Patent Application
20240101799
The present invention relates to a polar resin composition and a laminate, and more specifically relates to a polar resin composition containing a polar resin component and a laminate including a polar resin layer composed of the polar resin composition.
Polyolefin resins, representative examples thereof including polyethylene and polypropylene, have been used in various fields because of their low energy consumption for production, light weight and excellent recyclability.
However, polyolefin resins in general do not contain polar groups in their molecules, and therefore they have poor compatibility with polar resins such as polyamide, polyester, and an ethylene-vinyl alcohol copolymer (EVOH), resulting in a problem of making it difficult to utilize them by blending or stacking with these materials. In order to improve low compatibility between polyolefins and polar polymers, the mixture thereof may be sometimes further compounded with polyolefinic grafted polymers.
For example, Patent Literature 1 discloses a laminate having a polyolefin layer/a regrind layer/an ethylene-vinyl alcohol copolymer layer/a regrind layer/a polyolefin layer, stacked in this order, wherein the regrind layer is composed of a composition including (A) an ethylene-vinyl alcohol copolymer, (B) a polyolefin, and (C) a grafted polymer using a polyolefin, and the literature also describes that the laminate is excellent in, for example, impact resistant property.
Patent Literature 2 discloses a multilayer laminate having a recycled layer composed of an easily recyclable resin composition (D) including a polyolefin resin (B), an ethylene/vinyl alcohol copolymer (C), and a composition (A) including a modified polyethylene resin obtained by graft-modifying a polyethylene resin with, for example, an unsaturated carboxylic acid; and it also discloses, as a specific example of the modified polyethylene resin, a copolymer obtained by graft-modifying an ethylene/butene copolymer with maleic anhydride and a peroxide. Furthermore, the literature discloses that the modified polyethylene resin composition (A) has compatibilization ability to enhance the polyolefin resin (B) and the ethylene vinyl alcohol copolymer (C), resulting in that the multilayer laminate has excellent mechanical strengths such as an impact strength and a tensile elongation as well as its excellent appearance without yellowing as well.
Patent Literature 3 discloses that compounding of a low viscosity ethylene/α-olefin interpolymer modified with, for example, maleic anhydride compatibilizes an ethylenic polymer and a polar polymer, leading to improved optical properties and tensile properties of, for example, a film obtained from a composition including these polymers.
However, there has been room for further improvements in terms of transparency and mechanical strengths (in particular impact resistance, or impact resistance and puncture resistance) in conventional laminates with layers containing polar resins.
Thus, an object of the present invention is to provide a laminate having a layer including a polar resin with excellent transparency and mechanical strengths (in particular impact resistance, or preferably impact resistance and puncture resistance), and a polar resin composition for forming a polar resin layer of the laminate having such properties.
The present invention relates to, for example, [1] to [9] below.
[1]
A polar resin composition comprising:
[2]
The polar resin composition according to [1], wherein the modified ethylene/α-olefin copolymer (C) satisfies the following requirement (C-2):
Requirement (C-2): The density is 850 to 930 kg/m3.
[3]
The polar resin composition according to [1] or [2], wherein the resin component (B) is a mixture comprising:
[4]
The polar resin composition according to any one of [1] to [3], wherein the polar resin component (B) comprises a polar resin (BB) selected from the group consisting of a polyamide resin, a polyester resin, an ethylene/vinyl alcohol copolymer, an ethylene/vinyl acetate copolymer, and combinations thereof.
[5]
The polar resin composition according to [4], wherein the polyamide resin is an aliphatic polyamide resin.
[6]
A laminate comprising a polyethylene layer, a polar resin layer formed of the polar resin composition according to any one of [1] to [5], and a polyethylene layer, stacked in this order.
[7]
The laminate according to [6] having a film impact strength measured in accordance with JIS P8134 of 20 kJ/m or more.
[8]
The laminate according to [6] or [7] having an internal haze measured in accordance with JIS K7136 of 10% or less.
[9]
A regrind material obtained by pulverizing a formed product of the polar resin composition according to any one of [1] to [5].
A laminate having a layer including the polar resin composition of the present invention, has excellent transparency and mechanical strengths (in particular impact resistance, or preferably impact resistance and puncture resistance). Moreover, according to the polar resin composition of the present invention, a polar resin layer of the laminate having such properties can be formed.
The present invention will be more specifically described below.
[Polar Resin Composition]
The polar resin composition according to the present invention contains an ethylenic polymer (A), a polar resin component (B), and a modified ethylene/α-olefin copolymer (C).
<Ethylenic Polymer (A)>
Examples of the ethylenic polymer (A) include high-density polyethylene, low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and an ethylene/α-olefin (with 3 or more carbon atoms) copolymer.
A MFR (190° C., 2.16 kg load) of the ethylenic polymer (A) is preferably 0.5 to 50 g/10 minutes, more preferably 0.5 to 25 g/10 minutes, further preferably 0.5 to 10 g/10 minutes, and particularly preferably 1 to 10 g/10 minutes. The MFR (190° C., 2.16 kg load) of the ethylenic polymer (A) within this range renders excellent formability.
The density of the ethylenic polymer (A) is preferably 860 to 960 kg/m3, more preferably 880 to 950 kg/m3, further preferably 900 to 945 kg/m3, and preferably 920 to 940 kg/m3. The density of the ethylenic polymer (A) within this range results in excellent formability and rigidity.
A proportion of the ethylenic polymer (A) (excluding an ethylenic polymer (BA) contained in the polar resin component (B) described below) in the polar resin composition of the present invention is 5 to 30% by mass.
The lower limit value of the proportion of the ethylenic polymer (A) in the polar resin composition of the present invention is preferably 5% by mass, more preferably 6% by mass, and further preferably 8% by mass. The proportion of the ethylenic polymer (A) within the lower limit value or more results in providing excellent formability and excellent mechanical strengths.
The upper limit value of the proportion of the ethylenic polymer (A) in the polar resin composition of the present invention is, on the other hand, preferably 29% by mass, more preferably 28% by mass, and further preferably 25% by mass.
<Polar Resin Component (B)>
The polar resin component (B) is a component containing a polar resin (BB).
The polar resin (BB) is preferably selected from the group consisting of a polyamide resin, a polyester resin, an ethylene/vinyl alcohol copolymer, an ethylene/vinyl acetate copolymer, and combinations thereof, and more preferably selected from the group consisting of a polyamide and an ethylene/vinyl alcohol copolymer, and combinations thereof, and further preferably contains a polyamide resin.
Of the aforementioned polyamide resins, preferable are aliphatic polyamide resins, and more preferable are 6 nylon, 6,6 nylon, 11 nylon, and 12 nylon.
The melting point of the polyamide resin is preferably 150° C. to 330° C. and more preferably 150 to 270° C.
In the present invention, a blend of two or more polyamides, such as a mixture of 6 nylon and 6,6 nylon, can also be used as the polyamide resin.
The ethylene/vinyl alcohol copolymer is not particularly limited, and is a copolymer mainly having a constituent unit derived from ethylene and a constituent unit derived from a vinyl alcohol. The ethylene/vinyl alcohol copolymer is obtained, for example, by saponifying a copolymer composed of ethylene and a vinyl ester by using, for example, an alkali catalyst. Examples of a vinyl ester include a vinyl acetate as a representative compound, and other fatty acid vinyl esters such as vinyl propionate, and vinyl pivalate can also be used.
The ethylene/vinyl alcohol copolymer can also be copolymerized with, for example, a vinyl silane compound, propylene, butylene, an unsaturated carboxylic acid or esters thereof, and a vinyl pyrrolidone as copolymerization components.
The ethylene/vinyl alcohol copolymer preferably has a constituent unit derived from ethylene in an amount of 20 to 60 mol % and more preferably 25 to 50 mol %.
A MFR (190° C., 2.16 kg load) of the ethylene/vinyl alcohol copolymer is preferably 0.1 to 50 g/10 minutes, more preferably 0.5 to 20 g/10 minutes, and further preferably 0.7 to 10 g/10 minutes.
A proportion of the polar resin (BB) in the polar resin component (B) is preferably from 5 to 49.5% by mass and more preferably from 10 to 39.5% by mass.
The polar resin component (B) may further contain an ethylenic polymer (BA). Specific examples of the ethylenic polymer (BA) include specific examples of the ethylenic polymer (A). The ethylenic polymer (BA) may be the same as or different from the ethylenic polymer (A).
A proportion of the ethylenic polymer (BA) in the polar resin component (B) is preferably 50 to 90% by mass and more preferably 60 to 80% by mass.
The polar resin component (B) may further contain a modified ethylene/α-olefin copolymer (BC). Specific examples of the modified ethylene/α-olefin copolymer (BC) include the specific examples of the modified ethylene/α-olefin copolymer (C) described below. The modified ethylene/α-olefin copolymer (BC) may be the same as or different from the modified ethylene/α-olefin copolymer (C) described below.
A proportion of the modified ethylene/α-olefin copolymer (BC) in the polar resin component (B) is preferably 0.5 to 5% by mass and more preferably 0.5 to 1.5% by mass. The polar resin component (B) may also contain various additives that may be contained in a resin formed body containing the polar resin, in addition to the aforementioned components.
A proportion of the polar resin component (B) in the polar resin composition of the present invention is 40 to 85% by mass.
The lower limit value of the proportion of the polar resin component (B) in the polar resin composition of the present invention is preferably 42% by mass, more preferably 45% by mass, and further preferably 50% by mass.
The upper limit value of the proportion of the polar resin component (B) in the polar resin composition of the present invention is preferably 83% by mass, more preferably 80% by mass, and further preferably 70% by mass. The proportion of the polar resin component (B) within the above upper limit value or less results in providing the laminate of the present invention, having excellent formability, mechanical strengths, and transparency.
The polar resin component (B) is prepared by mixing the polar resin (BB), the ethylenic polymer (BA), the modified ethylene/α-olefin copolymer (BC) and optionally additives, and preferably by melt kneading and then pelletizing them.
<Modified Ethylene/α-Olefin Copolymer (C)>
The modified ethylene/α-olefin copolymer (C) is the one obtained by modifying an ethylene/α-olefin copolymer (C0) (which may be a composition of two or more types of ethylene/α-olefin copolymers) satisfying the following requirements (C0-1) and (C0-2) with an unsaturated carboxylic acid or a derivative thereof.
The modified ethylene/α-olefin copolymer (C) functions as a compatibilizer, i.e., it is considered to compatibilize the ethylenic polymer (A) and the polar resin component (B).
«Ethylene/α-olefin copolymer (C0)»
The α-olefin preferably has 3 to 10 carbon atoms and more preferably 3 to 8 carbon atoms.
Examples of the α-olefin include propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, and 1-octene with 1-butene being preferred.
The α-olefin may be used singly or two or more types thereof may be combined for use.
Specific examples of an ethylene/α-olefin copolymer (before modification) include an ethylene/propylene copolymer, an ethylene/1-butene copolymer, an ethylene/1-hexene copolymer, an ethylene/4-methyl-1-pentene copolymer, and an ethylene/1-octene copolymer, with the ethylene/1-butene copolymer being preferred among them. The ethylene/α-olefin copolymer is usually a random copolymer. The ethylene/α-olefin copolymers also include LLDPE.
The ethylene/α-olefin copolymer contains constituent units derived from ethylene as a major component (50% by mass or more relative to the total constituent units).
Requirement (C0-1):
The melt flow rate (190° C., 2.16 kg load) of the ethylene/α-olefin copolymer (C0) is preferably 0.1 to 50 g/10 minutes, more preferably 0.2 to 45 g/10 minutes, further preferably 0.5 to 30 g/10 minutes, and particularly preferably 0.5 to 20 g/10 minutes.
The melt flow rate within the above lower limit value or more results in providing the laminate of the present invention having excellent formability.
Requirement (C0-2):
The density of the ethylene/α-olefin copolymer (C0) is preferably 850 to 930 kg/m3, more preferably 855 to 925 kg/m3, further preferably 860 to 890 kg/m3, and particularly preferably 865 to 875 kg/m3. Since the density is within the above lower limit value or more, the laminate of the present invention has excellent formability and rigidity. Since the density is within the above upper limit value or less, the laminate of the present invention has excellent mechanical strengths (in particular impact resistance and preferably impact resistance and puncture resistance).
«Modified Ethylene/α-Olefin Copolymer (C)»
Examples of the unsaturated carboxylic acid include acrylic acid, methacrylic acid, maleic acid, fumaric acid, and itaconic acid.
Examples of the derivatives include acid anhydrides such as maleic anhydride, endic anhydride (cis-5-norbornene-endo-2,3-dicarboxylic anhydride), itaconic anhydride, and citraconic anhydride;
Of these unsaturated carboxylic acids and their derivatives, preferred are maleic acid and maleic anhydride, with maleic anhydride being more preferred.
The modified ethylene/α-olefin copolymer (C) may be used singly or in combinations with two or more thereof.
Ethylene/α-olefin copolymers can be modified with unsaturated carboxylic acids or derivatives thereof by conventionally publicly known methods, such as those described in the paragraph of patent literature WO2012/133008.
A degree of modification of the modified ethylene/α-olefin copolymer (C), defined by the formula below and calculated based on a peak intensity at wavenumber 1780 cm−1 assigned to a carbonyl group as measured by Fourier transform infrared spectroscopy, is, for example, 0.1 to 20% by mass, preferably 0.2 to 10% by mass, and more preferably 0.3 to 5% by mass. When the degree of modification of the modified ethylene/α-olefin copolymer (C) is within this range, the laminate of the present invention has excellent formability, mechanical strengths, and transparency.
Degree of modification (grafted amount) (% by mass)=(total mass of constituent units having a structure derived from a monomer having in the molecule an ethylenically unsaturated group and a group derived from an unsaturated carboxylic acid or derivatives thereof)/(mass of modified ethylene/α-olefin copolymer (C))×100
Requirement (C-1):
The melt flow rate (in accordance with ASTM D1238, 190° C., 2.16 kg load) of the modified ethylene/α-olefin copolymer (C) is 0.1 to 50 g/10 minutes, preferably 0.2 to 45 g/10 minutes, more preferably 0.3 to 43 g/10 minutes, further preferably 0.5 to 30 g/10 minutes, and particularly preferably 0.5 to 20 g/10 minutes.
When the melt flow rate is the above lower limit value or more, the laminate of the present invention has excellent formability. When the melt flow rate is the upper limit value or less, the laminate of the present invention has an excellent mechanical strength (in particular impact resistance and preferably impact resistance and puncture resistance).
The laminate of the present invention has excellent mechanical strengths (in particular impact resistance and preferably impact resistance and puncture resistance) because of its melt flow rate being the upper limit value or less. The reason therefore is presumed to be increased entanglements of molecular chains of the modified ethylene/α-olefin copolymer (C) present at interfaces with the polar resin (BB) contained in the polar resin component (B), the ethylenic polymer (A), and the ethylenic polymer (BA).
Requirement (C-2):
The density of the modified ethylene/α-olefin copolymer (C) is, for example, 850 to 930 kg/m3, preferably 855 to 925 kg/m3, more preferably 860 to 890 kg/m3, further preferably 863 to 887 kg/m3, and particularly preferably 865 to 875 kg/m3.
In the case of the density being the lower limit value or more, the laminate of the present invention has excellent formability and rigidity. In the case of the density being the upper limit value or less, the laminate of the present invention has excellent mechanical strengths (in particular impact resistance and preferably impact resistance and puncture resistance).
A proportion of the modified ethylene/α-olefin copolymer (C) in the polar resin composition according to the present invention is 10 to 40% by mass.
The lower limit value of the proportion of the modified ethylene/α-olefin copolymer (C) in the polar resin composition of the present invention is preferably 11% by mass, more preferably 12% by mass, and further preferably 15% by mass. The upper limit value of the proportion of the modified ethylene/α-olefin copolymer (C) in the polar resin composition of the present invention is, on the other hand, preferably 39% by mass, more preferably 38% by mass, and further preferably 35% by mass. When the proportion of the modified ethylene/α-olefin copolymer (C) stays within the range, the laminate of the present invention has excellent transparency and rigidity.
[Laminate]
The laminate according to the present invention is a laminate having a polyethylene layer, a polar resin layer and a polyethylene layer, stacked in this order, and wherein the polar resin layer is formed of the polar resin composition according to the present invention described above.
<Polyethylene Layer>
The polyethylene layer is a layer composed of polyethylene, and examples of the polyethylene include ethylenic polymers such as high-density polyethylene, low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), an ethylene/α-olefin (with 3 or more carbon atoms) copolymer.
The thicknesses of the two polyethylene layers are each independently usually from 3 to 50 μm, preferably from 3 to 50 μm, more preferably from 4 to 40 μm, further preferably from 5 to 20 μm, and particularly preferably from 6 to 15 μm.
<Polar Resin Layer>
The polar resin layer is a layer formed of the polar resin composition according to the present invention.
The polar resin layer can be formed by melt kneading the polar resin composition according to the present invention by using, for example, an extruder, and then shaping the resultant.
The thickness of the polar resin layer is usually 4 to 300 μm, preferably 15 to 150 μm, more preferably 25 to 90 μm, further preferably 30 to 70 μm, and particularly preferably 40 to 60 μm.
<Optional Layers>
The laminate according to the present invention may further have a layer other than the two polyethylene layers and the polar resin layer (hereinafter also described as “optional layer”). A type, thickness, number, and position of the optional layer in the laminate are not particularly limited, and can be appropriately set with reference to conventionally publicly known laminates.
(Laminate)
The laminate according to the present invention is usually in the form of film or sheet, and its thickness is usually from 10 to 360 μm, preferably from 20 to 300 μm, more preferably from 30 to 190 μm, further preferably from 40 to 110 μm, and particularly preferably from 50 to 90 μm.
In each layer constituting the laminate according to the present invention, additives such as fillers, stabilizers, nucleating agents, antistatic agents, flame retardants, and foaming agents, may be compounded to the extent that the effects of the present invention are not impaired.
A film impact strength of the laminate according to the present invention, as measured in accordance with JIS K7136, is preferably 14 kJ/m or more, more preferably 16 kJ/m or more, further preferably 18 kJ/m or more, and particularly preferably 20 kJ/m or more, the upper limit thereof may be, for example, 40 kJ/m.
The internal haze of the laminate according to the present invention, as measured in accordance with JIS K7136, is preferably 10% or less and more preferably 6% or less, the lower limit thereof may be, for example, 0.1%.
(Production Method of Laminate)
The laminate according to the present invention can be produced by conventionally publicly known methods, except that the polar resin layer is formed of the polar resin composition of the present invention as described above. Examples of the production method include a method including separately supplying a raw material for the polyethylene layer, a raw material for the polar resin layer (i.e., the polar resin composition of the present invention), and a raw material for another polyethylene layer to respective extruders, melting each therein, then stacking them after having been merged, and extruding the obtained laminate from a T-die into a sheet form (co-extrusion method).
(Laminate)
As examples of applications of the laminate according to the present invention, it is used for packaging materials, in particular, materials for packaging foodstuffs, pharmaceuticals, industrial parts, and electronic materials, for example. The laminate can also be applied, for example, to packaging films for inner bags of back-in-boxes, which are often filled with highly fluid materials such as liquids, or to packaging films such as pillow packaging and vacuum-formed packaging, which are used as packaging of processed meats, processed marine products and electronic materials. In particular, the laminate can be suitably used as packaging films for electronic components such as capacitors with hard corners, or packaging films for meat with bones, food containing a lot of spices and foods with irregularly shaped and hard portions such as shells.
The present invention will be described by way of Examples, however, the present invention is not limited to Examples below.
[Measurement Method and Evaluation Method]
«Raw Materials»
The properties of the raw materials (polymers) used in Examples and the like were measured as follows.
(Degree of Modification)
The degree of modification (maleic anhydride content) of a compatibilizer, expressed in the following formula was determined from a separately prepared calibration curve based on the peak intensity at wavenumber 1780 cm−1 assigned to a carbonyl group measured by FT-IR.
Degree of modification (% by mass)=(total mass of constituent units having a structure derived from a monomer having in the molecule an ethylenically unsaturated group and a group derived from maleic anhydride)/mass of compatibilizer)×100
(Melt Flow Rate)
The melt flow rate (MFR) was measured in accordance with ASTM D1238 at 190° C. and a load of 2.16 kg.
(Density)
The density was measured in accordance with ASTM D1505.
«Laminate film» Properties of the laminate films produced in Examples and the like were measured or evaluated as follows.
(Tensile Properties)
A test piece with 15 mm wide×150 mm long was cut from the 70 μm thick film obtained in Examples and the like. Then, in accordance with JIS K7127, a tensile modulus (YM) (unit: MPa), tensile elongation at break (EL) (unit: %) and tensile strength at break (TS) (unit: MPa) of the test piece were measured using a universal material testing machine “AG-X-5” manufactured by Shimadzu Corporation under the conditions of a distance of 50 mm between chucks, a tensile rate of 300 mm/min and a temperature of 23° C.
(Puncture Energy (Puncture Resistance))
A universal material testing machine “AG-5kNX” manufactured by Shimadzu Corporation was used to measure energy required to puncture a film sample with a needle with a tip having a shape of 1 mm cp at a rate of 50 mm/min and −20° C. and pierce it through in accordance with JIS 21707 (hereinafter referred to as “puncture energy”).
(Film Impact Strength (Impact Resistance)) the Film Impact Strength at −20° C. was Measured by Using a film impact tester with an impact head having a spherical shape: 1 inch φ, manufactured by Toyo Seiki Seisaku-sho, Ltd., in accordance with JIS P8134.
(Internal Haze (Transparency))
A haze meter “HM-150” manufactured by Murakami Color Research Laboratory was used to measure the films (thickness of 70 μm) fabricated in Examples and the like in cyclohexanol, in accordance with JIS K7136 and to calculate an internal haze in accordance with the following formula.
Internal haze (%)=100×(amount of diffused transmitted light)/(total amount of transmitted light)
[Raw Materials]
The polymers used as raw materials in Examples and the like are as follows.
A commercially available linear low-density polyethylene (MFR (190° C., 2.16 kg load) 15 g/10 minutes, density 914 kg/m3)
A commercially available linear low-density polyethylene (MFR (190° C., 2.16 kg load) 19 g/10 minutes, density 918 kg/m3)
A commercially available linear low-density polyethylene (MFR (190° C., 2.16 kg load) 3.4 g/10 minutes, density 923 kg/m3)
A commercially available ethylene/l-butene copolymer (MFR (190° C., 2.16 kg load) 0.5 g/10 minutes, density 870 kg/m3)
A commercially available ethylene/l-butene copolymer (MFR (190° C., 2.16 kg load) 35 g/10 minutes, density 870 kg/m3)
A commercially available ethylene/l-butene copolymer (MFR (190° C., 2.16 kg load) 3.6 g/10 minutes, density 870 kg/m3)
A polyamide resin (6-nylon) (AMILAN (registered trademark) CM1021XF, melting point 225° C., manufactured by Toray Industries, Inc.)
An ethylene/vinyl alcohol resin (EVAL (registered trademark) F101A, 32 mol % content of constituent units derived from ethylene, MFR (190° C., 2.16 kg load): 1.6 g/10 minutes, manufactured by KURARAY CO., LTD.)
[Preparation of Compatibilizer]
The following are preparation methods of the compatibilizers (Q-1) to (Q-5) used in Examples described below.
(Preparation of Compatibilizer (Q-1))
A solution of 150 g of maleic anhydride (MAH) and 6 g of PERHEXA (registered trademark) 25B (manufactured by Nippon Yushi Industry Co., Ltd.) dissolved in acetone, and 10 kg of LLDPE-1 were blended to obtain a blend 1. The blend 1 was then fed through a hopper of a twin-screw extruder with a screw diameter of 32 mm and L/D=42, and extruded into strands at a resin temperature of 200° C., screw speed of 240 rpm, and discharge rate of 12 kg/hr. The resulting strands were cooled sufficiently and granulated to obtain a compatibilizer (Q-1). Table 1 shows the physical properties of compatibilizer (Q-1).
(Preparation of Compatibilizer (Q-2))
A solution of 60 g of MAH and 2 g of PERHEXA 25B dissolved in acetone and 10 kg of the LLDPE-2 were blended to obtain a blend 2. A compatibilizer (Q-2) was obtained in the same manner as the preparation of compatibilizer (Q-1), except that the blend 1 was changed to the blend 2. Table 1 shows the physical properties of compatibilizer (Q-2).
(Preparation of Compatibilizer (Q-3))
A solution of 50 g of MAH and 2 g of PERHEXA 25B dissolved in acetone, and 10 kg of EBR-1 were blended to obtain a blend 3. A compatibilizer (Q-3) was obtained in the same manner as the preparation of compatibilizer (Q-1), except that the blend 1 was changed to the blend 3. Table 1 shows the physical properties of compatibilizer (Q-3).
(Preparation of Compatibilizer (Q-4))
A solution of 50 g of MAH and 2 g of PERHEXA 25B dissolved in acetone, and 10 kg of EBR-2 were blended to obtain a blend 4. A compatibilizer (Q-4) was obtained in the same manner as the preparation of compatibilizer (Q-1), except that the blend 1 was changed to the blend 4. Table 1 show the physical properties of compatibilizer (Q-4).
(Preparation of Compatibilizer (Q-5))
A solution of 50 g of MAH and 2 g of PERHEXA 25B dissolved in acetone, and 10 kg of EBR-3 were blended to obtain a blend 5. A compatibilizer (Q-5) was obtained in the same manner as the preparation of compatibilizer (Q-1), except that the blend 1 was changed to the blend 5. Table 1 shows the physical properties of compatibilizer (Q-5).
[Preparation of Polar Resin Component]
The following are preparation methods of the polar resin components (B-1) to (B-3) used in Examples described below.
[Preparation of Polar Resin Component (B-1)]
LLDPE-3, PA6, and the compatibilizer (Q-1) were blended in the mass ration of 70/29/1, respectively, as described in Table 2, and then supplied to a single-screw extruder (L/D=26, 40 mm φ) set at 250° C. to prepare pellets of a polar resin component (B-1). The resulting pellets of the polar resin component (B-1) were dried at 80° C. for one day and night.
[Preparation of Polar Resin Component (B-2)]
A polar resin component (B-2) was obtained in the same manner as the polar resin component (B-1), except that LLDPE-3, EVOH, and the compatibilizer (Q-1) were blended in the mass ratio of 90/8/2, respectively, as described in Table 2, instead of the blend of the LLDPE-3, PA6, and compatibilizer (Q-1).
[Preparation of Polar Resin Component (B-3)]
A polar resin component (B-3) was obtained in the same manner as the polar resin component (B-1), except that LLDPE-3, PA6, EVOH, and the compatibilizer (Q-1) were blended in the mass ratio of 64/25/10/1, respectively, as described in Table 2, instead of the blend of the LLDPE-3, PA6, and compatibilizer (Q-1).
(Production of Laminate Film)
The resin for skin layers (polyethylene layers) and the polar resin composition for an intermediate layer (polar resin layer) shown below, were supplied to respective extruders, and the extrusion amount of each extruder was set so that a resin temperatures was 250° C. and thicknesses of the skin layer, intermediate layer, and skin layer were 10 μm/50 Tim/10 μm in this order, by using a die (die width 350 mm cp, lip gap 1 mm) to obtain a 70 μm thick multilayer film by coextrusion molding. The molding speed was 4 m/min.
LLDPE-3
A resin composition obtained by blending the LLDPE-3, the polar resin component (R-1), and the compatibilizer (Q-1) in a mass ratio of 20/60/20, respectively.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-1) in a mass ratio of 10/60/30, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-2) in a mass ratio of 20/60/20, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-2) in a mass ratio of 10/60/30, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-3) in a mass ratio of 20/60/20, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-3) in a mass ratio of 10/60/30, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-4) in a mass ratio of 20/60/20, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-4) in a mass ratio of 10/60/30, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-5) in a mass ratio of 20/60/20, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-1), and the compatibilizer (Q-5) in a mass ratio of 10/60/30, respectively. The results are shown in Table 3.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-1) in a mass ratio of 30/60/10, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-1) in a mass ratio of 20/60/20, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-2) in a mass ratio of 30/60/10, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-2) in a mass ratio of 20/60/20, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-3) in a mass ratio of 30/60/10, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-3) in a mass ratio of 20/60/20, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-4) in a mass ratio of 30/60/10, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-4) in a mass ratio of 20/60/20, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-5) in a mass ratio of 30/60/10, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-5) in a mass ratio of 20/60/20, respectively. The results are shown in Table 4.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-3), and the compatibilizer (Q-1) in a mass ratio of 30/60/10, respectively. The results are shown in Table 5.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-3), and the compatibilizer (Q-1) in a mass ratio of 20/60/20, respectively. The results are shown in Table 5.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-3), and the compatibilizer (Q-3) in a mass ratio of 30/60/10, respectively. The results are shown in Table 5.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-3), and the compatibilizer (Q-4) in a mass ratio of 30/60/10, respectively. The results are shown in Table 5.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-3), and the compatibilizer (Q-4) in a mass ratio of 20/60/20, respectively. The results are shown in Table 5.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3 and the polar resin component (B-1) in a mass ration of 40/60, respectively. The results are shown in Table 6.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3 and the polar resin component (B-2) in a mass ratio of 40/60, respectively. The results are shown in Table 6.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-1) in a mass ratio of 35/60/5, respectively. The results are shown in Table 6.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3, the polar resin component (B-2), and the compatibilizer (Q-4) in a mass ratio of 35/60/5, respectively. The results are shown in Table 6.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to a resin composition obtained by blending the LLDPE-3 and the polar resin component (B-3) in a mass ratio of 40/60, respectively. The results are shown in Table 6.
A multilayer film was obtained in the same manner as in Example 1, except that the polar resin composition for the intermediate layer was changed to the LLDPE-3. The results are shown in Table 6.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2021-055948 | Mar 2021 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2022/010189 | 3/9/2022 | WO |
