Claims
- 1. A polymer composition suitable for use as a hot melt having the formula: ##STR6## wherein R.sub.1 is hydrogen, methyl or ethyl, R.sub.2 is alkyl of from 1 to 6 carbon atoms, --PE-- is selected from the group consisting of polyethers, polyesters and mixtures thereof, x is an integer of from 2 to 50 and R.sub.4 is alkyl, alkene, aryl or alicyclic.
- 2. A polymer composition as in claim 1 suitable for use as a hot melt wherein --PE-- is selected from the group consisting of polyethylene glycol, poly (ethylene glycol adipate), poly (diethylene glycol adipate), poly (ethylene oxide), poly (propylene oxide), poly (tetramethylene oxide), poly (ethylene oxide-propylene oxide), poly (nonamethylene oxide) and poly (caprolactone).
- 3. A polymer composition as in claim 2 suitable for use as a hot melt wherein R.sub.4 is ethylene.
- 4. A method for preparing a polymer composition wherein the polymer consists essentially of a polymer having single terminal unsaturation at one end and a terminal carboxyl group at the other end comprising the steps of:
- (a) providing an organic diisocyanate wherein the organic moiety is free of carbon-carbon reactive unsaturation;
- (b) mixing an amount of an acrylate selected from the group consisting of hydroxy alkyl acrylates, hydroxy alkyl methacrylates and hydroxy alkyl ethyl acrylates sufficient to react with at least one of the isocyanate groups of said diisocyanate and reacting said acrylate and diisocyanate to form a urethane adduct having terminal unsaturation and a terminal isocyanate group;
- (c) mixing a polymer selected from the group consisting of polyesters and polyethers having terminal hydroxyl groups, and mixtures thereof, in an amount sufficient to react with the isocyanate group of said urethane adduct and reacting the same to produce a prepolymer having terminal unsaturation at one end and a terminal hydroxyl group at the other end; and
- (d) mixing said prepolymer with an amount of a cyclic anhydride sufficient to react with the terminal hydroxyl groups of said prepolymer and thereby produce a polymer composition wherein the polymer consists essentially of a polymer having single terminal unsaturation at one end and a terminal carboxyl group at the other end.
- 5. A method for preparing a polymer as in claim 4 wherein said organic diisocyanate is selected from the group consisting of hexamethylene diisocyanate, toluene diisocyanate, xylxylene diisocyanate, diphenylmethane diisocyanate, phenylene diisocyanate, naphthalene diisocyanate and isophorone diisocyanate and said cyclic anhydride is selected from the group consisting of maleic anhydride, citraconic anhydride, itaconic anhydride, phthalic anhydride, tetrahydrophthalic anhydride and hexahydrophthalic anhydride.
- 6. A method for preparing a polymer as in claim 5 wherein said polymer has the structure: ##STR7## wherein R.sub.1 is hydrogen, methyl or ethyl, R.sub.2 is alkyl of from 1 to 6 carbon atoms, R.sub.3 is alkyl, aryl or alkylaryl, (PE) is selected from the group consisting of polyethers, polyesters and mixtures thereof, x is an integer of from 2 to 50 and R.sub.4 is alkyl, alkene, aryl or alicyclic.
- 7. A method for preparing a polymer as in claim 4 wherein an additive having the structure: ##STR8## wherein R.sub.4 is hydrogen, methyl or ethyl, R.sub.5 is alklyl of from 1 to 6 carbon atoms and R.sub.6 is alkyl, alkene, aryl or alicyclic is cosynthesized with said polymer.
- 8. A method for preparing a polymer as in claim 7 wherein said additive is cosynthesized in the step of reacting said prepolymer with a cyclic anhydride by adding to said reaction mixture an acrylate selected from the group consisting of an hydroxy alkyl acrylates, hydroxy alkyl methacrylates and mixtures thereof and a further amount of cyclic anhydride to react with the hydroxyl group of said acrylate.
- 9. A polymer composition which can be melted and applied to a printed circuit board substrate as a melt, cooled to a solid and selectively contacted with actinic light to cure the polymer composition in certain areas wherein the polymer consists essentially of a hot melt having single terminal alkene unsaturation at one end, a terminal carboxyl group at the other end, a molecular weight of about 250 to 10,000 and an acid content of about 0.1 to 4.0 milliequivalents/gram.
Parent Case Info
This application is a division of application Ser. No. 06/225,809, filed Jan. 16, 1981, now U.S. Pat. No. 4,422,914.
US Referenced Citations (16)
Foreign Referenced Citations (7)
Number |
Date |
Country |
1289075 |
Sep 1972 |
GBX |
1489425 |
Oct 1977 |
GBX |
1507808 |
Apr 1978 |
GBX |
1519013 |
Jul 1978 |
GBX |
2002531 |
Feb 1979 |
GBX |
2034492 |
Jun 1980 |
GBX |
2070634 |
Sep 1981 |
GBX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
225809 |
Jan 1981 |
|