and which forms an outer skin of the tire at the sidewall portion 3, and a rubber-deviation preventing clinch rubber 4G which is continuous with the sidewall rubber 3G at radially inner side and which forms an outer skin of the tire at the bead portion 4 and which comes into contact with a rim R are also made of conductive rubber composite whose volume-intrinsic electrical resistance value is less than 1.0×108 (Ω·cm) using carbon black as rubber filler like the conventional tire.
Next, a tread rubber 2G is disposed radially outside of the tread reinforcing cord layer 10. In this example, the tread rubber 2G comprises two layers, i.e., a base rubber layer 20 which is superposed on the tread reinforcing cord layer 10 and which is located radially inside, and a tread rubber portion 22 which is a so-called cap rubber layer 21 which is superposed radially outer side and whose radially outer surface forms a tread-ground contact surface TS.
The base rubber layer 20 is made of conductive rubber composite in which carbon black is used as the rubber filler and the volume-intrinsic electrical resistance value is less than 1.0×108 (Ω·cm). The base rubber layer 20 is electrically connected to the rim R through the tread reinforcing cord layer 10, the sidewall rubber 3G, the clinch rubber 4G and the like. Therefore, in this example, the base rubber layer 20 form a conductive tread conductive part 23 which is disposed inside of the tread portion 2 and which can be electrically connected to the rim R.
The tread rubber portion 22 (cap rubber layer 21) is made of rubber strip winding body in which a rubber strip 25 made of silica-mixed rubber as rubber filler is spirally wound and superposed in the circumferential direction. Since the tread rubber 22 is made of silica-mixed rubber, the wet grip performance of the tread rubber 2G is enhanced and rolling resistance on a dry road surface can be reduced.
In the case of the silica-mixed rubber, the amount of mixed silica is in a range of 30 to 100 parts by weight with respect to 100 parts by weight rubber base material. It is preferable that the lower limit value of the amount of mixed silica is 40 parts by weight, and the upper limit value thereof is 80 parts by weight, and more preferably 60 parts by weight. With this, it becomes possible to excellently satisfy both the low rolling resistance and wet grip performance. Examples of the rubber base material are natural rubber (NR), butadiene rubber (BR) which is polymer of butadiene, so-called styrene butadiene rubber (E-SBR) of emulsion polymerization, styrene butadiene rubber (S-SBR) of solution polymerization, composite polyisoprene rubber (IR) of isoprene polymer, nitrile rubber (NBR) which is copolymer of butadiene and acrylonitrile, and chloroprene rubber (CR) which is polymer of chloroprene. They can be used alone or in combination.
Silica to be mixed is not especially limited, but preferable silica is one showing colloidal characteristics in which nitrogen absorption specific surface (BET) is in a range of 150 to 250 m2*/g, oil suction amount of dibutyl phthalate (DBP) is 180 ml/100 g or more because reinforcing effect of rubber and rubber working performance are excellent. Preferable silane coupling agents are bis (triethoxy silil propyl) tetra sulfide, and α-mercapt propyl trimethoxy silane.
To give other rubber properties, i.e., rubber elasticity, rubber hardness and the like to the silica-mixed rubber, carbon black can be mixed accessorily. At that time, it is preferable that the amount of carbon black to be mixed to the silica-mixed rubber is smaller than the amount of mixed silica, and is 15 parts by weight or smaller with respect to 100 parts by weight rubber base material, and more preferably 10 parts by weight or smaller. If the amount of carbon black exceeds 15 parts by weight, the low rolling resistance caused by silica is deteriorated, the rubber is prone to be harder, and satisfactory rubber properties as the tread rubber portion 22 (cap rubber layer 21) can not easily be obtained. It is not preferable if the amount of silica to be mixed exceeds 100 parts by weight because it becomes difficult to mix carbon black to obtain the other rubber properties.
In this invention, to suppress the increase in tire electric resistance value caused by using the silica-mixed rubber for the tread rubber portion 22 (cap rubber layer 21), as shown in
In terms of discharging performance, it is preferable that the conductive path 27 is wound at least once, preferably three times or more in the circumferential direction of the tire. However, the conductive film 26 forming the conductive path 27 is a foreign matter and there is an adverse possibility that the conductive film 26 may cause peeling-off between the rubber strips 25 and 25. Therefore, it is preferable that the number of windings of the conductive path 27 is smaller than the total number of windings of the rubber strip 25, and the number of windings of the conductive path 27 is 50% or less of the total number of windings of the rubber strip 25, and more preferably 20% or less. The position where the conductive path 27 is formed is not especially limited only if the conductive path 27 is formed in a region other than in a vertical groove 28 extending in the circumferential direction of the tire, and this position is set in accordance with a tread pattern. In this regard, a tread central region Yc which is a width region of 50% of a tread ground-contact width TW around a tire equator C is preferable because the ground-contact length is long and stable grounding can be obtained. Since the conductive path 27 is continuous in the circumferential direction of the tire and its thickness is extremely thin, it is possible to suppress the deviated wear and adverse influence on running performance.
Next, a producing method of the pneumatic tire 1 having such a tread rubber portion 22 (cap rubber layer 21) will be explained.
In the pneumatic tire, when a raw tire 30 before vulcanization formation is to be produced, as shown in
The tire base body 31 comprises members other than the tread ring 32, e.g., the carcass ply 6A, the sidewall rubber 3G, the clinch rubber 4G, an inner liner rubber 1G and the bead apex rubber 8. Alternatively, the sidewall rubber 3G and the like may be adhered to an outer side of the carcass ply 6A after the tread ring 32 is adhered. To form the tread ring 32, the belt plies 7A and 7B and the band ply 9A are sequentially wound on a rotatable cylindrical drum 33, thereby forming the tread reinforcing cord layer 10, and the tread rubber 2G is formed on its outer peripheral surface, thereby producing the tread ring 32.
Here, steps other than a forming step S of the tread rubber 2G, e.g., a forming step of the tire base body 31, a forming step of the tread reinforcing cord layer 10 and the like are not especially limited, and conventionally known technique can appropriately be employed. Therefore, in this specification, only the forming step S of the tread rubber 2G which is different from the conventional technique will be explained.
In this example, the forming step S of the tread rubber 2G includes a base rubber layer forming step S1 and a tread rubber portion forming step S2. In the base rubber layer forming step S1 of this example, as shown in
In the tread rubber portion forming step S2, unvulcanized rubber strip 25 comprising the silica-mixed rubber is spirally superposed and wound around the outer peripheral surface of the base rubber layer 20 in the circumferential direction. With this, the tread rubber portion 22 (cap rubber layer 21) is formed as the rubber strip winding body. At that time, the conductive film 26 using conductive material is provided on at least one surface of the rubber strip 25 (outer surface of the rubber strip 25 facing radially outside at the time of winding in this example), and a conductive path 27 which is wound at least once is formed in the tread rubber portion 22.
In this example, when the rubber strip 25 is supplied to the drum 33, the conductive film 26 is formed by applying, to the rubber strip 25, conductive solution in which conductive material is dissolved or dispersed in solvent. As the conductive material, carbon and metal powder having excellent conductivity can preferably be used. Especially carbon is mixed in a normal tire rubber, and the carbon is preferable in terms of safety. Water and organic solvent can be used as the solvent, but organic solvent such as toluene and hexane is preferable in terms of drying time of applied conductive solution. It is also preferable that rubber is mixed in the solvent in a form of latex because this enhances adhering strength with respect to the rubber strip 25, enhances viscosity and secures sufficient thickness of the conductive film 26. At that time, the rubber to be mixed is preferably the same rubber as the rubber base material of the silica-mixed rubber which forms the rubber strip 25 (e.g., NR if the silica-mixed rubber is NR, and SBR if the silica-mixed rubber is SBR) in terms of adhering strength.
If a lateral sending pitch in the axial direction of the drum when the rubber strips 25 and 34 are spirally wound is controlled, cross sections of the base rubber layer 20 and the tread rubber portion 22 (cap rubber layer 21) into desired shapes. At that time, in this example, the rubber strips 25 and 34 are wound from one side to the other side of the tread rubber 2G in the same direction. With this, it is unnecessary to put the winding operation of the rubber strip 25 on standby until the formation of the base rubber layer 20 is completed. With this, the winding operation of the rubber strip 25 can be started slightly after the winding operation of the rubber strip 34, and the forming efficiency of the tread rubber 2G can be enhanced. To obtain the base rubber layer 20 and the tread rubber portion 22 (cap rubber layer 21) having desired cross sections, it is preferable to use, as the rubber strips 25 and 34, laterally long flat thin ribbon strips having width Ws of 5 to 20 mm and thickness Ts of 0.5 to 2.0 mm as shown in
In this example, an endless continuous cord-like transfer belt 46 is wound by a plurality of guide rollers 55 including the winding roller 44 such that the transfer belt 46 can be turned, and the rubber strip 25 is adhered to the transfer belt 46 and is transferred and supplied. In the drawing, a symbol 47 represents a motor which drives the transfer belt 46, a symbol 48 represents cutting means which cut the rubber strip 25 at desired length, a symbol 49 represents a guide rail which guides the moving stage 41 such that the moving stage 41 can move laterally, and the lateral sending pitch of the moving stage 41 is controlled by control means (not shown). The applying roller 45 can come into contact with and separate from the rubber strip 25 by expansion of a cylinder 50 or the like. The applying roller 45 can form the conductive path 27 at desired position of the tread rubber portion 22 (cap rubber layer 21) at desired number of windings.
In this invention, the base rubber layer 20 can also be formed by once winding an extruded product which is extruded from a rubber extruder with desired cross section shape without using the rubber strip winding body. The tread rubber 2G can also be formed using only the tread rubber portion 22 (cap rubber layer 21) without using the base rubber layer 20. In this case, the tread reinforcing cord layer 10 constitutes the tread conductive part 23.
According to the present invention, it is possible to form various tire rubber members other than the tread rubber portion 22 such as the sidewall rubber 3G, the inner liner rubber 1G, the clinch rubber 4G and the bead apex rubber 8 by means of the rubber strip winding body. Although especially preferable embodiment of the present invention has been described in detail, the invention is not limited to the illustrated embodiment, and the invention can variously be modified and carried out.
Pneumatic tires (size: 225/55R16) having the basic structure shown in
In the tires of the example of the present invention and comparative example, tread rubber portions (cap rubber layers) are formed by the strip wind method. The mixed amount of rubber strip in rubber is shown in Table 2. Only in the examples of the present invention, conductive solution is applied to one surface of the rubber strip to form a conductive film (conductive path). The same rubber (SBR) as that of the rubber base material of the tread rubber portion and carbon which was conductive material were dissolved in solvent (toluene), and this was used as the conductive solution. The mixed amount of carbon is 30 parts by weight with respect to 100 parts by weight rubber.
(1) Rolling Resistance:
A rolling resistance tester is used, and the rolling resistance was measured at three different running speeds, i.e., 40 km/h, 80 km/h, 120 km/h under conditions of rim (16×7JJ), internal pressure of 200 kPa and load of 4.8 kN. The rolling resistance of each running speed was converted into index in which rolling resistance of the tire of the comparative example 1 was set to 100, and average value of the converted values of the rolling resistance at each running speed was indicated as a rolling resistance index of each tire. The smaller the value is, the smaller and better the rolling resistance is.
(2) Electric Resistance of Tire
As shown in
A mold release agent and contamination are sufficiently eliminated from a surface of the tire T, the tire is sufficiently dried, the tire is mounted on a conductive rim (16×7JJ) made of aluminum alloy, and internal pressure (200 kPa) and load (5.3 kN: load of 80% of maximum load ability) are applied. Test environment temperature (test room temperature) is set to 25° C., and moisture is set to 50%. A surface of the metal plate 52 is polished, and electric resistance value is set to 10 Ω or less. Electric resistance value of the insulative plate 51 is set to 1012 Ω or more. A measuring range of the electric resistance measuring device 54 is 103 to 1.6×1016 Ω, and test voltage (applied voltage) is set to 1000 V.
The test is carried out in the following manner:
<1> A mold release agent and contamination are sufficiently eliminated from the tire T, the tire is sufficiently dried as described above, and the rim is mounted on the tire T using soapy water.
<2> The tire T is left for two hours in a test room and then, the tire is mounted on the tire mounting shaft 53.
<3> A break-in load operation is carried out. More concretely, the load (5.3 kN) is applied to the tire T for 0.5 minutes, the load is further applied for 0.5 minutes after release, and the load is further applied for two minutes after release.
<4> Then, the test voltage (1000 V) is applied and after five minutes elapsed, electric resistance value between the tire mounting shaft 53 and the metal plate 52 is measured by the electric resistance measuring device 54. The resistance value is measured at four positions separated from one another through 90° in the circumferential direction of the tire, and the maximum value is employed as the electric resistance value (measured value) of the tire T.
As shown in Table 1, in the case of the tire of the example of the invention, it can be confirmed that the electric resistance of the tire can be suppressed to a low value while maintaining excellent low rolling resistance even if the tread rubber portion (cap rubber layer) is formed by the strip wind method.
Number | Date | Country | Kind |
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2004-254581 | Sep 2004 | JP | national |