Claims
- 1. A molecular weight controlled and endcapped poly(benzimidazole) consisting of repeat units having the general structural formula ##STR30## wherein the catenation of oxygen is selected from the group consisting of meta-meta, para-para, and para-meta;
- wherein Ar is a radical selected from the group consisting of ##STR31## wherein Z is a bond or Z is a radical selected from the group consisting of ##STR32## wherein X is a radical selected from the group consisting of ##STR33## wherein EC is a radical selected from the group consisting of: ##STR34## wherein W is a radical selected from the group consisting of ##STR35## wherein n is an integer between 4 and 1000.
- 2. The molecular weight controlled and endcapped poly(benzimidazole) of claim 1, wherein Ar is a radical having the formula of ##STR36## X is a radical having the formula ##STR37## EC is a radical having the formula ##STR38## W is a radical represented by H.
- 3. A process for synthesizing molecular weight controlled and endcapped poly(benzimidazole)s by aromatic nucleophilic displacement which comprises reacting (A) di(hydroxyphenyl)benzimidazole, (B) a monofunctional benzimidazole having the general structure ##STR39## wherein EC is a radical selected from the group consisting of: ##STR40## wherein W is a radical selected from the group consisting of ##STR41## wherein V is selected from the group consisting of OH, Cl, F, and NO.sub.2 ; and wherein the catenation of V is selected from meta and para; and (C) an activated aromatic dihalide or aromatic dinitro compound having the general structure ##STR42## wherein X is a radical selected from the group consisting of ##STR43## wherein Y is selected from the group consisting of Cl, F, and NO.sub.2 ; wherein said reaction is carried out in a polar aprotic solvent selected from the group consisting of N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, sulfolane, diphenylsulfone, N-cyclohexyl-2-pyrrolidinone, and dimethylsulfoxide; wherein said reaction is also carried out in the presence of an alkali metal base selected from the group consisting of potassium carbonate, sodium carbonate, potassium hydroxide, and sodium hydroxide, and wherein said reaction is carried out with the application of heat.
- 4. The process of claim 3, wherein X is ##STR44## Ar is ##STR45## EC is ##STR46## W is H, and V is OH.
- 5. The process of claim 4, wherein Y is selected from the group consisting of Cl and F.
- 6. The process of claim 5, wherein Y is F, and the solvent is N,N-dimethylacetamide.
- 7. A film prepared from the molecular weight controlled and endcapped poly(benzimidazole) of claim 1.
- 8. A fiber prepared from the molecular weight controlled and endcapped poly(benzimidazole) of claim 1.
- 9. A molding prepared from the molecular weight controlled and endcapped poly(benzimidazole) of claim 1.
- 10. An adhesive prepared from the molecular weight controlled and endcapped poly(benzimidazole) of claim 1.
- 11. A matrix resin for composites prepared from the molecular weight controlled and endcapped poly(benzimidazole) of claim 1.
ORIGIN OF THE INVENTION
The invention described herein was jointly made by employees of the United States Government and a contract employee in the performance of work under NASA Grant No. NAG-1-448 and is subject to the provisions of Public Law 96-517 (35 USC 202) in which the contractor has elected not to retain title.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5149755 |
Perry |
Sep 1992 |
|