Claims
- 1. An acid-functional polymer having a poly(alkylene carbonate) backbone and on the average at least about 0.05 and up to one terminal acid group per molecule or a salt thereof.
- 2. The acid-functional polymer of claim 1 comprising (I) a random poly(alkylene carbonate) polyahl obtained by reacting a monofunctional C.sub.4-30 alcohol, alcohol alkoxylate, mercaptan, mercaptan alkoxylate, carboxylic acid, carboxylic acid alkoxylte, primary or secondary amine, primary or secondary amine alkoxylate, C.sub.3-24 alkylphenol or alkylphenol alkoxylate with
- (a) an alkylene carbonate,
- (b) an alkylene oxide and carbon dioxide,
- (c) an alkylene carbonate, alkylene oxide and carbon dioxide or
- (d) a poly(alkylene carbonate) polyahl, and (II) a residue of a donor capable of reacting with said random polyahl to add a terminal acidic group thereto.
- 3. The polymer of claim 2 wherein the donor capable of reacting with said random polyahl to add a terminal acidic group thereto is selected from the group consisting of cyclic organic acid anhydrides, halo and haloalkyl sulfonic acids, halo and haloalkyl carboxylic acids and inorganic acid anhydrides.
- 4. The polymer of claim 3 wherein the donor capable of reacting with said random polyahl to add a terminal acidic group is a cyclic organic acid anhydride selected from the group consisting of succinic anhydride, phthalic anhydride and maleic anhydride.
- 5. The acid-functional polymer of claim 1 in the form of a metal salt, amine salt or ammonium salt.
- 6. The acid-functional polymer of claim 5 wherein the salt is selected from the group consisting of alkali metal and alkaline earth metal salts, alkyl, cycloalkyl, alkylaryl and aralkyl amine salts, hydroxyalkyl, hydroxycycloalkyl, hyroxyalkylaryl, hydroxyaralkyl amine, and ammonium salts.
- 7. The acid-functional polymer of claim 1 having the formula
- R.sup.1 --(X).sub.n --(Y).sub.m --(I).sub.k --O--A
- wherein
- R.sup.1 is independently in each occurrence a C.sub.1-24 aliphatic, C.sub.6-24 cycloaliphatic, a C.sub.1-24 aliphatic or C.sub.6-24 cycloaliphatic alkoxylate containing 1-30 alkyleneoxy moieties, a C.sub.3-24 alkyl substituted phenol or a C.sub.1-24 hydrocarbon substituted with one or more substituents having oxygen, nitrogen or sulfur,
- X is separately in each occurrence --ZCOOC(R.sup.2).sub.2 --C(R.sup.2).sub.2 --O--C(R.sup.2).sub.2 --C(R.sup.2).sub.2 --, wherein Z is separately in each occurrence selected from the group consisting of --O, --S, --NH or --NR.sup.3, wherein R.sup.3 is C.sub.1-24 alkyl,
- Y is separately in each occurrence --O--C(RHU 2).sub.2 --C(R.sup.2).sub.2 --, wherein R.sup.2 is independently in each occurrence hydrogen, C.sub.1-20 alkyl, C.sub.1-20 haloalkyl, C.sub.1-20 alkenyl or phenyl,
- I is separately in each occurrence the residue of a polyfunctional C.sub.2-24 aliphatic, C.sub.6-30 cycloaliphatic or C.sub.6-30 aromatic alcohol, mercaptan, amine or phenol which optionally also contains one or more oxygen, nitrogen or sulfur,
- m is independently in each occurrence 0 to 200,
- n is independently in each occurrence 1 to 40, and
- k is independently in each occurrence 0 to 8,
- A is an acid functional moiety; with the proviso that X, Y and I are randomly spaced in the polymer backbone.
- 8. The acid-functional polymer of claim 7 wherein
- R.sup.1 is independently in each occurrence a monovalent C.sub.1-20 alkane, or C.sub.6-20 cycloalkane or C.sub.6-20 alkyl which contains 1-15 alkyleneoxy moieties, substituted with hydrogen or one or more oxygen, nitrogen or sulfur moieties;
- R.sup.2 is independently in each occurrence hydrogen, halogen, nitro, cyano, C.sub.1-20 hydroxycarbyl substituted with hydrogen or one or more of halo, cyano, nitro, thioalkyl, tert-amino, C.sub.1-18 alkoxy, C.sub.6-18 aryloxy, C.sub.7-20 aralkoxy, carbonyl dioxy(C.sub.1-18)alkyl, carbonyl dioxy(C.sub.6-20)aryl, carbonyl dioxy(C.sub.7-20)aralkyl, C.sub.1-18 alkoxy carbonyl, C.sub.6-20 aryloxycarbonyl, C.sub.7-20 aralkoxycarbonyl, C.sub.1-18 alkylcarbonyl, (C.sub.6-20) aralcarbonyl, C.sub.7-20 aralkylarbonyl, C.sub.1-18 alkylsulfinyl, C.sub.6-20 arylsulfinyl, (C.sub.7-20) aralkylsulfinyl, C.sub.1-18 alkylsulfonyl, C.sub.6-20 arylsulfonyl or C.sub.7-20 aralkylsulfonyl.
- 9. The acid-functional polymer of claim 8 wherein
- R.sup.1 is a monovalent C.sub.4-18 alkane or C.sub.6-18 cycloalkane, substituted with hydrogen or one or more oxygen, nitrogen or sulfur groups,
- R.sup.2 is hydrogen, C.sub.1-3 alkyl, C.sub.2-3 alkenyl, or phenyl,
- B is an organic carboxylic acid or carboxylic acid salt, and
- k is O.
- 10. The acid-functional polymer of claim 1 having an average moleculr weight between about 200 and 10,000.
- 11. The acid-functional polymer of claim 10 wherein the average molecular weight is between about 200 and 3000.
- 12. An acid-functional poly(alkylene carbonate) polyahl prepared by a process comprising
- reacting a random non-ionic poly(alkylene carbonate) polyahl obtained by reacting a monofunctional (C.sub.4 -C.sub.30) alcohol, carboxylic acid, primary or secondary amine, mercaptan, (C.sub.3 -C.sub.24) alkyl phenol or alkoxylates thereof with
- (a) an alkylene carbonate,
- (b) an alklene oxide and CO.sub.2,
- (c) an alkylene oxide, an alkylene carbonate and CO.sub.2, or
- (d) a poly(alkylee carbonate) polyahl, to obtain a random non-ionic poly(alkylene carbonate) polyahl,
- admixing a compound capable of reacting with the reaction product to add a terminal acidic group thereto; the proportion of said random non-ionic poly(alkylene carbonate) polyahl to said compound between about 20:1 and 1:1.
- 13. A stable water-based emulsion or dispersion comprising
- a surfactant composition comprising between about 5 weight percent and 95 weight percent of the polyahl of claim 1, and
- between about 95 weight percent and 5 weight percent of a non-ionic polymer; and
- one or more materials selected from the group consisting of polyether polyahls, polyester polyahls and poly(alkylene carbonate) polyahls.
- 14. The polymer of claim 2 wherein the terminal acidic group is --COOH, --SO.sub.2 H, --SO.sub.3 H, --SO.sub.4 H, --PO.sub.4 H.sub.2, --PO.sub.3 H.sub.2 or sulfosuccinate.
Parent Case Info
This is a divisional of application Ser. No. 909,992, filed Sept. 22, 1986, now U.S. Pat. No. 4,745,162 issued 5/17/88.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4686274 |
Harris et al. |
Aug 1987 |
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Divisions (1)
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Number |
Date |
Country |
Parent |
909992 |
Sep 1986 |
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