Patent Application
20090236022
The present invention relates to a pneumatic tire having a belt layer buried in a tread part thereof. More particularly, the present invention relates to a pneumatic tire with a durability improved by preventing the oxidation degradation of a belt layer.
There are factors adversely affecting the durability of a pneumatic tire having a belt layer buried in a tread part thereof. Such factors include separation of a cord and a coating rubber in both end portions, in the axial direction of the tire, of the belt layer. In particular, deterioration of the belt layer makes the separation of the cord and the coating rubber likely to occur. It has been pointed out that, in a process where air inside the tire permeates to the outside of the tire, oxygen in the air oxidizes the coating rubber of the belt layer, thus accelerating such deterioration of the belt layer.
In this respect, the following configuration for a pneumatic tire has been proposed. Specifically, a cord reinforcing layer is prepared by arranging multiple cords in the axial direction of the tire, and is buried in a buttress part of the pneumatic tire. In addition, the cord reinforcing layer includes a belt-inner-side part, an extending part, and a close part. The belt-inner-side part extends in a region below the belt layer. The extending part extends outward in the axial direction of the tire, and the close part is located close to the outer surface of the tire. With this configuration, air moving inside the tire is guided to the outside of the tire by using the cord reinforcing layer, so that a large amount of oxygen is prevented from passing through the vicinity of each end portion of the belt layer. As a result, the oxidation degradation of the coating rubber of the belt layer is suppressed (see, for example, Patent Document 1).
However, the following problem arises in the above-described pneumatic tire in which a cord reinforcing layer prepared by arranging multiple cords is buried in a buttress part thereof, and in which the end portion of the cord reinforcing layer is located close to the outer surface of the tire. Specifically, the buttress part is relatively frequently brought into contact with water at the time of running on a wet road surface. For this reason, if the end portion of the cord reinforcing layer is located close to the outer surface of the tire in the vicinity of the buttress part, water is fed to the belt layer via the cord reinforcing layer. In this event, the water accelerates deterioration of the belt cords, eventually leading to a reduction in the durability of the pneumatic tire. Moreover, the buttress part is deformed by a relatively large amount at the running of the tire. For this reason, if the end portion of the cord reinforcing layer is located close to the outer surface of the tire, damage is likely to originate at the close part, resulting in a cause of a reduction in the durability of the pneumatic tire as well. In other words, even if the oxidation degradation of the belt layer is prevented by using the cord reinforcing layer, an effect of improving the durability of the pneumatic tire cannot be sufficiently obtained.
An object of the present invention is to provide a pneumatic tire with a durability improved by preventing the oxidation degradation of a belt layer.
A pneumatic tire according to the present invention (a first invention) for achieving the above object has the following characteristics. The pneumatic tire includes: an air permeation preventive layer disposed in the inner surface of the tire; a belt layer buried in a tread part; and a cord layer formed by arranging a plurality of cords. The cord layer is disposed between the air permeation preventive layer and the belt layer, and extends to a bead part side further from a tire maximum width position. At least a part of the cord layer is located, close to the outer surface of the tire, at a position closer to the bead part side than the tire maximum width position, so that the distance between the cords and the outer surface of the tire is not more than 2 mm.
In the first invention, the cord layer is disposed between the air permeation preventive layer and the belt layer, and at least a part of the cord layer is located close to the outer surface of the tire. Accordingly, in a process where air inside the tire permeates to the outside of the tire, air moving toward the belt layer is taken in the cords of the cord layer. The air can thus be discharged to the outside of the tire from the part located close to the outer surface of the tire. This structure makes it possible to reduce the amount of oxygen passing through the belt layer, and thus to suppress the oxidation degradation of the belt layer. In this manner, the durability of the pneumatic tire can be improved.
Moreover, at least the part of the cord layer is located close to the outer surface of the tire at the position closer to the bead part side than the tire maximum width position. For this reason, it is possible to prevent the cord layer itself from becoming a cause of reduction in the durability. Specifically, consider the case where the part, located close to the outer surface of the tire, of the cord layer is disposed at the position close to the bead part. This disposition makes water unlikely to penetrate into the cord layer during the running of the tire on a wet road surface. Accordingly, water is prevented from being fed to the belt layer through the cord layer. In addition, the part closer to the bead part side than the tire maximum width position in the pneumatic tire has a relatively small amount of deformation occurring during the running of the tire. For this reason, when the part, located close to the outer surface of the tire, of the cord layer is disposed at the position close to the bead part, it is possible to make damage originating at the close part unlikely to occur. As a result, the effect of improving the durability using the cord layer can be taken advantage of to the maximum extent.
Note that, the cord layer guides, to the outside of the tire, only air having passed through the air permeation preventive layer. Since the performance of the pneumatic tire in maintaining the internal pressure is secured based on the air permeation preventive layer, the cord layer does not cause the performance of the pneumatic tire in maintaining the internal pressure to be reduced.
In the first invention, it is preferable that at least a part of the cord layer be located close to the outer surface of the tire, at a height in a range from 0.1H to 0.5H, from a bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire, so that the distance between the cords and the outer surface of the tire is not more than 2 mm. This makes it possible to more securely obtain the effect of improving the durability.
It is preferable a carcass layer laid between a pair of bead parts be used as the cord layer. The cord layer may be one different from the carcass layer, but it is desirable that the overlapping width, in the axial direction of the tire, of the cord layer and the belt layer be at least 10 mm from the end portion of the belt layer. This makes it possible to securely protect the vicinity, where separation failure is likely to occur, of the end portion of the belt layer. Note that, if the end portion of the cord layer is disposed in the region below the belt layer, the end portion becomes a factor of a failure. For this reason, it is favorable that the end portion of the cord layer is not disposed in the region below the belt layer.
On the other hand, a pneumatic tire according to the present invention (a second invention) for achieving the above-described object has the following characteristics. Specifically, the pneumatic tire includes: a carcass layer laid between a pair of bead parts; a belt layer buried on the outer circumferential side of the carcass layer in a tread part; and a cord layer formed by arranging cords in parallel. In addition, an inner part of the cord layer is disposed between the carcass layer and the belt layer. An outer part of the cord layer is disposed on the outer circumferential side of the belt layer, along the belt layer. Moreover, each cord of the cord layer is continuously extended, in a straddling manner, between the inner and outer parts.
In the second invention, the cord layer is disposed to sandwich the belt layer from the inner side and the outer side of the belt layer in the radial direction of the tire. In addition, the cords of the cord layer are extended continuously between the inner part and the outer part in the straddling manner. Accordingly, in a process where air inside the tire permeates to the outside of the tire, air moving toward the belt layer is taken in the cords of the cord layer before entering the belt layer. The air thereby can be bypassed to the outer circumferential side of the belt layer. This structure makes it possible to reduce the amount of air passing through the belt layer, and thus to suppress the oxidation degradation of the belt layer. In this manner, the durability of the pneumatic tire can be improved.
Moreover, the inner part of the cord layer is disposed between the carcass layer and the belt layer, while the outer part of the cord layer is disposed on the outer circumferential side of the belt layer, along the belt layer. Accordingly, it is possible to prevent the cord layer itself from becoming a cause of reduction in the durability. Specifically, the end portion of each of the inner part and the outer part of the cord layer is disposed at a position with a small amount of deformation occurring. Accordingly, damage originating at the end portions of the cord layer is unlikely to occur. As a result, the effect of improving the durability using the cord layer can be taken advantage of to the maximum extent.
In the second invention, it is preferable that the end portion of each of the inner and outer parts of the cord layer be disposed in a range from 10 mm to 40 mm, from an edge part of the belt layer with the widest width toward a tread center side. This makes it possible to sufficiently obtain the effect of suppressing the oxidation degradation of the belt layer while suppressing an increase in the weight.
In addition, it is preferable that the outer part of the cord layer be extended so as to overlap a groove formed in the tread part. This allows air bypassed by the cord layer to be discharged to the outside of the tire from the groove portion. In this case, it is preferable that the relation between a tread gauge (A) and a groove-bottom gauge (B) at the position of the groove be 0.03≦B/A≦0.5. Here, the tread gauge (A) is a gauge from the tread surface to the cords of the cord layer, while the groove-bottom gauge (B) is a gauge from the bottom of the groove to the cords of the cord layer. Specifically, it is preferable to reduce the groove-bottom gauge (B) relative to the tread gauge (A) for the air discharge. However, when the groove-bottom gauge is excessively reduced, cracking becomes likely to occur in the bottom of the groove. For this reason, when the above relation is satisfied, air bypassed by the cord layer can be effectively discharged to the outside of the tire while an occurrence of cracking in the bottom of the groove is avoided.
As each cord of the cord layer, an organic fiber cord or a metal cord may be used. In any case, it is preferable that each cord be a cord formed by twisting three or more strands in order to ensure the ventilation in the cords.
Hereinafter, the configuration of the present invention will be described in detail with reference to the accompanying drawings.
In the above-described pneumatic tire, the carcass layer 4 supports a function of maintaining the internal pressure of the tire, and concurrently functions as a cord layer for preventing the oxidation degradation of the belt layers 7. Specifically, the carcass layer 4 is disposed between the air permeation preventive layer 6 and the belt layers 7, and extends from a region below the belt layers 7 to each bead part 3 side further from the tire maximum width position P (a position at which a cross-sectional width of the tire is the maximum). In addition, as shown in the enlarged view of
In the above-described pneumatic tire, the carcass layer 4 is disposed between the air permeation preventive layer 6 and the belt layers 7, and at least a part of the carcass layer 4 is located close to the outer surface of the tire. Accordingly, in a process where air inside the tire permeates to the outside of the tire due to the difference in pressure between the inside and the outside of the tire, air moving toward the belt layers 7 is taken in the cords of the carcass layer 4. The air can thus be discharged to the outside of the tire from the part located close to the outer surface of the tire. This structure makes it possible to reduce the amount of oxygen passing through the belt layers 7, and thus to suppress the oxidation degradation of the coating rubber of the belt layers 7. In this manner, the durability of the pneumatic tire can be improved.
Moreover, the part, which is located close to the outer surface of the tire, of the carcass layer 4 is disposed at the position closer to the bead part 3 side than the tire maximum width position P. For this reason, the durability can be prevented from being reduced due to the structure of the carcass layer 4. Specifically, consider the case where the part, located close to the outer surface of the tire, of the carcass layer 4 is disposed at the position closer to the bead part 3 side than the tire maximum width position P. In this case, water is unlikely to penetrate into the carcass layer 4 during the running on a wet road surface. Accordingly, water is prevented from being fed to the belt layers 7 through the carcass layer 4. In addition, this disposition prevents an occurrence of damage, such as a sidewall blowout, which would otherwise originating at the close part located close to the outer surface of the tire due to deformation during the running of the tire.
In particular, when a part of the carcass layer 4 is located close to the outer surface of the tire, it is preferable that the part be disposed at a position of the height in the range X from 0.1H to 0.5H, from the bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire. When the part, located close to the outer surface of the tire, of the carcass layer 4 exists at a position of a height of less than 0.1H from the bead heel, the part is brought into contact with the rim flange to be worn down, thus becoming a cause of a failure. On the other hand, when the part exists at a position of a height more than 0.5H from the bead heel, water is likely to enter from the part, and concurrently a failure is likely to occur from the part. The most preferable range X is in a range from 0.1H to 0.4H.
In the part, located close to the outer surface of the tire, of the carcass layer 4, the distance between the cords and the outer surface of the tire is set at not more than 2 mm. When the distance D of the cord layer is more than 2 mm, air guided into the cords is unlikely to be discharged to the outside of the tire. The cords of the cord layer may be exposed on the outer surface of the tire. In this case, the distance D is 0 mm.
In the above-described embodiment, the carcass layer laid between the pair of bead parts serves also as the cord layer. As the carcass layer serving also as the cord layer, it is possible to employ one folded back around the bead core from the inner side of the tire to the outer side thereof, or one extending from the tread part to each bead part without being wound around the bead core.
As shown in
In the above-described pneumatic tire, the same effect can be obtained as in the case of the first-mentioned pneumatic tire. Specifically, in a process where air inside the tire permeates to the outside of the tire due to the difference in pressure between the inside and the outside of the tire, air moving toward the belt layers 7 is taken in the cords of the cord layer 8. The air can thus be discharged to the outside of the tire from the part located close to the outer surface of the tire. This makes it possible to reduce the amount of oxygen passing through the belt layers 7, and thus to suppress the oxidation degradation of the coating rubber of the belt layers 7. In this manner, the durability of the pneumatic tire can be improved. Moreover, the part, located close to the outer surface of the tire, of the cord layer 8 is disposed at the position closer to the bead part 3 side than the tire maximum width position P. For this reason, the durability can be prevented from being reduced due to the structure of the cord layer 8.
In the above-described embodiment, the cord layer 8 extends over the belt layers 7, and thus does not have the end portions thereof in a region below the belt layers 7. Such structure having no end portion of the cord layer 8 in the region below the belt layers 7 is excellent in durability. However, it is also possible that the cord layer 8 is designed to overlap only the end portions of the belt layers 7, and that such cord layer 8 is then arranged on each of the end portions of the belt layers 7. In this case, it is desirable that the overlapping width, in the axial direction of the tire, of each cord layer 8 and the belt layers 7 be at least 10 mm from the corresponding end portion of the belt layers 7. This design makes it possible to securely protect the vicinity, where a separation failure is likely to occur, of each end portion of the belt layers 7.
In the above-described pneumatic tire, a cord layer 18 is buried in the tread part 1 in such a manner that the cord layer 18 sandwiches the belt layers 7 from the inner side and the outer side, in the radial direction of the tire, of the belt layers 7. As shown in
An inner part 18a of the cord layer 18 is disposed between the carcass layer 4 and the belt layers 7. An outer part 18b of the cord layer 18 is disposed on the outer circumferential side of the belt layers 7, and along the belt layers 7. In addition, the cords of the cord layer 18 are continuously extended, in a straddling manner, between the inner part 18a and the outer part 18b. In other words, the cords of the cord layer 18 form a bypass for air, and the bypass continuously extends from the inner part 18a to the outer part 18b.
In the above-described pneumatic tire, the cord layer 18 is disposed in such a manner that the cord layer 18 sandwiches the belt layers 7 from the inner side and the outer side, in the radial direction of the tire, of the belt layers 7, and the cords of the cord layer 18 continuously extend, in a straddling manner, between the inner part 18a and the outer part 18b. Accordingly, in a process where air inside the tire permeates to the outside of the tire due to the difference in pressure between the inside and the outside of the tire, air moving toward the belt layers 7 is taken in the cords of the cord layer 18 before entering the belt layers 7. The air can thus be bypassed to the outer circumferential side of the belt layers 7. This structure makes it possible to reduce the amount of oxygen passing through the belt layers 7, and thus to suppress the oxidation degradation of the coating rubber of the belt layers 7. In this manner, the long-term durability of the pneumatic tire can be improved.
Moreover, the inner part 18a of the cord layer 18 is disposed between the carcass layer 4 and the belt layers 7, while the outer part 18b of the cord layer 18 is disposed on the outer circumferential side of the belt layers 7, along the belt layers 7. For this reason, the durability can be prevented from being reduced due to the cord layer 18. Specifically, the end portion of each of the inner part 18a and the outer part 18b of the cord layer 18 is disposed at a position with a small amount of deformation occurring. Accordingly, damage originating at the end portions of the cord layer 18 is unlikely to occur.
In the above-described pneumatic tire, the following effect can be obtained by extending each of the inner and outer parts 18a and 18b of the cord layer 18 to have an end portion located at a distance of not less than 10 mm from the edge portion of the belt layer 7 with the widest width to the tread center side. Specifically, this arrangement provides the effect of protecting the vicinity, where a separation failure is likely to occur, of the edge portion of the belt layers 7. If necessary, each of the inner and outer parts 18a and 18b may extend to the edge portion on the opposite side. However, it is preferable that the end portion of each of the inner and outer parts 18a and 18b of the cord layer 18 be located in a range from 10 mm to 40 mm, from the edge portion of the belt layer 7 with the widest width to the tread center side. This arrangement provides a sufficient effect of suppressing the oxidation degradation of the belt layers 7 while suppressing an increase in weight.
To be more specific, refer to the enlarged view of
It is preferable that the outer part 18b of the cord layer 18 is extended so as to overlap a groove, such as a main groove 11 or a lug groove 12, which is formed in the tread part 1. By disposing the outer part 18b of the cord layer 18 in a region below the groove, such as the main groove 11 or the lug groove 12, formed in the tread part 1, air bypassed by the cord layer 18 can be effectively discharged to the outside of the tire from the groove part having a thin rubber gauge.
Here, the position where the outer part 18b overlaps a groove is a position where the groove and the outer part of the cord layer overlap at least partially each other when projected in a direction perpendicular to the tread surface. Consider a case, for example, where the cords of the cord layer 18 are arranged in the circumferential direction of the tire. In this case, it is preferable that the outer part 18b of the cord layer 18 extend so as to overlap a lug groove extending, in the width direction of the tire, in the shoulder region of the tread part. This allows the cords of the cord layer 18 to intersect the lug groove at multiple intersections. On the other hand, consider a case where the cords of the cord layer 18 are arranged in the width direction of the tire. In this case, it is preferable that the outer part 18b of the cord layer 18 extend so as to overlap a lug groove extending, in the width direction of the tire, in the shoulder region of the tread part, and also overlaps a main groove extending, in the circumferential direction of the tire, in the shoulder region. Note that, even when the outer part 18b of the cord layer 18 does not reach the position where the outer part 18b overlaps any groove, it is still possible to obtain the effect of bypassing air moving toward the belt layers 7.
In the case where the outer part 18b of the cord layer 18 extends to the position where the outer part 18b overlaps a groove, it is preferable, as shown in
The preferred embodiments of the present invention have been described so far. However, it is to be understood that various modifications, substitutions, and replacements may be made thereon without departing from the spirit and scope of the present invention defined by the scope of the attached claims.
Regarding the first invention, prepared were pneumatic tires of Conventional Example 1, Comparative Example 1, and Examples 1 to 3 with various tire structures different from one another. Each of these tires had a tire size of 195/65R15.
In the tire of Conventional Example 1, belt layers were buried on the outer circumferential side of a carcass layer in a tread part, while an air permeation preventive layer was provided in the inner surface of the tire. The tire of Comparative Example 1 had the same structure as that of Conventional Example 1 except the following points. Specifically, a cord layer was additionally provided in a buttress part to be laid between the carcass layer and the end portions of the belt layers. In addition, each end portion of the cord layer was located close to the outer surface of the tire at a height in a range from 0.7H to 0.8H, from the bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire. Here, the position of the end portion was also set so that the distance between the cords and the outer surface of the tire was 1 mm.
The tire of Example 1 had the same structure as that of Conventional Example 1 except the following points. Specifically, the end portion of the folded-back part of the carcass layer was located close to the outer surface of the tire at a height in a range from 0.1H to 0.2H, from the bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire. Here, the position of the end portion was set so that the distance between the cords and the outer surface of the tire was 1 mm. The tire of Example 2 had the same structure as that of Conventional Example 1 except the following points. Specifically, the end portion of the folded-back part of the carcass layer was located close to the outer surface of the tire at a height in a range from 0.3H to 0.4H, from the bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire. Moreover, the position of the end portion was set so that the distance between the cords and the outer surface of the tire was 1 mm. The tire of Example 3 has the same structure as that of Conventional Example 1 except the following points. Specifically, the end portion of a folded-back part of the carcass layer is located close to the outer surface of the tire at a height in a range from 0.4H to 0.5H, from the bead heel, in the radial direction of the tire, with respect to the cross-sectional height H of the tire. Moreover, the position of the end portion was set so that the distance between the cords and the outer surface of the tire was 1 mm.
A durability test and an air leakage test were performed on these test tires by the following test methods. The results of the tests are shown in Table 1.
Durability Test:
Each of the test tires was mounted on a wheel having a rim size of 15×6JJ, then inflated to an air pressure of 200 kPa. The tire and wheel are mounted on a passenger vehicle having an engine displacement of 1800 cc, and the vehicle was driven for 50,000 km on a paved road. After the driving, it is determined whether or not belt-edge separation or sidewall cracking occurred.
Air Permeation Test:
Each of the test tires was mounted on a wheel having a rim size of 15×6JJ, and then left for three months, with an initial air pressure of 250 kPa, at room temperature of 21° C., and under a no-load condition. During the test, the pressure was measured at predetermined measurement intervals. The internal pressure was measured at every three hours, and a value α was obtained by regression from the following equation (1) where Pt, P0, and t represent a measured pressure, the initial pressure, and the number of days elapsed, respectively.
Pt/P0=exp(−αt) (1)
Then, a value β was obtained from the following equation (2) by using the value α obtained from the equation (1), and concurrently by assigning 30 (days) to the value t.
β=[1−exp(−αt)]×100 (2)
The value β thus obtained was taken as a rate of decrease in pressure per month (%/month).
As shown in Table 1, in each of the tires of Examples 1 to 3, neither belt-edge separation nor sidewall cracking had occurred when the durability test was completed. Each of these tires also showed an excellent result of the air leakage test. On the other hand, in the tire of Conventional Example 1, belt-edge separation had occurred. In addition, in the tire of Comparative Example 1, belt-edge separation was prevented from occurring, but sidewall cracking had occurred instead.
Next, regarding the second invention, prepared were pneumatic tires of Conventional Example 11, Comparative Examples 11 and 12, as well as Examples 11 and 12 with various tire structure different from one another. Each of these tires had a tire size of 195/65R15.
In the tire of Conventional Example 11, belt layers were buried on the outer circumferential side of a carcass layer in a tread part. The tire of Comparative Example 11 had the same structure as that of Conventional Example 11 except the following points. Specifically, a cord layer was formed by arranging Nylon multifilament cords of 840 denier at an angle of 90° to the circumferential direction of the tire. An inner part of the cord layer was disposed between the carcass layer and the belt layers, while an outer part of the cord layer was disposed on the outer circumferential side of the belt layers, along the belt layers. The cords of the cord layer were non-continuous between the inner part and the outer part. The tire of Comparative Example 12 had the same structure as that of Conventional Example 11 except the following points. Specifically, a cord layer was formed by arranging Nylon multifilament cords of 840 denier at an angle of 90° to the circumferential direction of the tire. The cord layer was then disposed between the carcass layer and the end portions of the belt layers in the buttress part. In addition, the end portion of the cord layer was located close to the outer surface of the tire so that the distance between the cords and the outer surface of the tire was 1 mm.
The tire of Example 11 had the same structure as that of Conventional Example 11 except the following points. Specifically, a cord layer was formed by arranging Nylon multifilament cords of 840 denier at an angle of 90° to the circumferential direction of the tire. In addition, an inner part of the cord layer was disposed between the carcass layer and the belt layers, while an outer part of the cord layer was disposed on the outer circumferential side of the belt layers, along the belt layers. Moreover, the cords of the cord layer were continuously extended, in a straddling manner, between the inner part and the outer part of the cord layer. The tire of Example 12 had the same structure as that of Conventional Example 11 except the following points. Specifically, a cord layer was formed by arranging Nylon multifilament cords of 840 denier at an angle of substantially 0° to the circumferential direction of the tire. In addition, an inner part of the cord layer was disposed between the carcass layer and the belt layers, while an outer part of the cord layer was disposed on the outer circumferential side of the belt layers, along the belt layers. Moreover, the cords of the cord layer were continuously extended, in a straddling manner, between the inner part and the outer part of the cord layer. Note that, each of these above dimensions is shown in Table 2.
A durability test was performed on these test tires by the following test method. The results of the test are shown in Table 2.
Durability Test:
Each of the test tires was mounted on a wheel having a rim size of 15×6JJ, then inflated to an air pressure of 200 kPa. The tire and wheel are mounted on a passenger vehicle having an engine displacement of 1800 cc, and the vehicle was driven for 80,000 km on a paved road. After the driving, it is determined whether or not belt-edge separation or sidewall cracking occurred.
As shown in Table 2, in each of the tires of Examples 11 and 12, neither belt-edge separation nor sidewall failure had occurred when the durability test was completed. On the other hand, in each of the tires of Conventional Example 11 and Comparative Example 11, belt-edge separation had occurred. In addition, in the tire of Comparative Example 12, belt-edge separation was prevented from occurring, but cracking had occurred in the outer surface of the tire, near the end portion of the cord layer.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2006-012414 | Jan 2006 | JP | national |
| 2006-012438 | Jan 2006 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2006/323132 | 11/20/2006 | WO | 00 | 5/22/2008 |
