Claims
- 1. A polyester comprised of repeat units which are derived from (A) a diacid component which is comprised of (1) from 20 to 90 mole percent of at least one member selected from the group consisting of dimethylterephthalate and terephthalic acid, (2) from 1 to 6 mole percent of at least one salt of an organic sulfonic acid monomer, and (3) from 4 to 74 mole percent of at least one member selected from the group consisting of alkyl dicarboxylic acids having from 4 to 36 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 38 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 22 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 22 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acid: and (B) a diol component which is comprised of (1) from 20 to 100 mole percent ethylene glycol, and (2) from 0 to 80 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms: wherein said polyester is terminated with carboxyl end groups.
- 2. A polyester as specified in claim 1 wherein said salt of an organic sulfonic acid monomer is an alkali salt of a sulfo dialkyl isophthalate or an alkali salt of a sulfo isophthalatic acid.
- 3. A polyester as specified in claim 2 wherein said alkali salt of a sulfo dialkyl isophthalate is a sodium salt of sulfo dimethyl isophthalate.
- 4. A polyester as specified in claim 2 wherein said polyester is terminated with 2 carboxyl end groups at said polyesters chain ends.
- 5. A polyester as specified in claim 4 wherein said polyester is carboxyl terminated with trimellitic anhydride.
- 6. A polyester as specified in claim 2 wherein said diol component is comprised of (1) from 50 to 100 mole percent ethylene glycol and (2) from 0 to 50 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms.
- 7. A polyester as specified in claim 6 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are glycols having from 3 to 8 carbon atoms and glycol ethers having from 4 to 8 carbon atoms.
- 8. A polyester as specified in claim 6 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are selected from the group consisting of 1,3-propylene glycol, 1,2-propylene glycol, 2,2-diethyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-2-isobutyl-1,3propanediol, 1,3butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexandeiol, 2,2,4-trimethyl-1,6-hexanediol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
- 9. A polyester as specified in claim 3 wherein said diol component is ethylene glycol.
- 10. A polyester as specified in claim 1 wherein said polyester has a molecular weight of about 1000 to about 7000.
- 11. A polyester as specified in claim 6 wherein said polyester has a molecular weight of about 1000 to about 7000.
- 12. A polyester as specified in claim 6 wherein said members selected from the group consisting of alkyl dicarboxylic acids having from 4 to 20 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 20 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having 11 to 20 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 20 carbon atoms, dimethylorthopthalate, dimethylisophthalate, orthopthalic acid, and isophthalic acid are selected from the group consisting of isophthalic acid and azelaic acid and wherein said diol component is comprised of from 50 to 100 mole percent ethylene glycol and from 0 to 50 mole percent neopentyl glycol.
- 13. A polyester as specified in claim 12 wherein said polyester has a molecular weight of 2000 to 5000.
Parent Case Info
This is a divisional, of application Ser. No. 600,862, filed on Apr. 16, 1984 (now issued as U.S. Pat. No. 4,525,524).
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Number |
Name |
Date |
Kind |
3563942 |
Heiberger |
Feb 1971 |
|
4257928 |
Vachon et al. |
Mar 1981 |
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4483976 |
Yamamoto et al. |
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Divisions (1)
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Number |
Date |
Country |
Parent |
600862 |
Apr 1984 |
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