Claims
- 1. A new water-insoluble polymeric composition having polythiaacetal-ketal linkages therein, of the formula: ##STR21## wherein: R.sub.1 and R.sub.4 are independently selected from the group consisting of hydrogen and a monovalent residue of monomercaptans and monoalcohols, said monovalent residue that forms terminal groups being present in the statistical average polymer chain at least to about 50 mole percent of the terminal groups, and R.sub.1 and R.sub.4 are not both hydrogen in the statistical average polymer chain; R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and perchlorocarbyl and chlorohydrocarbyl radicals each having from 1 to 10 carbon atoms. X.sub.1, X.sub.2, X.sub.3 and X.sub.4 being independently selected from the group consisting of sulphur and oxygen with at least 30 mole percent of sulfur present in the total selection; A is the divalent residue of the compounds selected from the group consisting of dimercaptans, monomercapto alcohols and diols; and n is an integer from 2 to 50; said monovalent residue selected from the group consisting of primary alkyl, thia-alkyl, oxa-alkyl, aralkyl, alkenyl and mixtures thereof; and said divalent residue selected from the group consisting of primary alkylene, thia-alkylene, oxa-alkylene, aralkylene, and mixtures thereof.
- 2. The composition of claim 1 in which the divalent residue is derived from a dimercaptan having from 4 to 20 carbon atoms.
- 3. The composition of claim 1 in which the divalent residue is derived from a monomercapto alcohol having from 4 to 20 carbon atoms.
- 4. The composition of claim 1 in which the divalent residue is derived from a diol having from 4 to 20 carbon atoms.
- 5. The composition of claim 1 in which the monovalent residue is derived from a monoalcohol having from 7 to 20 carbon atoms.
- 6. The composition of claim 1 in which the monovalent residue is derived from a monomercaptan having from 7 to 20 carbon atoms.
- 7. The composition of claim 1 in which is the liquid phase reaction product of a mercaptan, an aldehyde, and a diol.
- 8. The composition of claim 1 which is the liquid phase reaction product of a mercaptan, an aldehyde, and a dimercaptan.
- 9. The composition of claim 1 which is the liquid phase reaction product of a mercaptan, an aldehyde, and a monomercapto alcohol.
- 10. The composition of claim 1 which is the liquid phase reaction product of mercaptan, a ketone, and a diol.
- 11. The composition of claim 1 which is the liquid phase reaction product of mercaptan, a ketone, and a dimercaptan.
- 12. The composition of claim 1 which is the liquid phase reaction product of mercaptan, a ketone, and a monomercapto alcohol.
- 13. The composition of claim 7 in which the aldehyde is paraformaldehyde.
- 14. The composition of claim 10 in which the ketone is acetophenone.
- 15. The composition of claim 1 in which diol moiety in the polymer chain is not greater than 50% by weight of dimercaptan and 25% by weight of monomercapto alcohol.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of application Ser. No. 300,685 entitled "Novel Plasticizer Compositions and Method for Their Preparation," filed Oct. 25, 1972, now abandoned.
US Referenced Citations (8)
Non-Patent Literature Citations (2)
Entry |
Lienhard et al., J. Am. Chem. Soc. 88 pp. 3982-3995 (1966). |
Walker; "Formaldehyde" (1963) pp. 279-280. |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
300685 |
Oct 1972 |
|