Claims
- 1. An organic composition susceptible to ultraviolet light degradation stabilized against such degradation with a stabilizing amount of at least one polychromophoric compound having the formula:
- A--B--C--B--A
- wherein A is a member of the group consisting of benzoxazoles, benzothiazoles, benzotriazoles, benzimidazoles, and indoles having the structure ##STR11## wherein
- X and Y are a carbon atom or a nitrogen atom;
- Z is an oxygen atom, a sulfur atom, a nitrogen atom, or a nitrogen atom containing a hydrogen atom or an unsubstituted or substituted lower alkyl group having 1 to 12 carbon atoms or an aryl group or substituted aryl group having 6 to 18 carbon atoms;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, phenyl, substituted phenyl, lower alkyl phenyl, alkoxy, amino, cyano, and carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the Y substituent and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, said B connecting group is attached to the benzenoid ring in the ortho, meta or para positions from the carbon atom connected to the Y substituent, said I substituents can all be one of the substituents listed above or different listed substituents;
- wherein B is a linking group connecting A and C and can be alkylene, arylene, carbonyloxy, oxycarbonylalkyleneoxy, oxycarbonyl, alkyleneoxycarbonyloxy, oxyalkylenecarbonyloxy, oxycarbonyloxy, alkyleneoxy, oxyalkylene, alkyleneoxyalkyleneoxy, thio, thioalkyleneoxy, sulfinyldioxy, oxy(alkoxy)phosphinooxy, alkyloxyphosphinylidene, aryloxyphosphinylidene, oxy(alkyl)phosphinyloxy, aminocarbonyl, N-alkylaminocarbonyl, N-arylaminocarbonyl, aminocarbonylalkyleneoxy, N-alkylaminocarbonylalkyleneoxy, N-arylaminocarbonylalkyleneoxy, aminocarbonylamino, N-alkylaminocarbonylamino, N,N-dialkylaminocarbonyl, N-arylaminocarbonyl, N-alkylaminocarbonyl, N,N-diarylaminocarbonyl, amino, N-alkylamino, N-arylamino, N-alkylaminoalkyleneoxy, N-arylaminoalkyleneoxy, oxyalkyleneoxy, oxyaryleneoxy, alkyleneaminoalkylene, aryleneaminoarylene, aryleneaminoalkylene and alkyleneaminoarylene; and
- wherein C is a hydroxybenzophenone group having the formula ##STR12## I is the same substituent as listed above and is present in all positions of the benzenoid rings except the carbon atom attached to the B group connecting the A and C moieties, and the B connecting group is attached to the benzenoid ring in the ortho, meta or para position from the keto group of the benzophenone, and said I substituents can all be one of the substituents listed above or different listed substituents.
- 2. An organic composition according to claim 1 wheren said polychromophoric compound has the formula: ##STR13## wherein E is a member selected from the group consisting of an alkylene group or cycloalkylene group containing 1 to 8 carbon atoms, carbonyl alkylene, alkylene carbonyl and F is oxygen, nitrogen or sulfur;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, cyano, and carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the FEF substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
- 3. An organic composition according to claim 2 wherein said polychromophoric compound has the formula: ##STR14## wherein E is a member selected from the group consisting of an alkylene group or cycloalkylene group containing 1 to 8 carbon atoms, carbonyl alkylene, alkylene carbonyl and F is oxygen, nitrogen, or sulfur;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, substituted amino, cyano, and carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzoid ring, except the carbon atom attached to the FEF substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
- 4. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR15##
- 5. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR16##
- 6. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR17##
- 7. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR18##
- 8. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR19##
- 9. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR20##
- 10. An organic composition according to claim 3 wherein sia polychromophoric compound has the formula: ##STR21##
- 11. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR22##
- 12. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR23##
- 13. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR24##
- 14. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR25##
- 15. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR26##
- 16. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR27##
- 17. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR28##
- 18. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR29##
- 19. An organic composition according to claim 3 wherein said polychromophoric compound has the formula: ##STR30##
- 20. An organic composition according to claim 1 wherein Z of sai polychromophoric compound is a nitrogen atom.
- 21. A composition of matter according to claim 20 wherein said polychromophoric compound has the formula: ##STR31## wherein E is a member selected from the group consisting of an alkylene group or cycloalkylene group containing 1 to 8 carbon atoms, carbonyl alkylene, alkylene carbonyl and F is oxygen, nitrogen or sulfur;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, alkoxy, amino, cyano, carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the FEF substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
- 22. An organic composition according to claim 21 wherein said polychromophoric compound has the formula: ##STR32## wherein E is a member selected from the group consisting of an alkylene group or cycloalkylene group containing 1 to 8 carbon atoms, carbonyl alkylene, alkylene carbonyl and F is oxygen, nitrogen or sulfur;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, alkoxy, amino, cyano, carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the FEF substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
- 23. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR33##
- 24. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR34##
- 25. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR35##
- 26. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR36##
- 27. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR37##
- 28. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR38##
- 29. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR39##
- 30. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR40##
- 31. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR41##
- 32. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR42##
- 33. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR43##
- 34. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR44##
- 35. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR45##
- 36. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR46##
- 37. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR47##
- 38. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR48##
- 39. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR49##
- 40. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR50##
- 41. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR51##
- 42. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR52##
- 43. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR53##
- 44. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR54##
- 45. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR55##
- 46. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR56##
- 47. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR57##
- 48. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR58##
- 49. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR59##
- 50. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR60##
- 51. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR61##
- 52. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR62##
- 53. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR63##
- 54. An organic composition according to claim 22 wherein said polychromophoric compound has the formula: ##STR64##
- 55. An organic composition according to claim 24 wherein said polychromophoric compound has the formula: ##STR65## wherein E is a member selected from the group consisting of an alkyl group containing 1 to 8 carbon atoms, carbonyl alkylene, alkylene carbonyl and F is oxygen, nitrogen or sulfur;
- R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen, hydroxy, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, alkoxy, amino, cyano, carboxy;
- I is the same as R.sub.1, R.sub.2, R.sub.3 and R.sub.4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the FEF substituent, said I substituents can also be one of the substituents listed above or different listed substituents.
- 56. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR66##
- 57. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR67##
- 58. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR68##
- 59. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR69##
- 60. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR70##
- 61. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR71##
- 62. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR72##
- 63. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR73##
- 64. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR74##
- 65. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR75##
- 66. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR76##
- 67. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR77##
- 68. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR78##
- 69. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR79##
- 70. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR80##
- 71. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR81##
- 72. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR82##
- 73. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR83##
- 74. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR84##
- 75. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR85##
- 76. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR86##
- 77. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR87##
- 78. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR88##
- 79. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR89##
- 80. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR90##
- 81. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR91##
- 82. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR92##
- 83. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR93##
- 84. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR94##
- 85. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR95##
- 86. An organic composition according to claim 55 wherein said polychromophoric compound has the formula: ##STR96##
Parent Case Info
This is a division of Application Ser. No. 502,329, filed Sept. 3, 1974, now abandoned, which was refiled as Continuation application Ser. No. 829,752, filed Sept. 1, 1977.
US Referenced Citations (8)
Divisions (1)
|
Number |
Date |
Country |
Parent |
502329 |
Sep 1974 |
|