The present disclosure relates to polycrystalline transparent ceramics for use with a logging sensor or tool. In a specific embodiment, it relates to polycrystalline aluminum oxynitride (ALON) for use with a logging sensor or tool. The present disclosure also relates to a logging sensor or tool or a logging sensor or tool component containing a polycrystalline transparent ceramic.
During drilling operations, such as during the drilling of an oil well, it is often helpful to obtain information about conditions downhole in the well. For instance, information about the formation characteristics is often obtained using various measurement techniques, such as logging while drilling (LWD), measuring while drilling (MWD), and wireline tests. Various properties may also be measured using such techniques. For example, properties of downhole fluids may be measured.
In order to effect downhole measurements, a variety of sensors are often used. The sensing components of these sensors are normally not able to withstand downhole conditions. As a result, sensors are normally provided with a protective component that both protects the sensing components and is transparent to electromagnetic wavelengths sensed by the sensing components. These protective components are currently often formed from sapphire, which is a single crystal aluminum oxide. However, sapphire cannot be easily shaped or attached to other sensor or downhole components.
For a more complete understanding of certain embodiments of the present disclosure and their features and advantages, reference is now made to the following description, taken in conjunction with the accompanying drawings, in which:
The present disclosure relates to polycrystalline transparent ceramics for use with a logging sensor or tool. The present disclosure also relates to a logging sensor or tool or a logging sensor or tool component containing a polycrystalline transparent ceramic.
As used herein, the term “optical computing device” refers to an optical device that is configured to receive an input of electromagnetic radiation associated with a substance, such as a fluid and produce an output of electromagnetic radiation from a processing element arranged within the optical computing device. The processing element may be, for example, an integrated computational element (ICE) used in the optical computing device. The electromagnetic radiation that optically interacts with the processing element is changed so as to be readable by a detector, such that an output of the detector can be correlated to a characteristic of the fluid or a phase of the fluid. The output of electromagnetic radiation from the processing element can be reflected electromagnetic radiation, transmitted electromagnetic radiation, and/or dispersed electromagnetic radiation. Whether the detector analyzes reflected, transmitted, or dispersed electromagnetic radiation may be dictated by the structural parameters of the optical computing device as well as other considerations known to those skilled in the art. In addition, emission and/or scattering of the fluid or a phase thereof, for example via fluorescence, luminescence, Raman, Mie, and/or Raleigh scattering, can also be monitored by the optical computing devices.
As used herein, the term “characteristic” refers to a chemical, mechanical, or physical property of a substance and may be used herein interchangeably with the phrase “analyte of interest.” Illustrative characteristics of a substance that can be monitored with the optical computing devices disclosed herein can include, for example, chemical composition (identity and concentration, in total or of individual components), impurity content, pH, viscosity, density, ionic strength, total dissolved solids, salt content, porosity, opacity, bacteria content, combinations thereof, and the like.
In a specific embodiment, the polycrystalline transparent ceramic may include or be formed substantially from polycrystalline aluminum oxynitride (ALON). ALON is an isotropic material with a spinel crystal structure stabilized by incorporation of nitrogen into aluminum oxide. ALON has a general chemical formula of Al23O27N5. ALON is typically transparent to electromagnetic radiation with wavelengths from the ultraviolet to the mid-infrared range (10 nm to 7000 nm), including the ultraviolet range (10 nm to 380 nm), the visible range (380 nm to 700 nm), the near-infrared range (700 nm to 1400 nm), the short wavelength infrared range (1400 nm to 3000 nm), and the mid-infrared range (3000 nm to 7000 nm). ALON may be equivalent to sapphire in its optical qualities and also similarly exhibits low density, high strength, and high durability. Like sapphire, ALON may also be chemically resistant. ALON may also generally be subjected to greater tension without breaking than sapphire may be.
Because ALON is an isotropic material, it is generally uniform in all directions and may not experience problems with refractive index along certain axes, such as problems exhibited with respect to the C axis in sapphire. ALON may be used without a calcium fluoride component, avoiding optical reflection losses associated with calcium fluoride may be avoided and a sensor containing ALON in place of a sapphire/calcium fluoride component may have at least a 7% increase in optical throughput.
Due to its polycrystalline nature ALON may be shaped into complex geometries during its casting process. Various casting techniques may be used to form ALON, including hot pressing and slip casting. Other conventional methods for forming polycrystalline materials from powder may also be used with ALON.
In another specific embodiment, the polycrystalline transparent ceramic may include or be formed substantially from polycrystalline magnesium aluminate spinel. Magnesium aluminate spinel has a general chemical formula of MgAl2O4 with a spinel crystal structure. Magnesium aluminate spinel is typically transparent to electromagnetic radiation with wavelengths from 200 nm to 5500 nm. Magnesium aluminate spinel may exhibit superior optical properties in the infrared range (700 nm to 8000 nm) as compared to ALON.
Magnesium aluminate spinel may also be shaped into complex geometries during its casting process using conventional method for forming polycrystalline materials from powder, such as sinter/hot isostatic pressing (HIP), hot pressing, and hot pressing/HIP methods. The use of HIP method with magnesium aluminate spinel may improve its optical and physical properties. Magnesium aluminate spinel may be formed into particular geometries at a lower temperature than that typically required for ALON.
In other embodiments, the polycrystalline ceramic material may include or be formed substantially from magnesium oxide, yttrium oxide, aluminum oxide, aluminum nitride, silicon carbide, boron nitride, silicon nitride, boron carbide, silicon oxide, titanium carbide, titanium nitride, or zirconium silicon oxide.
The polycrystalline ceramic material may include or be formed substantially from a combination of at least two of any of the above materials. The polycrystalline ceramic material may be a nanocomposite.
In another embodiment, the disclosure relates to a component for use in a logging sensor or tool, the component containing a polycrystalline transparent ceramic, such as ALON or magnesium aluminate spinel. The disclosure further relates to a logging sensor or tool containing such components.
One example component and logging sensor or tool are shown in
Electromagnetic radiation from electromagnetic source 50 may pass through polycrystalline transparent ceramic components 40 to reach detector 60. Accordingly, these components 40 may be between source 50 and detector 60. They need not, however, be located so as to allow a straight line path for the electromagnetic radiation from source 50 to detector 60. For example, passage 20 may include a reflective component (not shown) that may alter the path of the electromagnetic radiation. Alternatively, components 40 may be configured to alter the path of electromagnetic radiation in passage 20 from the either the source 50 (collecting and/or collimating) or to the detector 60 (focusing) in the form of an optical lens.
Properties of fluid 30 may be analyzed measuring the effects of the fluid 30 on electromagnetic radiation passing from source 50 to detector 60. Although not expressly shown, other sensors of this disclosure may also contain a detector. Also not expressly shown, other optical components may be included in the sensor to allow for the properties of the fluid 30 to be measured. Other components include, but are not limited to, filter photometers, spectrometers, optical gratings, optical filters, integrated computational elements (ICE), and other sensor components not related specifically to interact with the fluid 30 or to alter the path of electromagnetic radiation from the source to the detector.
A detector may be able to detect at least one wavelength or range of electromagnetic radiation from source 50 and may be able to separately detect multiple wavelengths. Alternatively, detector 60 may contain sub-detectors, each able to detect a certain wavelength or range of wavelengths of electromagnetic radiation. A detector may contain or be in communication with a processor and data storage device as well as an output device. The data storage device or output device may be located downhole or at the surface. The polycrystalline transparent ceramic may be transparent to at least one wavelength emitted by source 50 and detected by detector 60.
Electronic apparatus 1065 may be used in conjunction with the controller 1025 to perform tasks associated with taking measurements downhole at least one sensor 1010 of at least one evaluation tool 1005. The communications unit 1040 may include downhole communications in a drilling operation. Such downhole communications may include a telemetry system.
The system 1000 may also include a bus 1027, where the bus 1027 provides electrical conductivity among at least two components of the system 1000. The bus 1027 may include an address bus, a data bus, or a control bus, each independently configured if more than one is present. The bus 1027 may also use common conductive lines for providing one or more of address, data, or control, the use of which may be regulated by the controller 1025. The bus 1027 may include an optical transmission medium to provide optical signals among two or more of the various components of system 1000. The bus 1027 may be configured such that the components of the system 1000 are distributed. The bus 1027 may include network capabilities. Such distribution may be arranged between downhole components such as at least one sensor 1010 of at least one evaluation tool 1005 and components that can be disposed on the surface of a well. Alternatively, various of these components may be co-located such as on one or more collars of a drill string, on a wireline structure, or in another measurement arrangement.
As used herein, the term “electromagnetic radiation” refers to radio waves, microwave radiation, infrared and near-infrared radiation, visible light, ultraviolet light, X-ray radiation and gamma ray radiation.
As used herein, the term “optically interact” or variations thereof refers to electromagnetic radiation that has been reflected, transmitted, scattered, diffracted, or absorbed by, emitted, or re-radiated, for example, using an integrated computational element, but may also apply to interaction with a substance, such as a fluid.
As used herein, the term “fluid” refers to any substance that is capable of flowing, including particulate solids, liquids, gases, slurries, emulsions, powders, muds, glasses, mixtures, combinations thereof, and the like. The fluid may be a single phase or a multiphase fluid. In some embodiments, the fluid can be an aqueous fluid, including water, brines, or the like. In other embodiments, the fluid may be a non-aqueous fluid, including organic compounds, more specifically, hydrocarbons, oil, a refined component of oil, petrochemical products, and the like. In some embodiments, the fluid can be acids, surfactants, biocides, bleaches, corrosion inhibitors, foamers and foaming agents, breakers, scavengers, stabilizers, clarifiers, detergents, a treatment fluid, fracturing fluid, a formation fluid, or any oilfield fluid, chemical, or substance as found in the oil and gas industry and generally known to those skilled in the art. The fluid may also have one or more solids or solid particulate substances entrained therein. For instance, fluids can include various flowable mixtures of solids, liquids and/or gases. Illustrative gases that can be considered fluids according to the present embodiments, include, for example, air, nitrogen, carbon dioxide, argon, helium, methane, ethane, butane, and other hydrocarbon gases, hydrogen sulfide, combinations thereof, and/or the like.
Because polycrystalline transparent ceramic components 40 may both be formed as single, integrated units, they are not subject to problems caused by the interface in sapphire/calcium fluoride components designed for similar purposes.
The use of these ALON components can improve optical throughput, and increase signal-to-noise ratio (SNR), in optical sensors by combining multiple optical elements into fewer optical elements. This increase in SNR may be accomplished by eliminating some optical interfaces, which cause reflection losses
Components with shapes such as those shown in
In still other embodiments, layers of polycrystalline transparent ceramic may be used to protect other elements downhole, for example by shielding the elements from corrosive materials such as hydrogen sulfide and carbon dioxide or by preventing physical erosion of the elements.
In one embodiment, a polycrystalline transparent ceramic component may be formed by placing a power precursor in a sensor component, then performing a conventional process on the assembly. For example, to form a polycrystalline transparent ceramic component 40 as shown in
In another example, shown in
In another example, shown in
In still another example, a polycrystalline transparent ceramic may be formed as a layer, such as shown in
In another example, a polycrystalline transparent ceramic component may be machined or polished after casting. Polycrystalline transparent ceramics may be less prone to breakage during machining or polishing than sapphire, accordingly machining and polishing techniques not usable with sapphire may be used and polycrystalline transparent ceramics may be machined to a much greater degree than sapphire.
In a specific example, the sensor may contain or be connected to an optical computing device. Any optical computing device techniques may be used to analyze the data from the detector or sub-detectors. For example, a characteristic of a fluid passing through the sensor may be identified by a “fingerprint” modification of a variety of electromagnetic radiation wavelengths. Modifications of electromagnetic radiation wavelengths from known fluid components and interferents may be filtered from the detector data during this process.
Drilling Devices Containing Sensors with Polycrystalline Transparent Components
As shown in
At various times during the drilling process, the drill string 8 may be removed from the borehole 16 as shown in
Data from analyses of drilling fluid performed by logging sensor or tool 26 in
Although only exemplary embodiments of the invention are specifically described above, it will be appreciated that modifications and variations of these examples are possible without departing from the spirit and intended scope of the invention.
Filing Document | Filing Date | Country | Kind |
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PCT/US2013/073840 | 12/9/2013 | WO | 00 |