Claims
- 1. Fibers or films of (co)polyazomethines consisting essentially of the following recurring structural units ##STR96## wherein units I and II are present in substantially equimolar amounts; Z.sub.1 and Z.sub.2, which may be the same or different, are selected from the group of a hydrogen atom or a methyl or ethyl radical; and R.sub.1 and R.sub.2, are radicals selected from the group of (1) single and fused 6-membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system, if attached to a single ring, are positioned 1,4- to each other, and if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions and R.sub.1 may be a chemical bond.
- 2. Fibers or films of claim 1 wherein up to 40 mol % of the total I and II units are replaced by polyazomethine forming unit(s) not conforming to those previously described.
- 3. Fiber or films according to claim 1 of polymer wherein at least 25% of the total number of ring systems in such units I and II are ring-substituted with a member of the group consisting of chloro- and methyl radicals.
- 4. Fibers of claim 1 having a tenacity of at least 10 gpd, a modulus of at least 150 gpd, an X-ray orientation angle of less than 45.degree., an elongation of at least 2% and which will not melt below 175.degree. C.
- 5. As-spun fibers having an X-ray orientation angle of less than 45.degree. of (co)polyazomethines consisting essentially of the following recurring structural units ##STR97## wherein units I and II are present in substantially equimolar amounts; Z.sub.1 and Z.sub.2 which may be the same or different, are selected from the group of a hydrogen atom or a methyl or ethyl radical; and R.sub.1 and R.sub.2 are radicals selected from the group of (1) single and fused 6-membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system, if attached to a single ring, are positioned 1,4- to each other, and, if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions and R.sub.1 may be a chemical bond.
- 6. As-spun fibers according to claim 5 of polymer wherein at least 25% of the total number of ring systems in such units I and II are ring-substituted with a member of the group consisting of chloro- and methyl radicals.
- 7. Fibers of films of copolyazomethines consisting essentially of the following recurring structural units ##STR98## wherein units I and II are present in substantially equimolar amounts; Z.sub.1, Z.sub.2 and Z.sub.3 which may be the same or different, are selected from the group of a hydrogen atom or a methyl or ethyl radical; and R.sub.1, R.sub.2 and R.sub.3 are radicals selected from the group of (1) single and fused 6-membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system, if attached to a single ring, are positioned, 1,4- to each other, and if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions and R.sub.1 may be a chemical bond.
- 8. A (co)polyazomethine that is melt spinnable into fibers and has a polymer melt temperature below 375.degree. C, an inherent viscosity of at least 0.2 and which displays optical anisotropy in the molten state and which consists essentially of the following recurring structural units ##STR99## wherein Z.sub.1 and Z.sub.2 which may be the same or different, are selected from the group of a hydrogen atom or a methyl or ethyl radical; and R.sub.1 and R.sub.2 are radicals selected from the group (1) single and fused 6-membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system if attached to a single ring, are positioned 1,4- to each other, and if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions and R.sub.1 may be a chemical bond.
- 9. A copolyazomethine according to claim 8 which additionally contains the following recurring structural unit ##STR100## wherein Z.sub.3 is selected from the group of a hydrogen atom or a methyl or ethyl radical and R.sub.3 is a radical selected from the group of (1) single and fused 6membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system if attached to a single ring, are positioned 1,4- to each other, and if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions.
- 10. Copolyazomethines of claim 8 wherein up to 40 mol % of the total I and II units are replaced by polyazomethine forming unit(s) not conforming to those previously described.
- 11. (Co)polyazomethines of claim 8 wherein R.sub.1 is selected from the group of 1,4-phenylene, chloro-, bromo-, methoxy, fluoro-, methyl-, hydroxy- and nitro-1, 4-phenylene; 4,4'-biphenylene; 3,3'-dimethyl-4,4'-biphenylene, 4,4'-methylenediphenylene; 4,4'-dimethylenediphenylene; 4,4'-trimethylenediphenylene; 4,4'-tetramethylenediphenylene; 2,6-naphthylene; 1,5-naphthylene; 2,6-dichloro-1,4-phenylene; trans-1,4-cyclohexylene; trans-2-methyl-1,4-cyclohexylene; trans-4,4'-methylenedicyclohexylene; 3,3'-dimethyl-4,4'-tetramethylenedioxydiphenylene; 4,4'-azoxydiphenylene; 3,3'-dimethyl-4,4'-azodiphenylene; and a bond, and R.sub.2 is selected from the group of 1,4-phenylene; chloro-1,4-phenylene; methyl-1, 4-phenylene; 4,4'-biphenylene; 4,4'-oxydiphenylene; 4,4'-ethylenediphenylene; 4,4'-methylenediphenylene; 4,4'-ethylenedioxydiphenylene; 2,5-pyridinediyl; 1,5-naphthylene; 2,6-naphthylene; 1,4-naphthylene; 2,5-dichloro-1,4-phenylene; 2,5-dibromo-1,4-phenylene; 2,5-dimethoxy-1,4-phenylene; 2-bromo-1,4-phenylene; 2-methoxy-1,4-phenylene; and 2-hydroxy-1, 4-phenylene radicals.
- 12. (Co)polyazomethines of claim 11 wherein at least 25% of the total number of ring systems in such units I and II are ring-substituted with a member of the group consisting of chloro- and methyl radicals.
- 13. (Co)polyazomethines of claim 11 wherein R.sub.1 is methyl-1,4-phenylene.
- 14. (Co)polyazomethines according to claim 11 wherein R.sub.1 is 1,4-phenylene
- 15. Copolyazomethines of claim 11 wherein more than one kind of unit I is present.
- 16. (Co)polyazomethines of claim 11 wherein R.sub.2 is chloro-1,4-phenylene.
- 17. (Co)polyazomethines of claim 11 wherein R.sub.2 is 1,4-phenylene.
- 18. (Co)polyazomethines of claim 8 which are endcapped.
- 19. (Co)polyazomethines of claim 11 which are endcapped.
- 20. A method for preparing melt spinnable (co)polyazomethines according to claim 8 comprising reacting a diamine of the formula H.sub.2 N--R.sub.1 --NH.sub.2 with a dialdehyde or diketone of the formula ##STR101## functionally equivalent derivatives of any such reactants and wherein R.sub.1 and R.sub.2 are radicals selected from the group of (1) single and fused 6-membered carbocyclic ring systems in which one of the ring carbons of an aromatic ring, if present, may be replaced by nitrogen and wherein the chain extending bonds of the ring system, if attached to a single ring, are positioned 1,4- to each other, and if attached to different rings, are in positions parallel and oppositely directed, and (2) multiple ring, preferably carbocyclic ring, systems in which the individual rings are joined by a chemical bond or a bridging unit not exceeding fourteen, preferably not exceeding four, atoms in length and in which the chain extending bonds of each ring are in the 1,4-positions and R.sub.1 may be a chemical bond and Z.sub.1 and Z.sub.2 are selected from the group of a hydrogen atom or amethyl or ethyl radical.
COPENDING RELATED APPLICATION
This application is a continuation-in-part application of Ser. No. 576,236 now abandoned, filed May 9, 1975.
US Referenced Citations (10)
Foreign Referenced Citations (1)
Number |
Date |
Country |
1,080,526 |
Aug 1967 |
UK |
Non-Patent Literature Citations (4)
Entry |
J. Poly. Sci., Part A-1, v. 5, 1659-1669 (1967) Dyer et al. |
J. Poly. Sci., Part Cn. 29, pp. 37-46 (1970) Hodgkin et al. |
Encyclopedia of Polymer Science & Technology (1969) v. 10, pp. 659-670, G. F. D'Alelio. |
J. Macromol. Sci (Chem) A-(1) 147-178 (1967) Delman et al. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
576236 |
May 1975 |
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