PNEUMATIC TIRE

Information

  • Patent Application
  • 20230080547
  • Publication Number
    20230080547
  • Date Filed
    February 12, 2021
    3 years ago
  • Date Published
    March 16, 2023
    a year ago
Abstract
Provided is a pneumatic tire that can provide improved transponder durability while ensuring tire durability. The pneumatic tire includes: a tread portion (1) extending in a tire circumferential direction and having an annular shape; a pair of sidewall portions (2) disposed on both sides of the tread portion (1); and a pair of bead portions (3) disposed on an inner side in a tire radial direction of the sidewall portions (2). The tire is embedded with a transponder (20) covered with a covering layer (23). A glass transition temperature (Tg) of the covering layer (23) is in a range of from −70° C. to −45° C.
Description
TECHNICAL FIELD

The present technology relates to a pneumatic tire in which a transponder covered with a covering layer is embedded and particularly relates to a pneumatic tire that can provide improved transponder durability while ensuring tire durability.


BACKGROUND ART

For pneumatic tires, embedment of an RFID (radio frequency identification) tag (transponder) in a tire has been proposed (see, for example, Japan Unexamined Patent Publication No. H07-137510). In the case where a transponder is embedded in the tire, the durability of the tire or the transponder cannot be sufficiently ensured if the physical properties of the covering layer for protecting the transponder are inadequate. For example, in a case where the glass transition temperature of the covering layer is too high, the durability of the tire at low temperature degrades, and the transponder is likely to be damaged due to tire deformation during travel at low temperature.


SUMMARY

The present technology provides a pneumatic tire that can provide improved transponder durability while ensuring tire durability.


A pneumatic tire according to an embodiment of the present technology includes: a tread portion extending in a tire circumferential direction and having an annular shape; a pair of sidewall portions disposed on both sides of the tread portion; and a pair of bead portions disposed on an inner side in a tire radial direction of the sidewall portions. The tire is embedded with a transponder covered with a covering layer. A glass transition temperature Tg of the covering layer is in a range of from −70° C. to −45° C.


In an embodiment of the present technology, the transponder is covered with the covering layer, and the glass transition temperature Tg of the covering layer is set in the range described above, and thus cracking in the covering layer during travel in a low-temperature environment can be prevented, while the protective effect of the covering layer on the transponder during travel at high temperature can be ensured. This can improve the durability of the transponder while ensuring the durability of the tire.


In the pneumatic tire according to an embodiment of the present technology, a storage modulus E′c (−20° C.) at −20° C. of the covering layer is preferably in a range of from 3 MPa to 17 MPa. This can effectively improve the durability of the transponder in a low-temperature environment while ensuring the durability of the tire.


The covering layer preferably has a relative dielectric constant of 7 or less. This can ensure the radio wave transmissivity of the transponder and improve the communication performance of the transponder.


Preferably, the transponder is embedded on an outer side in a tire width direction of the carcass layer, and a storage modulus E′c (−20° C.) at −20° C. of the covering layer and a storage modulus E′out (−20° C.) at −20° C. of a rubber member having a largest storage modulus at 20° C. of rubber members located on the outer side in the tire width direction of the transponder satisfy a relationship 0.1≤E′c (−20° C.)/E′out (−20° C.)≤1.5. This can effectively improve the durability of the transponder in a low-temperature environment while ensuring the durability of the tire.


The covering layer is preferably formed of a rubber or an elastomer and 20 phr or more of a white filler. This can lower the relative dielectric constant of the covering layer and effectively improve the communication performance of the transponder.


The white filler preferably includes from 20 phr to 55 phr of calcium carbonate. This can lower the relative dielectric constant of the covering layer and effectively improve the communication performance of the transponder.


A center of the transponder is preferably disposed 10 mm or more away in the tire circumferential direction from a splice portion of a tire component. This can effectively improve the durability of the tire.


The transponder is preferably disposed between a position 15 mm away from and on an outer side in the tire radial direction of an upper end of a bead core of the bead portion and a tire maximum width position. Accordingly, the transponder is disposed in a region where the stress amplitude during travel is small. This can effectively improve the durability of the transponder, and does not degrade the durability of the tire.


A distance between a cross-sectional center of the transponder and a tire surface is preferably 1 mm or more. This can effectively improve the durability of the tire as well as improve the scratch resistance of the tire.


A thickness of the covering layer preferably ranges from 0.5 mm to 3.0 mm. This can effectively improve the communication performance of the transponder without making the tire surface uneven.


Preferably, the transponder includes an IC (integrated circuit) substrate that stores data and an antenna that transmits and receives data, and the antenna has a helical shape. This allows the transponder to follow deformation of the tire during travel, improving the durability of the transponder.


In an embodiment of the present technology, the glass transition temperature Tg is a temperature at which a tan δ reaches a maximum value due to glass transition, the tan δ being measured while varying the temperature at a temperature elevation speed of 2° C./min. The tan δ is measured at a frequency of 10 Hz, an initial strain of 10%, a dynamic strain of ±2% in a tensile deformation mode using a viscoelastic spectrometer in accordance with JIS (Japanese Industrial Standard)-K 6394. The storage modulus E′ is measured at a designated temperature, a frequency of 10 Hz, an initial strain of 10%, and a dynamic distortion of ±2% using a viscoelasticity spectrometer in a tensile deformation mode in accordance with JIS-K6394.





BRIEF DESCRIPTION OF DRAWINGS


FIG. 1 is a meridian semi-cross-sectional view illustrating a pneumatic tire according to an embodiment of the present technology.



FIG. 2 is a meridian cross-sectional view schematically illustrating the pneumatic tire of FIG. 1.



FIG. 3 is an equatorial cross-sectional view schematically illustrating the pneumatic tire of FIG. 1.



FIG. 4 is an enlarged cross-sectional view illustrating a transponder embedded in the pneumatic tire of FIG. 1.



FIGS. 5A and 5B are perspective views each illustrating a transponder that can be embedded in a pneumatic tire according to an embodiment of the present technology.



FIG. 6 is an explanatory diagram illustrating the position in a tire radial direction of a transponder in a test tire.





DETAILED DESCRIPTION

A configuration according to an embodiment of the present technology will be described in detail below with reference to the accompanying drawings. FIGS. 1 to 4 illustrate a pneumatic tire according to an embodiment of the present technology.


As illustrated in FIG. 1, the pneumatic tire according to the present embodiment includes a tread portion 1 extending in a tire circumferential direction and having an annular shape, a pair of sidewall portions 2 disposed on both sides of the tread portion 1, and a pair of bead portions 3 disposed on an inner side in a tire radial direction of the pair of sidewall portions 2.


At least one carcass layer 4 (one layer in FIG. 1) formed by arraying a plurality of carcass cords in a radial direction is mounted between the pair of bead portions 3. The carcass layer 4 is covered with rubber. The carcass cords forming the carcass layer 4 are preferably organic fiber cords of nylon, polyester, or the like. The bead portions 3 are each embedded with a bead core 5 having an annular shape, and a bead filler 6 made of a rubber composition and having a triangular cross-section is disposed on an outer circumference of the bead core 5.


On the other hand, a plurality of belt layers 7 (two layers in FIG. 1) are embedded on a tire outer circumferential side of the carcass layer 4 of the tread portion 1. The belt layers 7 include a plurality of reinforcing cords that are inclined with respect to the tire circumferential direction, and the reinforcing cords intersect each other between the layers. In the belt layers 7, the inclination angle of the reinforcing cords with respect to the tire circumferential direction is set in a range of, for example, from 10° to 40°. The reinforcing cords of the belt layers 7 are preferably steel cords.


To improve high-speed durability, at least one belt cover layer 8 (two layers in FIG. 1) formed by arraying reinforcing cords at an angle of, for example, 5° or less with respect to the tire circumferential direction is disposed on the tire outer circumferential side of the belt layers 7. In FIG. 1, the belt cover layer 8 located on the inner side in the tire radial direction forms a full cover that covers the entire width of the belt layers 7, and the belt cover layer 8 located on an outer side in the tire radial direction forms an edge cover layer that covers only end portions of the belt layers 7. The reinforcing cords of the belt cover layer 8 are preferably organic filament cords of nylon, aramid, or the like.


In the pneumatic tire described above, both ends 4e of the carcass layer 4 are each folded back from a tire inner side to a tire outer side around the bead core 5, wrapping around the bead core 5 and the bead filler 6. The carcass layer 4 includes: a body portion 4A corresponding to a portion extending from the tread portion 1 through each of the sidewall portions 2 to each of the bead portions 3; and a turned up portion 4B corresponding to a portion turned up around the bead core 5 at each of the bead portions 3 and extending toward a sidewall portion 2 side.


A tire inner surface includes an innerliner layer 9 disposed along the carcass layer 4. The tread portion 1 includes a cap tread rubber layer 11, the sidewall portion 2 includes a sidewall rubber layer 12, and the bead portion 3 includes a rim cushion rubber layer 13.


The pneumatic tire described above includes a transponder 20 embedded in a portion on an outer side in a tire width direction of the carcass layer 4. The transponder 20 extends along the tire circumferential direction. The transponder 20 may be inclined at an angle in a range of from −10° to 10° with respect to the tire circumferential direction. As illustrated in FIG. 4, the transponder 20 is covered with a covering layer 23. The covering layer 23 covers the transponder 20 completely so as to sandwich both front and rear surfaces of the transponder 20. The covering layer 23 may be formed from a rubber having physical properties identical to those of a rubber forming the sidewall rubber layer 12 or the rim cushion rubber layer 13, or may be formed from a rubber having different physical properties.


The transponder 20 may be, for example, a radio frequency identification (RFID) tag. As illustrated in FIGS. 5A and 5B, the transponder 20 includes an IC substrate 21 for storing data and an antenna 22 for transmitting and receiving data in a non-contact manner. The transponder 20 as described above can be used to write or read information related to the tire on a timely basis and to efficiently manage the tire. Note that “RFID” refers to an automatic recognition technology formed of a reader/writer including an antenna and a controller and of an ID (identification) tag including an IC substrate and an antenna, the automatic recognition technology allowing data to be communicated in a wireless manner.


The overall shape of the transponder 20 is not particularly limited, and can be, for example, a pillar-like shape or plate-like shape as illustrated in FIGS. 5A and 5B. In particular, the transponder 20 having a pillar-like shape as illustrated in FIG. 5A can follow deformation of the tire in various directions, and thus is suitable. In this case, the antenna 22 of the transponder 20 projects from each of both end portions of the IC substrate 21 and has a helical shape. This allows the transponder 20 to follow deformation of the tire during travel, improving the durability of the transponder 20. The length of the antenna 22 can be appropriately changed to ensure communication performance.


In the pneumatic tire thus configured, a glass transition temperature Tg of the covering layer 23 covering the transponder 20 is set in a range of from −70° C. to −45° C. In particular, the glass transition temperature Tg of the covering layer 23 is preferably in the range of from −60° C. to −50° C.


In the pneumatic tire described above, the transponder 20 is covered with the covering layer 23, and the glass transition temperature Tg of the covering layer 23 is set in the range described above, and thus cracking in the covering layer 23 during travel in a low-temperature environment can be prevented, while the protective effect of the covering layer 23 on the transponder 20 during travel at high temperature can be ensured. This can improve the durability of the transponder 20 while ensuring the durability of the tire.


Here, in a case where the glass transition temperature Tg of the covering layer 23 is lower than the lower limit value, the heat resistance of the covering layer 23 degrades, the protective effect of the covering layer 23 on the transponder 20 during travel at high temperature degrades, and the transponder 20 is likely to be damaged. Conversely, in a case where the glass transition temperature Tg of the covering layer 23 is higher than the upper limit value, a crack is likely to be generated in the covering layer 23 during travel in a low-temperature environment, and thus the durability of the tire at low temperature degrades, and the transponder is likely to be damaged due to tire deformation during travel at low temperature.


Further, in the pneumatic tire described above, the transponder 20 is embedded on the outer side in the tire width direction of the carcass layer 4, and thus there is no tire component blocking radio waves during communication with the transponder 20, and the communication performance of the transponder 20 can be favorably ensured. In a case where the transponder 20 is embedded on the outer side in the tire width direction of the carcass layer 4, the transponder 20 can be disposed between the turned up portion 4B of the carcass layer 4 and the rim cushion rubber layer 13, or between the carcass layer 4 and the sidewall rubber layer 12. In another configuration, the transponder 20 can be disposed between the turned up portion 4B of the carcass layer 4 and the bead filler 6, or between the main body portion 4A of the carcass layer 4 and the bead filler 6.


In the pneumatic tire described above, a storage modulus E′c (−20° C.) at −20° C. of the covering layer 23 is preferably in a range of from 3 MPa to 17 MPa. By thus setting the physical properties of the covering layer 23, the durability of the transponder 20 can be effectively improved in a low-temperature environment.


Here, in a case where the storage modulus E′c (−20° C.) at −20° C. of the covering layer 23 is lower than the lower limit value, the rigidity of the covering layer 23 decreases, and the protective effect thereof degrades. Conversely, in a case where the storage modulus E′c (−20° C.) at −20° C. of the covering layer 23 is higher than the upper limit value, the rigidity of the covering layer 23 increases, the covering layer 23 becomes brittle, and the covering layer 23 becomes prone to breakage, and thus the transponder 20 is likely to be damaged.


The storage modulus E′c (−20° C.) at −20° C. of the covering layer 23 and the storage modulus E′c (0° C.) at 0° C. of the covering layer 23 preferably satisfy the relationship 1.0≤E′c (−20° C.)/E′c (0° C.)≤1.5. By thus setting the physical properties of the covering layer 23, the temperature dependency of the covering layer 23 decreases (the covering layer 23 is less likely to generate heat), and this prevents the covering layer 23 from softening even with a rise in tire temperature during high-speed travel, effectively improving the durability of the transponder 20.


In the pneumatic tire described above, of the rubber memb ers located on the outer side in the tire width direction of the transponder 20 (the sidewall rubber layer 12 and the rim cushion rubber layer 13 in FIG. 1), the rubber member having the largest storage modulus E′out (20° C.) at 20° C. (hereinafter sometimes referred to as an external member) corresponds to the rim cushion rubber layer 13. Note that the rubber member (external member) having the largest storage modulus at 20° C. does not include the covering layer 23 covering the transponder 20.


Furthermore, in a structure in which the transponder 20 is embedded on the outer side in the tire width direction of the carcass layer 4, the storage modulus E′ out (−20° C.) at −20° C. of the external member and the storage modulus E′c (−20° C.) at −20° C. of the covering layer 23 preferably satisfy the relationship 0.1≤E′c (−20° C.)/E′out (−20° C.)≤1.5. In particular, the relationship 0.15≤E′c (−20° C.)/E′out (−20° C.)≤1.30 is preferably satisfied. This can effectively improve the durability of the transponder 20 while ensuring the durability of the tire in a low-temperature environment.


Here, in a case where the value of E′c (−20° C.)/E′out (−20° C.) is smaller than the lower limit value, the rigidity of the covering layer 23 decreases, and the protective effect thereof degrades. Conversely, in a case where the value of E′c (−20° C.)/E′out (−20° C.) is larger than the upper limit value, the rigidity of the covering layer 23 increases, the covering layer 23 becomes brittle, and the covering layer 23 becomes prone to breakage, and thus the transponder 20 is likely to be damaged.


The composition of the covering layer 23 is preferably a rubber or an elastomer and 20 phr or more of a white filler. Such a composition of the covering layer 23 can lower the relative dielectric constant of the covering layer 23, compared to a composition containing carbon, and effectively improve the communication performance of the transponder 20. Note that “phr” means weight parts per 100 parts by weight of a rubber component (elastomer).


The white filler forming the covering layer 23 preferably includes from 20 phr to 55 phr of calcium carbonate. This can lower the relative dielectric constant of the covering layer 23 and effectively improve the communication performance of the transponder 20. However, too much calcium carbonate in the white filler makes the covering layer 23 brittle and lowers its strength, and this is not preferable. The covering layer 23 can optionally include 20 phr or less of a silica (white filler) or 5 phr or less of a carbon black in addition to calcium carbonate. An addition of a small amount of silica and carbon black can lower the relative dielectric constant of the covering layer 23 while ensuring the strength thereof.


The covering layer 23 preferably has a relative dielectric constant of 7 or less, and more preferably of from 2 to 5. By thus setting the relative dielectric constant of the covering layer 23 as appropriate, the radio wave transmissivity of the transponder 20 during emission of radio waves can be ensured, and the communication performance of the transponder 20 can be effectively improved. Note that the rubber forming the covering layer 23 has a relative dielectric constant of from 860 MHz to 960 MHz at ambient temperature. Here, the ambient temperature is 23±2° C. and 60%±5% RH (relative humidity) in accordance with the standard conditions of the JIS standard. The relative dielectric constant of the rubber is measured in accordance with an electrostatic capacitance method after a 24-hour treatment at 23° C. and 60% RH. The range from 860 MHz to 960 MHz described above corresponds to currently allocated frequencies of the RFID in a UHF (ultra high frequency) band, but in a case where the allocated frequencies are changed, it is only required that the relative dielectric constant in the range of the allocated frequencies be specified as described above.


A thickness t of the covering layer 23 is preferably from 0.5 mm to 3.0 mm, and more preferably from 1.0 mm to 2.5 mm. Here, the thickness t of the covering layer 23 is a rubber thickness at a position including the transponder 20, and is, for example, a rubber thickness obtained by summing a thickness t1 and a thickness t2 on a straight line extending through the center of the transponder 20 and intersecting a tire surface (tire outer surface in FIG. 4) at right angles as illustrated in FIG. 4. By thus setting the thickness t of the covering layer 23 as appropriate, the communication performance of the transponder 20 can be effectively improved without making the tire surface uneven. Here, the covering layer 23 having a thickness t of less than 0.5 mm will fail to yield an effect of improving the communication performance of the transponder 20, whereas the covering layer 23 having a thickness t exceeding 3.0 mm will make the tire surface uneven, and this is not preferable for appearance. Note that the cross-sectional shape of the covering layer 23 is not particularly limited and can be, for example, a triangular shape, a rectangular shape, a trapezoidal shape, or a spindle shape. The cross-sectional shape of the covering layer 23 of FIG. 4 is substantially spindle-shaped.


In the pneumatic tire described above, the transponder 20 is preferably disposed in a placement region in the tire radial direction between a position P1 15 mm away from and on the outer side in the tire radial direction of an upper end 5e (an end portion on the outer side in the tire radial direction) of the bead core 5 and a position P2 where the tire width is greatest. That is, the transponder 20 is preferably disposed in a region S1 illustrated in FIG. 2. The transponder 20 disposed in the region S1 is positioned in a region where the stress amplitude during travel is small, and this can effectively improve the durability of the transponder 20, and does not degrade the durability of the tire. Here, the transponder 20 disposed on the inner side in the tire radial direction of the position P1 is too close to a metal member such as the bead core 5, and this tends to degrade the communication performance of the transponder 20. On the other hand, the transponder 20 disposed on the outer side in the tire radial direction of the position P2 is positioned in a region where the stress amplitude during travel is large, and damage to the transponder 20 itself and interfacial failure in a periphery of the transponder 20 are likely to occur, and this is not preferable.


As illustrated in FIG. 3, a plurality of splice portions formed by overlaying end portions of tire components are on a tire circumference. FIG. 3 illustrates positions Q in the tire circumferential direction of the splice portions. The center of the transponder 20 is preferably disposed 10 mm or more away in the tire circumferential direction away from the splice portion of the tire component. That is, the transponder 20 is preferably disposed in a region S2 illustrated in FIG. 3. Specifically, the IC substrate 21 forming the transponder 20 is preferably located 10 mm or more away in the tire circumferential direction from the position Q. More preferably, all of the transponder 20 including the antenna 22 is located 10 mm or more away in the tire circumferential direction from the position Q, and most preferably, all of the transponder 20 covered with a covering rubber is located 10 mm or more away in the tire circumferential direction from the position Q. Also, the tire component disposed away from the transponder 20 is preferably the sidewall rubber layer 12, the rim cushion rubber layer 13, or the carcass layer 4, which is disposed adjacent to the transponder 20. By thus disposing the transponder 20 away from the splice portion of the tire component, the durability of the tire can be effectively improved.


Note that while the embodiment of FIG. 3 illustrates an example in which the positions Q in the tire circumferential direction of the splice portions of the tire components are disposed at equal intervals, no such limitation is intended. The positions Q in the tire circumferential direction can be set anywhere, and in either case, the transponder 20 is disposed 10 mm or more away in the tire circumferential direction from the splice portions of the tire components.


As illustrated in FIG. 4, a distance d between the cross-sectional center of the transponder 20 and the tire surface is preferably 1 mm or more. By thus spacing the transponder 20 and the tire surface apart from each other, the durability of the tire can be effectively improved, and the scratch resistance of the tire can be improved. In the embodiment of FIG. 4, the distance d is the distance between the cross-sectional center of the transponder 20 and the tire outer surface, whereas in a case where the transponder 20 is disposed in a position close to the innerliner layer 9, the distance d is the distance between the cross-sectional center of the transponder 20 and the tire inner surface. In particular, the distance d between the cross-sectional center of the transponder 20 and the tire outer surface is preferably 2 mm or more.


While the embodiment described above illustrates an example in which the end 4e of the turned up portion 4B of the carcass layer 4 is disposed at or near an upper end 6e of the bead filler 6, no such limitation is intended, and the end 4e of the turned up portion 4B of the carcass layer 4 can be disposed at any height.


EXAMPLES

Tires according to Comparative Examples 1 to 2 and Examples 1 to 14 were manufactured. The tires were each a pneumatic tire having a tire size of 265/40ZR20 and including: a tread portion extending in a tire circumferential direction and having an annular shape; a pair of sidewall portions disposed on both sides of the tread portion; and a pair of bead portions disposed on an inner side in a tire radial direction of the sidewall portions. A transponder was embedded on an outer side in the tire width direction of the carcass layer, the transponder being covered with a covering layer. The position in the tire radial direction of the transponder, the glass transition temperature Tg of the covering layer, the storage modulus E′c (−20° C.) of the covering layer, E′c (−20° C.)/E′out (−20° C.), the relative dielectric constant of the covering layer, and the thickness of the covering layer were set as in Table 1.


Comparative Examples 1 to 2 and Examples 1 to 14 used a transponder having a pillar-like shape, and set the distance in the tire circumferential direction from the center of the transponder to a splice portion of a tire component to 10 mm and the distance from the cross-sectional center of the transponder to a tire outer surface to 2 mm or more.


In Table 1, the position in the tire radial direction of the transponder corresponds to one of positions A to E illustrated in FIG. 6.


The test tires were subjected to tire evaluation (durability) and transponder evaluation (communication performance and durability) in accordance with a test method described below, and the results are indicated together in Table 1.


Tire Durability (Low Temperature):

With each test tire mounted on a wheel of a standard rim, a travel test was performed using a drum testing machine at a temperature of −20° C., an air pressure of 120 kPa, 65% of the maximum load, and a travel speed of 81 km/h, and the distance traveled at the time of a tire failure was measured. Evaluation results are expressed as index values with Comparative Example 1 being assigned an index value of 100. Larger index values indicate superior tire durability.


Communication Performance of Transponder:

For each test tire, a communication operation with the transponder was performed using a reader/writer. Specifically, the maximum communication distance was measured with the reader/writer set at a power output of 250 mW and a carrier frequency of from 860 MHz to 960 MHz. Evaluation results are expressed as index values with Comparative Example 1 being assigned an index value of 100. Larger index values indicate superior communication performance.


Durability of Transponder (Low Temperature):

After performing the tire durability test described above at low temperature, each test tire was checked for whether the transponder was communicable and whether the same was damaged, and the results are indicated in three levels: “Excellent” in a case where the transponder was communicable and not damaged; “Good” in a case where the transponder was communicable but damaged; and “Poor” in a case where the transponder was not communicable.


Durability of Transponder (High Temperature):

With each test tire assembled on a standard rim wheel, a high-speed durability test under the ECE (Economic Commission for Europe) R30 conditions was performed at a temperature of 38° C., an air pressure of 360 kPa, and 80% of the maximum load, and then each test tire was checked for whether the transponder was communicable and whether the same was damaged, and the results are indicated in three levels: “Excellent” in a case where the transponder was communicable and not damaged; “Good” in a case where the transponder was communicable but damaged; and “Poor” in a case where the transponder was not communicable.















TABLE 1-1







Comparative
Comparative
Example
Example
Example



Example 1
Example 2
1
2
3





















Position in tire radial direction
C
C
C
C
C


of transponder


Glass transition temperature Tg
−75
−30
−70
−60
−50


of covering layer (° C.)


Storage modulus E′c (−20° C.) of
10.0
10.0
10.0
10.0
3.0


covering layer (MPa)


E′c (−20° C.)/E′out (−20° C.)
0.8
0.8
0.8
0.8
0.3


Relative dielectric constant of
8
8
8
8
8


covering layer


Thickness of covering layer (mm)
0.2
0.2
0.2
0.2
0.2













Tire
Durability (low
100
90
103
102
100


evaluation
temperature)


Transponder
Communication
100
100
100
100
100


evaluation
performance



Durability (low
Excellent
Poor
Excellent
Excellent
Good



temperature)



Durability (high
Poor
Excellent
Good
Excellent
Good



temperature)























TABLE 1-2







Example
Example
Example
Example
Example
Example



4
5
6
7
8
9






















Position in tire radial direction
C
C
C
E
D
B


of transponder


Glass transition temperature Tg
−50
−50
−45
−50
−50
−50


of covering layer (° C.)


Storage modulus E′c (−20° C.) of
10.0
17.0
10.0
10.0
10.0
10.0


covering layer (MPa)


E′c (−20° C.)/E′out (−20° C.)
0.8
1.4
0.8
0.8
0.8
0.8


Relative dielectric constant of
8
8
8
8
8
8


covering layer


Thickness of covering layer (mm)
0.2
0.2
0.2
0.2
0.2
0.2














Tire
Durability (low
102
102
100
102
102
102


evaluation
temperature)


Transponder
Communication
100
100
100
98
100
100


evaluation
performance



Durability (low
Excellent
Good
Good
Excellent
Excellent
Excellent



temperature)



Durability (high
Excellent
Good
Excellent
Excellent
Excellent
Excellent



temperature)






















TABLE 1-3







Example
Example
Example
Example
Example



10
11
12
13
14





















Position in tire radial direction
A
C
C
C
C


of transponder


Glass transition temperature Tg
−50
−50
−50
−50
−50


of covering layer (° C.)


Storage modulus E′c (−20° C.) of
10.0
10.0
10.0
10.0
10.0


covering layer (MPa)


E′c (−20° C.)/E′out (−20° C.)
0.8
0.8
0.8
0.8
0.8


Relative dielectric constant of
8
7
7
7
7


covering layer


Thickness of covering layer (mm)
0.2
0.2
0.5
1.0
3.0













Tire
Durability (low
100
102
102
102
102


evaluation
temperature)


Transponder
Communication
100
102
103
105
107


evaluation
performance



Durability (low
Excellent
Excellent
Excellent
Excellent
Excellent



temperature)



Durability (high
Excellent
Excellent
Excellent
Excellent
Excellent



temperature)









As can be seen from Table 1 here, tire durability and transponder durability were improved in a well-balanced manner in the pneumatic tires of Examples 1 to 14, compared to Comparative Examples 1 to 2.


In Comparative Example 1, the glass transition temperature Tg of the covering layer was too low, and thus the durability of the transponder at high temperature was poor. In Comparative Example 2, the glass transition temperature Tg of the covering layer was too high, and thus the durability of the tire and the transponder at low temperature was poor.

Claims
  • 1. A pneumatic tire, comprising: a tread portion extending in a tire circumferential direction and having an annular shape;a pair of sidewall portions disposed on both sides of the tread portion; anda pair of bead portions disposed on an inner side in a tire radial direction of the sidewall portions;the tire being embedded with a transponder covered with a covering layer; anda glass transition temperature Tg of the covering layer being in a range of from −70° C. to −45° C.
  • 2. The pneumatic tire according to claim 1, wherein a storage modulus E′c (−20° C.) at −20° C. of the covering layer is in a range of from 3 MPa to 17 MPa.
  • 3. The pneumatic tire according to claim 1, wherein the covering layer has a relative dielectric constant of 7 or less.
  • 4. The pneumatic tire according to claim 1, wherein the transponder is embedded on an outer side in a tire width direction of a carcass layer, anda storage modulus E′c (−20° C.) at −20° C. of the covering layer and a storage modulus E′out (−20° C.) at −20° C. of a rubber member having a largest storage modulus at 20° C. of rubber members located on the outer side in the tire width direction of the transponder satisfy a relationship 0.1≤E′c (−20° C.)/E′out (−20° C.)≤1.5.
  • 5. The pneumatic tire according to claim 1, wherein the covering layer is formed of a rubber or an elastomer and 20 phr or more of a white filler.
  • 6. The pneumatic tire according to claim 5, wherein the white filler comprises from 20 phr to 55 phr of calcium carbonate.
  • 7. The pneumatic tire according to claim 1, wherein a center of the transponder is disposed 10 mm or more away in the tire circumferential direction from a splice portion of a tire component.
  • 8. The pneumatic tire according to claim 1, wherein the transponder is disposed between a position 15 mm away from and on an outer side in the tire radial direction of an upper end of a bead core of the bead portion and a tire maximum width position.
  • 9. The pneumatic tire according to claim 1, wherein a distance between a cross-sectional center of the transponder and a tire surface is 1 mm or more.
  • 10. The pneumatic tire according to claim 1, wherein a thickness of the covering layer ranges from 0.5 mm to 3.0 mm.
  • 11. The pneumatic tire according to claim 1, wherein the transponder comprises an IC substrate that stores data and an antenna that transmits and receives data, and the antenna has a helical shape.
  • 12. The pneumatic tire according to claim 2, wherein the covering layer has a relative dielectric constant of 7 or less.
  • 13. The pneumatic tire according to claim 12, wherein the transponder is embedded on an outer side in a tire width direction of a carcass layer, anda storage modulus E′c (−20° C.) at −20° C. of the covering layer and a storage modulus E′out (−20° C.) at −20° C. of a rubber member having a largest storage modulus at 20° C. of rubber members located on the outer side in the tire width direction of the transponder satisfy a relationship 0.1≤E′c (−20° C.)/E′out (−20° C.)≤1.5.
  • 14. The pneumatic tire according to claim 13, wherein the covering layer is formed of a rubber or an elastomer and 20 phr or more of a white filler.
  • 15. The pneumatic tire according to claim 14, wherein the white filler comprises from 20 phr to 55 phr of calcium carbonate.
  • 16. The pneumatic tire according to claim 15, wherein a center of the transponder is disposed 10 mm or more away in the tire circumferential direction from a splice portion of a tire component.
  • 17. The pneumatic tire according to claim 16, wherein the transponder is disposed between a position 15 mm away from and on an outer side in the tire radial direction of an upper end of a bead core of the bead portion and a tire maximum width position.
  • 18. The pneumatic tire according to claim 17, wherein a distance between a cross-sectional center of the transponder and a tire surface is 1 mm or more.
  • 19. The pneumatic tire according to claim 18, wherein a thickness of the covering layer ranges from 0.5 mm to 3.0 mm.
  • 20. The pneumatic tire according to claim 19, wherein the transponder comprises an IC substrate that stores data and an antenna that transmits and receives data, and the antenna has a helical shape.
Priority Claims (1)
Number Date Country Kind
2020-024292 Feb 2020 JP national
PCT Information
Filing Document Filing Date Country Kind
PCT/JP2021/005237 2/12/2021 WO