Claims
- 1. A fluorescent pigment composition comprising a solid state solution of fluorescent dye dissolved in a resin which is a condensation product of a diamine of the formula:
- H.sub.2 N--R--NH.sub.2
- wherein R is a straight or branched chain alkylene group of from 2 to 20 carbon atoms, or a cycloalkylene group of from 5 to 6 carbon atoms optionally having up to three ring substitutions which may be the same or different, selected from the group consisting of C.sub.1 -C.sub.5 alkyl; and a diacid of the formula:
- R'(COOH).sub.2
- wherein R' is a straight or branched chain alkylene group of from 3 to 20 carbon atoms, a cycloalkylene group of from 5 to 6 carbon atoms optionally having up to three ring substitutions which may be the same or different, selected from the group consisting of C.sub.1 -C.sub.5 alkyl, or a mono-cyclic or bicyclic arylene group of from 6 to 10 carbon atoms optionally having up to six ring substitutions which may be the same or different selected from the group consisting of C.sub.1 -C.sub.5 alkyl, or a C.sub.1 -C.sub.2 dialkyl ester or an anhydride of said diacid, said diacid being present in an excess stoichiometric amount to form said condensation product, said resin consisting essentially of polymers having a weight-average molecular weight in the range from about 3,000 to about 50,000.
- 2. A pigment composition according to claim 1, wherein R is a branched chain alkylene group of from 4 to 16 carbon atoms and said diacid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, adipic acid, azelaic acid and mixtures thereof.
- 3. A pigment composition according to claim 2, wherein said resin has a weight-average molecular weight in the range of from about 4,000 to about 15,000.
- 4. A pigment composition according to claim 3, wherein from about 1.5 to about 1.0 moles of diacid are present for each mole of diamine in said resin.
- 5. A pigment composition according to claim 4, wherein said pigment includes from about 0.5 to about 15% fluorescent dye based on the total weight of the pigment.
- 6. A pigment composition according to claim 5, wherein said composition is a particulate ranging in particle size from about 10 to about 50 microns.
- 7. A pigment composition according to claim 6, including a modifier selected from the group consisting of bifunctional acids, monofunctional acids, monofunctional amines, monofunctional alcohols, epoxies, glycols, metal oxides, metal carbonates and metal acetates, said modifier comprising from about 1 to about 10% by weight of said pigment composition.
- 8. A pigment composition according to claim 2, wherein said diamine is selected from the group consisting of 2-methylpentamethylenediamine and 1-amino-3-aminomethyl-3,5,5-trimethyl cyclohexane and said diacid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, adipic acid, azelaic acid and mixtures thereof.
- 9. A masterbatch colorant for use in coloring a first plastic comprising a melt blend of a second plastic and said pigment composition according to claim 1.
- 10. A masterbatch colorant according to claim 9, wherein said colorant contains from about 30 to about 50% by weight of said pigment composition based on the weight of the colorant.
- 11. A masterbatch colorant according to claim 10, wherein said pigment composition and said second plastic comprise a homogeneous melt blend.
- 12. A masterbatch colorant according to claim 10, wherein said first and second plastic are the same.
- 13. A masterbatch colorant according to claim 12, wherein said diamine is selected from the group consisting of 2-methylpentamethylenediamine and 1-amino-3-aminomethyl-3,5,5-trimethyl cyclohexane and said diacid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, adipic acid, azelaic acid and mixtures thereof.
- 14. A method for imparting fluorescent color properties to a plastic to be molded comprising forming a mixture of the plastic to be molded and a colorant including the pigment composition according to claim 1, heating the mixture to form a homogeneous melt of said plastic and colorant, and molding said melt.
- 15. A method according to claim 14, wherein said colorant is a masterbatch colorant comprising a melt blend of a portion of the plastic to be molded and said pigment composition.
- 16. A method according to claim 15, wherein said masterbatch colorant contains from about 30 to about 50% by weight of said pigment composition based on the weight of the colorant.
- 17. A method according to claim 16, wherein said pigment is dispersed in a matrix of said plastic to be molded.
- 18. A method according to claim 17, wherein said melt blend is provided by extruding a blend of said pigment composition and said plastic to be molded and pelletizing the extruded blend.
- 19. A method according to claim 14, wherein said diamine is selected from the group consisting of 2-methylpentamethylenediamine and 1-amino-3-aminomethyl-3,5,5-trimethyl cyclohexane and said diacid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, adipic acid, azelaic acid and mixtures thereof.
- 20. A fluorescent pigment composition comprising a solid state solution of fluorescent dye dissolved in a resin which is a condensation product of a diamine of the formula:
- H.sub.2 N--R--NH.sub.2
- wherein R is a straight or branched chain alkylene group of from 2 to 20 carbon atoms, or a cycloalkylene group of from 5 to 6 carbon atoms optionally having up to three ring substitutions which may be the same or different, selected from the group consisting of C.sub.1 -C.sub.5 alkyl; and a diacid of the formula:
- R'(COOH).sub.2
- wherein R' is a straight or branched chain alkylene group of from 3 to 20 carbon atoms, a cycloalkylene group of from 5 to 6 carbon atoms optionally having up to three ring substitutions which may be the same or different, selected from the group consisting of C.sub.1 -C.sub.5 alkyl, or a mono-cyclic or bicyclic arylene group of from 6 to 10 carbon atoms optionally having up to six ring substitutions which may be the same or different selected from the group consisting of C.sub.1 -C.sub.5 alkyl, or a C.sub.1 -C.sub.2 dialkyl ester or an anhydride of said diacid, said diacid being present in an excess stoichiometric amount ranging from about 1.5 to about 1.0 moles of diacid for each mole of diamine present to form said condensation product, said resin consisting essentially of polymers having a weight-average molecular weight in the range from about 3,000 to about 15,000.
- 21. A pigment composition according to claim 20, wherein said diamine is selected from the group consisting of 2-methylpentamethylenediamine and 1-amino-3-aminomethyl-3,5,5-trimethyl cyclohexane and said diacid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, adipic acid, azelaic acid and mixtures thereof.
Parent Case Info
This is a continuation of application Ser. No. 409,099, filed Sept. 19, 1989 now abandoned.
US Referenced Citations (6)
Foreign Referenced Citations (1)
Number |
Date |
Country |
47-14702 |
May 1972 |
JPX |
Continuations (1)
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Number |
Date |
Country |
Parent |
409099 |
Sep 1989 |
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