Claims
- 1. A light stabilized acrylic resin for use in acrylic lacquer or acrylic enamel coatings comprising an acrylic prepolymer having at least first and second different types of reactive functional groups, the first type of reactive functional group being a hydroxyalkyl ester group, the second type of reactive group being one or more of a carboxyl group, an anhydride group, an epoxy group or an isocyanate group, the acrylic resin further comprising a light stabilizer group chemically bound to the acrylic prepolymer wherein said light stabilizer group or groups are bound to at least one of the reactive functional groups on the prepolymer through a hydrazido functional linkage.
- 2. A light stabilized acrylic resin according to claim 1 wherein the light stabilizer group is at least one of a hindered amine light stabilizer, a 2-hydroxybenzophenone, a 2-(2-hydroxyphenyl)-2H-benzotriazole, an aryl salicylate or an oxalanilide.
- 3. A light stabilized acrylic resin according to claim 1 wherein the acrylic prepolymer comprises about 10 to about 80 weight percent unbranched or branched alkyl acrylate, unbranched or branched alkyl methacrylate or thereof, wherein the alkyl group is an unsubstituted or substituted alkyl of 1 to 18 carbons, where the substituents are alkoxy of 1 to 4 carbons, chloro, phenyl or dialkylamino of 2 to 4 carbons; about 15 to about 50 weight percent hydroxyalkyl methacrylate, hydroxyalkyl acrylate or mixtures thereof, wherein the alkyl portion of the hydroxyalkyl acrylate or hydroxyalkyl methacrylate is unsubstituted or substituted alkyl of 2 to 8 carbons, where the substituents are of 1 to 4 carbons, alkoxy of 1 to 4 carbons, chloro or hydroxyl; about 0 to about 50 weight percent styrene; and up to about 10 weight percent of any of maleic anhydride, acrylic acid, methacrylic acid, 5-norbornene-2,3-dicarboxylic anhydride, glycidyl acrylate, glycidyl methacrylate, isocyanatoethyl acrylate or isocyanatoethyl methacrylate, or mixtures thereof.
- 4. A light stabilized acrylic resin according to claim 3 wherein the acrylic prepolymer comprises about 30 weight percent n-butyl acrylate, about 20 weight percent n-butyl methacrylate, about 25 weight percent 2-hydroxyethyl acrylate, about 10 weight percent methyl methacrylate, about 10 weight percent styrene and about 5 weight percent maleic anhydride.
- 5. A light stabilized acrylic resin according to claim 3 wherein the acrylic prepolymer comprises about 40 weight percent n-butyl acrylate; about 25 weight percent n-butyl methacrylate; about 25 weight percent 2-hydroxyethyl acrylate; about 7.5 weight percent styrene; and about 2.5 weight percent maleic anhydride.
- 6. A light stabilized acrylic resin according to claim 3 wherein the acrylic prepolymer comprises about 30 weight percent n-butyl acrylate; about 20 weight percent n-butyl methacrylate; about 25 weight percent 2-hydroxyethyl acrylate; about 10 weight percent methyl methacrylate; about 10 weight percent styrene; and about 5 weight percent methacrylic acid.
- 7. A light stabilized acrylic resin according to claim 3 wherein the acrylic prepolymer comprises about 30 weight percent n-butyl acrylate; about 20 weight percent n-butyl methacrylate; about 25 weight percent 2-hydroxyethyl acrylate; about 10 weight percent methyl methacrylate; about 10 weight percent styrene; and about 5 weight percent of any of glycidyl methacrylate, 5-norbornene-2,3-dicarboxylic anhydride, isocyanatoethyl methacrylate or mixtures thereof.
CROSS-REFERENCE TO RELATED APPLICATION
This is a division of U.S. patent application Ser. No. 275,452, filed Nov. 23, 1988 now U.S. Pat. No. 4,927,891.
US Referenced Citations (13)
Non-Patent Literature Citations (1)
Entry |
M. Dexter et al., "Light and Heat Stabilizers for Coatings," Handbook of Coating Additives, pp. 225-269 (1987). |
Divisions (1)
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Number |
Date |
Country |
Parent |
275452 |
Nov 1988 |
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