Claims
- 1. Tri-, tetra- and penta-azamacrocyclic complexes O transition metals of formulas (IV), (V) or (VI): in which n, m, p, q and r, which can be the same or different, are equal to 2 or 3, M is a transition metal that is selected from the group consisting of Ti, Mn, Fe, CO, Ni, Cu, Ru, Rh and Ir, R1 is a solid support and R2 represents a hydrogen atom or the group (CH2)2—R3, R3 is a functional group that is selected from the group consisting of COOH, CONH2, CH2OH, CN and COOR4, R4 representing an alkyl or benzyl group, or R2 representing (CH2)—R5, R5 representing COOH or PO3R6, and R6 representing hydrogen or an alkyl group, with the exclusion (a) of polyazacycloalkanes of formula (II): in which R1 represents a solid support derived from silica and complying with the formula: S representing a silca gel, each R2 represents a hydrogen atom and (i) n and p are equal to 2 and m and q are equal to 3 or (ii) n and p are equal to 3 and m and q are equal to 2 and and (b) polyazacycloalkanes of formula (II) in which R1 represents a solid support consisting of an organic polymer and each R2 represents a hydrogen atom.
- 2. Tri-, tetra- and penta-azamacrocyclic complexes according to claim 1 wherein R1 is a solid support comprising a crosslinked or non-crosslinked organic polymer or is a solid support derived from silica and having the formula: or the formula: S representing a silica gel, b is an integer between 1 and 4, and R7 an alkyl group or a hydrogen atom.
- 3. Tri-, tetra- and penta-azamacrocyclic complexes according to claim 2 wherein the solid support is a radical of a crosslinked or non-crosslinked, organic polymer with an alkyl halide termination.
- 4. Tri-, tetra- and penta-azamacrocyclic complexes according to claim 2 wherein b is equal to 3.
Priority Claims (1)
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94 11904 |
Oct 1994 |
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Parent Case Info
This application is a continuation of application Ser. No. 09/189,805, filed Nov. 12, 1998 now U.S. Pat. No. 6,174,505, which is divisional of Application Ser. No. 08/646,330 filed Apr. 25, 1997 now U.S. Pat. No. 5,891,574, which was filed as PCT/FR95/01287, filed Oct. 4, 1995.
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Continuations (1)
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09/189805 |
Nov 1998 |
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09/667506 |
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