Various types and shapes of earth boring bits are used in various applications in the earth drilling industry. Earth boring bits have bit bodies which include various features such as a core, blades, and cutter pockets that extend into the bit body or roller cones mounted on a bit body, for example. Depending on the application/formation to be drilled, the appropriate type of drill bit may be selected based on the cutting action type for the bit and its appropriateness for use in the particular formation.
Drag bits, often referred to as “fixed cutter drill bits,” include bits that have cutting elements attached to the bit body, which may be a steel bit body or a matrix bit body formed from a matrix material such as tungsten carbide surrounded by a binder material. Drag bits may generally be defined as bits that have no moving parts. However, there are different types and methods of forming drag bits that are known in the art. For example, drag bits having abrasive material, such as diamond, impregnated into the surface of the material which forms the bit body are commonly referred to as “impreg” bits. Drag bits having cutting elements made of an ultra hard cutting surface layer or “table” (typically made of polycrystalline diamond material or polycrystalline boron nitride material) deposited onto or otherwise bonded to a substrate are known in the art as polycrystalline diamond compact (“PDC”) bits.
PDC bits drill soft formations easily, but they are frequently used to drill moderately hard or abrasive formations. They cut rock formations with a shearing action using small cutters that do not penetrate deeply into the formation. Because the penetration depth is shallow, high rates of penetration are achieved through relatively high bit rotational velocities.
PDC cutters have been used in industrial applications including rock drilling and metal machining for many years. In PDC bits, PDC cutters are received within cutter pockets, which are formed within blades extending from a bit body, and are typically bonded to the blades by brazing to the inner surfaces of the cutter pockets. The PDC cutters are positioned along the leading edges of the bit body blades so that as the bit body is rotated, the PDC cutters engage and drill the earth formation. In use, high forces may be exerted on the PDC cutters, particularly in the forward-to-rear direction. Additionally, the bit and the PDC cutters may be subjected to substantial abrasive forces. In some instances, impact, vibration, and erosive forces have caused drill bit failure due to loss of one or more cutters, or due to breakage of the blades.
In a typical application, a compact of polycrystalline diamond (PCD) (or other ultrahard material) is bonded to a substrate material, which is typically a sintered metal-carbide to form a cutting structure. PCD comprises a polycrystalline mass of diamonds (typically synthetic) that are bonded together to form an integral, tough, high-strength mass or lattice. The resulting PCD structure produces enhanced properties of wear resistance and hardness, making PCD materials extremely useful in aggressive wear and cutting applications where high levels of wear resistance and hardness are desired.
A PDC cutter is conventionally formed by placing a sintered carbide substrate into the container of a press. A mixture of diamond grains or diamond grains and catalyst binder is placed atop the substrate and treated under high pressure, high temperature conditions. In doing so, metal binder (often cobalt) migrates from the substrate and passes through the diamond grains to promote intergrowth between the diamond grains. As a result, the diamond grains become bonded to each other to form the diamond layer, and the diamond layer is in turn integrally bonded to the substrate. The substrate often comprises a metal-carbide composite material, such as tungsten carbide-cobalt. The deposited diamond layer is often referred to as the “diamond table” or “abrasive layer.”
An example of a prior art PDC bit having a plurality of cutters with ultra hard working surfaces is shown in
A plurality of orifices 116 are positioned on the bit body 110 in the areas between the blades 120, which may be referred to as “gaps” or “fluid courses.” The orifices 116 are commonly adapted to accept nozzles. The orifices 116 allow drilling fluid to be discharged through the bit in selected directions and at selected rates of flow between the blades 120 for lubricating and cooling the drill bit 100, the blades 120 and the cutters 150. The drilling fluid also cleans and removes the cuttings as the drill bit 100 rotates and penetrates the geological formation. Without proper flow characteristics, insufficient cooling of the cutters 150 may result in cutter failure during drilling operations. The fluid courses are positioned to provide additional flow channels for drilling fluid and to provide a passage for formation cuttings to travel past the drill bit 100 toward the surface of a wellbore (not shown).
Referring to
Cutters are conventionally attached to a drill bit or other downhole tool by a brazing process. In the brazing process, a braze material is positioned between the cutter and the cutter pocket. The material is melted and, upon subsequent solidification, bonds (attaches) the cutter in the cutter pocket. Selection of braze materials depends on their respective melting temperatures, to avoid excessive thermal exposure (and thermal damage) to the diamond layer prior to the bit (and cutter) even being used in a drilling operation. Specifically, alloys suitable for brazing cutting elements with diamond layers thereon have been limited to only a couple of alloys which offer low enough brazing temperatures to avoid damage to the diamond layer and high enough braze strength to retain cutting elements on drill bits.
Cracking (and/or formation of micro-cracks) in the bit body can also occur during the cutter brazing process in the area surrounding the cutter pockets. The formation and propagation of cracks in the matrix body during the drilling process may result in the loss of one or more PDC cutters. A lost cutter may abrade against the bit, causing further accelerated bit damage.
A significant factor in determining the longevity of PDC cutters is the exposure of the cutter to heat. Conventional polycrystalline diamond is stable at temperatures of up to 700-750° C. in air, above which observed increases in temperature may result in permanent damage to and structural failure of polycrystalline diamond. This deterioration in polycrystalline diamond is due to the significant difference in the coefficient of thermal expansion of the binder material, cobalt, as compared to diamond. Upon heating of polycrystalline diamond, the cobalt and the diamond lattice will expand at different rates, which may cause cracks to form in the diamond lattice structure and result in deterioration of the polycrystalline diamond. Damage may also be due to graphite formation at diamond-diamond necks leading to loss of microstructural integrity and strength loss, at extremely high temperatures.
Exposure to heat (through brazing or through frictional heat generated from the contact of the cutter with the formation) can cause thermal damage to the diamond table and eventually result in the formation of cracks (due to differences in thermal expansion coefficients) which can lead to spalling of the polycrystalline diamond layer, delamination between the polycrystalline diamond and substrate, and conversion of the diamond back into graphite causing rapid abrasive wear. As a cutting element contacts the formation, a wear flat develops and frictional heat is induced. As the cutting element is continued to be used, the wear flat will increase in size and further induce frictional heat. The heat may build-up that may cause failure of the cutting element due to thermal mis-match between diamond and catalyst discussed above. This is particularly true for cutters that are immovably attached to the drill bit, as conventional in the art.
Accordingly, there exists a continuing need to develop ways to extend the life of a cutting element.
In one aspect, embodiments disclosed herein relate to a cutting element that includes a substrate; and an ultrahard material layer having a substantially planar upper surface disposed on an upper surface of the substrate; wherein at least a portion of the side surface between the upper surface of the substrate and a lower end of the substrate form at least one conic surface, wherein the at least one conic surface extends a height relative to the total height of the substrate and ultrahard material layer ranging from about 1:10 to 9:10, and wherein the substrate comprises a substantially planar lower surface.
In another aspect, embodiments disclosed herein relate to a cutter assembly that includes an outer support element; and inner rotating cutting element, a portion of which is disposed in the outer support element, where the inner rotating cutting element includes a substrate; and an ultrahard material layer having a substantially planar upper surface disposed on an upper surface of the substrate; wherein at least a portion of the side surface between the upper surface of the substrate and a lower end of the substrate form at least one conic surface, wherein the at least one conic surface extends a height relative to the total height of the substrate and ultrahard material layer ranging from about 1:10 to 9:10, and wherein the substrate comprises a substantially planar lower surface.
In another aspect, embodiments disclosed herein relate to a cutter assembly that includes an outer support element; and an inner rotating cutting element comprising an ultrahard material forming a substantially planar upper surface at its upper end; wherein the inner rotatable cutting element has a smaller diameter than the outer diameter of the inner rotatable cutting element along at least about 10 to 90 percent of the inner rotatable cutting element from a lower end.
In yet another aspect, embodiments disclosed herein relate to a downhole cutting tool that includes a cutting element support structure having at least one cutter pocket formed therein; at least one cutting element disposed within the at least one cutter pocket, where in the at least one cutting element comprises: a substrate; and an ultrahard material layer having a substantially planar upper surface disposed on an upper surface of the substrate; wherein at least a portion of the side surface between the upper surface of the substrate and a lower end of the substrate form at least one conic surface, wherein the at least one conic surface extends a height relative to the total height of the substrate and ultrahard material layer ranging from about 1:10 to 9:10, and wherein the substrate comprises a substantially planar lower surface.
In yet another aspect, embodiments disclosed herein relate to a downhole cutting tool that includes a cutting element support structure having at least one cutter pocket formed therein; at least one rotatable cutting element disposed within the at least one cutter pocket, where in the at least one rotatable cutting element comprises an ultrahard material forming a substantially planar upper surface at its upper end; wherein the inner rotatable cutting element has a smaller diameter than the outer diameter of the inner rotatable cutting element along at least about 10 to 90 percent of the inner rotatable cutting element from a lower end; and at least one retaining element configured to retain the rotatable cutting element in the cutter pocket.
In another aspect, embodiments disclosed herein relate to a cutting element that includes a substrate comprising a substantially planar lower surface; and an ultrahard material layer having a substantially planar upper surface disposed on an upper surface of the substrate; wherein at least a portion of the side surface between the upper surface of the substrate and a lower end of the substrate form at least one conic surface, wherein the at least one conic surface extends toward a longitudinal axis of the cutting element such that a diameter of the substantially planar lower surface relative to a diameter of the ultrahard material layer ranges from about 1:10 to less than 4:5.
In yet another aspect, embodiments disclosed herein relate to a cutter assembly, that includes an outer support element; and an inner rotating cutting element comprising an ultrahard material forming a substantially planar upper surface at its upper end; wherein the inner rotatable cutting element has a substantially planar lower surface; and wherein the substantially planar lower surface of the inner rotatable cutting element is in contact with the outer support element at a diameter relative to the upper surface of the inner rotatable cutting element ranging from about 1:10 to less than 4:5.
In yet another aspect, embodiments disclosed herein relate to a fixed cutter drill bit that includes a bit body; at least one blade extending radially from a center of the bit body; at least one cutter pocket formed in the at least one blade; at least one cutting element or cutter assembly of the above paragraphs disposed within the at least one cutter pocket.
Other aspects and advantages of the invention will be apparent from the following description and the appended claims.
In one aspect, embodiments disclosed herein relate to polycrystalline diamond compact cutters having a conic or other shaped end (remote from the cutting surface) and bits or other cutting tools incorporating the same. More particularly, embodiments disclosed herein relate to cutters having a conic or other shaped end (remote from the cutting surface) that may be immovably attached to the bit or tool on which it is being used or it may be retained on the bit or tool in such a manner that it is free to rotate about its longitudinal axis. While much of the prior art on cutting elements concerns the cutting end of the element, the present disclosure is directed to shaping the remote end of the cutting element to improve cutter and bit life.
Further, the conic surface 24c″ extends from an outer radial position towards a longitudinal axis of the cutting element such that the lower surface 24b possesses a smaller diameter d than the upper surface 24a of the substrate 24 (or largest diameter of the cutting element 20)'s diameter D. In various embodiments, d may range from about D/10 to less than D. Other embodiments may use a d ranging from any of a lower limit of any of D/10, D/5, D/4, D/3, D/2, ⅔(D), ¾(D), ⅘(D) to an upper limit of any of D/5, D/4, D/3, D/2, ⅔(D), ¾(D), ⅘(D), and less than D. Further, conic surface 24c″ may form an angle α with cylindrical surface 24c′. In various embodiments, such angle α may range from about 15 degrees to about 70 degrees. Further, transitions between cylindrical surface 24c′ and conic surface 24c″ and/or conic surface 24c″ and lower surface 24b may be radiused for a smooth transition. For example, such transition may be smoothly and continuously curved so as to be free of sharp edges and/or transitions with radii of at least about 0.005 inches, or at least about 0.020 inches in another embodiment, and up to 0.50 inches in yet another embodiment.
Referring now to
In some embodiments, surface 34c″ may also be a conic surface that terminates at an apex 34b, as illustrated in
Referring now to
Referring now to
It is within the scope of the present disclosure that the ultrahard material layer 56 disposed on the lower surface 54b of substrate 54 may also be included in cutting elements having geometry as illustrated in
Referring now to
Referring now to
Referring now to
Further, as described above, the various embodiment of cutting elements described herein may be used on a drill bit or other cutting tool, where the cutting elements are immovably attached to the drill bit or other cutting tool or where the cutting elements are retained on the drill bit or other cutting tool in such a manner that the cutting element is still capable of rotating about its longitudinal axis.
In the embodiment illustrated in
In other embodiments, the cutting elements of the present disclosure may be affixed to a tool so that the cutting element is capable of rotating about its longitudinal axis. For example, as shown in
In some embodiments, the outer support element 1012 may be integral with the cutting tool support structure (i.e., blade extending from a bit body) (not shown in
In embodiment using a discrete outer support element 1112, as illustrated in
While inner rotatable cutting elements must be free to rotate about their longitudinal axis, their retention on a cutting tool may be achieved through the shape of the outer support element, generally, which may include one or more discrete components to achieve such retention. Certain components that may particularly provided such retention function may be separately referred to as a retention mechanism. The type of such retention mechanism is no limitation on the present disclosure, but may include retention by covering and/or interacting with an upper surface of the inner rotatable cutting element, a side surface of the inner rotatable cutting element, or a lower surface of the inner rotatable cutting element. In the embodiment shown in
While the illustrated embodiments of cutting elements of the present disclosure installed on a cutting element support structure (i.e., drill bit or other cutting tool) as a rotatable cutting element all show the geometry illustrated in
Referring now to
Further, it is also within the scope of the present disclosure the outer support element may include such a protrusion in combination with at least one conic surface (such as illustrated in above described embodiments). For example, as illustrated in
Each of the embodiments described herein have at least one ultrahard material included therein. Such ultra hard materials may include a conventional polycrystalline diamond table (a table of interconnected diamond particles having interstitial spaces therebetween in which a metal component (such as a metal catalyst) may reside, a thermally stable diamond layer (i.e., having a thermal stability greater than that of conventional polycrystalline diamond, 750° C.) formed, for example, by removing substantially all metal from the interstitial spaces between interconnected diamond particles or from a diamond/silicon carbide composite, or other ultra hard material such as a cubic boron nitride. Further, in particular embodiments, the inner rotatable cutting element may be formed entirely of ultrahard material(s), but the element may include a plurality of diamond grades used, for example, to form a gradient structure (with a smooth or non-smooth transition between the grades). In a particular embodiment, a first diamond grade having smaller particle sizes and/or a higher diamond density may be used to form the upper portion of the inner rotatable cutting element (that forms the cutting edge when installed on a bit or other tool), while a second diamond grade having larger particle sizes and/or a higher metal content may be used to form the lower, non-cutting portion of the cutting element. Further, it is also within the scope of the present disclosure that more than two diamond grades may be used.
As known in the art, thermally stable diamond may be formed in various manners. A typical polycrystalline diamond layer includes individual diamond “crystals” that are interconnected. The individual diamond crystals thus form a lattice structure. A metal catalyst, such as cobalt, may be used to promote recrystallization of the diamond particles and formation of the lattice structure. Thus, cobalt particles are typically found within the interstitial spaces in the diamond lattice structure. Cobalt has a significantly different coefficient of thermal expansion as compared to diamond. Therefore, upon heating of a diamond table, the cobalt and the diamond lattice will expand at different rates, causing cracks to form in the lattice structure and resulting in deterioration of the diamond table.
To obviate this problem, strong acids may be used to “leach” the cobalt from a polycrystalline diamond lattice structure (either a thin volume or entire tablet) to at least reduce the damage experienced from heating diamond-cobalt composite at different rates upon heating. Examples of “leaching” processes can be found, for example, in U.S. Pat. Nos. 4,288,248 and 4,104,344. Briefly, a strong acid, typically hydrofluoric acid or combinations of several strong acids may be used to treat the diamond table, removing at least a portion of the co-catalyst from the PDC composite. Suitable acids include nitric acid, hydrofluoric acid, hydrochloric acid, sulfuric acid, phosphoric acid, or perchloric acid, or combinations of these acids. In addition, caustics, such as sodium hydroxide and potassium hydroxide, have been used to the carbide industry to digest metallic elements from carbide composites. In addition, other acidic and basic leaching agents may be used as desired. Those having ordinary skill in the art will appreciate that the molarity of the leaching agent may be adjusted depending on the time desired to leach, concerns about hazards, etc.
By leaching out the cobalt, thermally stable polycrystalline (TSP) diamond may be formed. In certain embodiments, only a select portion of a diamond composite is leached, in order to gain thermal stability without losing impact resistance. As used herein, the term TSP includes both of the above (i.e., partially and completely leached) compounds. Interstitial volumes remaining after leaching may be reduced by either furthering consolidation or by filling the volume with a secondary material, such by processes known in the art and described in U.S. Pat. No. 5,127,923, which is herein incorporated by reference in its entirety.
Alternatively, TSP may be formed by forming the diamond layer in a press using a binder other than cobalt, one such as silicon, which has a coefficient of thermal expansion more similar to that of diamond than cobalt has. During the manufacturing process, a large portion, 80 to 100 volume percent, of the silicon reacts with the diamond lattice to form silicon carbide which also has a thermal expansion similar to diamond. Upon heating, any remaining silicon, silicon carbide, and the diamond lattice will expand at more similar rates as compared to rates of expansion for cobalt and diamond, resulting in a more thermally stable layer. PDC cutters having a TSP cutting layer have relatively low wear rates, even as cutter temperatures reach 1200° C. However, one of ordinary skill in the art would recognize that a thermally stable diamond layer may be formed by other methods known in the art, including, for example, by altering processing conditions in the formation of the diamond layer.
The substrate on which the cutting face is disposed may be formed of a variety of hard or ultra hard particles. In one embodiment, the substrate may be formed from a suitable material such as tungsten carbide, tantalum carbide, or titanium carbide. Additionally, various binding metals may be included in the substrate, such as cobalt, nickel, iron, metal alloys, or mixtures thereof. In the substrate, the metal carbide grains are supported within the metallic binder, such as cobalt. Additionally, the substrate may be formed of a sintered tungsten carbide composite structure. It is well known that various metal carbide compositions and binders may be used, in addition to tungsten carbide and cobalt. Thus, references to the use of tungsten carbide and cobalt are for illustrative purposes only, and no limitation on the type substrate or binder used is intended. In another embodiment, the substrate may also be formed from a diamond ultra hard material such as polycrystalline diamond and thermally stable diamond. While the illustrated embodiments show the cutting face and substrate as two distinct pieces, one of skill in the art should appreciate that it is within the scope of the present disclosure the cutting face and substrate are integral, identical compositions. In such an embodiment, it may be preferable to have a single diamond composite forming the cutting face and substrate or distinct layers. Specifically, in embodiments where the cutting element is a rotatable cutting element, the entire cutting element may be formed from an ultrahard material, including thermally stable diamond (formed, for example, by removing metal from the interstitial regions or by forming a diamond/silicon carbide composite).
The outer support element may be formed from a variety of materials. In one embodiment, the outer support element may be formed of a suitable material such as tungsten carbide, tantalum carbide, or titanium carbide. Additionally, various binding metals may be included in the outer support element, such as cobalt, nickel, iron, metal alloys, or mixtures thereof, such that the metal carbide grains are supported within the metallic binder. In a particular embodiment, the outer support element is a cemented tungsten carbide with a cobalt content ranging from 6 to 13 percent. It is also within the scope of the present disclosure that the outer support element (including a back retention mechanism) may also include more lubricious materials to reduce the coefficient of friction. The components may be formed of such materials in their entirely or have portions of the components including such lubricious materials deposited on the component, such as by chemical plating, chemical vapor deposition (CVD) including hollow cathode plasma enhanced CVD, physical vapor deposition, vacuum deposition, arc processes, or high velocity sprays). In a particular embodiment, a diamond-like coating may be deposited through CVD or hallow cathode plasma enhanced CVD, such as the type of coatings disclosed in US 2010/0108403, which is assigned to the present assignee and herein incorporated by reference in its entirety.
In other embodiments, the outer support element may be formed of alloy steels, nickel-based alloys, and cobalt-based alloys. One of ordinary skill in the art would also recognize that cutting element components may be coated with a hardfacing material for increased erosion protection. Such coatings may be applied by various techniques known in the art such as, for example, detonation gun (d-gun) and spray-and-fuse techniques.
The cutting elements of the present disclosure may be incorporated in various types of cutting tools, including for example, as cutters in fixed cutter bits or as inserts in roller cone bits. Bits having the cutting elements of the present disclosure may include a single rotatable cutting element with the remaining cutting elements being conventional cutting elements, all cutting elements being rotatable, or any combination therebetween of rotatable and conventional cutting elements.
In some embodiments, the placement of the cutting elements on the blade of a fixed cutter bit or cone of a roller cone bit may be selected such that the rotatable cutting elements are placed in areas experiencing the greatest wear. For example, in a particular embodiment, rotatable cutting elements may be placed on the shoulder or nose area of a fixed cutter bit. Additionally, one of ordinary skill in the art would recognize that there exists no limitation on the sizes of the cutting elements of the present disclosure. For example, in various embodiments, the cutting elements may be formed in sizes including, but not limited to, 9 mm, 13 mm, 16 mm, and 19 mm.
Further, one of ordinary skill in the art would also appreciate that any of the design modifications as described above, including, for example, side rake, back rake, variations in geometry, surface alteration/etching, seals, bearings, material compositions, etc, may be included in various combinations not limited to those described above in the cutting elements of the present disclosure. In one embodiment, a cutter may have a side rake ranging from 0 to ±45 degrees. In another embodiment, a cutter may have a back rake ranging from about 5 to 35 degrees.
A cutter may be positioned on a blade with a selected back rake to assist in removing drill cuttings and increasing rate of penetration. A cutter disposed on a drill bit with side rake may be forced forward in a radial and tangential direction when the bit rotates. In some embodiments because the radial direction may assist the movement of inner rotatable cutting element relative to outer support element, such rotation may allow greater drill cuttings removal and provide an improved rate of penetration. One of ordinary skill in the art will realize that any back rake and side rake combination may be used with the cutting elements of the present disclosure to enhance rotatability and/or improve drilling efficiency.
As a cutting element contacts formation, the rotating motion of the cutting element may be continuous or discontinuous. For example, when the cutting element is mounted with a determined side rake and/or back rake, the cutting force may be generally pointed in one direction. Providing a directional cutting force may allow the cutting element to have a continuous rotating motion, further enhancing drilling efficiency.
Embodiments of the present disclosure may provide at least one of the following advantages. For cutting elements immovably attached to the tool, as described above, during a conventional cutter brazing process, cracks or micro-cracks often form in the bit body in the area surrounding the cutter pockets, particularly at the corners of the pockets, and especially when harder matrix materials are used to form the bit body. However, the present inventors found that by using cutting elements (and cutter pockets) having the geometries described herein, a reduction in stresses at the corners of the cutting pockets may be achieved, reducing the initiation and propagation of such cracks in the bit body. The present design may also reduce the amount of flux and/or porosity often found in the corners, which may result in an increased brazing strength.
Further, the use of conic or other shaped cutting ends may allow for improved rotation within the outer support element. Rotatable cutting elements may avoid the high temperatures generated by typical fixed cutters. Because the cutting surface of prior art cutting elements is constantly contacting formation at a fixed spot, a wear flat can quickly form and thus induce frictional heat. The heat may build-up and cause failure of the cutting element due to thermal mis-match between diamond and catalyst, as discussed above. Embodiments in accordance with the present invention may avoid this heat build-up as the edge contacting the formation changes. The lower temperatures at the edge of the cutting elements may decrease fracture potential, thereby extending the functional life of the cutting element. By decreasing the thermal and mechanical load experienced by the cutting surface of the cutting element, cutting element life may be increase, thereby allowing more efficient drilling.
Further, rotation of a rotatable portion of the cutting element may allow a cutting surface to cut formation using the entire outer edge of the cutting surface, rather than the same section of the outer edge, as provided by the prior art. The entire edge of the cutting element may contact the formation, generating more uniform cutting element edge wear, thereby preventing formation of a local wear flat area. Because the edge wear is more uniform, the cutting element may not wear as quickly, thereby having a longer downhole life, and thus increasing the overall efficiency of the drilling operation.
Additionally, because the edge of the cutting element contacting the formation changes as the rotatable cutting portion of the cutting element rotates, the cutting edge may remain sharp. The sharp cutting edge may increase the rate of penetration while drilling formation, thereby increasing the efficiency of the drilling operation. Further, as the rotatable portion of the cutting element rotates, a hydraulic force may be applied to the cutting surface to cool and clean the surface of the cutting element.
While the invention has been described with respect to a limited number of embodiments, those skilled in the art, having benefit of this disclosure, will appreciate that other embodiments can be devised which do not depart from the scope of the invention as disclosed herein. Accordingly, the scope of the invention should be limited only by the attached claims.
This applications claims benefit of U.S. Patent Application No. 61/479,183, filed on Apr. 26, 2011, the entirety of which is herein incorporated by reference.
Number | Date | Country | |
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61479183 | Apr 2011 | US |