Claims
- 1. A composition comprising a thermoplastic polymer and an oxygen scavenging composition, wherein the thermoplastic polymer comprises: polyesters, polyolefins, polyamides, polyurethanes, styrene: containing polymers and copolymers, polyacrylates, epoxy-amines, polyvinyl chloride, acrylonitrile containing polymers and copolymers, vinylidene chloride containing polymers and copolymers, polycarbonates, and ethylene copolymers and mixtures thereof, and the oxygen scavenging composition comprises: a) an oxidation catalyst, wherein the catalyst comprises at least one transition metal which can readily interconvert between at least two oxidation states; and b) at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof.
- 2. The composition of claim 1 wherein said polyether is selected from the group consisting of poly(ethylene glycol), poly(trimethylene glycol), poly(tetramethylene glycol), poly(pentamethylene glycol), poly(hexamethylene glycol), poly(heptamethylene glycol), poly(octamethylene glycol) and mixtures thereof.
- 3. The composition of claim 2 wherein said poly (alkylene glycol)s comprise poly(ethylene glycol), poly(tetramethylene glycol) and mixtures thereof.
- 4. The composition of claim 1 wherein said poly(alkylene glycol) has a number average molecular weight of about 500 to about 5000.
- 5. The composition of claim 1 wherein said polyether comprises a copolymer of poly(alkylene glycol)s selected from the group consisting of alternating, random, segmented, block, graft and branched poly(alkylene glycol) copolymers and mixtures thereof.
- 6. The composition of claim 5 wherein said copolymer of poly(alkylene glycol)s selected from the group consisting of poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) and poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol).
- 7. The composition of claim 1 wherein said polyether comprises a polymeric or oligomeric either derived from cyclic ether monomers.
- 8. The composition of claim 7 wherein said cyclic polyether is selected from the group consisting of poly(2,3-dihydrofurandiyl) and polymers derived from monomers of structure I or II, wherein n+m is an integer between 3 and 10, and R1, R2, R3, R4, R5, and R6 are the same or different and are selected from the group consisting of hydrogen atom and lower alkyl groups having 1 to 4 carbons or a halogen atom:
- 9. The composition of claim 8 wherein said lower alkyl group is selected from the group consisting of alkyls having up to four carbon atoms.
- 10. The composition of claims 7-9 wherein said polymeric and oligomeric ethers are functionalized at least one terminal end with reactive functionality capable of copolymerizing, grafting, or reactive extruding into or on other polymer compositions on at least one terminal end group.
- 11. The composition of claim 1 wherein said transition metal comprises a transition metal salt wherein said transition metal is selected from the first, second or third transition series of the Periodic Table.
- 12. The composition of claim 1 wherein said transition metal is selected from the group consisting of manganese II or III, iron II or III, cobalt II or III, nickel II or III, copper I or II, rhodium II, III or IV and ruthenium I, II or IV.
- 13. The composition of claim 11 wherein said transition metal salt comprises at least one counterion for the metal selected from the group consisting of chloride, acetate, acetylacetonate, stearate, palmitate, 2-ethylhexanoate, neodecanoate, naphthenate and mixtures thereof.
- 14. The composition of claim 11 wherein said transition metal salt comprises an ionomer and said oxidation catalyst further comprises a polymeric counterion.
- 15. The composition of claim 1 wherein said thermoplastic polymer is present in amounts up to about 99.9 weight percent of said total composition.
- 16. The composition of claim 1 wherein said thermoplastic polymer is selected from the group consisting of polyesters, polyamides, polyolefins, polycarbonates, EVOH and mixtures thereof.
- 17. The composition of claim 1 further comprising at least one antioxidant in an amount effective to improve the stability of the poly(alkylene glycol).
- 18. The composition of claim 17 wherein said antioxidant is selected from the group consisting of hindered phenols, phosphites, primary antioxidants, secondary antioxidants, hindered amine light stabilizers and mixtures thereof.
- 19. The composition of claim 17 wherein said antioxidant is selected from the group consisting of 2,6-di-(t-butyl)-4-methylphenol (BHT), 2,2′-methylene-bis(6-t-butyl-p-cresol), triphenylphosphite, tris-(nonylphenyl)phosphite, dilaurylthiodipropionate, Irganox 1010 (pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenol) proprianate)) and mixtures thereof.
- 20. The composition of claim 17 wherein said antioxidant is present in an amount from about 10 ppm to about 10,000 ppm.
- 21. The composition of claim 1 further comprising at least one photoinitiator.
- 22. The composition of claim 21 wherein said photoinitiator is selected from the group consisting of singlet oxygen generating photosensitizers, polymeric photoinitators, substituted aryl ketones, α,β-diketones and mixtures thereof.
- 23. The composition of claim 21 wherein said photoinitiator is selected from the group consisting of benzophenone, o-methoxybenzophenone, acetophenone, o-methoxy-acetophenone, acenaphthenquinone, methyl ethyl ketone, valerophenone, hexanophenone, α-phenylbutyrophenone, p-morpholinopropiophenone, dibenzosuberone, 4-morpholinobenzophenone, benzoin, benzoin methyl ether, 4-o-morpholinodeoxybenzoin, p-diacetylbenzene, 4-aminobenzophenone, 4′-methoxyacetophenone, α-tetralone, 9-acetylphenanthrene, 2-acetylphenanthrene, 10-thioxanthenone, 3-acetylphenanthrene, 3-acetylindole, 9-fluorenone, 1-indanone, 1,3,5-triacetylbenzene, thioxanthen-9-one,xanthene-9-one,7H-benz[de]anthracen-7-one, benzoin tetrahydropyranyl ether, 4,4′-bis(dimethylamino)-benzophenone, 1′-acetonaphthone, 2′-acetonaphthone, acetonaphthone and 2,3-butanedione, benz[a]anthracene-7,12-dione, 2,2-dimethoxy-2-phenylacetophenone, α,α-diethoxyacetophenone, α,α-dibutoxyacetophenone, Rose Bengal, methylene blue, tetraphenyl porphyrin, zinc phthalocyanine, poly(ethylene carbon monoxide), oligo[2-hydroxy-2-methyl-1-[4-(1-methylvinyl)phenyl]propanone], 2(4) isopropyl thioxanthen-9-one and mixtures thereof.
- 24. The composition of claim 21 wherein said photoinitiator is selected from the group consisting of 10-thioxanthenone, thioxanthen-9-one, xanthene-9-one and 2(4) isopropyl thioxanthen-9-one.
- 25. The composition of claim 24 wherein said photoinitiator is present in an amount from about 10 ppm to about 10,000 ppm.
- 26. The composition of claim 1 wherein said poly(alkylene glycol) comprises at least about 5 weight % of said oxygen scavenging composition.
- 27. The composition of claim 1 wherein said poly(alkylene glycol) comprises at least about 10 weight % of said oxygen scavenging composition.
- 28. The composition of claim 1 wherein said poly(alkylene glycol) comprises between about 10 and about 15 weight % of said oxygen scavenging composition.
- 29. The composition of claim 1 wherein said polyether is a copolymer of poly(alkylene glycol) or a blend containing poly(alkylene glycol) and is present in an amount at least about 2 weight % of said oxygen scavenging composition.
- 30. The composition of claim 1 wherein said polyether is a copolymer of poly(alkylene glycol) or a blend containing poly(alkylene glycol) and is present in an amount at least about 4 weight % of said oxygen scavenging composition.
- 31. A method for improving the stability of a composition comprising a thermoplastic polymer and an oxygen scavenging composition, wherein the thermoplastic polymer comprises one or more of: polyesters, polyolefins, polyamides, polyurethanes, styrene containing polymers and copolymers, polyacrylates, epoxy-amines, polyvinyl chloride, acrylonitrile containing polymers and copolymers, vinylidene chloride containing polymers and copolymers, polycarbonates, and ethylene copolymers and mixtures thereof, and the oxygen scavenging composition comprises: a) an oxidation catalyst, wherein the catalyst comprises at least one transition metal which can readily interconvert between at least two oxidation states; and b) at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof, wherein the method comprises incorporating an antioxidant in the thermoplastic polymer/oxygen scavenging composition.
- 32. An article comprising at least one layer comprising a thermoplastic polymer and an oxygen scavenging composition wherein the thermoplastic polymer comprises polyesters, polyolefins, polyamides, polyurethanes, styrene containing polymers and copolymers, polyacrylates, epoxy-amines, polyvinyl chloride, acrylonitrile containing polymers and copolymers, vinylidene chloride containing polymers and copolymers, polycarbonates, and ethylene copolymers and mixtures thereof, and the oxygen scavenging composition comprises: a) an oxidation catalyst wherein the catalyst comprises at least one transition metal which can readily interconvert between at least two oxidation states; and b) at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof.
- 33. The article of claim 32 wherein said is selected from the group consisting of film, sheet, tubing, profiles, pipes, fiber, containers, preforms, thermoformed articles and flexible bags.
- 34. The article of claim 32 wherein said is selected from the group consisting of film, sheet, tubing, profiles, pipes, fiber, containers and preforms.
- 35. The article of claim 32 wherein said article is a container or a preform comprising at least three layers in at least a portion of said article.
- 36. The article of claim 35 wherein said one layer comprising the thermoplastic polymer/oxygen scavenging composition comprises an intermediate layer disposed between a first and third layer each of which comprises at least one polyester.
- 37. The article of claim 36 wherein the thermoplastic polymer comprises a recycled polyester.
- 38. The article of claim 32 wherein said article is a container or a preform comprising at least four layers in at least a portion of said article.
- 39. The article of claim 38 wherein said one layer comprising the thermoplastic polymer/oxygen scavenging composition comprises an intermediate layer disposed between a first and fourth layer each of which comprises at least one polyester.
- 40. The article of claim 39 wherein the thermoplastic polymer is recycled polyester.
- 41. The article of claim 39 wherein a second intermediate layer comprises at least one performance polymer.
- 42. The article of claim 41 wherein said performance polymer comprises polyamide or EVOH.
- 43. The article of claim 42 wherein said polyamide further comprises platelet particles dispersed therein.
- 44. The composition of claim 1 wherein said polyether comprises a cyclic polyether.
- 45. The composition of claim 44 wherein said cyclic polyether is selected from the group consisting of crown ethers such as 12-crown-4 (1,4,7,10-tetraoxacyclododecane), 15-crown-5 (1,4,7,10,13-pentaoxaeyclopentadecane), or 18-crown-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) and mixtures thereof.
- 46. The composition of claim 44-45 wherein said cyclic polyether is functionalized with reactive functionality capable of copolymerizing, grafting, or reactive extruding into or on other polymeric compositions.
- 47. The composition of claim 1 having less than about 5% haze and less than about 1 cc(stp)mil/100 in2/day/atm in a 5 mil extruded film.
CROSS REFERENCES TO RELATED APPLICATIONS
This application claims the benefit of U.S. Provisional Application Ser. No. 60/148,168 filed Aug. 10, 1999.
US Referenced Citations (23)
Foreign Referenced Citations (3)
Number |
Date |
Country |
301719 |
Jan 1989 |
EP |
340637 |
Aug 1989 |
EP |
WO 9812127 |
Mar 1998 |
WO |
Provisional Applications (1)
|
Number |
Date |
Country |
|
60/148168 |
Aug 1999 |
US |